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Advancements in steelmaking technologies 炼钢技术的进步
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-02-05 DOI: 10.1007/s11015-025-01856-0
A. I. Dagman, A. V. Yaroshenko, S. S. Emelyanov, E. N. Tyulenev
{"title":"Advancements in steelmaking technologies","authors":"A. I. Dagman,&nbsp;A. V. Yaroshenko,&nbsp;S. S. Emelyanov,&nbsp;E. N. Tyulenev","doi":"10.1007/s11015-025-01856-0","DOIUrl":"10.1007/s11015-025-01856-0","url":null,"abstract":"<div><p>In recent years, significant advancements have been made in the steelmaking operations at Novolipetsk Steel (NLMK, Lipetsk, Russia). New and renovated units in converter shops have been commissioned, while ongoing operational and technological enhancements are being implemented. This resulted in an increase in steel production up to 14.0 million tons in 2023, an expansion of the product range through introducing special purpose steel, and a notable improvement in product quality. The article presents the principal technological methods and results achieved to ensure the chemical composition of the primary elements within narrow specified limits, along with the macrostructure of slabs and the content of non-metallic inclusions.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 10","pages":"1432 - 1437"},"PeriodicalIF":0.8,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143668057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal analysis of mechanically activated Cr–B mixture 机械活化Cr-B混合物的热分析
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-14 DOI: 10.1007/s11015-024-01845-9
O. N. Pripisnov, E. V. Shelekhov, S. I. Rupasov
{"title":"Thermal analysis of mechanically activated Cr–B mixture","authors":"O. N. Pripisnov,&nbsp;E. V. Shelekhov,&nbsp;S. I. Rupasov","doi":"10.1007/s11015-024-01845-9","DOIUrl":"10.1007/s11015-024-01845-9","url":null,"abstract":"<div><p>A chromium-boron mixture with the atomic composition corresponding to CrB<sub>2</sub> was subjected to mechanical activation in a high-energy planetary mill for 6–40 min at a balls-to-material ratio of 20:1. The milled powders were analyzed by X‑ray diffraction and other methods. Then the mixture was heated at an initial rate of ~ 6 °C/s to a temperature of 1000 °C. Exothermic peaks associated with the formation of borides were observed on the heating curves. The onset temperature of this transformation decreased with the milling time to 15 min and then reached a plateau. This is due to the formation of a thin layered structure as the milling time increases and the limit of structure thinning is reached. The optimal milling time for preparing the mixture for self-propagating high-temperature synthesis should be 15–20 min, since the thinning of the roll layers after this practically stops or becomes very slow. At such milling duration, boride formation does not occur in the grinder, that is, the energy charge of the mixture is not consumed. At the same time, some literature data suggest that during milling for 40 h, up to 50% of boron is converted into CrB<sub>2</sub>.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1338 - 1344"},"PeriodicalIF":0.8,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143361960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tellurium and selenium in the gold-silver ore of the Baleysky ore field (Eastern Transbaikalia) and development of their associated extraction method 东外贝加尔Baleysky矿田金银矿石中的碲、硒及其伴生提取方法研究
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-08 DOI: 10.1007/s11015-024-01854-8
Georgy A. Yurgenson, Lidia V. Shumilova
