Petroleum Chemistry最新文献_第6页

Hydrogenation of Carbon Oxides in Slurry Reactor over Catalytic Nanodispersions 碳氧化物在催化纳米分散体上的浆状反应器加氢

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-04-09 DOI: 10.1134/S0965544125600481

Ya. V. Morozova, S. A. Svidersky, O. S. Dementeva, M. V. Kulikova, A. L. Maximov

引用次数: 0

Aromatization of Isophorone to 3,5-Xylenol over Cation-Exchanged Granulated Hierarchical Yh Zeolites 异佛尔酮在阳离子交换的粒状分级Yh沸石上芳构化成3,5-二甲酚

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-04-03 DOI: 10.1134/S0965544125600572

V. Yu. Kirsanov, L. F. Korzhova, A. N. Khazipova, V. R. Bikbaeva, D. V. Serebrennikov, S. G. Karchevsky, B. I. Kutepov, N. G. Grigor’eva

{"title":"Aromatization of Isophorone to 3,5-Xylenol over Cation-Exchanged Granulated Hierarchical Yh Zeolites","authors":"V. Yu. Kirsanov, L. F. Korzhova, A. N. Khazipova, V. R. Bikbaeva, D. V. Serebrennikov, S. G. Karchevsky, B. I. Kutepov, N. G. Grigor’eva","doi":"10.1134/S0965544125600572","DOIUrl":"10.1134/S0965544125600572","url":null,"abstract":"A series of catalysts were prepared from a granulated hierarchical (micro–meso–macroporous) NaYh zeolite: NaYh, H-NaYh, H-Yh, Li-NaYh, K-NaYh, Ca-NaYh, Mg-NaYh, and La-NaYh. Their physicochemical properties were characterized, and their catalytic activity and product selectivity were investigated in the aromatization of isophorone. The highest performance in the synthesis of 3,5-dimethylphenol was achieved in the presence of K-NaYh, the catalyst distinguished both by the highest basicity among the tested samples and by low concentrations of weak Brønsted acid sites and Lewis acid sites. This sample exhibited a 3,5-dimethylphenol selectivity of 78.6% at an isophorone conversion of 98.9%. H-Yh, H-NaYh, Ca-NaYh, Mg-NaYh, and La-NaYh provided the highest possible isophorone conversion (up to 100.0% at 400°C and 1 h–1), with the reaction products mainly consisting of dimethylbenzenes and trimethylbenzenes (their selectivity reached up to 72.9 wt %). In the presence of low-activity samples (NaYh and Li-NaYh), the predominant products were methylbenzenes (dimethylbenzenes and trimethylbenzenes, 26.6–30.9%) and isophorone derivatives (β-isophorone and dihydroisophorone, 30.5–33.0%).","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 4","pages":"405 - 414"},"PeriodicalIF":1.1,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effects of Promoters of Cobalt-Based Catalysts on the Yield of Diesel-Range Hydrocarbons in Fischer–Tropsch Synthesis 钴基催化剂促进剂对费托合成柴油系烃产率的影响

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-04-03 DOI: 10.1134/S0965544125600493

O. L. Eliseev, E. M. Smirnova, K. M. Mazurova, R. V. Kazantsev, I. N. Zubkov, R. E. Yakovenko, N. R. Demikhova, A. P. Glotov, A. V. Stavitskaya

{"title":"Effects of Promoters of Cobalt-Based Catalysts on the Yield of Diesel-Range Hydrocarbons in Fischer–Tropsch Synthesis","authors":"O. L. Eliseev, E. M. Smirnova, K. M. Mazurova, R. V. Kazantsev, I. N. Zubkov, R. E. Yakovenko, N. R. Demikhova, A. P. Glotov, A. V. Stavitskaya","doi":"10.1134/S0965544125600493","DOIUrl":"10.1134/S0965544125600493","url":null,"abstract":"The paper investigates the effects of lanthanum and manganese promotion (3 wt %) on the physicochemical properties and catalytic performance of a supported 15%Co/Al2O3 catalyst in the synthesis of hydrocarbons from Co and H2. The catalysts were prepared by impregnating the support with relevant metal nitrate solutions followed by drying, calcination, and hydrogen activation. The samples were characterized by X-ray diffraction analysis (XRD), low-temperature nitrogen adsorption, temperature-programmed reduction (TPR), and transmission electron microscopy (TEM). The catalytic performance was tested in fixed-bed flow-type reactors at 240°C, 2 MPa, and CO/H2 = 1 : 2 with the feed GHSV being varied. At a CO conversion of about 50%, the promoted catalysts exhibited an increase in the C5+ selectivity and a drop in the methane selectivity in the order of Co < Co–La < Co–Mn. The Mn promotion increased the hydrocarbon chain growth probability up to 0.89, thus enhancing the yield of the most valuable products such as diesel-range and solid hydrocarbons. In the presence of 15Co3.15Mn/Al2O3, a C5+ selectivity of 45.3% was achieved at 86% CO conversion. Under high CO conversion conditions (80–86%), the selectivity towards higher hydrocarbons markedly declined, apparently due to the intensification of the water gas shift reaction. Nonetheless, even under these conditions, the Co–Mn catalyst provided the highest relative content of diesel-range hydrocarbons in the products. For 15Co3.15Mn/Al2O3, the C11–C18 selectivity reached 56.7 at 51.4% CO conversion and 41.2 at 86% CO conversion. The C11–C18 selectivity values provided by 15Co/Al2O3 were 10–20% lower (51.8 and 35.0%, respectively).","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 3","pages":"268 - 276"},"PeriodicalIF":1.1,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Evaluating the Effect of the Local Organic Fly Ash on the Properties of Water-Based Drilling Fluid 局部有机粉煤灰对水基钻井液性能影响的评价

