Petroleum Chemistry最新文献_第5页

Behavior of Nanocatalysts in Fischer–Tropsch Synthesis in Various Types of Three-Phase Slurry Reactors 纳米催化剂在不同类型三相淤浆反应器中进行费托合成的行为

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-07-08 DOI: 10.1134/S096554412403006X

A. E. Kuz’min, O. S. Dementeva, M. V. Kulikova, Ya. V. Morozova, S. A. Svidersky, A. L. Maximov

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Preparation of the Au/TiO2 Catalyst for the Oxidation of 2-Phenylethyl Alcohol using a Cacumen Platycladi Extract as a Reducing Agent 使用 Cacumen Platycladi 提取物作为还原剂制备氧化 2-苯基乙醇的 Au/TiO2 催化剂

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-27 DOI: 10.1134/S0965544124030125

Jiali Xiao, Longsheng Zhou, Dangqin Jin, Hui Zhou, Dongfan Liu, Bingyun Zheng

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Complex-Oxide Catalysts in Cracking of Propane 复合氧化物催化剂在丙烷裂解中的应用

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Petroleum Chemistry Pub Date : 2024-06-21 DOI: 10.1134/S0965544124030083

A. V. Kurochkin, K. A. Seromlyanova, M. M. Selivanova, D. N. Malyshev, A. D. Tereshkina, N. N. Lobanov, E. B. Markova, A. G. Cherednichenko

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Insight into the Structure of Asphaltene after Its Disaggregation by Chemical Processing 透视沥青烯经化学处理分解后的结构

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-21 DOI: 10.1134/S0965544124030113

Shengchao Wei, Dan Lu, Zhilin Yao, Lijun Zhu, Changlong Yin, Daohong Xia

{"title":"Insight into the Structure of Asphaltene after Its Disaggregation by Chemical Processing","authors":"Shengchao Wei, Dan Lu, Zhilin Yao, Lijun Zhu, Changlong Yin, Daohong Xia","doi":"10.1134/S0965544124030113","DOIUrl":"10.1134/S0965544124030113","url":null,"abstract":"In order to understand the structure of asphaltene after its disaggregating by chemical processing, a comprehensive study for exploring the structural changes of asphaltene after acylation as a case of chemical processing was conducted. Functional groups, crystal parameters, hydrogen types, and micromorphology of acylated asphaltenes were analyzed by FT-IR, XPS, XRD, 1H NMR, SEM and IFM (inverted fluorescence microscope) methods. Additionally, fluorescence spectroscopy methods were performed to analyze the effect of acylation on the aggregation ability of asphaltene. Experimental results indicated that the C=O double bond was enhanced and the content of O–C=O was increased on the surface of acylated asphaltene. The number of stacking layers and the aggregate size of asphaltene decreased obviously after acylation. Fluorescence spectral analysis showed that the critical aggregation concentration of acylated asphaltenes increased compared to the raw asphaltenes. These results indicate that acylation reaction can disaggregate asphaltenes and hinder their re-aggregation in a solution. The disaggregation effect of asphaltene acylation can be attributed to the weakening of a hydrogen bonding and enhancement of a steric hindrance in the asphaltene molecule. This study provided the further understanding of the structural changes of asphaltene after the chemical treatment.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 3","pages":"346 - 356"},"PeriodicalIF":1.3,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Plasma-Assisted Carbon Dioxide Methane Reforming: Relationships of the Formation of Oxygenates on Adding a Catalyst (a Review) 等离子体辅助二氧化碳甲烷转化：等离子体辅助二氧化碳甲烷转化：添加催化剂时生成氧酸盐的关系（综述）

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-21 DOI: 10.1134/S0965544124030034

O. V. Golubev, P. S. Il’chuk, A. L. Maximov

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Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins 多孔芳香族框架支撑的钼催化剂在烯烃环氧化中的应用

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-14 DOI: 10.1134/S0965544124020208

V. A. Makhova, L. A. Kulikov, A. V. Akopyan, E. A. Karakhanov

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Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks 多孔芳香族框架支撑的钌催化剂上的糠醛加氢反应

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-14 DOI: 10.1134/S0965544124020191