{"title":"Tellurium and selenium in the gold-silver ore of the Baleysky ore field (Eastern Transbaikalia) and development of their associated extraction method","authors":"Georgy A. Yurgenson,&nbsp;Lidia V. Shumilova","doi":"10.1007/s11015-024-01854-8","DOIUrl":"10.1007/s11015-024-01854-8","url":null,"abstract":"<div><p>One important tellurium source may be the ores of the Baleysky ore field in Transbaikalia. Our studies of the material composition of the gold-silver ores in the Baleysky ore field enabled the first analysis of the tellurium and selenium content in the primary and oxidized ores of the Baleysky ore field. Moreover, it has been established that tellurium in run-of-mine ores is within the limits of its association with certain mineral forms of gold and silver. The article considers their parageneses. The average tellurium content is 0.65 g/t. The average selenium content amounts to 2.59 g/t. However, no principal selenium minerals were found in the ores of the Baleysky ore field. Additionally, we developed a framework for the hydrometallurgical method of extracting tellurium and selenium from the tailings left over after processing gold-silver ores of the Taseyevsky deposit (its undeveloped reserves amount to about 105 t) and the Baleysky ore field (its gold resources by category P1 are approximately 35 t).</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1413 - 1423"},"PeriodicalIF":0.8,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Layered synthesis of billets by pulse MIG welding using austenitic flux-cored wire with nitrogen 用含氮奥氏体药芯焊丝脉冲MIG焊接分层合成钢坯
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01826-y
A. S. Smolentsev, D. N. Trushnikov, G. L. Permyakov, V. E. Veselova, E. B. Votinova
{"title":"Layered synthesis of billets by pulse MIG welding using austenitic flux-cored wire with nitrogen","authors":"A. S. Smolentsev,&nbsp;D. N. Trushnikov,&nbsp;G. L. Permyakov,&nbsp;V. E. Veselova,&nbsp;E. B. Votinova","doi":"10.1007/s11015-024-01826-y","DOIUrl":"10.1007/s11015-024-01826-y","url":null,"abstract":"<div><p>The possibility of producing multilayer billets by wire arc additive manufacturing (WAAM) technology with layer-by-layer forging using Cr20Mn5Ni4Mo2.5Cu3N0.3 flux-cored wire of 1.6 mm diameter as electrode material is investigated. The applied method resulted in the production of a weld metal with austenitic-ferritic structure (δ<i>F </i>≈ 1.5 vol %) without defects, which demonstrates a good combination of strength and plastic properties (σ<sub>B</sub> = 960 MPa, σ<sub>0.2</sub> = 670 MPa, δ = 35%).</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 8","pages":"1166 - 1174"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of iron stearate and sintering conditions on the structure and properties of powder alloy steel SP50S2KhF 硬脂酸铁和烧结条件对粉末合金钢SP50S2KhF组织和性能的影响
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01843-x
J. V. Eremeeva, Yu. S. Ter-Vaganyants
{"title":"The influence of iron stearate and sintering conditions on the structure and properties of powder alloy steel SP50S2KhF","authors":"J. V. Eremeeva,&nbsp;Yu. S. Ter-Vaganyants","doi":"10.1007/s11015-024-01843-x","DOIUrl":"10.1007/s11015-024-01843-x","url":null,"abstract":"<div><p>This article examines the influence of iron stearate and sintering conditions on the structure and properties of powder alloy steel SP50S2KhF. Studies have been carried out to establish the influence of temperature and soaking time during sintering on the structure of powder steel SP50S2KhF. At a sintering temperature of 1200 °C and soaking time of 120 min, practically no undissolved ferroalloy particles are observed in the structure, and the pores have a round shape. The structure of the samples after sintering consists of alloyed ferrite and pearlite. As a result of studying the mechanical properties, it was found that the addition of iron stearate to steel SP50S2KhF has a positive effect on its mechanical characteristics. At higher iron stearate content, an increase in hardness and bending strength is observed.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1323 - 1328"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dearsenizing roasting of fine copper-smelting dusts 细铜冶炼粉尘的脱砷焙烧
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01853-9
Pavel A. Kozlov, Dmitry A. Ivakin, Sergey A. Krayuhin, Vasily A. Kochin, Konstantin L. Timofeev
