Petroleum Chemistry最新文献_第6页

Oxidative Desulfurization of Lighter Petroleum Fractions Using Supported Heteropoly-Acid Catalysts (A Review) 负载型杂多酸催化剂催化轻质石油馏分氧化脱硫研究进展

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-30 DOI: 10.1134/S0965544125601577

Ayat N. Mahmood, Bashir Y. Al-Zaidi, Zaidoon M. Shakor, Yasameen Mundher J., Ali Al-Shathr

{"title":"Oxidative Desulfurization of Lighter Petroleum Fractions Using Supported Heteropoly-Acid Catalysts (A Review)","authors":"Ayat N. Mahmood, Bashir Y. Al-Zaidi, Zaidoon M. Shakor, Yasameen Mundher J., Ali Al-Shathr","doi":"10.1134/S0965544125601577","DOIUrl":"10.1134/S0965544125601577","url":null,"abstract":"Desulfurization is a significant problem in fuel refining. Hydrodesulfurization was the subject of extensive research for many years as a commercial and conventional method to remove sulfur compounds. However, the removal of organic sulfur compounds by hydrodesulfurization became more challenging with increasingly stringent environmental policies on fuel. As a result, non-hydrodesulfurization methods have advanced quickly in the last several years. Oxidative desulfurization (ODS), with its mild reaction conditions and high efficiency, performs best of all new desulfurization technologies. ODS is one of several synthetically selective transformations of organic substances that use heteropoly acids (HPAs). HPAs, which have a distinct ionic structure and high proton mobility, have been extensively studied for their great potential for catalysis. Nevertheless, HPAs have drawbacks, including their limited specific surface area and high solubility in polar solvents. Numerous attempts have been made to combine HPAs with other materials to overcome these limitations. Supported HPAs, polyoxometalate-based ionic liquids, and phase-transfer HPAs are the primary HPA derivatives used in ODS as catalysts. Following modification, HPAs’ catalytic activity and reusability are significantly enhanced.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"66 4","pages":"377 - 395"},"PeriodicalIF":1.1,"publicationDate":"2026-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148434086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermocatalytic Decomposition of Methane over Ni-Based Catalysts for Hydrogen and Carbon Nanotube Synthesis: an Experimental and Theoretical Study ni基催化剂上甲烷热催化分解合成氢碳纳米管的实验与理论研究

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-25 DOI: 10.1134/S0965544126600189

Igor V. Kudinov, Anton V. Eremin, Viktor D. Dolgikh, Yuriy A. Kryukov, Nikolay A. Vinogradov, Denis M. Davydov, Vladislav A. Novikov, Vladimir S. Pavelyev, Nishant Tripathi, Andrey A. Pimenov

{"title":"Thermocatalytic Decomposition of Methane over Ni-Based Catalysts for Hydrogen and Carbon Nanotube Synthesis: an Experimental and Theoretical Study","authors":"Igor V. Kudinov, Anton V. Eremin, Viktor D. Dolgikh, Yuriy A. Kryukov, Nikolay A. Vinogradov, Denis M. Davydov, Vladislav A. Novikov, Vladimir S. Pavelyev, Nishant Tripathi, Andrey A. Pimenov","doi":"10.1134/S0965544126600189","DOIUrl":"10.1134/S0965544126600189","url":null,"abstract":"The activity of four nickel-based catalysts (60Ni/40SiO2, 60Ni/40Al2O3, 80Ni/10Cu/10SiO2, and 90Ni/10Al2O3) was evaluated in methane pyrolysis experiments. The highest hydrogen molar concentrations were achieved with 60Ni/40SiO2 (12.7% at 550°C) and 80Ni/10Cu/10SiO2 (32.8% at 650°C and 57% at 750°C). The study proposes a novel gas-flow mathematical model for the thermocatalytic decomposition of methane (TCDM), presenting both analytical and numerical solutions. Model verification against experimental data yielded a digital twin of the process with a 10% error margin. Characterization of the carbonaceous products by X-ray phase diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) showed the multiplicity of multiwalled carbon nanotubes (MWCNTs) in all cases. However, the copper-promoted catalyst produced MWCNTs with a broader diameter distribution, poorer wall alignment, and the presence of amorphous carbon, whereas the copper-free catalysts yielded nanotubes with superior uniformity, alignment, and surface purity.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"66 4","pages":"420 - 434"},"PeriodicalIF":1.1,"publicationDate":"2026-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Morphology Control of ZSM-23 Zeolites for the Development of Highly Efficient n-Hexadecane Hydroisomerization Catalysts 开发高效正十六烷加氢异构催化剂ZSM-23分子筛的形貌控制

