胶束电离度的适当解释。批评性评论

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Journal of Solution Chemistry Pub Date : 2025-09-21 DOI:10.1007/s10953-025-01478-9

Erica Patricia Schulz, Guillermo A. Durand, Pablo Carlos Schulz

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引用次数: 0

摘要

本文对胶束（α）的电离度进行了评述，分析了其从静电学中推导的过程，以及不同因素的影响及其解释。我们考虑了碳氢化合物链长、聚集数、极性基团的大小和水解、反离子的电荷以及非离子表面活性剂或酒精分子被纳入离子胶束的情况。α的适当解释不仅取决于所研究系统的性质，而且取决于测定α的方法。我们得出的结论是，最合适的名称是逆释放度。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Appropriate Interpretation of the Ionization Degree of the Micelles. A Critical Review

The present work presents a critical review on the ionization degree of the micelles (α), analyzing its derivation from electrostatics, as well as the influence of different factors and their interpretation. We have considered the effect of the hydrocarbon chain length, the aggregation number, the polar group’s size and hydrolysis, the counterions´ charge and cases when non-ionic surfactants or alcohol molecules are included into ionic micelles. The appropriate interpretation of α depends not only on the nature of the system studied but also on the methodology employed for its determination. We have concluded that the most appropriate denomination for this property is degree of counterion release.

Graphical Abstract

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.