Journal of Nanoparticle Research最新文献

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Sintering of Ti–Al nanoparticle pairs: a molecular dynamics simulation study 钛铝纳米粒子对的烧结:分子动力学模拟研究
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-06 DOI: 10.1007/s11051-025-06335-w
Yong Niu, Xiang Lv, Yunjie Jia, Yanchun Zhu, Yaoqi Wang
{"title":"Sintering of Ti–Al nanoparticle pairs: a molecular dynamics simulation study","authors":"Yong Niu,&nbsp;Xiang Lv,&nbsp;Yunjie Jia,&nbsp;Yanchun Zhu,&nbsp;Yaoqi Wang","doi":"10.1007/s11051-025-06335-w","DOIUrl":"10.1007/s11051-025-06335-w","url":null,"abstract":"<div><p>Molecular dynamics simulations were used to investigate the effects of aluminum content and sintering temperature on the sintering process of Ti–Al nanoparticles. The target sintering temperatures were set to 1300 K, 1400 K, 1500 K, and 1600 K, with aluminum atomic fractions of 0%, 1%, 3%, 5%, 8%, and 10%. The sintering performance was evaluated through common neighbor analysis, sintering neck width, radius of gyration, and mean square displacement (MSD). The results show that higher sintering temperatures lead to a greater degree of sintering; when the temperature exceeds 1500 K, the nanoparticles can fully merge. Additionally, the neck width, MSD growth rate during the heating stage, and the drop rate of the radius of gyration at the sudden decrease all increase with rising temperature. Furthermore, increasing the aluminum content inhibits sintering. When the aluminum fraction exceeds 8%, complete sintering becomes difficult. Both the growth rate of the neck width and the MSD growth rate, as well as the drop rate of the radius of gyration, decrease with increasing aluminum content.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143913782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interaction of muscovite nanoparticles and fulvic acid in simulated surface waters 白云母纳米颗粒与黄腐酸在模拟地表水中的相互作用
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-06 DOI: 10.1007/s11051-025-06326-x
Alexandr Ivaneev, Tatiana Dzherayan, Mikhail Ermolin, Natalia Vanifatova
{"title":"Interaction of muscovite nanoparticles and fulvic acid in simulated surface waters","authors":"Alexandr Ivaneev,&nbsp;Tatiana Dzherayan,&nbsp;Mikhail Ermolin,&nbsp;Natalia Vanifatova","doi":"10.1007/s11051-025-06326-x","DOIUrl":"10.1007/s11051-025-06326-x","url":null,"abstract":"<div><p>Natural nanoparticles (NPs) and natural organic matter (NOM) are ubiquitous in the environments such as soils, sediments, and surface waters. The adsorption of NOM onto mineral NPs is a key natural process, which has significant effects on the fate and biogeochemical cycles of many chemicals including toxic ones. For the first time, complex of complimentary analytical methods including capillary zone electrophoresis (CZE), dynamic light scattering, and laser Doppler velocimetry (LDV) has been used for study of effect of NOM on the fate of natural NPs in simulated surface waters. Muscovite NPs and fulvic acid (FA) have been taken as examples. It has been demonstrated that CZE can be an efficient tool for the study on interactions of mineral NPs and FA. CZE allowed one to discriminate muscovite NPs, FA, and products of their interaction—organometallic complex. It is most likely that FA forms a complex with Al. It is found that Al<sup>3+</sup>-FA complex has an intermediate electrophoretic mobility (46.6 cm<sup>2</sup>V<sup>−1</sup> s<sup>−1</sup>) between muscovite NPs (31.6 cm<sup>2</sup>V<sup>−1</sup> s<sup>−1</sup>) and FA (49.3 cm<sup>2</sup>V<sup>−1</sup> s<sup>−1</sup>) as measured for suspension with pH value of 6. It is also demonstrated that electrophoretic mobility of Al<sup>3+</sup>-FA complex is less susceptible to pH of medium as compared to muscovite NPs. The absolute value of electrophoretic mobility increases with increasing pH of buffer solution from 31.0 to 37.9·10<sup>−5</sup> cm<sup>2</sup>V<sup>−1</sup> s<sup>−1</sup> for muscovite NPs and from 46.3 to 50.0·10<sup>−5</sup> cm<sup>2</sup>V<sup>−1</sup> s<sup>−1</sup> for Al<sup>3+</sup>-FA complex. The obtained zeta-potential values (from − 45 to − 55 mV) have demonstrated that muscovite NPs are characterized by good stability in simulated surface waters. Thus, the results obtained have confirmed that NOM can significantly affect the fate of natural NPs in aquatic environments.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing agriculture in Africa through nanotechnology: A systematic review 通过纳米技术推进非洲农业:一项系统综述
