Chengyao Deng, Haoxuan Sun, Xinze Wu, Yi Fang, Yifei Guo, Xudong Sun, Zhenkun Li
{"title":"Study of Magnetic Hydrogel 4D Printability and Smart Self-Folding Structure","authors":"Chengyao Deng, Haoxuan Sun, Xinze Wu, Yi Fang, Yifei Guo, Xudong Sun, Zhenkun Li","doi":"10.1002/adem.202401602","DOIUrl":"https://doi.org/10.1002/adem.202401602","url":null,"abstract":"<p>4D printing technology offers the potential to create smart structures that respond to external stimuli. This study focuses on a novel magnetic hydrogel with promising applications in 4D printing, particularly for medical devices such as guidewire robots, drug delivery systems, and vascular stents. Magnetic-responsive hydrogels suitable for 4D printing are scarce, and their complex rheological properties pose challenges for printing. The study investigates these properties and optimizes them through adjustments in ink composition and the application of an external magnetic field, improving printability. Using the direct writing (DLP) method, which allows magnetic programming of individual strands, the study achieves greater flexibility compared to the traditional SLA method. Optimized printing parameters and material ratios produced high-quality single strands, grids, and sheet-like structures, demonstrating responsiveness to varying magnetic fields. Results confirm that DLP can be effectively applied to hydrogel 4D printing, achieving flexible structures with tunable mechanical properties. Additionally, magnetic-responsive, self-folding hydrogel structures were created, with a response speed of 180 ms under a magnetic field. This research establishes a foundation for magnetic hydrogel 4D printing and offers insights for the development of future smart medical devices.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiu Ye, Xiaojin Miao, Xiaojie Shi, Peipei Lu, Meiping Wu
{"title":"Effect of Porosity and Gradient Parameters on Compressive Mechanical Properties of Sheet Gyroid Gradient Porous Structures and Construction of Mechanical Properties Prediction Model","authors":"Xiu Ye, Xiaojin Miao, Xiaojie Shi, Peipei Lu, Meiping Wu","doi":"10.1002/adem.202401426","DOIUrl":"https://doi.org/10.1002/adem.202401426","url":null,"abstract":"<p>A series of uniform porous structures and radial stepwise and radial linear gradient structures are designed based on sheet-gyroid to explore the influence mechanism of porosity and gradient parameters on forming quality and compressive mechanical properties. On this basis, mathematical models for predicting mechanical properties of porous structures based on uniform, discrete gradient, and linear gradient porosity distribution are established. The volume fraction deviation of uniform porous structures increases gradually with the increase of porosity. The relative density of porous structures ranges from 96.78 to 98.79%. The influence of porosity on compressive mechanical properties is investigated, and a prediction model of the equivalent elastic modulus and yield strength of porous structures is constructed based on the generalized G-A model. The elastic modulus of the radial stepwise gradient porous structures is predicted by combining the rule of mixing. The deviation between the predicted results and the experimental results ranges from 0.21 to 2.61%. At the same time, a prediction model of the compressive mechanical properties of the radial linear gradient porous structure is constructed, and it is found that the predicted value is somewhat different from the experimental value, which is related to the synergistic strengthening effect of the gradient porous structure.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abdelrahman Hussein, Byungki Kim, Kim Verbeken, Tom Depover
{"title":"The Effect of Grain Boundary Misorientation on Hydrogen Flux Using a Phase-Field-Based Diffusion and Trapping Model","authors":"Abdelrahman Hussein, Byungki Kim, Kim Verbeken, Tom Depover","doi":"10.1002/adem.202401561","DOIUrl":"https://doi.org/10.1002/adem.202401561","url":null,"abstract":"<p>Understanding hydrogen–grain boundary (GB) interactions is critical to the analysis of hydrogen embrittlement in metals. This work presents a mesoscale fully kinetic model to investigate the effect of GB misorientation on hydrogen diffusion and trapping using phase-field-based representative volume elements (RVEs). The flux equation consists of three terms: a diffusive term and two terms for high and low angle grain boundary (H/LAGB) trapping. Uptake simulations show that decreasing the grain size results in higher hydrogen content due to increasing the GB density. Permeation simulations show that GBs are high-flux paths due to their higher enrichment with hydrogen. Since HAGBs have higher enrichment than LAGBs, due to their higher trap-binding energy, they generally have the highest hydrogen flux. Nevertheless, the flux shows a convoluted behavior as it depends on the local concentration, alignment of GB with external concentration gradient as well as the GB network connectivity. Finally, decreasing the grain size resulted in a larger break-through time and a larger steady-state exit flux.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alexander Lau, Yiran Mao, Rui Shu, Jan W. Coenen, Melina Poll, Christian Linsmeier, Jesus Gonzalez-Julian
