Journal of Superconductivity and Novel Magnetism最新文献

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A Novel Method for Identifying the Magnetic Interaction and Reversal Mechanisms in Nickel Nanowires Using FORC Diagrams and Micromagnetic Slicing 利用FORC图和微磁切片识别镍纳米线磁相互作用和反转机制的新方法
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-25 DOI: 10.1007/s10948-025-06958-z
Yaqi Jiang, Jiaqi Feng, Guoqing Liu, Zixuan Chen, Qin Xu, Junmeng Zhang, Guangyu Wen, Peipei Lu, Lihu Liu, Huiyuan Sun
{"title":"A Novel Method for Identifying the Magnetic Interaction and Reversal Mechanisms in Nickel Nanowires Using FORC Diagrams and Micromagnetic Slicing","authors":"Yaqi Jiang,&nbsp;Jiaqi Feng,&nbsp;Guoqing Liu,&nbsp;Zixuan Chen,&nbsp;Qin Xu,&nbsp;Junmeng Zhang,&nbsp;Guangyu Wen,&nbsp;Peipei Lu,&nbsp;Lihu Liu,&nbsp;Huiyuan Sun","doi":"10.1007/s10948-025-06958-z","DOIUrl":"10.1007/s10948-025-06958-z","url":null,"abstract":"<div><p>In this work, 1-D nickel nanowires with different diameters were synthesized. Magnetic properties of the products were investigated by using first-order reversal curves (FORC) experimental testing, and magnetization reversal processes were theoretically simulated based on the Object Oriented Micro Magnetic Framework (OOMMF) software. The experimental results show different shapes of FORC patterns, indicating the influence of the diameter on the magnetization switching processes of the nanowires. Micromagnetic simulations were carried out on a model of two parallel cylindrical nanowire systems, and the simulation results indicated that both the shape anisotropy and magnetostatic interactions played important roles in identifying the magnetization reversal processes. Furthermore, by means of micromagnetic slicing, the real time distribution status of magnetic moments in the two parallel nickel nanowires had been illustrated visually, which showed that the magnetization reversal process in the two parallel nanowires were different especially in the <i>x</i> and <i>y</i> directions, although of the same objective condition.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On Trapped Flux in a Small Crystal of CaKFe(_4)As(_4) and Implications for High-Pressure Hydrides CaKFe (_4) As (_4)小晶体中的捕获通量及其对高压氢化物的影响
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-25 DOI: 10.1007/s10948-025-06948-1
J. E. Hirsch, F. Marsiglio
{"title":"On Trapped Flux in a Small Crystal of CaKFe(_4)As(_4) and Implications for High-Pressure Hydrides","authors":"J. E. Hirsch,&nbsp;F. Marsiglio","doi":"10.1007/s10948-025-06948-1","DOIUrl":"10.1007/s10948-025-06948-1","url":null,"abstract":"<div><p>In recent work (Bud’ko et al. Supercond. Sci. Technol. <b>37</b>, 065010 2024), Bud’ko et al. present experimental results for trapped magnetic flux for a tiny sample of a type II superconductor, <span>(CaKFe_4As_4)</span>. The paper aims to provide evidence in support of the interpretation that similar measurements performed in samples of hydrogen-rich materials under high pressure by Minkov et al. (Nat. Phys. <b>19</b>, 1293 2023) are conclusive evidence (Eremets Nat. Sci. Rev. <b>11</b>, nwae047 2024) for superconductivity in hydrides under pressure. Here, we point out that the new evidence presented by Bud’ko et al. (Supercond. Sci. Technol. <b>37</b>, 065010 2024) further supports our interpretation (Hirsch and Marsiglio J. Supercond. Nov. Magn. <b>35</b>, 3141–3145 2022; Hirsch and Marsiglio Phys. C <b>620</b>, 1354500 2024) that the reported measurements of trapped flux on hydrides under pressure (Minkov et al. Nat. Phys. <b>19</b>, 1293 2023) are not consistent with what would be expected from a superconducting sample.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10948-025-06948-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mean-Field Study of Magnetic Properties and Magnetocaloric Effect in Iron(III) Nitride-Based Antiperovskite Materials 氮化铁基反钙钛矿材料磁性能和磁热效应的平均场研究
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-21 DOI: 10.1007/s10948-025-06957-0
M. Salama, H. Kerrai, H. Saadi, E. M. Jalal, N. Hachem, E. B. Choubabi, M. El Bouziani
