Advanced Engineering Materials最新文献

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Low Loss Chip-to-Chip Couplers for High-Density Co-Packaged Optics
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-18 DOI: 10.1002/adem.202570012
Drew Weninger, Samuel Serna, Luigi Ranno, Lionel Kimerling, Anuradha Agarwal
{"title":"Low Loss Chip-to-Chip Couplers for High-Density Co-Packaged Optics","authors":"Drew Weninger,&nbsp;Samuel Serna,&nbsp;Luigi Ranno,&nbsp;Lionel Kimerling,&nbsp;Anuradha Agarwal","doi":"10.1002/adem.202570012","DOIUrl":"https://doi.org/10.1002/adem.202570012","url":null,"abstract":"<p><b>Co-Packaged Optics</b>\u0000 </p><p>In article number 2402095, Drew Weninger, Samuel Serna, and co-workers present a co-packaged optics system with an electrical chip (black, center) surrounded by 8 silicon photonic chips. Chips are bonded using an automated pick-and-place tool, shown placing the final chip into position. The automation is enabled by a novel optical chip-to-chip coupler (green callout).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 4","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202570012","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Skin-Inspired, High-Resolution, Intelligent Aerosol Jet 3D-Printed Palmtop with Multisensory Integration
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-18 DOI: 10.1002/adem.202401988
Anoop Kumar Sinha, Guo Liang Goh, Wei Qi Jaw, Guanbo Chen, Laya Pothunuri, Wai Yee Yeong, Yiyu Cai
{"title":"Skin-Inspired, High-Resolution, Intelligent Aerosol Jet 3D-Printed Palmtop with Multisensory Integration","authors":"Anoop Kumar Sinha,&nbsp;Guo Liang Goh,&nbsp;Wei Qi Jaw,&nbsp;Guanbo Chen,&nbsp;Laya Pothunuri,&nbsp;Wai Yee Yeong,&nbsp;Yiyu Cai","doi":"10.1002/adem.202401988","DOIUrl":"https://doi.org/10.1002/adem.202401988","url":null,"abstract":"<p>Electronic skin (E-skin) with multimodal sensing demonstrates significant capability in acquiring object characteristics grasped by robotic artifacts. As the spatial resolution of the sensing nodes increases on the E-skin, it introduces challenges related to compact design and wiring. Herein, the design, fabrication, and characterization of an ultrathin, ultralow cost, highly compact, and flexible multimodal sensing hierarchical palmtop with 390 piezoresistive tactile pressure sensing nodes and 5 capacitive hydration sensing nodes are presented. Each tactile pressure sensing node consists of two 3D-printed Ag nanoparticle ink electrodes sandwiching a piezoresistive film. The hydration sensing nodes in contrast are capacitive type with 3D-printed Archimedean spiral Ag nanoparticle ink electrodes. Upon characterization, the pressure sensors exhibit a sensitivity of 1.188 kPa<sup>−1</sup> and an impressive sensing range from 10 to 600 kPa. Meanwhile, the hydration sensing nodes display a sensitivity of 3.124 per percentage increase in hydration level, with a hydration sensing range of 25%–75%. Subsequently, machine learning is used to discriminate the region touched on the palmtop, object shapes, and hydration levels. Given its multifaceted capabilities, this palmtop is poised to find potential applications in various robotic contexts such as robotic hands, rehabilitation hand exoskeletons, and in the sphere of augmented reality.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation on the Microstructural Evolution and Mechanical Properties of Ti/Al/Ti Clad Sheets via Cryorolling and Annealing
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-15 DOI: 10.1002/adem.202402211
Lingling Song, Xinyao Peng, Haitao Gao, Zhengyu Wang, Huijie Cui, Ahmed Fouly, Charlie Kong, Hailiang Yu