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-03-24 DOI: 10.1134/S0965544124602357

Sahmi A. Mohammed, Fatimah H. A. Al-Ogaili, Darya Khalid Faidhllah, Zainab A. Al-Rubiay, Duraid Albayati

{"title":"Evaluating the Effect of the Local Organic Fly Ash on the Properties of Water-Based Drilling Fluid","authors":"Sahmi A. Mohammed, Fatimah H. A. Al-Ogaili, Darya Khalid Faidhllah, Zainab A. Al-Rubiay, Duraid Albayati","doi":"10.1134/S0965544124602357","DOIUrl":"10.1134/S0965544124602357","url":null,"abstract":"Recently the petroleum industry has been turning to the use of environmentally friendly additives particularly in oil well drilling operations. Switching to bio-based green biodegradable additives reduces pollution caused by dumping of wetted cuttings containing residual drilling fluid. The daily production of animal-origin biomass waste in farms poses serious health risks to both humans and animals if they are accumulated untreated. In this study, we used cow manure as a source of organic fly ash via burning it at temperatures below 370‒400°C to provide a manure conversion into powder and added it to a water-based drilling fluid. The results of the study showed that the biomass of the animal origin could successfully serve as a drilling fluid additive. For example, the rheological properties of the drilling fluid were improved via the provision of a sufficient YP/PV ratio and enhanced gelation properties. In addition, increasing fly ash concentration provided a subtle impact on mud density. XRD and EDS tests classified organic fly ash as a low-calcium/Class F, and the mud pH increased as the fly ash concentration increased. A FE-SEM imaging demonstrated that the fly ash morphology was amorphous with nano-sized particles dispersed among micro-sized particles. However, it is recommended to maintain the additive concentration below 0.55 wt %. Therefore, the use of the organic fly ash powder as an environmentally friendly additive is a good practice in oil well drilling operations.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 2","pages":"218 - 225"},"PeriodicalIF":1.1,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145168485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hierarchical Sn-BEA Zeolites in Catalytic Oxidation of Dihydrocarvone with Hydrogen Peroxide 分级Sn-BEA分子筛在双氧水催化氧化双氢香豆酮中的应用

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-03-18 DOI: 10.1134/S0965544125600213

R. Yu. Barakov, A. V. Smirnov

引用次数: 0

Efficiency of Fe/MFI, Fe/FAU, and Fe/FER Zeolites: Reduction of NOx in Cracking Catalyst Regeneration Flue Gas Fe/MFI、Fe/FAU和Fe/FER沸石对裂化催化剂再生烟气中NOx的还原效率

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-03-18 DOI: 10.1134/S0965544125600377

E. O. Kuziuberdina, V. A. Koveza, T. V. Bobkova, O. V. Potapenko

引用次数: 0

Innovative Porous Organic Amine Catalyst Boosts the Oil Yield and Quality in the Oil Shale Conversion 新型多孔有机胺催化剂提高油页岩转化油收率和质量

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2025-03-13 DOI: 10.1134/S0965544124602400

Xinbo Wang, Pengcheng Ma, Cong Yu, Bin Shan, Junjie Bian, Xianglong Meng

{"title":"Innovative Porous Organic Amine Catalyst Boosts the Oil Yield and Quality in the Oil Shale Conversion","authors":"Xinbo Wang, Pengcheng Ma, Cong Yu, Bin Shan, Junjie Bian, Xianglong Meng","doi":"10.1134/S0965544124602400","DOIUrl":"10.1134/S0965544124602400","url":null,"abstract":"Oil shale, an abundant unconventional resource, can be transformed into fossil fuels via pyrolysis, presenting a potential solution of energy shortages. This study explores the catalytic hydrothermal pyrolysis of oil shale using a novel organic porous amine catalyst, HCP-BBA, under subcritical water conditions. The study is focused on improving the efficiency and quality of shale oil extraction by overcoming the limitations of existing methods, such as high pyrolysis temperatures and extended heating time. The HCP-BBA catalyst, synthesized via a Friedel‒Crafts reaction, demonstrates excellent catalytic performance. Experimental results demonstrate that the introduction of HCP-BBA increases shale oil yield from 22.63 to 26.79%, shifts the product composition towards lower carbon numbers and lower boiling points, and increases the saturated hydrocarbon content by 13.1%, thereby enhancing the energy value of the shale oil. This study provides a promising approach for efficient and sustainable in situ oil shale conversion, proposing both theoretical and technical support for advanced extraction technologies.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 2","pages":"168 - 177"},"PeriodicalIF":1.1,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145164764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study of the Salt-Adding Extractive Distillation of Cyclopentane-2,2-dimethylbutane Using Composite Extract for the Production of High-Pure Cyclopentane 复合萃取物加盐萃取精馏环戊烷-2,2-二甲基丁烷生产高纯环戊烷的研究

