用可编程温度质谱法研究鸵鸟蛋壳的微纳米结构特征

O. Bordunova, V. Loboda, R. Dolbanosova, P. Danylchenko, S. Danilchenko, V. Chivanov, Vjacheslav Popsui, A. Stepanenko, O. I. Ivanova
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引用次数: 1

摘要

对鸵鸟蛋壳全样和破片的热破坏率随加热温度的变化曲线(热图)进行了分析。结果表明,热图的复杂特征主要是由于蛋壳各个形态成分的破坏速度不同所致。在特定温度下,作为蛋壳热破坏的产物,蛋壳的每个微纳米结构形态成分(乳状层,栅栏层和结晶层)在二氧化碳(CO2)的整体产量中的比较贡献被显示。计算了各壳层组分的活化能(Ea)。为发展蛋壳的纳米和微观结构成分分析方法奠定了理论基础。提出了采用温度可编程质谱法(TPD-MS)评价工业化家禽养殖场食品和孵化蛋质量的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Study of Micro - and Nanostructure Characteristics of Ostrich (Struthio camelus) Eggshell by the Method of Temperature-Programmable Mass Spectrometry
The analysis of curves of the dependence of thermal destruction rate vs. temperature at heating (thermogram) of whole samples and fragments of ostrich (Struthio camelus) eggshell was carried out. It was shown that the complex character of the thermograms is mainly due to the difference in the rate of destruction of individual morphological components of the eggshell. The comparative contribution of each micro-nanostructural morphological components of the eggshell (mamillary, palisade, and crystalline layers) in the integral yield of carbon dioxide (CO2) as a product of eggshell thermal destruction at specific temperatures was shown. The activation energies (Ea) for individual shell components were calculated. The theoretical foundations for the development of the method for the analysis of nano- and microstructural components of eggshells have been developed. It is proposed to use the temperature-programmable mass spectrometry (TPD-MS) method to assess the quality of food and hatching eggs in industrial poultry farming.
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