{"title":"Investigation on the Microstructural Evolution and Mechanical Properties of Ti/Al/Ti Clad Sheets via Cryorolling and Annealing","authors":"Lingling Song,&nbsp;Xinyao Peng,&nbsp;Haitao Gao,&nbsp;Zhengyu Wang,&nbsp;Huijie Cui,&nbsp;Ahmed Fouly,&nbsp;Charlie Kong,&nbsp;Hailiang Yu","doi":"10.1002/adem.202402211","DOIUrl":"https://doi.org/10.1002/adem.202402211","url":null,"abstract":"<p>The Ti/Al/Ti clad sheets were fabricated through hot rolling (HR) and cryorolling (CR), followed by annealing treatment. The influences of cryogenic deformation and different annealing temperatures on the microstructure and mechanical properties of clad sheets were systematically investigated. Results showed that the CR clad sheet exhibited the highest tensile strength of 507 MPa. CR can fabricate the clad sheet with good interfacial bonding quality, devoid of defects such as pores and cracks. Moreover, CR introduced significant fine-grain strengthening and dislocation strengthening effects. After annealing, the Ti and Al layers underwent varying degrees of recovery and recrystallization, thereby improving the elongation of clad sheets, and attained optimal elongation at 773 K (28.3%). During annealing, the element diffusion layer thickness at the interface gradually increased with temperature, along with the enhancement of the metallurgical bonding effect, resulting in improved interfacial bonding strength. However, the mechanical properties of the clad sheet decreased at 823 K because of the production of TiAl<sub>3</sub> intermetallic compounds. The rolling and heat treatment processes utilized in this study provide valuable insights into the production of high-performance Ti/Al/Ti clad sheets.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the Versatility of Photocrosslinkable Silk Fibroin Using an Eco-Friendly Solvent
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-15 DOI: 10.1002/adem.202402401
Anne Katherine Brooks, Vamsi K. Yadavalli
{"title":"Enhancing the Versatility of Photocrosslinkable Silk Fibroin Using an Eco-Friendly Solvent","authors":"Anne Katherine Brooks,&nbsp;Vamsi K. Yadavalli","doi":"10.1002/adem.202402401","DOIUrl":"https://doi.org/10.1002/adem.202402401","url":null,"abstract":"<p>Silk fibroin (SF), known for its biocompatibility and versatility, has been widely studied in tissue engineering and biomedical devices. The modification of SF with photoreactive groups has been used to create novel biomaterials that undergo a liquid-to-solid transition upon exposure to light, enabling precise control over structure formation, pore geometry, and degradation. This advancement of PF has been shown for the biofabrication of hydrogels, 3D scaffolds, and micro-patterned surfaces suitable for biomedical applications, including tissue scaffolds and bioelectronics. Herein, further improvement using a water-based ternary solvent of calcium chloride-ethanol-water (Ajisawa reagent (AR)) is presented, to dissolve PF, offering a sustainable alternative to previously used organic solvents. PF in AR is shown to be compatible with various light-based manufacturing techniques including soft lithography, photolithography, and 3D printing, enabling the fabrication of multiscale structures with high fidelity. The gels formed demonstrate excellent cytocompatibility, supporting cell adhesion and growth without additional coatings, making them ideal for regenerative medicine. The integration of conductive polymers, such as PEDOT:PSS as a 3D printable conducting gel opens possibilities for bioelectronics. The research represents a significant step forward in employing the versatile PF as a sustainable, high-performance photoresin biomaterial for diverse applications.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202402401","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Energy-Storage Density and Resistive Switching Behavior in Lead-Free Ba0.7Sr0.3TiO3/Ba0.6Sr0.4TiO3 Multilayer Thin Films
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-15 DOI: 10.1002/adem.202402610
Kaushiga Chandrasekaran, Kesavan Jawahar, Salla Gangi Reddy, Venkateswarlu Annapureddy
