Journal of Solution Chemistry最新文献_第10页

Measurement and Prediction of Phase Equilibria of Quaternary System LiCl–KCl–SrCl2–H2O at 273.2 K and its Applications 273.2 K 下 LiCl-KCl-SrCl2-H2O 四元体系相平衡的测量和预测及其应用

IF 1.4 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-28 DOI: 10.1007/s10953-023-01328-6

Hu Chen, Shi-Hua Sang, Chun-Xia He, Xiao-Feng Guo, Hong-Bao Ren

{"title":"Measurement and Prediction of Phase Equilibria of Quaternary System LiCl–KCl–SrCl2–H2O at 273.2 K and its Applications","authors":"Hu Chen, Shi-Hua Sang, Chun-Xia He, Xiao-Feng Guo, Hong-Bao Ren","doi":"10.1007/s10953-023-01328-6","DOIUrl":"10.1007/s10953-023-01328-6","url":null,"abstract":"<div>The underground brines in the Sichuan Basin of China are rich in lithium, potassium, strontium, chlorine, etc. In order to fully develop and utilize these brine resources, it is necessary to carry out phase equilibrium research about the quaternary system LiCl–KCl–SrCl2–H2O and develop a reasonable lithium extraction process. The quaternary system LiCl–KCl–SrCl2–H2O at 273.2 K were determined using the isothermal dissolution equilibrium method. As a result, the corresponding phase diagrams were drawn based on the data. The phase diagram shows that the quaternary system LiCl–KCl–SrCl2–H2O has no double salt or solid solution at 273.2 K and there are two invariant points, five univariate curves and four solid phase crystallization fields, which are LiCl·2H2O, SrCl2·2H2O, SrCl2·6H2O and KCl. Furthermore, Pitzer’s model was used to predict the solubility of salts in the quaternary system. The calculated values are in good agreement with the experimental ones. Finally, combined with isothermal evaporation method and the phase diagram of the quaternary system, a brine evaporation process was designed.\u0000</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"53 2","pages":"294 - 313"},"PeriodicalIF":1.4,"publicationDate":"2023-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136233726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

[(EtO)3Si(CH2)3N+H3][CH3COO−] as Basic Ionic Liquid Catalyst Promoted Green Synthesis of Benzo[a]pyrano[2,3-c]phenazine Derivatives in Homogenous Solution 以[(EtO)3Si(CH2)3N+H3][CH3COO-]为碱性离子液体催化剂在均相溶液中促进苯并[a]吡喃并[2,3-c]吩嗪衍生物的绿色合成

IF 1.4 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-26 DOI: 10.1007/s10953-023-01332-w

Farhad Shirzaei, Hamid Reza Shaterian

引用次数: 0

Binary and Ternary Oxovanadium (IV) Complexes with Picolinic Acid and Some Potentially Bidentate Amino Acids Studied by Potentiometric Measurements in 1.0 mol·dm−3 NaCl at 25 °C 在 25 °C 的 1.0 mol-dm-3 NaCl 溶液中通过电位测量法研究吡啶甲酸和一些潜在双齿氨基酸与氧化钒 (IV) 的二元和三元络合物

IF 1.4 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-23 DOI: 10.1007/s10953-023-01331-x

Sabrina Rodríguez, Mary Lorena Araujo, Edgar Del Carpio, Lino Hernández, Vito Lubes

引用次数: 0

Volumetric and Dielectric Properties in Liquid Phase of Dimethyl Ether–Ethanol at (293.2–313.2) K and 1.00 MPa 二甲醚-乙醇在 (293.2-313.2) K 和 1.00 MPa 下的液相体积特性和介电特性

IF 1.4 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-21 DOI: 10.1007/s10953-023-01329-5

