富芳烃流体催化裂化浆料合成中间相沥青:主要优点

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
Mingzhi Wang, Xiaolong Zhou
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引用次数: 0

摘要

本研究提出了一种新型材料FCC-BL,该材料在优化的反应条件下通过直接热缩聚转化为具有广域流线型光学织构和大畴织构的中间相沥青。微晶结构有序,产率高,克服了传统FCC浆料难以合成光学织构良好的中间相沥青;通过连续筛选反应条件和热缩聚制得具有特定各向异性结构的中间相沥青,并利用偏光显微镜、FTIR、1H NMR和XRD对其性质和结构进行表征和分析。实验结果表明,在温度为420℃、压力为2 MPa、反应时间为6 h的条件下,获得了性能最优的中间相沥青。所得中间相沥青产品在大分水岭内呈流线型织构,软化点仅为233℃,杂质含量低,非常适合用于碳纤维的生产。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of Mesophase Pitch from Aromatic-Rich Fluid Catalytic Cracking Slurry: Key Advantages

Synthesis of Mesophase Pitch from Aromatic-Rich Fluid Catalytic Cracking Slurry: Key Advantages

This study presents FCC-BL, a novel material that can be converted into the mesophase pitch, characterized by a wide-area streamlined optical texture and large domain texture, via the direct thermal polycondensation under optimized reaction conditions. It has an ordered microcrystalline structure and great yield overcoming the difficulty of synthesizing mesophase pitch with a good optical texture in the traditional FCC slurry; Mesophase pitch with a specific anisotropic structure is produced by a continuous screening of reaction conditions and thermal polycondensation, and its properties and structure are characterized and analyzed using the polarizing microscope, FTIR, 1H NMR, and XRD. The experimental results reveal that mesophase pitch with the optimal performance is obtained at a temperature of 420°C, a pressure of 2 MPa, and a reaction time of 6 h. The resulting mesophase pitch product exhibits a streamlined texture in a large watershed, with a softening point at only 233°C and low impurity content, that makes the material highly suitable for the production of carbon fibers.

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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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