{"title":"Enhanced Energy-Storage Density and Resistive Switching Behavior in Lead-Free Ba0.7Sr0.3TiO3/Ba0.6Sr0.4TiO3 Multilayer Thin Films","authors":"Kaushiga Chandrasekaran,&nbsp;Kesavan Jawahar,&nbsp;Salla Gangi Reddy,&nbsp;Venkateswarlu Annapureddy","doi":"10.1002/adem.202402610","DOIUrl":"https://doi.org/10.1002/adem.202402610","url":null,"abstract":"<p>\u0000Ferroelectric thin-film capacitors are of interest for energy storage due to their high charge/discharge rates, essential for compact electronics. As alternatives to Pb-based materials, environmentally friendly barium titanate–based systems show great energy-storage potential. Herein, Ba<sub>0.7</sub>Sr<sub>0.3</sub>TiO<sub>3</sub> (BST7)/Ba<sub>0.6</sub>Sr<sub>0.4</sub>TiO<sub>3</sub> (BST6) thin films altering the layer structure are designed and constructed on boron-doped Si &lt;100&gt; substrates by solution-based spin-coating method. The structural and electric properties of trilayer thin films are investigated, and the results are compared with those of monolayer thin films such as BST7 and BST6. An enhanced polarization and improved breakdown strength are simultaneously achieved in the BST767 (Ba<sub>0.7</sub>Sr<sub>0.3</sub>TiO<sub>3</sub>/Ba<sub>0.6</sub>Sr<sub>0.4</sub>TiO<sub>3</sub>/Ba<sub>0.7</sub>Sr<sub>0.3</sub>TiO<sub>3</sub>) trilayer thin film caused by the interfacial effect, which leads to an ultrahigh energy-storage density (<i>W</i><sub>rec</sub>) of ≈56.9 J cm<sup>−3</sup> accompanying an efficiency (<i>η</i>) of ≈72%. The BST767 trilayer capacitor processes a fast charging/discharging speed and a giant power density of 0.72 MW cm<sup>−3</sup>. These thin-film capacitors exhibit a relatively high resistive switching behavior with an improved on–off ratio compared to ceramic capacitors. The mechanisms underlying current conduction are thoroughly analyzed. Such performance makes them suitable for future portable electronics, hybrid vehicles, and aerospace applications.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical Properties and Failure Mechanisms of Carbon Fiber/Resin Composites with Hot Press, Single-Vacuum-Bag, and Double-Vacuum-Bag Processes
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-14 DOI: 10.1002/adem.202402136
Liangliang Ren, Deyuan Zhang
{"title":"Mechanical Properties and Failure Mechanisms of Carbon Fiber/Resin Composites with Hot Press, Single-Vacuum-Bag, and Double-Vacuum-Bag Processes","authors":"Liangliang Ren,&nbsp;Deyuan Zhang","doi":"10.1002/adem.202402136","DOIUrl":"https://doi.org/10.1002/adem.202402136","url":null,"abstract":"<p>In order to compare the mechanical properties of materials, acquire the crack propagation law and failure mode under different processes of carbon fiber/resin composites, the hot press process, double-vacuum-bag (DVB) process, and single-vacuum-bag (SVB) process were used to manufacture laminates in this paper, the void content and void morphology of the composite materials were observed by ultrasonic C-scan, optical microscope, and scanning electron microscope. Four different types of mechanical tests were carried out: tensile, compressive, bending, and short-beam shear tests, and the fracture morphology of the specimens was observed and analyzed. The failure mechanisms of the materials under different processes were explored based on the stress analysis. It is found that in the materials manufactured by SVB process, voids can induce stress concentration effect, reduce the stress area and interlayer bonding force, and cracks are more prone to initiate and propagate around voids. These are all factors contributing to the reduction of bearing capacity and accelerating the failure process in the material. The void contents of laminates manufactured by DVB process and hot press process are extremely low, it is difficult for cracks to propagate within the material, and the composites can maintain excellent mechanical properties.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Radial Deposition for Mechanical Bonding of Dissimilar Metals in Wire Arc Additive Manufacturing
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-14 DOI: 10.1002/adem.202401978
Lile Squires, Michael B. Myers, Amit Bandyopadhyay