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-05 DOI: 10.1007/s11051-025-06334-x
Yohannes Gelaye
{"title":"Advancing agriculture in Africa through nanotechnology: A systematic review","authors":"Yohannes Gelaye","doi":"10.1007/s11051-025-06334-x","DOIUrl":"10.1007/s11051-025-06334-x","url":null,"abstract":"<div><p>Across Africa, the adoption and progress of nanotechnology face significant challenges, including a lack of technical expertise and supportive government policies. Only a handful of African countries have taken steps to develop comprehensive strategies and policies. This review evaluates the application of nanotechnology in the agricultural sector across Africa, where agriculture employs more than 60% of the population. Globally, agriculture is a major field for nanoparticle applications, with the United States, Russia, China, India, and Iran leading in agricultural nanoparticle production. Nanoparticles are recognized as transformative technologies capable of modernizing traditional agricultural systems. The main applications of nanotechnology in agriculture include advanced agrochemical formulations, improved crop protection, and precise sensor technologies for detecting pollutants at the molecular level. Despite these promising benefits, the adoption of nanotechnology remains limited in Africa, with only a few countries, such as Egypt, South Africa, Ghana, Tunisia, and Algeria, attempting to integrate it into sectors like agriculture and healthcare. Furthermore, only a small number of African nations have established formal strategies and policies for nanotechnology. Therefore, to support Africa’s commitment to international obligations, including the Paris Climate Agreement and the African Union’s Agenda in 2063, to achieve Sustainable Development, governments must prioritize transformative policy development, encourage regional and international collaboration, and invest in education and research in nanotechnology.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geometric structure and temperature effects on the coalescence of Ag-Pt nanoparticles Ag-Pt纳米颗粒聚结的几何结构和温度影响
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-05 DOI: 10.1007/s11051-025-06331-0
Nagihan Zorlu, Songül Taran, Haydar Arslan
{"title":"Geometric structure and temperature effects on the coalescence of Ag-Pt nanoparticles","authors":"Nagihan Zorlu,&nbsp;Songül Taran,&nbsp;Haydar Arslan","doi":"10.1007/s11051-025-06331-0","DOIUrl":"10.1007/s11051-025-06331-0","url":null,"abstract":"<div><p>The coalescence of Ag and Pt nanoparticles was performed by molecular dynamics simulations. In the first case, we investigate the temperature effect on the coalescence of Ag and Pt nanoparticles with same geometric structure and a truncated octahedron (TO) of 140 Ag atoms (<span>({Ag}_{140}^{TO})</span>) collides with a TO of 140 Pt atoms (<span>({Pt}_{140}^{TO})</span>) and an icosahedral (Ih) of 147 Ag atoms (<span>({Ag}_{147}^{Ih})</span>) collides with an Ih of 147 Pt atoms (<span>({Pt}_{147}^{Ih})</span>). Then, we consider the coalescence of Ag and Pt nanoparticles with different geometric structures and <span>({Ag}_{140}^{TO})</span> collides with <span>({Pt}_{147}^{Ih})</span> and <span>({Ag}_{147}^{Ih})</span> collides with <span>({Pt}_{140}^{TO})</span>. In order to underline the role of temperature in the coalescence process, it is simulated at five different temperatures (400, 450, 500, 550, and 600 K) and we analyze structural and chemical ordering changes using some descriptors such as radius of gyration and common neighbor analysis (CNA) for all systems considered.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Au nanoparticles by the reaction of HAuCl4·nH2O with organoaluminum compounds 用HAuCl4·nH2O与有机铝化合物反应合成金纳米颗粒
