Journal of Solution Chemistry最新文献

Solubilities of Ethylene and Ethane in CuAlCl4 + Toluene Solutions 乙烯和乙烷在CuAlCl4 +甲苯溶液中的溶解度

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-10-06 DOI: 10.1007/s10953-026-01659-0

Radmehr Omidi, Saeed Ovaysi

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Gibbsite Solubility Measurements in NaOH + NaNO3 Solutions at 60 °C, and a Thermodynamic Model for Interactions of Aluminate Ion (Al(OH)4–) with Nitrate 60℃下NaOH + NaNO3溶液中三水铝石溶解度的测定，以及铝酸盐离子（Al(OH)4 -）与硝酸盐相互作用的热力学模型

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-10-05 DOI: 10.1007/s10953-026-01653-6

Yongliang Xiong, Vanessa Mercado, Scott Wood, Yifeng Wang, Guangping Xu

{"title":"Gibbsite Solubility Measurements in NaOH + NaNO3 Solutions at 60 °C, and a Thermodynamic Model for Interactions of Aluminate Ion (Al(OH)4–) with Nitrate","authors":"Yongliang Xiong, Vanessa Mercado, Scott Wood, Yifeng Wang, Guangping Xu","doi":"10.1007/s10953-026-01653-6","DOIUrl":"10.1007/s10953-026-01653-6","url":null,"abstract":"<div>The interactions of aluminate ion (Al(OH)4−) with nitrate are important to numerous fields including nuclear waste management, and extraction of aluminum from bauxite ores. In the field of nuclear waste management, aluminum (Al) is a prevalent component in tank waste sludge phase at various sites, and accounts for high percentages of the total inventory of tank waste sludge. Three predominant Al-bearing solid phases are sodium aluminate [NaAl(OH)4], gibbsite [α-Al(OH)3], and boehmite. Nitrate and nitrite have high concentrations in the supernatant liquids. Therefore, the knowledge of the interactions of aluminum with nitrate and nitrite is important to the realization of a scientifically sound and effective pretreatment approach for tank waste sludge. To gain a deeper knowledge of such interactions, we are conducting systematic experiments coupled with the thermodynamic modeling. In this work, we report our solubility measurements at 60 °C. Based on our experimental data, we develop a thermodynamic model to describe the interactions of aluminate ion with nitrate. Then, the thermodynamic model is tested against the experimental data of gibbsite in mixtures of NaOH and NaNO3 from the literature. Those literature data are not utilized in the model development. The tests show that the values predicted by the model are in good agreement with the experimental data that are independent from the model development.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2857 - 2876"},"PeriodicalIF":1.3,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Micellar and Thermodynamic Study of CPC and SDBS in the Presence of an Anionic Antibiotic Drug Cloxacillin Sodium: A Temperature and Drug Concentration Effect 阴离子抗生素氯西林钠存在下CPC和SDBS的胶束和热力学研究：温度和药物浓度的影响

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-10-04 DOI: 10.1007/s10953-026-01668-z