{"title":"Radial Deposition for Mechanical Bonding of Dissimilar Metals in Wire Arc Additive Manufacturing","authors":"Lile Squires,&nbsp;Michael B. Myers,&nbsp;Amit Bandyopadhyay","doi":"10.1002/adem.202401978","DOIUrl":"https://doi.org/10.1002/adem.202401978","url":null,"abstract":"<p>High energy input creates enormous challenges for direct fusion bonding between dissimilar metals in wire-arc directed energy deposition (DED). Vast differences in material properties, such as those between aluminum and stainless steel, cause significant compatibility issues. Their combination for higher performance is a compelling goal, but attempts are usually limited to nonadditive mechanical fastening. Wire-based additive for direct fusion has never been attempted, and only powder-based additive metal fusion manufacturing (AM) has shown any promise. Concentric radial deposition patterns are used in a wire-arc DED system to produce a layer-by-layer in situ bimetallic coupling between AA5356 and SS308L to address this. The additively generated mechanical bond is held together by residual pressure, created by different thermal expansion coefficients between the concentric material bands during cooling. This produces a purely additive yet viable mechanical joint with minimal metallurgical bonding. Destructive testing defines the integrity of the additively coupled unit, with the radial overlap sustaining 732.96 Nm in torsion, 34.17 kN in tension, and a maximum of 475 MPa in compression. Fracture modes confirm the importance of concentric residual loads in creating the mechanically viable joint. Interfacial characterization shows a 300× reduction in crack width for concentrically constrained interfaces with narrowed diffusion zones.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling and Simulation of Dynamic Recrystallization of Incoloy825 High-Temperature Alloy during Hot Deformation Based on Cellular Automata
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-14 DOI: 10.1002/adem.202402387
Guanghui Zhao, Min Li, Lifei Liu, Yugui Li, Huaying Li, Juan Li
{"title":"Modeling and Simulation of Dynamic Recrystallization of Incoloy825 High-Temperature Alloy during Hot Deformation Based on Cellular Automata","authors":"Guanghui Zhao,&nbsp;Min Li,&nbsp;Lifei Liu,&nbsp;Yugui Li,&nbsp;Huaying Li,&nbsp;Juan Li","doi":"10.1002/adem.202402387","DOIUrl":"https://doi.org/10.1002/adem.202402387","url":null,"abstract":"<p>Thermal compression experiments are carried out on Incoloy825 high-temperature alloy to study its thermal deformation behavior under different strain rates (0.01–10 s<sup>−1</sup>) and deformation temperatures (1000–1150 °C). The microstructure of Incoloy825 high-temperature alloy under different deformation conditions is characterized using electron backscatter diffraction. Modified Laasraoui–Jonas (L–J) dislocation density model and thermal processing map at peak stress for Incoloy825 alloy are established. A cellular automaton (CA) is coupled to the DEFORM-3D software to simulate the microstructure evolution during hot deformation, and numerical simulation of hot extrusion molding of tubes of Incoloy825 alloy is carried out based on the optimal thermal processing region determined by the thermal processing map. The results show that the average absolute relative error (AARE) between the simulated predicted and experimentally obtained values of dynamic recrystallization (DRX) volume fraction is 10.87%, indicating that the developed CA model can accurately predict the DRX behavior of Incoloy825 alloy. The best hot extrusion parameters of the Incoloy825 alloy tube are obtained through hot extrusion simulation: the initial temperature is 1150 °C, and the extrusion speed is 120–160 mm s<sup>−1</sup>.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and Research of an Aircraft Ice Control System Based on Multilayer Functional Film
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-13 DOI: 10.1002/adem.202402352
Jie Pang, Wenli Qiu, Qingan Meng, Junjie Zhou, Xiaopeng Wang, Yue Yue