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-02 DOI: 10.1007/s11051-025-06328-9
Lyudmila V. Parfenova, Almira Kh. Bikmeeva, Pavel V. Kovyazin, Eldar R. Palatov, Leonard M. Khalilov, Nina M. Ivanova, Semen N. Sergeev
{"title":"Synthesis of Au nanoparticles by the reaction of HAuCl4·nH2O with organoaluminum compounds","authors":"Lyudmila V. Parfenova,&nbsp;Almira Kh. Bikmeeva,&nbsp;Pavel V. Kovyazin,&nbsp;Eldar R. Palatov,&nbsp;Leonard M. Khalilov,&nbsp;Nina M. Ivanova,&nbsp;Semen N. Sergeev","doi":"10.1007/s11051-025-06328-9","DOIUrl":"10.1007/s11051-025-06328-9","url":null,"abstract":"<div><p>The reaction of HAuCl<sub>4</sub><sup>.</sup>nH<sub>2</sub>O with organoaluminum compounds (HAlBu<sup>i</sup><sub>2</sub> or AlR<sub>3,</sub> R = Me, Et, Bu<sup>i</sup>) in organic solvents, followed by hydrolysis in the presence of a tertiary thiol (5-methylundecane-5-thiol), afforded gold nanoparticles (AuNPs). Particle sizes and size distributions depended largely on the structure of the original organoaluminum reagent and the nature of the solvent. The smallest particle sizes ranging from 2 to 20 nm were observed when reducing HAuCl<sub>4</sub> with HAlBu<sup>i</sup><sub>2</sub>. Nanoparticles have been characterized by the means of scanning transmission electron microscopy, photon cross-correlation spectroscopy, X-ray photoelectron spectroscopy, and UV–Vis spectroscopy. The proposed method may be further utilized for the deposition of metal nanoparticles onto solid supports for applications in catalysis and other fields.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
P123-CoMgAl composite for sustainable and high-conversion epoxide ring-opening polymerization 可持续高转化率环氧化合物开环聚合的P123-CoMgAl复合材料
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-05-01 DOI: 10.1007/s11051-025-06316-z
Xiaoyan Cao, Xiao Xu, Gongming Wu, Zhenggui Gu
{"title":"P123-CoMgAl composite for sustainable and high-conversion epoxide ring-opening polymerization","authors":"Xiaoyan Cao,&nbsp;Xiao Xu,&nbsp;Gongming Wu,&nbsp;Zhenggui Gu","doi":"10.1007/s11051-025-06316-z","DOIUrl":"10.1007/s11051-025-06316-z","url":null,"abstract":"<div><p>The ring-opening polymerization lays the foundation for synthesizing polypropylene glycol. Nevertheless, homogeneous alkali catalysts usually require complex post-treatments, hindering green synthesis and environmental sustainability. Here, we studied a heterogeneous epoxide polymerization method based on a P123-modified nanocomposite layered double oxide (CoMgAl-LDO(P123)). Thereafter, the composition, crystal structure, morphology, and thermal stability of the catalyst were characterized through SEM, XRD, FTIR, XPS, BET, and TG-DTG techniques. The results indicated that due to the designable and self-assembled P123 micelles, CoMgAl-LDO(P123) generated consistent mesoporous channels and a larger specific surface area. The introduction of cobalt enriched the alkaline sites on the CoMgAl-LDO(P123) surface. In the synthesis of small molecular weight poly(propylene glycol) (i.e., number average molecular weight less than 500), the catalytic performance of CoMgAl-LDO(P123) for the conversion of propylene oxide reached 96.3% under the optimal reaction conditions, which was superior to that of other catalysts. Our strategy addresses the trade-off issue that alkali catalysts faced in terms of sustainability and operational complexity, holding great promise in green chemistry.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892714","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced photocatalytic degradation efficiency for TiO2-carbon dots composite catalyst prepared via calcination-hydrothermal sequential treatment 煅烧-水热序贯法制备tio2 -碳点复合催化剂,提高了光催化降解效率
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-04-30 DOI: 10.1007/s11051-025-06325-y