{"title":"Dearsenizing roasting of fine copper-smelting dusts","authors":"Pavel A. Kozlov,&nbsp;Dmitry A. Ivakin,&nbsp;Sergey A. Krayuhin,&nbsp;Vasily A. Kochin,&nbsp;Konstantin L. Timofeev","doi":"10.1007/s11015-024-01853-9","DOIUrl":"10.1007/s11015-024-01853-9","url":null,"abstract":"<div><p>Fine dust from copper smelting production is processed together with zinc cake in Waelz kilns of a zinc plant to recover non-ferrous and precious metals. The resulting clinker into which copper, precious metals, and most of arsenic pass is used in the smelting of copper-containing raw materials, which causes undesirable accumulation of arsenic in inter-plant circulation. Moreover, the presence of chlorine and fluorine in dust necessitates their removal in the zinc recovery process. It appears rational to use dearsenizing roasting to remove arsenic, chlorine, and fluorine from dust before zinc production. The chemical and phase compositions of dusts are presented. Laboratory studies and pilot tests were performed to determine the optimal roasting conditions. The mode of mixing the starting dust was determined: 90–95% dust, 5–7.5% petcoke, 0–5% calcium oxide, 0–2% pyrite. It was proposed to roast a granulated charge in a rotary tubular kiln at a temperature of 1050 °C for two hours. With these parameters, the degrees of sublimation of arsenic, chlorine, and fluorine were 78–85%, &gt; 95%, and &gt; 97%, respectively, the loss of zinc with sublimates being 4.3–7.2%. The resulting clinker (yield = 51.9–67.4%) can be used to recover zinc at a zinc plant, while sublimates (3.3–4.9% Zn, 23.9–28.0% Pb, 25.4–38.6% As, &lt; 2.6% Cl, &lt; 0.04% F) are additionally processed to separately recover lead cake and transform arsenic to stable form for subsequent utilization.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1406 - 1412"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the stress-strain and thermal states of Ni–Ti-alloy billets subjected to screw piercing 螺杆穿孔镍钛合金坯料的应力-应变及热状态评价
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01848-6
M. M. Skripalenko, V. A. Andreev, B. A. Romantsev, V. S. Yusupov, S. O. Rogachev, M. P. Kuprikov, V. P. Kuznetsov, M. N. Skripalenko, E. V. Shuster
{"title":"Evaluation of the stress-strain and thermal states of Ni–Ti-alloy billets subjected to screw piercing","authors":"M. M. Skripalenko,&nbsp;V. A. Andreev,&nbsp;B. A. Romantsev,&nbsp;V. S. Yusupov,&nbsp;S. O. Rogachev,&nbsp;M. P. Kuprikov,&nbsp;V. P. Kuznetsov,&nbsp;M. N. Skripalenko,&nbsp;E. V. Shuster","doi":"10.1007/s11015-024-01848-6","DOIUrl":"10.1007/s11015-024-01848-6","url":null,"abstract":"<div><p>We performed computer simulations of the screw piercing of titanium-nickelide shells in two- and four-high mills. On the basis of the accumulated numerical results, we compute the parameters of the stress-strain and thermal states of the shells. The distributions of levels of the accumulated strain and the normalized mean stress show that a more homogeneous stress-strain state and a lower hazard of fracture of the shells are detected in the case of four-high piercing. The analysis of the temperature distribution shows that, in the case of four-high piercing, the obtained temperature state is more favorable for guaranteeing higher levels of plasticity of the materials of pierced shells.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1364 - 1370"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elevation of the wear resistance of a graphite reactor designed for melting thermite charge 用于熔化铝热剂装药的石墨反应器耐磨性的提高
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01847-7
V. A. Khudyakova, S. G. Zhilin, V. V. Predein, O. N. Komarov
{"title":"Elevation of the wear resistance of a graphite reactor designed for melting thermite charge","authors":"V. A. Khudyakova,&nbsp;S. G. Zhilin,&nbsp;V. V. Predein,&nbsp;O. N. Komarov","doi":"10.1007/s11015-024-01847-7","DOIUrl":"10.1007/s11015-024-01847-7","url":null,"abstract":"<div><p>In the process of manufacturing iron-aluminum alloys, the prospects of reducing the costs spent for the refractory and charge materials, as well as for the supply of thermal and electric energy are connected with the realization of the exothermal process of melting of the thermite charge, i.e., in fact, industrial wastes in the form of scale and metal shavings, in the reactor without applying traditional melting units. In view of the high temperature of formed melts, it seems reasonable to use carbon materials as refractories. The durability of the reactor strongly depends on the number of thermal cycles and the possibility of ensuring the mechanical strength and functionality of its elements subjected to the most aggressive thermal effects of the melts. As a result of a series of experiments, we determine the possibility of weakening of the thermal effect of iron–aluminum melts formed as a result of the exothermal reaction on the material of the graphite reactor by regulating the content of active aluminum. Moreover, we propose a version of measures connected with the possibility of updating the design of the graphite reactor aimed at increasing its service life.