{"title":"Design and Research of an Aircraft Ice Control System Based on Multilayer Functional Film","authors":"Jie Pang,&nbsp;Wenli Qiu,&nbsp;Qingan Meng,&nbsp;Junjie Zhou,&nbsp;Xiaopeng Wang,&nbsp;Yue Yue","doi":"10.1002/adem.202402352","DOIUrl":"https://doi.org/10.1002/adem.202402352","url":null,"abstract":"<p>Aiming to address the challenges of high energy consumption and low efficiency associated with current aircraft deicing or anti-icing systems, this study presents an innovative ice control system based on a multilayer functional film. The multilayer functional film utilizes carbon nanotube film as the electrothermal substrate, incorporates cobalt (Co) for its photothermal properties and silicon dioxide (SiO<sub>2</sub>) for enhancing surface roughness and light trapping, thereby constructing a photothermal superhydrophobic surface, referred to as PCoSi-PCNT, and integrates capacitive icing sensors, temperature sensors, and humidity sensors. The deicing or anti-icing controller processes data to detect icing status and regulate the electrically heated deicing or anti-icing system. The results demonstrate that the photothermal superhydrophobicity of the multilayer functional film surface significantly delays icing. Notably, a 30 μL droplet was completely iced for 563 s at an ambient temperature of −15 °C, while the surface temperature rises to 67.3 °C at a light intensity of 100 mW cm<sup>−2</sup>. The deicing or anti-icing controller accurately detects changes in capacitance during the icing process of surface water droplets and activates electric heating in real time. With the continuous operation of the electric heating system, the surface temperature is consistently maintained between 42 and 55 °C. This system achieves efficient deicing or anti-icing with minimal energy consumption, offering a promising solution for aircraft deicing or anti-icing applications.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PVDF-Nanofibers/PET-Nonwoven Sandwich Coated with Fine γ-AlO(OH): A Bilayer Hybrid Composite Separator for Lithium-Ion Batteries
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-02-13 DOI: 10.1002/adem.202402222
Fanghua Liang, Hayato Ezaki, Jeongjin Park, Kei Watanabe, Kenji Hyodo, Gopiraman Mayakrishnan, Wei Zhang, Ick Soo Kim
{"title":"PVDF-Nanofibers/PET-Nonwoven Sandwich Coated with Fine γ-AlO(OH): A Bilayer Hybrid Composite Separator for Lithium-Ion Batteries","authors":"Fanghua Liang,&nbsp;Hayato Ezaki,&nbsp;Jeongjin Park,&nbsp;Kei Watanabe,&nbsp;Kenji Hyodo,&nbsp;Gopiraman Mayakrishnan,&nbsp;Wei Zhang,&nbsp;Ick Soo Kim","doi":"10.1002/adem.202402222","DOIUrl":"https://doi.org/10.1002/adem.202402222","url":null,"abstract":"<p>Nanofiber-based separators fabricated via electrospinning for lithium-ion batteries have garnered widespread attention due to their attractive porous characteristics, improved thermal stability, and high electrolyte wettability. A double-layer PVDF/PET/γ-AlO(OH) hybrid composite membrane is prepared by combining simple electrospinning techniques with drop casting onto thermally pressed PET/PVDF surfaces, resulting in a finely dispersed and uniform boehmite (γ-AlO(OH)) coating. The 3D interconnected structure of the PVDF/PET/γ-AlO(OH) hybrid composite membrane exhibits excellent mechanical properties and demonstrates outstanding electrolyte absorption, with supervisor electrolyte uptake of 582.5% and remarkable ionic conductivity of 1.2 × 10<sup>−2</sup> S cm<sup>−1</sup>. Even after heating at 130 °C for 1 h, the membrane maintains good thermal stability. Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub>/LiNiMnCoO<sub>2</sub> batteries employing the double-layer PVDF/PET/γ-AlO(OH) hybrid composite membrane exhibit exceptional discharge capacity (105.7 mAh g<sup>−1</sup> at 0.2 C) and outstanding capacity retention (100%). The battery performance results clearly demonstrate the suitability of the double-layer PVDF/PET/γ-AlO(OH) hybrid composite membrane as a safe separator for lithium-ion batteries.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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