{"title":"Mean-Field Study of Magnetic Properties and Magnetocaloric Effect in Iron(III) Nitride-Based Antiperovskite Materials","authors":"M. Salama,&nbsp;H. Kerrai,&nbsp;H. Saadi,&nbsp;E. M. Jalal,&nbsp;N. Hachem,&nbsp;E. B. Choubabi,&nbsp;M. El Bouziani","doi":"10.1007/s10948-025-06957-0","DOIUrl":"10.1007/s10948-025-06957-0","url":null,"abstract":"<div><p>We investigated the magnetic, magnetocaloric, and hysteresis characteristics of the antiperovskite material Fe<span>(_{3})</span>ZnN by employing the mean-field approximation method. The findings indicate that magnetization gradually declines with rising temperature, whereas the application of an external magnetic field elevates the critical temperature <span>(T_{c})</span> by promoting greater alignment of the magnetic moments. A peak in the magnetic entropy change <span>(-Delta S_{m})</span>, at <span>(T_{c})</span>, indicating a significant magnetocaloric effect, ideal for magnetic refrigeration applications. Additionally, the relative cooling power (RCP) exhibits a linear increase with the strength of the magnetic field. The hysteresis analysis reveals a gradual decrease in coercivity and remanence with rising temperature, ultimately leading to the disappearance of the hysteresis loop above <span>(T_{c})</span>, signaling a transition to the paramagnetic phase. These findings suggest that the Fe<span>(_{3})</span>ZnN compound holds promise as a candidate material for magnetic refrigeration applications.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143667987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pressure-Induced Flat Bands and Electride Behavior in SC Mg SC Mg中压力诱导的平带和电化物行为
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-17 DOI: 10.1007/s10948-025-06947-2
Sabri F. Elatresh
{"title":"Pressure-Induced Flat Bands and Electride Behavior in SC Mg","authors":"Sabri F. Elatresh","doi":"10.1007/s10948-025-06947-2","DOIUrl":"10.1007/s10948-025-06947-2","url":null,"abstract":"<div><p>The high-pressure phase diagram of Magnesium (Mg) has attracted significant attention due to its relevance as a constituent of Earth’s inner core (IC), where it profoundly influences physical behavior and properties under extreme conditions. A recent study has revealed multiple crystal structure transitions in Mg, including the emergence of non-close-packed phases at extreme pressures. We investigate the electronic structure of simple cubic (SC) Mg under extreme pressure using Density Functional Theory (DFT) calculations. At 1320 GPa, our analysis shows that charge density accumulates at the center of the unit cell, increasing as pressure rises. The electron localization function (ELF) reveals that electrons are not just confined to atomic sites but also extend into interstitial regions, suggesting a shift in bonding character driven by <i>p</i>-<i>d</i>-orbital contributions. Additionally, the electronic band structure and density of states (DOS) confirm that Mg remains metallic at this pressure. A distinct flat band appears along the X-M path in the Brillouin zone, indicating enhanced electronic correlations that could influence the transport properties of Mg. These results highlight how extreme compression reshapes electronic interactions, potentially leading to novel high-pressure phenomena.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlation Between Local Structure and Interlayer Coupling Through Fluctuations-Induced Conductivity in La0.7Sr0.3MnO3-Added (Bi, Pb)-2223 Superconductors la0.7 sr0.3 mno3 -添加(Bi, Pb)-2223超导体中波动诱导电导率的局域结构与层间耦合关系
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-17 DOI: 10.1007/s10948-025-06956-1
Muhammad A. Anugrah, Jun-Yung Oh, Rico P. Putra, Byeongwon Kang