Ashwani Kumar Sood, Meenu Aggarwal

{"title":"Micellar and Thermodynamic Study of CPC and SDBS in the Presence of an Anionic Antibiotic Drug Cloxacillin Sodium: A Temperature and Drug Concentration Effect","authors":"Ashwani Kumar Sood, Meenu Aggarwal","doi":"10.1007/s10953-026-01668-z","DOIUrl":"10.1007/s10953-026-01668-z","url":null,"abstract":"<div>A study on the micellar and thermodynamic properties of drug-surfactant mixtures is of significant importance in order to achieve optimum therapeutic action of a drug. Therefore, herein, the micellar characteristics of cationic surfactant cetylpyridinium chloride (CPC) as well as anionic surfactant sodium dodecylbenzene sulfonate (SDBS) have been evaluated with the help of conductance measurements in the presence of cloxacillin sodium (CS), an anionic antibiotic drug, at various temperatures ranging from 288.15 to 313.15 K with a step size of 5.0 K. The results indicate that with the increase in the drug concentration, the critical micelle concentration (CMC) of CPC increases continuously, although a decrease in CMC at higher drug concentration (from 2.5 to 10.0 mmol·dm−3) has been observed in case of SDBS. The dissimilar behavior of the two surfactants has been explained on the basis of charges on the head groups and the molecular structure of the drug CS. The variation in CMC for both the surfactants shows a non-linear trend with the increase in temperature and exhibits a U-shaped behavior in case of aqueous and aqueous drug solutions. The values of enthalpy of micellization (∆Hom) and entropy of micellization (∆Som) indicate that drug-surfactant interactions show endothermic behavior (∆Hom > 0) at low temperatures and become exothermic (∆Hom < 0) at higher temperatures. The process of micellization has mostly been entropically favored as evidenced from T∆Som > ∆Hom.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2842 - 2856"},"PeriodicalIF":1.3,"publicationDate":"2026-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Kinetics and Reactivity Correlation in Diol Oxidation by Tetramethyl-Ethylenediammonium Dichromate Across Acetic Acid–Water Compositions 四甲基-重铬酸乙二铵跨乙酸-水组分氧化二醇的动力学及反应性相关性

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-10-03 DOI: 10.1007/s10953-026-01655-4

Dinesh Panday

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Design, Synthesis, and Photophysical Investigation of a Tetrahydrobenzo[h]quinoline Derivative: A Turn-ON Fluorescent Sensor for Zn2+ Ion 四氢苯并[h]喹啉衍生物的设计、合成及光物理研究：Zn2+离子的开启荧光传感器

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-10-02 DOI: 10.1007/s10953-026-01646-5

Suhail Ahmad, Zafer Alam, Salman A. Khan

{"title":"Design, Synthesis, and Photophysical Investigation of a Tetrahydrobenzo[h]quinoline Derivative: A Turn-ON Fluorescent Sensor for Zn2+ Ion","authors":"Suhail Ahmad, Zafer Alam, Salman A. Khan","doi":"10.1007/s10953-026-01646-5","DOIUrl":"10.1007/s10953-026-01646-5","url":null,"abstract":"<div>A tetrahydrobenzo[h]quinoline derivative 7-methoxy-2-oxo-4-(2,4,5-trimethoxyphenyl)-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile (MTQC) was efficiently synthesized via a one-pot multicomponent reaction. The structure of MTQC was confirmed by FT-IR, 1H NMR, 13C NMR, and mass spectrometry analyses. Photophysical investigations, including UV–visible and fluorescence spectroscopy, revealed that MTQC exhibits strong absorption, intense fluorescence, pronounced solvatochromism, and a high fluorescence quantum yield. Fluorescence studies using various metal ions in acetonitrile (1 × 10–5 mol·L–1) indicated that MTQC is highly selective and sensitive toward Zn2+ ions acting as an efficient turn-on fluorescent sensor. The binding interaction between MTQC and Zn2+ follows a 1:1 stoichiometry with a marked association constant 8.04 × 104 L mol–1, indicating strong interaction between MTQC and Zn2+. The limits of detection (LOD) and quantification (LOQ) for the MTQC–Zn2+ complex were determined to be 3.88 × 10–7 mol·L–1 and 1.18 × 10–6 mol·L–1 respectively. These results demonstrate the potential of MTQC as a highly sensitive and selective fluorescent chemosensor for Zn2+ detection.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2806 - 2826"},"PeriodicalIF":1.3,"publicationDate":"2026-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Modeling the Excess Molar Volumes of Six (Monoethanolamine+Alcohol) Mixtures: The influence of Equation of State, Association Scheme and Cross Association Energy on the Accuracy of the Estimations 六种（单乙醇胺+醇）混合物的过量摩尔体积建模：状态方程、缔合方案和交联能对估计精度的影响

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-09-30 DOI: 10.1007/s10953-026-01656-3