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2025-03-12 DOI: 10.1134/S0965544124601947

Hailun Ren, Weihong Li

{"title":"Study of the Salt-Adding Extractive Distillation of Cyclopentane-2,2-dimethylbutane Using Composite Extract for the Production of High-Pure Cyclopentane","authors":"Hailun Ren, Weihong Li","doi":"10.1134/S0965544124601947","DOIUrl":"10.1134/S0965544124601947","url":null,"abstract":"Cyclopentane is an important organic raw material for the production of refrigerants and foaming agents. The relative volatilities of 2,2-dimethylbutane (DMB) and cyclopentane were determined in the presence of four extractants including dimethyl formamide (DMF, 100 wt %), N-methyl pyrrolidone (NMP, 100 wt %), DMF (80 wt %) + NMP (20 wt %), and DMF (79 wt %) + NMP (19 wt %) + sodium acetate (AcONa, 2 wt %). The results showed that the complex solvent containing AcONa provided a good separation effect, and the accuracy of the relative volatility determination was verified by the extractive distillation experiment. The process conditions for separating DMB and cyclopentane by extractive distillation with DMF (79 wt %) + NMP (19 wt %) + AcONa (2 wt %) as the extractant were systematically discussed. At the mass percentage of AcONa in DMF and NMP of ~2.0–2.5 wt %, mass ratio of solvent of about 6, the number of theoretical plates of about 30, the reflux ratio of about 3, and the solvent feed temperature of about 50°C, the composite extract (DMF (79 wt %) + NMP (19 wt %) + AcONa (2 wt %)) exhibited a better separation efficiency of the cyclopentane–DMB azeotropic system. According to the calculations of the process simulation, under the same operating conditions, the reboiler energy consumption could be reduced by 25.1% and the energy consumption for cooling could be reduced by 28.4% compared to that for the DMF solvent only.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 1","pages":"82 - 92"},"PeriodicalIF":1.3,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Castor Oil-based Bifunctional Lubricant Additive 蓖麻油基双功能润滑油添加剂的合成

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2025-02-18 DOI: 10.1134/S0965544123600418

Liqin Ding, Xinyi Liu, Sifan Liu, Yuntao Xi, Xiao Guo, Hanbin Zhong

{"title":"Synthesis of Castor Oil-based Bifunctional Lubricant Additive","authors":"Liqin Ding, Xinyi Liu, Sifan Liu, Yuntao Xi, Xiao Guo, Hanbin Zhong","doi":"10.1134/S0965544123600418","DOIUrl":"10.1134/S0965544123600418","url":null,"abstract":"Poly(castor oil(CO)–styrene(St)) (PCOS) was synthesized in toluene with azodiisobutyronitrile (AIBN) as the initiator using a Schlenk technology. The structure of PCOS was characterized by the Fourier transform infrared spectroscopy (FT-IR), Proton nuclear magnetic resonance (1H NMR), and gel permeation chromatography (GPC), and the performance of the synthesized copolymer was evaluated as a solidification point depressant and a viscosity index improver. Experimental results show that when the optimum process conditions are m(CO) : m(St) = 1 : 1, and the AIBN mass fraction is 0.4% (based on the total mass of monomers) at 90°C for 6 h, the copolymer yield is 41%, the average relative molecular mass is 3.1 × 104, and the polydispersity index is 2.9. After addition of the synthesized copolymer, the solidification point of the lubricant fraction (350–395°C) can be decreased by 6–12°C, while the viscosity index can increase by 24–39. Therefore, the synthesized copolymer could be used as a lubricant additive with the double functions of reducing the solidification point and increasing the viscosity index.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 1","pages":"103 - 111"},"PeriodicalIF":1.3,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Erratum to: Heterogeneous Hydroformylation Catalysts with Rhodium Nanoparticles Immobilized on Functionalized Porous Aromatic Frameworks 在功能化多孔芳香框架上固定化铑纳米颗粒的非均相氢甲酰化催化剂的勘误

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2025-02-09 DOI: 10.1134/S0965544124090020

Wang Hanlin, M. V. Nenasheva, K. A. Cherednichenko, L. A. Kulikov, A. V. Akopyan, D. N. Gorbunov

引用次数: 0