{"title":"Spin States of s=1/2 Dimer with Non-Collinear Local Axes Exhibiting C2 Permutation Symmetry","authors":"A. Zhuravlev, Y. Pashkevich","doi":"10.1109/NAP51477.2020.9309645","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309645","url":null,"abstract":"Single-ion and exchange anisotropy effects in equal-spin $s^{(1)}=s^{(2)}$ dimeric single molecule magnets exhibiting C2 point group symmetry have been studied. The Hamiltonian which is written in two-spin $4times 4$ Pauli matrixes representation in the appropriate local coordinates has been used to derive energy levels and eigen spin states. The anomalous variation of the average spin system in dependence of non-collinear misalignment of the local anisotropy axes has been found. Particularly a fully non magnetic state of an $mathrm{s}=1/2$ spin dimer was predicted.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"1 1","pages":"01NMM09-1-01NMM09-3"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81901880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Composition-Structure-Property Relations in TiZr-C Nanocomposites","authors":"O. Maksakova, A. Pogrebnjak, L. Khomenko","doi":"10.1109/NAP51477.2020.9309542","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309542","url":null,"abstract":"This research focuses on the establishment of the relationship between composition-structure-properties of nanocomposite Ti-Zr-C coatings. The coatings have been deposited by the dual-target magnetron sputtering on Si substrates and explored with the atomic force microscopy, scanning electron microscopy with energy dispersive spectroscopy, X-ray diffraction and nanoindentation. It has been found that the coatings have a nanocrystalline microstructure, are sufficiently textured, and represent a solid solution of the fcc-phase. The atomic concentration of elements in the initial target affects the structure and composition of the resulting coatings. It is shown that Ti-Zr-C coating with the lowest surface roughness (0.8 nm), the stoichiometric composition by carbon (50 at. % C) and the coarsest crystalline structure (15 nm) has the maximum values of the hardness of $sim 35$ GPa and Young's modulus of $sim 310$ GPa.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"80 1","pages":"01TFC25-1-01TFC25-4"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78656280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Savkina, Aleksej Smirnov, Anatoly Luk`yanov, Dmytro Golyachenko, N. Voloshin, R. Grill
{"title":"Diamond-like Carbon Coating in Improving the Perfomance of II-VI Devices","authors":"R. Savkina, Aleksej Smirnov, Anatoly Luk`yanov, Dmytro Golyachenko, N. Voloshin, R. Grill","doi":"10.1109/NAP51477.2020.9309581","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309581","url":null,"abstract":"The primary goal of this paper is to highlight our achievement in the synthesis, characterization and application of DLC films for II-VI-based radiation detector improvement. “Soft” polymer-like a-C:H:N films with a stable adhesive contact to substrate, which is achieved both by lowering in the film stress, and by the additional treatment of the substrate surface with argon plasma, were obtained by PECVD method. We considered ways to adjust the properties of carbon-based materials to create an optical or protective coatings and applied a-C:H:N film as a passivation coating of IR and gamma radiation detectors based on II-VI materials.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"13 1","pages":"01TFC18-1-01TFC18-5"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78933584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rao Hasanain Muzaffar Ali, Mohd. Faraz Alam, K. Khan, Sughra Muzaffar
{"title":"Thermo-electric Impact of Nano-Materials on Transformer Oil and Synthetic Ester Oil","authors":"Rao Hasanain Muzaffar Ali, Mohd. Faraz Alam, K. Khan, Sughra Muzaffar","doi":"10.1109/NAP51477.2020.9309576","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309576","url":null,"abstract":"Transformer oil plays a vital role in the electrical insulation of transformers. It helps lower the operating temperature as well as protect the solid insulation from excess heat. However, due to the inherent meagre thermophysical and chemical properties of transformer oil, the demand for transformer oil based nanofluids becomes a binding need. Nanofluids exhibit innovative and unique properties because of the small size and high surface to volume ratio of the nanomaterials. This makes them a substantial material to be employed in the ongoing research related to the enhancement of thermal conductivity and other electrical properties of conventional fluids. Characteristics of nanoparticles like Brownian motion, interfacial resistance, morphology of suspended nanoparticles and their aggregating behavior has fascinated researchers for a long time now. In this paper, initially the nanomaterials are synthesized using the two-step method. The thermo-physical properties of nanofluids are studied, later on the conducting behavior of nanofluid is tailored by suitably choosing the nanoparticles. Subsequently, the thermal conductivity of nanofluid is discussed taking three different types of conducting and nonconducting metal oxide nanoparticles $(TiO_{2;}Al_{2}O_{3;}Fe2O_{3})$ in terms of their concentration. The prepared nano-fluids are used for calculating insulation resistance, dissipation factor and thermal conductivity in the temperature range of $20^{circ}{C}$ upto $80^{circ}{C}$ with a step size increase of $20^{circ}{C}$. The results reveal that these properties of the base fluid get enhanced with the use of nanoparticles resulting in the efficacy enhancement of insulation oil.