Fatemeh Biglar, Farnaz Rostami, Sara Beshkofeh, Shahin Khosharay

{"title":"Modeling the Excess Molar Volumes of Six (Monoethanolamine+Alcohol) Mixtures: The influence of Equation of State, Association Scheme and Cross Association Energy on the Accuracy of the Estimations","authors":"Fatemeh Biglar, Farnaz Rostami, Sara Beshkofeh, Shahin Khosharay","doi":"10.1007/s10953-026-01656-3","DOIUrl":"10.1007/s10953-026-01656-3","url":null,"abstract":"<div>In this study, the Cubic Plus Association (CPA) and Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT) equations of state were applied to describing the excess molar volumes of binary mixtures of monoethanolamine with six alcohols, including ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and 1-pentanol. The 2B association scheme was considered for all alcohols. Three association schemes of monoethanolamine, namely 2B, 3B, and 4C, together with two strategies for determining the cross-association energy, were applied to these six binary systems. The first strategy employed conventional combining rules, whereas the second strategy estimated the cross-association energy by fitting it to the experimental excess molar volume data of the investigated mixtures. The results show that the combination of the PC-SAFT equation of state, the second strategy, and the 4C association scheme of monoethanolamine is the most accurate approach, with average absolute deviation percentages in the range of (2.88–6.30)%. Furthermore, the PC-SAFT EoS was found to be significantly more sensitive to the cross-association energy than the CPA EoS.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2784 - 2805"},"PeriodicalIF":1.3,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Statistical Analysis of Stepwise Stability Constants in Homo- and Heteroligand Ni(II), Co(II), and Cu(II) Complexes with Benzohydrazide Derivatives and L-Histidine 苯并肼衍生物和l -组氨酸的Ni（II）、Co（II）和Cu（II）同异寡配配合物逐步稳定常数的统计分析

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-09-30 DOI: 10.1007/s10953-026-01666-1

Nikita V. Troshanin, Vadim V. Neklyudov, Tamara I. Bychkova

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Typical Spectral Characteristics and Optical Attenuation of Saline Water for Underwater Optical Communication 咸水水下光通信的典型光谱特性和光衰减

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-09-30 DOI: 10.1007/s10953-026-01667-0

Huaigang Cheng, Jiaoli Gao, Xun Zhang, Jing Zhao

{"title":"Typical Spectral Characteristics and Optical Attenuation of Saline Water for Underwater Optical Communication","authors":"Huaigang Cheng, Jiaoli Gao, Xun Zhang, Jing Zhao","doi":"10.1007/s10953-026-01667-0","DOIUrl":"10.1007/s10953-026-01667-0","url":null,"abstract":"<div>Underwater visible light communication is valuable for exploring salt lakes, but the effect of salt type is unclear. This study investigates the evolution laws of infrared, Raman, and UV–Vis absorption spectra of eight typical inorganic salt solutions under different concentrations and temperatures, as well as the visible radiation attenuation mechanism under different seasons. Elevated salt concentration modulates the O–H band through ionic hydration and hydrogen-bond rearrangement and enhances the characteristic signals of sulfate ions. Increasing temperature causes a blue shift of the O–H peak and a red shift of the sulfate peak, with non-monotonic intensity variations for both bands. Except for Li2SO4 and MgSO4, the absorbance of salt solutions increases with the increase of concentration and temperature, and the absorption peak shifts red, which is attributed to the destruction of hydrogen bonds and the change of anion electronic transition activity. The results of seasonal changes in visible radiation show that the attenuation coefficient of the same salt solution in summer is higher than that in winter, and the attenuation coefficient of chloride salts is higher than that of sulfates, which is consistent with the spectroscopic results. This study provides insights into how ionic hydration structures and hydrogen-bond networks are related to spectral responses and optical attenuation behavior, offering a theoretical basis for channel modeling and adaptive transmission design of underwater optical communication systems in complex salt lake environments.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2760 - 2783"},"PeriodicalIF":1.3,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Polyion–Counterion Interactions in Mixtures of Sodium Carboxymethylcellulose (aq) with Different Molar Masses 不同摩尔质量的羧甲基纤维素钠（aq）混合物中的多离子-反离子相互作用

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-09-27 DOI: 10.1007/s10953-026-01660-7