L. A. Kulikov, D. A. Makeeva, A. M. Dubiniak, M. V. Terenina, Yu. S. Kardasheva, S. V. Egazar’yants, A. F. Bikbaeva, A. L. Maximov, E. A. Karakhanov

{"title":"Hydrogenation of Furfural over Ruthenium Catalysts Supported on Porous Aromatic Frameworks","authors":"L. A. Kulikov, D. A. Makeeva, A. M. Dubiniak, M. V. Terenina, Yu. S. Kardasheva, S. V. Egazar’yants, A. F. Bikbaeva, A. L. Maximov, E. A. Karakhanov","doi":"10.1134/S0965544124020191","DOIUrl":"10.1134/S0965544124020191","url":null,"abstract":"The paper describes an investigation into hydrogenation of furfural over ruthenium catalysts supported on porous aromatic frameworks. The supports were designated as PAF-30-SO3H, PAF-30-NH2, and PAF-30. The synthesized catalysts were tested in furfural hydrogenation carried out in water and in tetrahydrofuran (with a concentration of 10 wt %) at 90–250°C and a hydrogen pressure of 3 MPa. Although the highest furfural conversion (96%) was achieved in the case of its hydrogenation in water at 250°C over Ru-PAF-30, these conditions did not favor product selectivity. The reaction products mainly consisted of furfuryl alcohol, tetrahydrofurfuryl alcohol, and cyclopentanone. The highest yield of cyclopentanone, 71% (with 80% conversion and 89% selectivity) was observed in furfural hydrogenation over Ru-PAF-30 at 200°C, whereas the conditions optimal for selective hydrogenation of furfural into furfuryl alcohol were found to include either tetrahydrofuran as a solvent or water as a solvent and low temperatures (90–150°C).","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 4","pages":"471 - 479"},"PeriodicalIF":1.3,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141340650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Influence of the Binder Type on the Activity of Pt-Containing Catalysts Based on MFI Zeolite in Isomerization of the Aromatic С8 Fraction 粘合剂类型对基于 MFI 沸石的含铂催化剂在芳香族 С8 馏分异构化中的活性的影响

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-14 DOI: 10.1134/S0965544124030058

G. A. Kireev, N. R. Demikhova, L. D. Zatsepina, E. M. Smirnova, Yu. F. Gushchina, Ya. A. Chudakov, E. V. Ivanov, A. P. Glotov

{"title":"Influence of the Binder Type on the Activity of Pt-Containing Catalysts Based on MFI Zeolite in Isomerization of the Aromatic С8 Fraction","authors":"G. A. Kireev, N. R. Demikhova, L. D. Zatsepina, E. M. Smirnova, Yu. F. Gushchina, Ya. A. Chudakov, E. V. Ivanov, A. P. Glotov","doi":"10.1134/S0965544124030058","DOIUrl":"10.1134/S0965544124030058","url":null,"abstract":"One of the steps in scaling the technology for the synthesis of zeolite-containing catalysts from the laboratory to commercial level is support forming. In this study, halloysite nanotubes and aluminum oxide were used as binders for preparing a support based on MFI (ZSM-5) zeolite. The Pt catalysts (Pt/ZSM-5/Al2O3 and Pt/ZSM-5/Hall) were tested in isomerization of the aromatic C8 fraction. The forming of supports influenced not only mechanical but also physicochemical properties of the catalysts. On introducing binders into the catalytic system, the fraction of mesopores in the total pore volume of the supports increased, the acidity of the samples decreased, and the ratio of the amounts of the weak and strong acid sites changed. The use of aluminum oxide and halloysite as binders leads to different pathways of the transformation of the aromatic feedstock. The main side reactions observed in the presence of Pt/ZSM-5/Al2O3 and Pt/ZSM-5/Hall catalysts are hydrocracking of alkylaromatic hydrocarbons and their transalkylation/disproportionation, respectively. The best results were obtained at 380°C and feed space velocity of 6 h–1 with Pt/ZSM-5/Hall: p-/о-xylene ratio 1.05, loss of xylenes 4.31%, and ethylbenzene conversion 34%.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 2","pages":"278 - 289"},"PeriodicalIF":1.3,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141341353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Statistical Analysis of Ethane and Propane Production from Greenhouse Gases in a DBD Plasma Reactor Using a Response Surface Methodology 利用响应面方法对 DBD 等离子体反应器中温室气体生产乙烷和丙烷的情况进行统计分析