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-25 DOI: 10.1134/S0965544126600554

Polina S. Kulikova, Tatiana O. Bok, Egor P. Andriako, Anastasiia P. Dubtsova, Akim D. Gogolev, Irina I. Ivanova

引用次数: 0

Ethylene/Propylene Copolymerization and Ethylene/Propylene/5-Ethylidene-2-Norbornene Terpolymerization Using Half-Sandwich Titanium Complexes with α-Naphthoxide Ligands as Catalysts α-萘酰配体半夹层钛配合物催化乙烯/丙烯共聚及乙烯/丙烯/5-乙基-2-降冰片烯共聚

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-14 DOI: 10.1134/S0965544126600281

Stanislav L. Saratovskikh, Igor V. Zharkov, Sergey A. Zhukov, Evgeny E. Faingol’d, Andrei N. Panin, Artur T. Kapasharov, Dmitriy A. Chernyayev, Natalia M. Bravaya

{"title":"Ethylene/Propylene Copolymerization and Ethylene/Propylene/5-Ethylidene-2-Norbornene Terpolymerization Using Half-Sandwich Titanium Complexes with α-Naphthoxide Ligands as Catalysts","authors":"Stanislav L. Saratovskikh, Igor V. Zharkov, Sergey A. Zhukov, Evgeny E. Faingol’d, Andrei N. Panin, Artur T. Kapasharov, Dmitriy A. Chernyayev, Natalia M. Bravaya","doi":"10.1134/S0965544126600281","DOIUrl":"10.1134/S0965544126600281","url":null,"abstract":"A novel half-sandwich titanium complex, Cp*Ti(1-C10H7O)Cl2, containing an α-naphthoxide fragment, was synthesized. Modified methylaluminoxane (MMAO-12) and perfluoroaryl boron-containing activators B(C6F5)3 and [Ph3C][B(C6F5)4] combined with triisobutylaluminum were used to activate the precatalyst. The resulting catalysts produced binary and ternary copolymers of ethylene with propylene and 5-ethylidene-2-norbornene. The composition, molecular weight characteristics, and thermophysical properties of the copolymers—including those of ethylene/propylene copolymer samples after stepwise isothermal melt crystallization—were characterized. The copolymerization performance of the catalysts was compared with previously studied similar systems based on the half-sandwich titanium complex Cp*Ti(O2,6iPr2C6H3)Cl2. The properties of the copolymers were also assessed comparatively. The synthesized catalytic systems produced polymer mixtures consisting of low-molecular-weight (comonomer-enriched) fractions and high-molecular-weight polyethylene fractions, likely due to the generation of two different types of active sites responsible for producing bimodal copolymers.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"66 4","pages":"464 - 476"},"PeriodicalIF":1.1,"publicationDate":"2026-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Allyl- and Propenyl-Substituted Nitrogen-Containing Aromatic Compounds as Antioxidants for Hydrocarbons 烯丙基和丙烯基取代含氮芳香族化合物作为烃类抗氧化剂的研究

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-14 DOI: 10.1134/S096554412660013X

Musa R. Bayramov, Vagif M. Farzaliyev, Gunay M. Mehdiyeva, Irada A. Rzayeva, Afsun R. Sujayev

引用次数: 0

Erratum to: Progress on Chemical Demulsifiers for Oil Fields 油田用化学破乳剂的研究进展

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-10 DOI: 10.1134/S0965544126030011

Jian Li, Yanzhong Han, Longlong Yan, Longlong Dou, Chaocheng Tan, Lei Han, Jungang Sun, Congyu Ke

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Effect of Phosphorus-to-Nickel Ratio on the Performance of Nickel-Based Catalysts in Hydroprocessing of Bisphenol A 磷镍比对双酚A加氢反应镍基催化剂性能的影响

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-10 DOI: 10.1134/S0965544126600566

Maria A. Golubeva, Anastasia M. Scherbakova, Valentin R. Atlasov, Anton L. Maximov

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Effects of the Cobalt-Based Component (Co/SiO2, Co/C, or Co/ZrO2) on the Properties and Performance of Zeolite-Containing Hybrid Catalysts for Fischer–Tropsch Synthesis 钴基组分（Co/SiO2、Co/C或Co/ZrO2）对含沸石杂化费托合成催化剂性能的影响

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-06-03 DOI: 10.1134/S0965544126600591