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"71 1","pages":"02IT06-1-02IT06-5"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87806668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stain Etching and Elemental Composition of Nanostructured Silicon","authors":"M. Melnichenko, K. Svezhentsova","doi":"10.1109/NAP51477.2020.9309658","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309658","url":null,"abstract":"Nanostructured silicon layers were obtained by stain etching (chemical etching) of initial and textured monocrystalline silicon. The surface morphology of nanostructured silicon was studied using a scanning electron microscope and a scanning tunneling microscope. The ratio of chemical elements on the surface and at a depth of nanostructured silicon layers was studied by electron Auger spectroscopy. It is shown that depending on the etchant composition and the concentration ratio of its components, there is a significant change in the elemental composition distribution of nanostructured silicon. The latter is crucial for optimizing the formation modes of nanostructured silicon layers with preset properties.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"17 1","pages":"01TFC01-1-01TFC01-4"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72680103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Terebilenko, O. Alekseev, M. Lazarenko, S. Nedilko, M. Slobodyanik, V. Boyko, V. Chornii
{"title":"Luminescent Bi-containing Phosphate-Molybdate Glass-Ceramics","authors":"K. Terebilenko, O. Alekseev, M. Lazarenko, S. Nedilko, M. Slobodyanik, V. Boyko, V. Chornii","doi":"10.1109/NAP51477.2020.9309625","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309625","url":null,"abstract":"The procedure of preparation of luminescent glass-ceramics consisting of 37.09K2 O-31.79$mathrm{P}_{2}mathrm{O}_{5-}$25.43Mo$mathrm{O}_{3-}$5.69B$mathrm{i}_{2}mathrm{O}_{3}$ glass and KB$mathrm{i}_{0.95}$Eu(MoO4)2 was described. The results of powder X-ray diffraction, scanning electron microscopy, thermo-gravimetrical analysis and luminescence spectroscopy studies have been discussed from viewpoint of the studied materials application in white light emitting diodes. It was found that glass-ceramics consist mainly of amorphous phase with inclusion of potassium bismuth molybdate micro/nanocrystals. The glass transition temperatures were determined as 333, 340 and 327°C for initial glass, Eu-doped glass and glass-ceramics studied, respectively. The initial glass reveals wide luminescence band that lies in 500 -- 750 nm spectral range under excitation at 473 nm at room temperature. Europium-doped glass and glass-ceramics samples mainly reveal luminescence bands of $f-f$ transitions in $mathrm{E}mathrm{u}^{3+}$ ions. The broadening of $mathrm{E}mathrm{u}^{3+}$ emission bands in glassceramic samples was ascribed to migration of some rare-earth ions from crystalline component into glass host.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"53 1","pages":"01NSSA11-1-01NSSA11-4"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74951636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Forcellese, T. Mancia, M. Simoncini, L. Greco, M. Pieralisi
{"title":"Buckling Behavior of Isogrid Composite Structures Obtained by Fused Deposition Modeling Technique","authors":"A. Forcellese, T. Mancia, M. Simoncini, L. Greco, M. Pieralisi","doi":"10.1109/NAP51477.2020.9309572","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309572","url":null,"abstract":"The Filament Deposition Modeling process was performed to additively manufacture different isogrid structures in reinforced polyamide with 20% in weight of short carbon fibers. Specifically, six different isogrid configurations were 3D printed by changing the rib thickness and rib width of the structures. The isogrid structures were subsequently tested under compression load in order to investigate the effect of geometric parameters on the buckling behavior, in terms of strength and specific strength. It has been observed that, depending on the geometry, isogrid structures exhibit different failure modes due to the global and local buckling. The configurations that are characterized by the highest strength are not the same of those giving the highest specific strength.","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"48 1","pages":"02SAMA12-1-02SAMA12-4"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86054019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Lesyk, V. Dzhemelinskyi, B. Mordyuk, S. Martínez, O. Stamann, A. Lamikiz
{"title":"Surface Polishing of Laser Powder Bed Fused Superalloy Components by Magnetic Post-treatment","authors":"D. Lesyk, V. Dzhemelinskyi, B. Mordyuk, S. Martínez, O. Stamann, A. Lamikiz","doi":"10.1109/NAP51477.2020.9309600","DOIUrl":"https://doi.org/10.1109/NAP51477.2020.9309600","url":null,"abstract":"The laser powder bed fusion (LPBF) process is one of an additive manufacturing method for the production of complexly shaped parts, which suffer from a rough surface, excessive residual porosity, and tensile residual stress in the near-surface layer. The magnetic polishing can be applied to improve the surface characteristics of complexly shaped and small-sized LPBF-built parts. This paper focuses on a study of the effect of magnetic treatment on the surface roughness, porosity, and hardness of Inconel 718 alloy parts printed by LPBF. The defects on the surface were also analyzed. Results indicated that applied magnetic polishing leads to a decrease in the surface roughness. The spherical or ellipsoidal balls and partially melted powder particles were successfully removed from the treated surface by magnetic treatment. The surface hardness was increased by about 20% in comparison with that of the LPBF-built specimen (32.2 HRC}$_{mathbf{10}}$).","PeriodicalId":6770,"journal":{"name":"2020 IEEE 10th International Conference Nanomaterials: Applications & Properties (NAP)","volume":"89 1","pages":"02SAMA17-1-02SAMA17-4"},"PeriodicalIF":0.0,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83879635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}