源自天然构件的纳米结构单原子催化剂

EES catalysis Pub Date : 2024-01-03 DOI:10.1039/D3EY00265A
Yajing Zhang, Guobin Yang, Jin Wang, Bin Zhao, Yunxiang He and Junling Guo
{"title":"源自天然构件的纳米结构单原子催化剂","authors":"Yajing Zhang, Guobin Yang, Jin Wang, Bin Zhao, Yunxiang He and Junling Guo","doi":"10.1039/D3EY00265A","DOIUrl":null,"url":null,"abstract":"<p >Single-atom catalysts (SACs) exhibit maximized atomic utilization with individual metal atoms anchored on supporting materials, where the pursuit of high performance and low cost presents challenges. In this case, carbon provides structural versatility and customizable properties as a supporting material, which has been extensively studied. Biomass materials have emerged as promising precursors for the preparation of carbon-based SACs due to their renewable nature for sustainability, abundance for low cost, and high carbon content for advanced performance. In this review, representative synthesis strategies and advanced characterization techniques for biomass-derived CS-SACs are summarized, which facilitate the establishment of guidelines for the rational design and fabrication of biomass-derived SACs. In addition, we provide a timely and comprehensive discussion on the use of a broad range of natural biomass for SACs, with insights into the specific carbon nature of biomass resources, including their carbon structures, metal-carbon coordination environment, and center metal species. Furthermore, the application areas of biomass-derived CS-SACs in various catalytic processes are reviewed. Overall, the challenges and future perspectives of using biomass as precursors for SACs are outlined. We hope that this review can offer a valuable overview of the current knowledge, recent progress, and directions of biomass-derived SACs.</p>","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 475-506"},"PeriodicalIF":0.0000,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00265a?page=search","citationCount":"0","resultStr":"{\"title\":\"Nanostructured single-atom catalysts derived from natural building blocks\",\"authors\":\"Yajing Zhang, Guobin Yang, Jin Wang, Bin Zhao, Yunxiang He and Junling Guo\",\"doi\":\"10.1039/D3EY00265A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Single-atom catalysts (SACs) exhibit maximized atomic utilization with individual metal atoms anchored on supporting materials, where the pursuit of high performance and low cost presents challenges. In this case, carbon provides structural versatility and customizable properties as a supporting material, which has been extensively studied. Biomass materials have emerged as promising precursors for the preparation of carbon-based SACs due to their renewable nature for sustainability, abundance for low cost, and high carbon content for advanced performance. In this review, representative synthesis strategies and advanced characterization techniques for biomass-derived CS-SACs are summarized, which facilitate the establishment of guidelines for the rational design and fabrication of biomass-derived SACs. In addition, we provide a timely and comprehensive discussion on the use of a broad range of natural biomass for SACs, with insights into the specific carbon nature of biomass resources, including their carbon structures, metal-carbon coordination environment, and center metal species. Furthermore, the application areas of biomass-derived CS-SACs in various catalytic processes are reviewed. Overall, the challenges and future perspectives of using biomass as precursors for SACs are outlined. We hope that this review can offer a valuable overview of the current knowledge, recent progress, and directions of biomass-derived SACs.</p>\",\"PeriodicalId\":72877,\"journal\":{\"name\":\"EES catalysis\",\"volume\":\" 2\",\"pages\":\" 475-506\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00265a?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"EES catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ey/d3ey00265a\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"EES catalysis","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ey/d3ey00265a","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

单原子催化剂(SAC)通过将单个金属原子锚定在支撑材料上,实现了原子利用率的最大化。碳为支撑材料提供了结构多样性和可定制的特性,并得到了广泛的研究。生物质材料因其可再生性有利于可持续发展、易获取性有利于低成本以及高碳含量有利于实现先进性能,而成为碳基 SAC 的前景广阔的前驱体。在这篇综述中,我们首先总结了生物质衍生 CS-SAC 的代表性合成策略和先进表征技术,这有助于为生物质衍生 SAC 的合理设计制造提供指导。此外,我们还针对生物质资源的碳特性,包括碳结构、金属-碳配位环境和中心金属物种等,及时全面地展示了多种天然生物质在 SACs 中的应用。此外,还回顾了生物质衍生 CS-SAC 在各种催化中的应用领域。总之,我们概述了使用生物质作为 SACs 前体所面临的挑战和未来展望。我们希望本综述能对生物质衍生 SAC 的现有知识、最新进展和发展方向提供有价值的概述。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Nanostructured single-atom catalysts derived from natural building blocks

Nanostructured single-atom catalysts derived from natural building blocks

Single-atom catalysts (SACs) exhibit maximized atomic utilization with individual metal atoms anchored on supporting materials, where the pursuit of high performance and low cost presents challenges. In this case, carbon provides structural versatility and customizable properties as a supporting material, which has been extensively studied. Biomass materials have emerged as promising precursors for the preparation of carbon-based SACs due to their renewable nature for sustainability, abundance for low cost, and high carbon content for advanced performance. In this review, representative synthesis strategies and advanced characterization techniques for biomass-derived CS-SACs are summarized, which facilitate the establishment of guidelines for the rational design and fabrication of biomass-derived SACs. In addition, we provide a timely and comprehensive discussion on the use of a broad range of natural biomass for SACs, with insights into the specific carbon nature of biomass resources, including their carbon structures, metal-carbon coordination environment, and center metal species. Furthermore, the application areas of biomass-derived CS-SACs in various catalytic processes are reviewed. Overall, the challenges and future perspectives of using biomass as precursors for SACs are outlined. We hope that this review can offer a valuable overview of the current knowledge, recent progress, and directions of biomass-derived SACs.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信