Taka-aki Hoshina, Kazunori Sato, Masaki Okada, Tomoya Tsuji, Toshihiko Hiaki

{"title":"Volumetric and Dielectric Properties in Liquid Phase of Dimethyl Ether–Ethanol at (293.2–313.2) K and 1.00 MPa","authors":"Taka-aki Hoshina, Kazunori Sato, Masaki Okada, Tomoya Tsuji, Toshihiko Hiaki","doi":"10.1007/s10953-023-01329-5","DOIUrl":"10.1007/s10953-023-01329-5","url":null,"abstract":"<div>Density and dielectric spectra have been measured in the liquid phase of dimethyl ether (DME)–ethanol by an oscillating U-tube densimeter and a complex dielectric spectrometer under 1.00 MPa. The density was measured at 303.15 and 313.15 K and converted to the excess molar volume. The excess molar volumes were no smaller than − 0.880 and − 0.909 cm3·mol–1 at 303.15 and 313.15 K, respectively. The mole fraction dependence can be correlated with the Redlich–Kister equation, whose minimum was found to be around 0.58 for the mole fraction of DME. The dielectric constant and the dielectric relaxation time were evaluated from the complex dielectric spectra in the frequency range from 0.5 to 18 GHz at (293.2–313.2) K and 1.00 MPa. The dielectric constants and the relaxation time were decreased with the mole fraction of DME, and the latter tended to be around 25 ps in the mole fraction range higher than 0.6. The logarithmic dielectric constants can be correlated with a similar function to the Hildebrand equation with the volume fraction. The effective Kirkwood g-factor was evaluated at 293.2–313.2 K and 1.00 MPa. The g-factors were given by two linear functions crossed around 0.6 for the mole fraction of DME. Considering an atomic composition (C2H6O), the molecular sizes are not so different for DME and ethanol. Then, the solution structure was thought to be microscopically changed around 0.6 for the mole fraction of DME. The mole fraction will be utilized to switch the solubility to extract amphipathic compounds.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"53 2","pages":"278 - 293"},"PeriodicalIF":1.4,"publicationDate":"2023-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135512085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigations on the Thermophysical Properties of Binary Systems of Fatty Acid Esters + Dimethyl Carbonate 脂肪酸酯+碳酸二甲酯二元体系的热物理性质研究

IF 1.4 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-07 DOI: 10.1007/s10953-023-01327-7

Xiang Gao, Biyuan Hong, Meiyu Zhang, Dan Li

引用次数: 0

Response to Comment on “Thermodynamic Data for Sn(IV) Species in Aqueous Solution: A Matter of Controversy and Error” (https://doi.org/10.1007/s10953-023-01323-x) 对“水溶液中Sn（IV）物种的热力学数据：一个有争议和错误的问题”评论的回应(https://doi.org/10.1007/s10953-023-01323-x)

IF 1.2 4区化学

Journal of Solution Chemistry Pub Date : 2023-10-07 DOI: 10.1007/s10953-023-01330-y

Peter M. May, Montserrat Filella

引用次数: 0

Ultrasonic and Conductometric Studies on l-Aspartic Acid and l-Glutamic Acid in Aqueous Solutions of Sodium Acetate 乙酸钠水溶液中l-天冬氨酸和l-谷氨酸的超声和电导研究

IF 1.2 4区化学

Journal of Solution Chemistry Pub Date : 2023-09-27 DOI: 10.1007/s10953-023-01321-z