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-14 DOI: 10.1134/S0965544124030101

Mohammad Hossein Afzali, Alireza Azimi, Masoumeh Mirzaei, Amir Hossein Shahbazi Kootenaei

{"title":"Statistical Analysis of Ethane and Propane Production from Greenhouse Gases in a DBD Plasma Reactor Using a Response Surface Methodology","authors":"Mohammad Hossein Afzali, Alireza Azimi, Masoumeh Mirzaei, Amir Hossein Shahbazi Kootenaei","doi":"10.1134/S0965544124030101","DOIUrl":"10.1134/S0965544124030101","url":null,"abstract":"In this study, a non-catalytic process of oxidative coupling of methane (CH4) and its conversion to ethane and propane in the presence of carbon dioxide (CO2) was statistically studied. Fifteen experiments were conducted under different conditions, including determination of the CH4/CO2 ratio (1.5‒3), the total feed flow rate (22.5‒80 mL/min), argon flow rate (50‒100 mL/min), and voltage (6‒11 kV) under atmospheric conditions. The statistical analysis of the experiments showed that the model applied for evaluating the percentage of CH4 conversion, Selective Internal Energy (SIE), and the reactor power was valid, and there was a good match between the experimental and predicted results. Based on the results, as the CH4/CO2 ratio increased, the selectivity of ethane and propane as well as the energy efficiency (EE) of a system increased, while CH4 conversion decreased. In addition, increase in the Ar flow rate caused an increase in the CH4 conversion and selectivity of ethane and propane. Moreover, CH4 conversion, power, ethane selectivity and SIE increased as the voltage increased, though EE and propane selectivity decreased. Finally, the total feed flow rate caused increase in the CH4 conversion and ethane selectivity, whereas propane selectivity and EE decreased.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 3","pages":"421 - 434"},"PeriodicalIF":1.3,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141338373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Interfacial Shear Rheology of the Waxy Oil-Water Interfacial Layer Construction by Span80/60/65: Influence of Hydrophobic Chain Structure Span80/60/65 构建的蜡状油水界面层的界面剪切流变学：疏水链结构的影响

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-06-06 DOI: 10.1134/S0965544124020087

Chuanshuo Wang, Xiaofang Lv, Bingcai Sun, Qianli Ma, Yang Liu, Shidong Zhou, Jimiao Duan

{"title":"Interfacial Shear Rheology of the Waxy Oil-Water Interfacial Layer Construction by Span80/60/65: Influence of Hydrophobic Chain Structure","authors":"Chuanshuo Wang, Xiaofang Lv, Bingcai Sun, Qianli Ma, Yang Liu, Shidong Zhou, Jimiao Duan","doi":"10.1134/S0965544124020087","DOIUrl":"10.1134/S0965544124020087","url":null,"abstract":"The waxy oil-water interface has become a topic issue in the field of a two-phase oil-water pipe flow. Although some progress has been achieved in the understanding of interfacial rheological properties of the water-in-oil emulsion (W/O), the effect of surfactants (the main constituents of petroleum crude oil) still remains unclear. To test whether the structure of hydrophobic chains of surfactants influences the waxy oil-water interface, we monitored interfacial rheological parameters under different nonionic surfactants (Span80/60/65) using a DWR interfacial shear rheometer. Among these surfactants, the oil-water interface of Span65 characterized by multi-hydrophobic chains had the largest interfacial viscosity and critical storage modulus. A weak strain overshoot interface of Span65 suggested that sorbitan tristearate molecules provided a dominant contribution to the interfacial rheological properties of the waxy oil-water interface with much fewer effects of the interaction between wax molecules and surfactants. However, Span60/80 with a single hydrophobic chain was coupled to wax molecules and reshaped the waxy oil-water interface structure, which replaced the original wax crystal position (the interfacial viscosity and critical storage modulus decrease) and yielded an interfacial structure (the critical strain increase). The wax-surfactant interactions of Span60/80 with different hydrophobic chain saturation were discussed. These interfacial properties are of practical importance for the technological operations in oil production.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 3","pages":"357 - 365"},"PeriodicalIF":1.3,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0