{"title":"Correlation Between Local Structure and Interlayer Coupling Through Fluctuations-Induced Conductivity in La0.7Sr0.3MnO3-Added (Bi, Pb)-2223 Superconductors","authors":"Muhammad A. Anugrah,&nbsp;Jun-Yung Oh,&nbsp;Rico P. Putra,&nbsp;Byeongwon Kang","doi":"10.1007/s10948-025-06956-1","DOIUrl":"10.1007/s10948-025-06956-1","url":null,"abstract":"<div><p>In this study, we investigated the relationship between excess conductivity and the local structure of Bi<sub>1.6</sub>Pb<sub>0.4</sub>Sr<sub>2</sub>Ca<sub>2</sub>Cu<sub>3</sub>O<sub>10+δ</sub> ((Bi, Pb)-2223) polycrystalline samples. A series of (Bi, Pb)-2223 + LSMO composites (0 – 1.5 wt%) were synthesized using the conventional solid-state reaction method. The critical temperature (<i>T</i><sub><i>c</i></sub>) determined from the temperature-dependent resistivity curves decreased with increasing LSMO content, from 106.65 K for the pure sample to 102.48 K to the 15 wt% sample, except for the 10 wt% sample, which exhibited a rise comparable to the pure sample. To elucidate the mechanisms affecting <i>T</i><sub><i>c</i></sub>, we applied the Aslamazov-Larkin (AL) and Lawrence-Doniach (LD) theories. We identified the Lawrence-Doniach temperature (<i>T</i><sub><i>LD</i></sub>) as the crossover point at which the system transitions from 2 to 3D fluctuations in the mean field region (MFR). Our calculations of excess conductivity within the MFR enabled us to quantify microscopic parameters such as the coherence length along the c-axis (<span>({xi }_{c})</span>), interlayer coupling strength (<span>(J)</span>), and interlayer coupling distance (<span>(d)</span>), revealing trends in <i>T</i><sub><i>c</i></sub> associated with LSMO addition in the (Bi, Pb)-2223 system. The local atomic structure of the CuO<sub>2</sub> plane was characterized using X-ray absorption fine structure measurements at the Cu K-edge. We observed contrasting behaviors between the Cu–O and Cu-Ca bonds, indicating weakened interaction between the CuO<sub>2</sub> superconducting layer and the space layer. Meanwhile, the Cu-Sr bond exhibited suppression or elongation due to LSMO addition. Notably, in the 10 wt% sample, the bond lengths from the absorbing atom were similar to those in the pure sample, suggesting an inhomogeneous distribution of LSMO in the samples. These findings indicate that local structural alterations due to LSMO addition decrease the carrier supply to the CuO<sub>2</sub> layers, thereby affecting the superconducting properties of the (Bi, Pb)-2223 system.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Crystal Structure, and Magnetic Characterization on a Frustrated S = 1 Magnet KNi(PO3)3 挫折S = 1磁体KNi(PO3)的合成、晶体结构和磁性表征
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-17 DOI: 10.1007/s10948-024-06884-6
Xiaofeng Li, Yuxia Gao, Zhaoming Tian, Weijie Ren, Xin Sun, Mingli Wang
{"title":"Synthesis, Crystal Structure, and Magnetic Characterization on a Frustrated S = 1 Magnet KNi(PO3)3","authors":"Xiaofeng Li,&nbsp;Yuxia Gao,&nbsp;Zhaoming Tian,&nbsp;Weijie Ren,&nbsp;Xin Sun,&nbsp;Mingli Wang","doi":"10.1007/s10948-024-06884-6","DOIUrl":"10.1007/s10948-024-06884-6","url":null,"abstract":"<div><p>KNi(PO<sub>3</sub>)<sub>3</sub> was successfully synthesized by solid-state method and the magnetic properties were characterized. The crystal structure of KNi(PO<sub>3</sub>)<sub>3</sub> belongs to trigonal crystal system with space group <i>R</i>3, where Ni<sup>2+</sup> ions form the distorted honeycomb-lattice within the ab-plane stacking in the “ABAB” type fashion along the <i>c</i>-axis. Magnetization measurements reveal the presence of antiferromagnetic (AFM) interaction with Curie Weiss (CW) temperature θ<sub>CW</sub> =  − 12.905 K but without long-range magnetic order down to 2 K. Notably, the CW fitted effective moment µ<sub>eff</sub> = 3.35µ<sub>B</sub> and saturated magnetization <i>M</i><sub>S</sub> = 2<i>μ</i><sub>B</sub>/Ni<sup>2+</sup> at 2 K support KNi(PO<sub>3</sub>)<sub>3</sub> as an <i>S</i> = 1 spin system. Intriguingly, the zero-field specific heat exhibits a broad peak maximized at ~ 2.5 K indicating the onset of short-range spin correlation between Ni<sup>2+</sup> ions, while the integrated magnetic entropy (<i>S</i><sub>mag</sub>) is close to the expected Rln3 for <i>S</i> = 1 system, indicative of large spin fluctuation below 2 K driven by spin frustration.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143638294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterizations of Arsenic Doped FeSe Bulks 掺砷FeSe块体的合成与表征
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-15 DOI: 10.1007/s10948-025-06952-5
Priya Singh, Manasa Manasa, Mohammad Azam, Tatiana Zajarniuk, Konrad Kwatek, Tomasz Cetner, Andrzej Morawski, Jan Mizeracki, Shiv J. Singh