Yungang Yuan, Zhuang Xiang, Yongjian Tong, Zhili Peng
{"title":"Enhanced photocatalytic degradation efficiency for TiO2-carbon dots composite catalyst prepared via calcination-hydrothermal sequential treatment","authors":"Yungang Yuan,&nbsp;Zhuang Xiang,&nbsp;Yongjian Tong,&nbsp;Zhili Peng","doi":"10.1007/s11051-025-06325-y","DOIUrl":"10.1007/s11051-025-06325-y","url":null,"abstract":"<div><p>Carbon dots (CDs) exhibit great potential in modifying TiO<sub>2</sub> to enhance its photocatalytic capacities. However, the influence of different compositing approaches on the TiO<sub>2</sub>/CDs photocatalytic performance has not been carefully studied. In this study, CDs-modified TiO<sub>2</sub> photocatalysts were prepared via hydrothermal treatment, direct calcination, and calcination-hydrothermal sequential treatment, respectively. Careful study revealed that the third catalyst demonstrated the most enhanced photocatalytic performance because in this synthesis approach; CDs not only improved the light absorption capacity of TiO<sub>2</sub> and increased the lifetime of charge carriers, but also enlarged the specific surface area of TiO<sub>2</sub>. With further optimization in CDs mass ratios, the degradation efficiencies of MB and RhB by the optimum catalyst were increased by 18% and 21%, respectively, from that of the pristine TiO<sub>2</sub>, highlighting the great potential of CDs as modification agents to enhance the photocatalytic performance of traditional photocatalysts.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143888764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on influence of pore structure on photocatalytic performance of nano-TiO2 cement paste 孔结构对纳米tio2水泥浆光催化性能影响的研究
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-04-29 DOI: 10.1007/s11051-025-06320-3
Xueli Nan, Jiang Fan, Jianrui Ji, Shuo Wang, Mengge Zhu, Weibin Tang
{"title":"Study on influence of pore structure on photocatalytic performance of nano-TiO2 cement paste","authors":"Xueli Nan,&nbsp;Jiang Fan,&nbsp;Jianrui Ji,&nbsp;Shuo Wang,&nbsp;Mengge Zhu,&nbsp;Weibin Tang","doi":"10.1007/s11051-025-06320-3","DOIUrl":"10.1007/s11051-025-06320-3","url":null,"abstract":"<div><p>The pore structure characteristics of nano-TiO<sub>2</sub> cement paste are critical in determining its photocatalytic efficiency. In this study, the composition of the cement paste was modified to optimize the pore structure and examine its effect on photocatalytic performance. Mercury intrusion porosimetry (MIP) was utilized to characterize the pore structure of nano-TiO<sub>2</sub> cement paste, revealing that material composition significantly influences the pore structure. Photocatalytic degradation tests using methylene blue (MB) demonstrated that degradation efficiency improved with an increased water-to-binder ratio (<i>W</i>/<i>B</i>) and higher dosages of fly ash (FA) and air-entraining agent (AEA). The presence of transitional pores (10–50 nm) and capillary pores (50–1000 nm), as well as increased porosity and total pore volume, enhanced photocatalytic efficiency, while the pore surface fractal dimension showed minimal impact. Kinetic modeling and scanning electron microscopy (SEM) analyses confirmed that MB degradation by nano-TiO<sub>2</sub> cement paste follows a first-order kinetic model. Additionally, in the paste containing 0.012% AEA, the C-S–H gel exhibited a looser, network-like morphology, significantly improving photocatalytic activity.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143888701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of quercetin long-circulating liposomes and their therapeutic effect on diabetic peripheral neuropathy 槲皮素长循环脂质体的制备及其对糖尿病周围神经病变的治疗作用
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-04-28 DOI: 10.1007/s11051-025-06323-0
Jing Wang, Mingjie Gong, Gongbing Tu, Bing Luo, Qilong Wang, Hui Ding, Xiulin Liang, Jie Chen
