{"title":"富芳烃流体催化裂化浆料合成中间相沥青:主要优点","authors":"Mingzhi Wang, Xiaolong Zhou","doi":"10.1134/S0965544123600807","DOIUrl":null,"url":null,"abstract":"<p>This study presents FCC-BL, a novel material that can be converted into the mesophase pitch, characterized by a wide-area streamlined optical texture and large domain texture, via the direct thermal polycondensation under optimized reaction conditions. It has an ordered microcrystalline structure and great yield overcoming the difficulty of synthesizing mesophase pitch with a good optical texture in the traditional FCC slurry; Mesophase pitch with a specific anisotropic structure is produced by a continuous screening of reaction conditions and thermal polycondensation, and its properties and structure are characterized and analyzed using the polarizing microscope, FTIR, <sup>1</sup>H NMR, and XRD. The experimental results reveal that mesophase pitch with the optimal performance is obtained at a temperature of 420°C, a pressure of 2 MPa, and a reaction time of 6 h. The resulting mesophase pitch product exhibits a streamlined texture in a large watershed, with a softening point at only 233°C and low impurity content, that makes the material highly suitable for the production of carbon fibers.</p>","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 2","pages":"190 - 205"},"PeriodicalIF":1.1000,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Mesophase Pitch from Aromatic-Rich Fluid Catalytic Cracking Slurry: Key Advantages\",\"authors\":\"Mingzhi Wang, Xiaolong Zhou\",\"doi\":\"10.1134/S0965544123600807\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study presents FCC-BL, a novel material that can be converted into the mesophase pitch, characterized by a wide-area streamlined optical texture and large domain texture, via the direct thermal polycondensation under optimized reaction conditions. It has an ordered microcrystalline structure and great yield overcoming the difficulty of synthesizing mesophase pitch with a good optical texture in the traditional FCC slurry; Mesophase pitch with a specific anisotropic structure is produced by a continuous screening of reaction conditions and thermal polycondensation, and its properties and structure are characterized and analyzed using the polarizing microscope, FTIR, <sup>1</sup>H NMR, and XRD. The experimental results reveal that mesophase pitch with the optimal performance is obtained at a temperature of 420°C, a pressure of 2 MPa, and a reaction time of 6 h. The resulting mesophase pitch product exhibits a streamlined texture in a large watershed, with a softening point at only 233°C and low impurity content, that makes the material highly suitable for the production of carbon fibers.</p>\",\"PeriodicalId\":725,\"journal\":{\"name\":\"Petroleum Chemistry\",\"volume\":\"65 2\",\"pages\":\"190 - 205\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2025-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petroleum Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0965544123600807\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0965544123600807","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis of Mesophase Pitch from Aromatic-Rich Fluid Catalytic Cracking Slurry: Key Advantages
This study presents FCC-BL, a novel material that can be converted into the mesophase pitch, characterized by a wide-area streamlined optical texture and large domain texture, via the direct thermal polycondensation under optimized reaction conditions. It has an ordered microcrystalline structure and great yield overcoming the difficulty of synthesizing mesophase pitch with a good optical texture in the traditional FCC slurry; Mesophase pitch with a specific anisotropic structure is produced by a continuous screening of reaction conditions and thermal polycondensation, and its properties and structure are characterized and analyzed using the polarizing microscope, FTIR, 1H NMR, and XRD. The experimental results reveal that mesophase pitch with the optimal performance is obtained at a temperature of 420°C, a pressure of 2 MPa, and a reaction time of 6 h. The resulting mesophase pitch product exhibits a streamlined texture in a large watershed, with a softening point at only 233°C and low impurity content, that makes the material highly suitable for the production of carbon fibers.
期刊介绍:
Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas.
Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.