Kshirabdhitanaya Dhal, Sulochana Singh, Malabika Talukdar

{"title":"Ultrasonic and Conductometric Studies on l-Aspartic Acid and l-Glutamic Acid in Aqueous Solutions of Sodium Acetate","authors":"Kshirabdhitanaya Dhal, Sulochana Singh, Malabika Talukdar","doi":"10.1007/s10953-023-01321-z","DOIUrl":"10.1007/s10953-023-01321-z","url":null,"abstract":"<div>l-Aspartic acid (ASP) and l-glutamic acid (GLU) in aqueous solution of a food additive, sodium acetate (SA) have been taken for acoustic and conductometric studies. The experimental results are analysed to predict and assess the solvation behaviour and types of interactions occurring in these ternary solutions [ASP/GLU + SA + water]. Compressibility parameters like isentropic compressibility and apparent molar isentropic compressibility along with their values at infinite dilution have been computed. Transfer values and ion pair and triplet interactions have been determined. Other thermodynamic parameters like internal pressure, molar free volume, relative association and acoustic impedance, have also been derived from the acoustic data. Specific conductance values measured experimentally led to the calculation of molar conduction of electric charge. Walden product sheds light on structure building or breaking properties of the amino acids. Gibbs thermodynamic functions predict the spontaneity of ion association process. Arrhenius equation is used to calculate activation energy which is indicative of the formation of high-energy transition state required for migration of ions. Analysis of these results establishes the amino acids as water-structure forming agents and predominance of ion–solvent, ion–ion and ion–hydrophilic interactions in the studied systems.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"52 12","pages":"1415 - 1445"},"PeriodicalIF":1.2,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41228893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multimers of 1-Propanol and their Heteromolecular Hydrogen Bonds with Ethyl Acetate: Fourier Transform Infrared Spectral Studies 1-丙醇多聚体及其与乙酸乙酯的杂分子氢键的傅立叶变换红外光谱研究

IF 1.2 4区化学

Journal of Solution Chemistry Pub Date : 2023-09-25 DOI: 10.1007/s10953-023-01325-9

R. Sahana, P. Mounica, K. Ramya, G. Arivazhagan

引用次数: 0

Comment on “Thermodynamic Data for Sn(IV) Species in Aqueous Solution: Matter of Controversy and Error” 对“水溶液中Sn（IV）物种的热力学数据：争议和错误的问题”的评论

IF 1.2 4区化学

Journal of Solution Chemistry Pub Date : 2023-09-21 DOI: 10.1007/s10953-023-01323-x

Dhanpat Rai

{"title":"Comment on “Thermodynamic Data for Sn(IV) Species in Aqueous Solution: Matter of Controversy and Error”","authors":"Dhanpat Rai","doi":"10.1007/s10953-023-01323-x","DOIUrl":"10.1007/s10953-023-01323-x","url":null,"abstract":"<div>May and Filella (J Solution Chem 52:754–761, 2023) concluded that they had verified the data in Gamsjäger et al. (Chemical thermodynamics of tin OECD, Nuclear Energy Agency Data Bank, Leoben, 2012). However, they used exactly the same primary data and not surprisingly came up with essentially the same values. They (1) provided no new data; (2) did not comment on/re-evaluate the existing experimental data (e.g., Sn–Cl complexes) that determine the accuracy of the E0 value for the (Sn4+/Sn2+) couple, but instead relied on a calculated value that is precise but of questionable accuracy; (3) disregarded extensive cassiterite (SnO2(cass)) solubility data that is critical to (a) ascertaining the accuracy of the E0 value based on ({mathrm{Sn}(mathrm{Cl})}_{y}^{4-mathrm{y}}) complexes presented in Gamsjäger et al. (2012) and May and Filella (2023), (b) determining the solubility product of SnO2(cass), and (c) determining reliable overall K0 values for SnO2(s) solubility reactions involving ({mathrm{Sn}(mathrm{OH})}_{n}^{4-n}) instead of Sn4+; and (4) in no way help resolve the many orders of magnitude differences in reported K0 values for various Sn(IV)–OH system reactions. These issues were extensively addressed in Rai (J Solution Chem.51:1169–1186, 2022) and are briefly discussed herein, and they help to determine that, contrary to May and Filella’s (2023) conclusions, the Sn(IV)–OH system thermodynamic constants presented in Rai (2022) are indeed reliable.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"52 12","pages":"1386 - 1393"},"PeriodicalIF":1.2,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10953-023-01323-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41228947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

“Where to Find Equilibrium Constants?” is Now Continuously Updated and Open “在哪里可以找到平衡常数？”现在不断更新并开放

IF 1.2 4区化学

Journal of Solution Chemistry Pub Date : 2023-09-20 DOI: 10.1007/s10953-023-01324-w

Montserrat Filella, Wolfgang Hummel

引用次数: 0