Sudipa Santra, Bidyut Debnath, Bijan Das

{"title":"Polyion–Counterion Interactions in Mixtures of Sodium Carboxymethylcellulose (aq) with Different Molar Masses","authors":"Sudipa Santra, Bidyut Debnath, Bijan Das","doi":"10.1007/s10953-026-01660-7","DOIUrl":"10.1007/s10953-026-01660-7","url":null,"abstract":"<div>This study explores polyion–counterion interactions in aqueous mixtures of a polyelectrolyte sodium carboxymethylcellulose (NaCMC) having two different molar masses. Previous dynamic light scattering (DLS) studies indicated an invariance of the polyion–counterion interactions with the total concentration or with the composition in mixed sodium polystyrene sulfonate (NaPSS) solutions, while conductivity studies reveal a definite dependence of these interactions in these systems. The objective of this research is to shed more light on these interactions for a different system not considered earlier namely mixtures of NaCMC with a quite low charge density compared to NaPSS, and to explore whether such effect prevails in other systems as well. Counterion-dissociation governing the polyion–counterion interactions are quantified using conductivity as the probe to unravel the nature of these interactions. Degrees of counterion-dissociation and hence the effective charges on the carboxymethylcellulose chains are found to increase with the total polyelectrolyte concentration. This study reveals a reduction in the degree of counterion-dissociation in mixtures richer in the higher molar mass sample, which becomes more pronounced in dilute solutions. Roles of the effective dielectric constant, screening of chain charges, and polyion chain-coiling in governing counterion-dissociation are critically assessed. Substantial proportion of the counterions has been found to move with the polyions, corroborating the inferences drawn on the basis of counterion-condensation. This study demonstrates a definite dependence of polyion–counterion interactions on both the total polyelectrolyte concentration and the composition of the mixtures.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2730 - 2744"},"PeriodicalIF":1.3,"publicationDate":"2026-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Solubility Behavior and Thermodynamic Analysis of (S)-Indoxacarb in Pure and Methanol–Water Binary Solvents (S)-茚虫威在纯溶剂和甲醇-水二元溶剂中的溶解行为和热力学分析

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2026-09-21 DOI: 10.1007/s10953-026-01664-3

Yihuan He, Yifan Zhang, Xiangchuan Wang, Wenguo Xing, Shuai Yu, Fumin Xue

{"title":"Solubility Behavior and Thermodynamic Analysis of (S)-Indoxacarb in Pure and Methanol–Water Binary Solvents","authors":"Yihuan He, Yifan Zhang, Xiangchuan Wang, Wenguo Xing, Shuai Yu, Fumin Xue","doi":"10.1007/s10953-026-01664-3","DOIUrl":"10.1007/s10953-026-01664-3","url":null,"abstract":"<div>The solubility of (S)-indoxacarb in four pure solvents (methanol, ethanol, n-propanol, i-propanol) and binary methanol–water mixtures was measured using the gravimetric method at atmospheric pressure and in the temperature range of 278.15 to 313.15 K. The dissolution thermodynamics and intermolecular interactions were systematically analyzed. The results showed that the solubility of (S)-indoxacarb increased with the rise of temperature in all tested solvent systems. In pure solvents, the solubility followed the order of methanol > ethanol > n-propanol > i-propanol, which presented a positive correlation with solvent polarity. In methanol–water mixtures, solubility increased with the molar fraction of methanol. The modified Apelblat model, Yaws model, and van’t Hoff model were applied to fit the solubility data, among which the modified Apelblat model and Yaws model exhibited better fitting effects, and all three models showed good correlation with the experimental data. Hirshfeld surface (HS) and molecular electrostatic potential surface (MEPS) analysis revealed that (S)-indoxacarb could form hydrogen bonds with alcoholic solvents, and H–H and H–O interactions dominated its crystal packing. Based on the van’t Hoff model, the thermodynamic parameters of the dissolution process were calculated, demonstrating that the dissolution of (S)-indoxacarb in the tested solvents is endothermic and non-spontaneous under the standard state at the mean temperature, and it is enthalpy-driven.</div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"55 10","pages":"2709 - 2729"},"PeriodicalIF":1.3,"publicationDate":"2026-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149222626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0