水、丙烯酸甲酯和不同溶剂三元体系在 303.2 K 和 101.3 kPa 下的液液平衡

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Qingsong Li, Shaohui Jiang, Houchun Yan, Wenyang Fan
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引用次数: 0

摘要

丙烯酸甲酯用途广泛,但在生产过程中通常会产生水性副产物。本研究选择了四种常用的醇类(1-戊醇、1-己醇、1-庚醇和 1-辛醇)作为萃取剂,探讨了水 + 丙烯酸甲酯 + 萃取剂的液液萃取行为。通过对分配系数(D)和分离系数(S)的分析,发现所有体系的数据均大于 1,表明四种烷基醇都能很好地从水溶液中分离出丙烯酸甲酯,其中 1-辛醇的分离效果最好。此外,还利用 Matlab 工具测试了回归数据和平线数据的二元相互作用参数之间的一致性,证明所获得的参数具有良好的一致性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Liquid–Liquid Equilibrium for the Ternary System of Water, Methyl Acrylate, and Different Solvents at 303.2 K under 101.3 kPa

Liquid–Liquid Equilibrium for the Ternary System of Water, Methyl Acrylate, and Different Solvents at 303.2 K under 101.3 kPa

Liquid–Liquid Equilibrium for the Ternary System of Water, Methyl Acrylate, and Different Solvents at 303.2 K under 101.3 kPa

Methyl acrylate has a wide range of uses, but the production process usually produces aqueous by-products. In this study, four commonly used alcohols (1-pentanol, 1-hexanol, 1-heptanol, and 1-octanol) were selected as extractants to explore the liquid–liquid extraction behavior of water + methyl acrylate + extractants. Through the analysis of partition coefficient (D) and separation coefficient (S), it is found that the data of all systems are greater than 1, indicating that all four alkyl alcohols can well separate methyl acrylate from aqueous solution, and 1-octanol is the best. In addition, the consistency between the binary interaction parameters of regression and tie-line data was tested using Matlab tools, proving that the obtained parameters have good consistency.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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