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1353 - 1363"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of small additions of aluminum on the structure and phase composition of (Fe0.25Co0.25Ni0.25Cr0.125V0.125)83B17 alloy 少量添加铝对(Fe0.25Co0.25Ni0.25Cr0.125V0.125)83B17合金组织和相组成的影响
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01840-0
Andrey I. Bazlov, Evgeny V. Ubyivovk, Ilya V. Strochko, Erzhena N. Zanaeva, Tatiana A. Sviridova
{"title":"Influence of small additions of aluminum on the structure and phase composition of (Fe0.25Co0.25Ni0.25Cr0.125V0.125)83B17 alloy","authors":"Andrey I. Bazlov,&nbsp;Evgeny V. Ubyivovk,&nbsp;Ilya V. Strochko,&nbsp;Erzhena N. Zanaeva,&nbsp;Tatiana A. Sviridova","doi":"10.1007/s11015-024-01840-0","DOIUrl":"10.1007/s11015-024-01840-0","url":null,"abstract":"<div><p>This work investigates the influence of small additions of aluminum on the structure of ingots from a high-entropy alloy of the (Fe<sub>0.25</sub>Co<sub>0.25</sub>Ni<sub>0.25</sub>Cr<sub>0.125</sub>V<sub>0.125</sub>)<sub>83</sub>B<sub>17</sub> composition. The structure of experimental alloys was analyzed using scanning electron microscopy and EDX analysis. The borides formed in the structure were analyzed by transmission electron microscopy, X‑ray diffraction, and electron backscatter diffraction. Aluminum addition was found to change the crystallization process of the alloys, affecting the type of primary boride crystals and eutectic composition. The addition of aluminum to the alloy in greater amounts changes the boride type from refractory boride of (V, Cr)B type to a more easily melting type of boride M<sub>3</sub>B<sub>2</sub>.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1293 - 1301"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analyzing the modifying ability of rods made from AD31 alloy waste by direct extrolling 分析了AD31合金废棒的直接焙烧改性能力
IF 0.8 4区 材料科学
Metallurgist Pub Date : 2025-01-07 DOI: 10.1007/s11015-024-01852-w
Sergey B. Sidelnikov, Ekaterina S. Lopatina, Nikita A. Terentev, Denis S. Voroshilov, Andrey V. Parubok, Dmitry I. Kuzin
{"title":"Analyzing the modifying ability of rods made from AD31 alloy waste by direct extrolling","authors":"Sergey B. Sidelnikov,&nbsp;Ekaterina S. Lopatina,&nbsp;Nikita A. Terentev,&nbsp;Denis S. Voroshilov,&nbsp;Andrey V. Parubok,&nbsp;Dmitry I. Kuzin","doi":"10.1007/s11015-024-01852-w","DOIUrl":"10.1007/s11015-024-01852-w","url":null,"abstract":"<div><p>The results of studying the structure and properties of master-alloy rods produced from AD31 alloy extrusion waste by direct extrolling are presented. A SLiPP‑2.5 unit, which is part of the combined processing line in the laboratory of the Department of Metal Forming of the School of Non-Ferrous Metals of the Siberian Federal University, was used to make rods with a diameter of 9 mm from AD31 alloy waste. The process parameters for producing rods from AD31 aluminum alloy by direct extrolling were determined: elongation = 16.5, melt temperature = 760 ±10 °C, rolling strain = 50%, roll speed = 5 rpm. It was established that the initial structure of the master-alloy rod affects the melt, and the rods made from AD31 alloy extrusion waste by direct extrolling have a stable ultra-fine subgrain structure, which allows them to be applied to AD31 alloy. The Alcan test revealed that introducing 3 to 4% rod with a diameter of 9 mm into a solidifying AD31 alloy ingot at a melt temperature of 720 °C and a melt holding time of at least 3 min ensures a stable modifying effect.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1397 - 1405"},"PeriodicalIF":0.8,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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