重油超声气泡处理的绿色技术

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
Dina Harith Shaker, Raheek Ismael Ibrahim, Manal Kadhim Oudah, Hussain H. Al-Kayiem
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引用次数: 0

摘要

低粘度原油储量的枯竭要求生产重质、高粘度原油。然而,由于稠油的高粘度,其运输具有挑战性。这项研究旨在开发一种可持续的解决方案,通过利用流体中的振荡气泡来降低稠油的粘度。这是因为传统的减阻方法除了经济成本高外,还会造成环境污染和危险排放。采用恒功率150w、频率40khz的超声装置,在不同温度下,超声辐照时间分别为10min和15min。粘度降低率(VRR)因子用于确定粘度的变化。在本实验条件和不同温度下,辐照时间为10 min时的降粘率(VRR)最高,可达36%以上。在70℃下,辐照时间达到15 min时,油样粘度增大。结果表明,超声波的空化效应、热效应和力学效应可以使原油的长碳链断裂,形成短链,从而降低粘度。增加辐照时间后粘度的增加可归因于分子间的重缔合。该技术有望成为一种环保、高效的稠油降粘替代品,减少化学品的使用,防止碳排放。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Ultrasonic Bubble Treatment of Heavy Oil as a Green Technology

Ultrasonic Bubble Treatment of Heavy Oil as a Green Technology

The depletion of low-viscosity crude oil reserves necessitates the production of heavy, high-viscosity crude oil. However, transportation of heavy oils is challenging due to their high viscosity. This study aims to develop a sustainable solution to reduce the viscosity of heavy oil by exploiting oscillating bubbles within the fluid. This is because traditional methods by drag reduction additives cause environmental pollution and dangerous emissions, in addition to their high economic cost. An ultrasonic device with a constant power of 150 W and a frequency of 40 kHz was used at different temperatures, while the ultrasonic irradiation time was 10 and 15 min. A viscosity reduction rates (VRR) factor was used to determine changes in viscosity. The viscosity reduction rate (VRR) was at its best at an irradiation time of 10 min under the present experimental conditions and at different temperatures, where it reached more than 36%. At 70°C, when the irradiation time reached 15 min, the viscosity of the oil samples increased. The results indicate that the cavitation, thermal, and mechanical effects of ultrasound can break the long carbon chains of crude oil and form short chains, thus reducing the viscosity. The increase in viscosity after increasing the irradiation time can be attributed to the re-association between molecules. The technique is promising as an eco-friendly and efficient method for heavy oil viscosity reducing alternative that reduces chemical usage and preventing carbon emissions.

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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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