{"title":"Synthesis and Characterizations of Arsenic Doped FeSe Bulks","authors":"Priya Singh,&nbsp;Manasa Manasa,&nbsp;Mohammad Azam,&nbsp;Tatiana Zajarniuk,&nbsp;Konrad Kwatek,&nbsp;Tomasz Cetner,&nbsp;Andrzej Morawski,&nbsp;Jan Mizeracki,&nbsp;Shiv J. Singh","doi":"10.1007/s10948-025-06952-5","DOIUrl":"10.1007/s10948-025-06952-5","url":null,"abstract":"<div><p>FeSe(11) family has a simple crystal structure belonging to iron-based superconductors (FBS) and has many stable phases including hexagonal and tetragonal structures, but only the tetragonal phase exhibits the superconductivity. In this study, we have investigated the effects of chemical pressure induced by As-doping at Se sites in the FeSe system by preparing a series of FeSe<sub>1-<i>x</i></sub>As<sub><i>x</i></sub> (<i>x</i> = 0.005, 0.01, 0.02, 0.05, 0.1 and 0.2) bulks. A broad characterization has been performed on these samples using structural, microstructural, transport and magnetic measurements. The obtained lattice parameters are increased by As-doping, which suggests the successful insertion of As at Se sites into the tetragonal lattice for low doping contents up to 5%, whereas the higher As substitution appears in the form of the FeAs impurity phase. The temperature dependence of the resistivity of all samples has similar behaviour and depicts the highest onset transition temperature of around 11.5 K, but the zero resistivity is not reached until the measured temperature of 7 K, which could be due to the presence of the impurity phases. Our study suggests that a dopant with a large ionic radius, i.e. arsenic, promotes the formation of the hexagonal phase of the 11 family and is effective for a small amount of doping level for the superconducting properties, whereas higher As-doping levels reduce the superconducting properties.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, Electronic, Optical, and Magnetic Properties of Gadolinium (Gd) doped Indium Aluminium Nitride (InAlN): a DFT Study 钆(Gd)掺杂铟铝氮化(InAlN)的结构、电子、光学和磁性能:DFT研究
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-14 DOI: 10.1007/s10948-025-06951-6
Sahil Soni, Dharamvir Singh Ahlawat
{"title":"Structural, Electronic, Optical, and Magnetic Properties of Gadolinium (Gd) doped Indium Aluminium Nitride (InAlN): a DFT Study","authors":"Sahil Soni,&nbsp;Dharamvir Singh Ahlawat","doi":"10.1007/s10948-025-06951-6","DOIUrl":"10.1007/s10948-025-06951-6","url":null,"abstract":"<div><p>In this research, the structural, electronic, optical, and magnetic characteristics of InAlN and Gd-doped InAlN were analyzed using the PBE-GGA and GGA + U method respectively. A first principle investigation using density functional theory (DFT) has been conducted to examine for these properties. The formation energy calculations indicate that the Gd atom preferentially substitutes for the In site. The lattice parameters of the InAlN alloy increase upon doping with Gd due to the larger ionic radius. Compared to InAlN, the Gd-doped InAlN becomes an indirect band gap semiconductor with a reduced band gap. Within the GGA + U framework, the total magnetic moment is precisely characterized by an integer value. Due to the presence of partially filled 4<i>f</i> electrons in Gd, the magnetic moment 6.85 <span>({mu }_{B})</span> primarily originates from the Gd atom, with minimal contributions from the In, Al, and N atoms. The calculations of optical properties revealed that Gd-doped InAlN exhibit high absorption rate in the UV region. The real and imaginary parts of the dielectric function, as well as the refractive index and extinction coefficient, have been calculated and displayed for photon energy up to 14 eV. This theoretical analysis may aid in the design of new optoelectronic devices and future solar cell generations.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Structural, Electrical Conductivity, Magnetic, and Electrochemical Properties of La-Doped Zinc Manganite la掺杂锌锰矿结构、电导率、磁性和电化学性能的影响
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-12 DOI: 10.1007/s10948-025-06930-x
A. Viji, K. Vanasundari, R. Vijayakumar, A. Prakasam