{"title":"Combining Chemical Vapor Deposition and Spark Plasma Sintering for the Production of Tungsten Fiber-Reinforced Tungsten (Hybrid – Wf/W)","authors":"Alexander Lau, Yiran Mao, Rui Shu, Jan W. Coenen, Melina Poll, Christian Linsmeier, Jesus Gonzalez-Julian","doi":"10.1002/adem.202470049","DOIUrl":"https://doi.org/10.1002/adem.202470049","url":null,"abstract":"<p><b>Tungsten Fiber-Reinforced Tungsten</b>\u0000 </p><p>In article number 2301929, Alexander Lau and co-workers explore potential synergies between CVD and SPS for the production of W<sub>f</sub>/W. A key finding involves the strategic application of thin CVD-W layers to the ceramic interface. This technique significantly improves the stability of yttria and W-fibers during SPS, substantially reducing the interaction with the surrounding matrix.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 20","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202470049","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Umer Masood Chaudry, Yeonju Noh, Jeong-Rim Lee, Si Mo Yeon, Jongcheon Yoon, Hyub Lee, Tea-Sung Jun
{"title":"Comparative Study of Room and Cryogenic Deformation Behavior of Additive Manufactured Ti–6Al–4V Alloy","authors":"Umer Masood Chaudry, Yeonju Noh, Jeong-Rim Lee, Si Mo Yeon, Jongcheon Yoon, Hyub Lee, Tea-Sung Jun","doi":"10.1002/adem.202470052","DOIUrl":"https://doi.org/10.1002/adem.202470052","url":null,"abstract":"<p><b>Additive Manufacturings</b>\u0000 </p><p>The image illustrates an additively manufactured material undergoing deformation at room and cryogenic temperatures. In article number 2301808, Tea-Sung Jun and co-workers show that at cryogenic temperatures, the material exhibits higher ultimate compression stress due to dislocation strengthening. The diagram shows the material fracturing at room temperature but remaining intact at cryogenic temperatures. In the center, the LPBF process is depicted, printing text indicating the powder composition.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 20","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202470052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dong Yeol Shin, Chaewon Kim, Yoon Jae Moon, Kunsik An, Byeong-Kwon Ju, Kyung-Tae Kang
{"title":"Ultrasonic Punching with Inkjet-Printed Dot Array for Fabrication of Perforated Metal Pattern as Transparent Heater","authors":"Dong Yeol Shin, Chaewon Kim, Yoon Jae Moon, Kunsik An, Byeong-Kwon Ju, Kyung-Tae Kang","doi":"10.1002/adem.202470053","DOIUrl":"https://doi.org/10.1002/adem.202470053","url":null,"abstract":"<p><b>Transparent Heaters</b>\u0000 </p><p>In article number 2400377, Kunsik An, Byeong-Kwon Ju, Kyung-Tae Kang, and co-workers present an aluminum transparent heater with a perforated pattern, manufactured using an inkjet printing process and vacuum deposition. Efficient Joule heating is achieved by optimizing the spacing of holes in the aluminum grid and they exhibit uniform temperature distribution over the device. The fabricated heater demonstrates its efficacy by melting ice within 120 seconds.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 20","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202470053","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Conductive Polyethylene/Polyester Textiles with Temperature-Strengthened Electromagnetic Interference Shielding Efficiency","authors":"Ziyang Jiang, Minghao Li, Chunhui Chen, Fang Zhao, Wenqing Hai, Huiqi Shao, Guangwei Shao, Jinhua Jiang, Nanliang Chen, Siyi Bi","doi":"10.1002/adem.202402088","DOIUrl":"https://doi.org/10.1002/adem.202402088","url":null,"abstract":"<p>\u0000The advancement of electromagnetic interference (EMI) shielding materials provides reliable protection for the communication technology. However, the performance of conventional EMI shielding materials is significantly diminished in high-temperature conditions. Herein, an efficient method is proposed to prepare conductive fabrics with temperature-strengthened EMI shielding performance via chemical plating technique. The as-prepared polyethylene/polyester-metallized fabric (PMF) coated with Ni–W–P alloy exhibits outstanding EMI shielding effectiveness (SE) in X band, which is strengthened from 16 to 59 dB with temperature raising from room temperature to 130 °C. Particularly, the corresponding temperature-strengthened shielding behaviors are investigated through simulations in Computer Simulation Technology. Additionally, PMF presents excellent corrosion resistance (corrosion voltage [<i>E</i><sub>coor</sub>] of −0.324 V and corrosion current [<i>I</i><sub>coor</sub>] of −6.760 A·cm<sup>−2</sup>) and admirable Joule heating performance, reaching maximum temperature of 74 °C at only 1.5 V. Therefore, the as-prepared PMF endows enormous potential in EMI protection under high temperature and harsh environments.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jonas Valloton, Abdoul-Aziz Bogno, Sven C. Vogel, Akankshya Sahoo, Hani Henein