{"title":"Preparation of quercetin long-circulating liposomes and their therapeutic effect on diabetic peripheral neuropathy","authors":"Jing Wang,&nbsp;Mingjie Gong,&nbsp;Gongbing Tu,&nbsp;Bing Luo,&nbsp;Qilong Wang,&nbsp;Hui Ding,&nbsp;Xiulin Liang,&nbsp;Jie Chen","doi":"10.1007/s11051-025-06323-0","DOIUrl":"10.1007/s11051-025-06323-0","url":null,"abstract":"<div><p>Diabetic peripheral neuropathy (DPN) is a prevalent chronic complication of diabetes mellitus, which often results in significant patient discomfort. The objective of this study was to enhance the solubility and bioavailability of quercetin by loading quercetin into long-circulating liposomes (Q-LL) to ultimately achieve the goal of enhancing the therapeutic impact of quercetin on DPN. The Q-LL was synthesized using the film dispersion method, followed by a comprehensive series of characterizations as well as in vitro release and in vivo pharmacokinetic studies. Subsequently, the DPN rat model was established before the administration of free quercetin and Q-LL to the rats. The potential mechanism of Q-LL in the treatment of DPN was postulated by detecting levels of blood lipid, oxidative stress, and inflammation in rats after 4 weeks of oral administration. Q-LLs were successfully developed, which had a particle size of 110.93 ± 1.49 nm, a PDI of 0.179 ± 0.012, a zeta potential of − 25.37 ± 0.31 mV, an encapsulation efficiency (EE)% of 93.57 ± 0.19%, and a drug loading (DL)% of 9.66 ± 0.12%, as well as displayed a sustained release effect. This Q-LL significantly increased the solubility and in vivo circulation time of quercetin, thus significantly improving the bioavailability of quercetin. Q-LL may alleviate DPN by reducing levels of blood lipid, oxidative stress, and inflammatory response. Overall, Q-LL may offer a new strategy for the potential extension of the in vivo circulation of quercetin and enhancement of its bioavailability for DPN treatment.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143879741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Functionalized POSS additives designed for enhanced anti-icing coating performance 功能化POSS添加剂设计用于增强防冰涂层性能
IF 2.1 4区 材料科学
Journal of Nanoparticle Research Pub Date : 2025-04-28 DOI: 10.1007/s11051-025-06262-w
Monika Pilz, Christian W. Karl, Bartlomiej Przybyszewski, Rafal B. Kozera
{"title":"Functionalized POSS additives designed for enhanced anti-icing coating performance","authors":"Monika Pilz,&nbsp;Christian W. Karl,&nbsp;Bartlomiej Przybyszewski,&nbsp;Rafal B. Kozera","doi":"10.1007/s11051-025-06262-w","DOIUrl":"10.1007/s11051-025-06262-w","url":null,"abstract":"<div><p>Environmentally friendly functionalized inorganic–organic hybrid materials (polyhedral oligomeric silsesquioxanes—POSS) imparting anti-icing properties to a commercial waterborne polyurethane coating matrix have been successfully synthesized deploying a possible industrial manufacturing route by a two-step procedure. Thereby, <sup>13</sup>C-nuclear magnetic resonance (NMR) spectroscopy was mainly used to ensure complete conversion of the given reactive polydimethylsiloxane-based modifier with selected amino-functionalized POSS intermediates at given stoichiometry. Two distinguished nanocomposite coatings based on the functionalized POSS additives were investigated for their suitability towards improved anti-icing properties. The characterization includes contact angle (CA) measurements and determination of freezing delay time (FDT) as well as scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS) to underline the results obtained. The findings clearly contribute to the complex interplay of material composition and coating interface emphasizing segregation of partly immiscible additives in the coating matrix being necessary for the enhanced water-repellence and anti-icing performance.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 5","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11051-025-06262-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143883693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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