Roman E. Yakovenko, Anastasia A. Chemes, Andrey V. Volik, Danila A. Ponomarev, Daniil V. Telegin, Yuri I. Razorenov, Alexander P. Savostyanov

{"title":"Effects of the Cobalt-Based Component (Co/SiO2, Co/C, or Co/ZrO2) on the Properties and Performance of Zeolite-Containing Hybrid Catalysts for Fischer–Tropsch Synthesis","authors":"Roman E. Yakovenko, Anastasia A. Chemes, Andrey V. Volik, Danila A. Ponomarev, Daniil V. Telegin, Yuri I. Razorenov, Alexander P. Savostyanov","doi":"10.1134/S0965544126600591","DOIUrl":"10.1134/S0965544126600591","url":null,"abstract":"This study investigates the effect of a cobalt-based component (selected from Co/SiO2, Co/C, and Co/ZrO2) on the physicochemical properties and catalytic performance of zeolite-containing composite catalysts for Fischer–Tropsch (FT) synthesis. The choice of catalyst support governs activity, selectivity toward liquid hydrocarbons, and the group composition of target products. Catalysts supported on SiO2 and ZrO2 showed similar CO conversion (~86%) and space-time yields (STY) of C5+ hydrocarbons (130–134 kg m–3 h–1). In contrast, the carbon-supported sample exhibited slightly lower CO conversion (71.7%) but superior C5+ selectivity (73.1%). Product distribution strongly depends on the support type: the ZrO2-supported catalyst gave the highest content of branched hydrocarbons (iso/n = 1.77); the SiO2-supported sample maximized olefin yield, indicative of low hydrogenating activity; and the carbon-supported sample excelled in high-molecular-weight (C19+) hydrocarbons (9.0 wt %). These results demonstrate that the FT product distribution can be tailored by an appropriate choice of the cobalt-based component.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"66 3","pages":"253 - 260"},"PeriodicalIF":1.1,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148208715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Direct Synthesis of Oxygenates over Fe-Based Composite Catalysts: Effect of Feed Gas Composition 铁基复合催化剂上氧合物的直接合成：原料气组成的影响

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-05-27 DOI: 10.1134/S0965544126600578

Ivan V. Bliznetsov, Mikhail I. Ivantsov, Mayya V. Kulikova

引用次数: 0

Hydroprocessing of Tetrabromobisphenol A over Phosphide Catalysts 磷化物催化剂上四溴双酚A加氢工艺研究

IF 1.1 4区工程技术

Petroleum Chemistry Pub Date : 2026-05-27 DOI: 10.1134/S0965544126600517

Eduard G. Dzhabarov, Nikita D. Kashirin, Natalia N. Petrukhina, Elena M. Zakharyan

{"title":"Hydroprocessing of Tetrabromobisphenol A over Phosphide Catalysts","authors":"Eduard G. Dzhabarov, Nikita D. Kashirin, Natalia N. Petrukhina, Elena M. Zakharyan","doi":"10.1134/S0965544126600517","DOIUrl":"10.1134/S0965544126600517","url":null,"abstract":"Using red phosphorus, a series of unsupported nanosized transition-metal phosphides (NiP, MoP, and FeP) were synthesized in situ in the presence of the brominated flame retardant tetrabromobisphenol A (TBBPA). Their catalytic activity was evaluated in the hydroprocessing of model polymer waste mixtures (polystyrene, polyethylene, polypropylene, and polyvinyl chloride) containing 10 wt % TBBPA. Reactions were conducted at 320–380°C, 6 MPa H2, with a metal-to-polymer weight ratio of 1 : 80 for 7 h. A comparative investigation of the three phosphides in the hydroprocessing of the polyethylene, polypropylene, and polystyrene mixtures with 10 wt % TBBPA demonstrates that at 320°C, NiP minimized the formation of organobromine intermediates such as 1-(1-methylethylene)-3,5-dibromo-4-hydroxybenzene (6 wt %) and 2,6-dibromophenol (4 wt %), achieving superior debrominating activity. Raising the temperature to 380°C enhanced debromination for all catalysts but reduced styrene selectivity due to aromatic hydrogenation. The optimal temperature for styrene yield was 340°C. Catalyst reuse led to gradual deactivation via the formation of metal bromides and agglomeration of catalyst particles, highlighting the need for effective regeneration methods.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"66 3","pages":"351 - 358"},"PeriodicalIF":1.1,"publicationDate":"2026-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148208740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0