{"title":"Microstructural Study of Containerless Solidification of Al–20wt%Ce Alloy","authors":"Jonas Valloton, Abdoul-Aziz Bogno, Sven C. Vogel, Akankshya Sahoo, Hani Henein","doi":"10.1002/adem.202401634","DOIUrl":"https://doi.org/10.1002/adem.202401634","url":null,"abstract":"<p>\u0000Containerless solidification of Al–20wt%Ce is investigated experimentally using the electromagnetic levitation (EML) and impulse atomization (IA) techniques. In the processed EML samples, small primary undercooling and minimal eutectic undercooling are shown. The microstructure consists of large primary Al<sub>11</sub>Ce<sub>3</sub> dendrites surrounded by an α-Al–Al<sub>11</sub>Ce<sub>3</sub> eutectic. Phase fractions determined by neutron diffraction are similar to the values obtained from a Scheil–Gulliver solidification simulation. Larger IA powders (between 425 and 1000 μm) show a microstructure qualitatively similar to that of EML samples, implying that they follow a similar solidification path. Quantitatively, microstructural features are finer due to the higher cooling rates involved in the solidification process. Atomized particles with a size lower than 425 μm show a strikingly different microstructure, with a very fine eutectic giving way to large intermetallic plates surround by a regular eutectic. Microhardness testing of the structures shows a significant increase in hardness as the sample size decreases, going from 45.8 ± 3.6 HV for the EML sample (lowest cooling rate) to 142.2 ± 12.0 HV for particles in the 106–150 μm range (highest cooling rate).</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202401634","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ricardo Magalhães, Claudia Nunes, Sofia A. Costa Lima, David Navas, Carolina Redondo, Rafael Morales, Miriam Jaafar, Célia Tavares de Sousa
{"title":"Vortex Nanodiscs Functionalization to Overcome Macrophage Recognition for Efficient Theragnosis Applications","authors":"Ricardo Magalhães, Claudia Nunes, Sofia A. Costa Lima, David Navas, Carolina Redondo, Rafael Morales, Miriam Jaafar, Célia Tavares de Sousa","doi":"10.1002/adem.202400369","DOIUrl":"https://doi.org/10.1002/adem.202400369","url":null,"abstract":"<p>Biological barriers prevent nanotherapeutics successful accumulation at target cells, limiting diagnosis and treatment responses. Magnetic nanodiscs with a spin-vortex ground state have shown great promise for magnetomechanical cancer cells annihilation and for neuronal stimulation, requiring very low concentrations for an effective result. However, the biological barriers that these particles encounter upon intravenous administration remain a challenge. Herein, the synthesis of biocompatible multilayered Au/Fe/Au nanodiscs with a spin-vortex ground state and their inert surface modification is reported. Two different surface modifications with two distinct polyethylene glycol (PEG) molecules are performed, which successfully reduce macrophage uptake, while maintaining the nanodiscs’ biocompatibility. By effectively preventing nanodisc uptake, innovative design features can be rationally incorporated to create a new generation of specific nanotherapeutics by modifying the PEG surface with specific targeting molecules.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 24","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202400369","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Le Fu, Xin Peng, Peng Zhang, Dangguo Yang, Yang Liu, Guangyuan Liu
{"title":"Additively Manufactured Stainless Steel Wind Tunnel Model Support Featuring Honeycomb Structures for Vibration Attenuation","authors":"Le Fu, Xin Peng, Peng Zhang, Dangguo Yang, Yang Liu, Guangyuan Liu","doi":"10.1002/adem.202401866","DOIUrl":"https://doi.org/10.1002/adem.202401866","url":null,"abstract":"<p>Wind tunnel model support (WTMS) is an indispensable component of wind tunnel testing. However, the presence of vibrations within the model-support system can compromise the accuracy of data and give rise to significant safety hazards. In this study, an approach for vibration attenuation by incorporating honeycomb structures into the design of the WTMS is proposed. To this end, stainless steel WTMSs with integrated honeycomb structures are fabricated by selective laser melting (SLM). Results showed that stainless steels prepared under optimized SLM processing parameters exhibit high crystallinity and consist of single-phase Fe–Cr–Ni alloy. The stainless steels exhibited robust mechanical properties, including a tensile strength of ≈1 GPa, an elongation of ≈8%, and a compressive strength of ≈1.4 GPa. These exceptional mechanical properties can be attributed to the formation of a cellular structure and tangled dislocations. The first-order and the third-order resonant response of WTMS honeycomb structures can be effectively reduced. The vibration reduction mechanism can be attributed to the occurrence of local resonance when the natural frequency of the internal periodic unit of the WTMS closely matched the vibration frequency of the model. The utilization of honeycomb structures holds significant potential for achieving vibration attenuation in WTMS.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"26 22","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}