{"title":"Effect of Structural, Electrical Conductivity, Magnetic, and Electrochemical Properties of La-Doped Zinc Manganite","authors":"A. Viji,&nbsp;K. Vanasundari,&nbsp;R. Vijayakumar,&nbsp;A. Prakasam","doi":"10.1007/s10948-025-06930-x","DOIUrl":"10.1007/s10948-025-06930-x","url":null,"abstract":"<div><p>Sol–gel auto combustion was used to create polycrystalline ZnMn<sub>2-x</sub>La<sub>x</sub>O<sub>4</sub> nanoparticles, where <i>x</i> = 0.0, 0.05, 0.1, and 0.15 zinc manganite. La concentration, structural, electrical conductivity, magnetic, and electrochemical properties were found to be strongly correlated. ZnMn<sub>2</sub>O<sub>4</sub> and other manganese-rich spinels have a tetragonal spinel structure due to the octahedral MnO<sub>6</sub> unit’s Jahn–Teller distortion. ZnMn<sub>2-x</sub>La<sub>x</sub>O<sub>4</sub> oxides progressively change to a cubic spinel structure as more La occurs in the place of manganese. Expanding La substitution causes the lattice parameter <i>c</i> to drop from 9.2178 to 9.2158 A° and the lattice parameter <i>a</i> = <i>b</i> to rise from 5.6869 to 5.9107 A°. For rare-earth dopants such as lanthanum, substitution doping is necessary due to their (La) large ionic radii in comparison to manganese and zinc. Smaller particles would form as a result of doping materials like La form Zn and Mn, which would change particle mobility. Differences between zinc manganite and zinc manganite doped with La may be due to lattice strain and structural disorder. The conductivity value from both pure and (0.15%) doped samples rises from 16.46 × 10<sup>−4</sup> S cm<sup>−1</sup> to 323.89 × 10<sup>−4</sup> S cm<sup>−1</sup> with increasing La substitution. The enhanced electrochemical performance is caused by the formation of a La doped ZnMn<sub>2</sub>O<sub>4</sub> which can suppress the volume expansion during the charge–discharge process.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143594832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Competing Magnetic Interactions in the Antiferromagnetic Kagome Semimetal Fe(_{1-y})Co(_y)Sn 反铁磁性Kagome半金属Fe (_{1-y}) Co (_y) Sn的竞争磁相互作用
IF 1.6 4区 物理与天体物理
Journal of Superconductivity and Novel Magnetism Pub Date : 2025-03-11 DOI: 10.1007/s10948-025-06943-6
Kritika Vijay, Kranti Kumar, Soma Banik
{"title":"Competing Magnetic Interactions in the Antiferromagnetic Kagome Semimetal Fe(_{1-y})Co(_y)Sn","authors":"Kritika Vijay,&nbsp;Kranti Kumar,&nbsp;Soma Banik","doi":"10.1007/s10948-025-06943-6","DOIUrl":"10.1007/s10948-025-06943-6","url":null,"abstract":"<div><p>Antiferromagnetic Kagome semimetal FeSn has gained significant attention due to the presence of topological flat bands and Dirac fermions. There has been immense interest to tune the bands with doping in FeSn for enhancing the magnetic and transport properties. Here, we report an experimental study of transport, magnetization, and electronic structure of Fe<span>(_{1-y})</span>Co<span>(_y)</span>Sn as a function of Co-doping concentration (<i>y</i>). Variation in the temperature-dependent resistivity with increasing <i>y</i> is associated with the increase in spin-dependent scattering. Co doping in FeSn gives rise to canted antiferromagnetism with the decrease in the Neel transition temperature (<span>(T_{N})</span>). The local moment of Co and Fe atoms has been estimated from the analysis of 3<i>s</i> core levels. The decrease in <span>(T_{N})</span> with increasing <i>y</i> is due to the decrease in the local moment of Fe atoms. The systematic shift in the valence states away from the Fermi level (<span>(E_{F})</span>), and the valence band broadening with the increase in <i>y</i> indicate an increase in the electron correlation and hybridization effects in Fe<span>(_{1-y})</span>Co<span>(_y)</span>Sn. An increase in both electron correlation and hybridization with doping leads to the strong magnetic interaction between the local moments of Fe and Co atoms which gives rise to the canted antiferromagnetism in Fe<span>(_{1-y})</span>Co<span>(_y)</span>Sn.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 2","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10948-025-06943-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143594805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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