{"title":"Low-Cost Flocculant Coated MIL-88B as Highly Efficient and Stable Fenton-Like Catalyst for Phenol Removal","authors":"Zhengbo Lai, Tao Huang, Hualan Zhou, Shengkang Wang, Jing Zhu, Yibo Zhao, Yinzhi Wang, Xiaoyuan Liao","doi":"10.1007/s10904-024-03356-1","DOIUrl":"10.1007/s10904-024-03356-1","url":null,"abstract":"<div><p>In this work, three kinds of Flocculant, microcrystalline cellulose (MCC), carboxymethyl cellulose (CMC), and Chitosan (CTS), coating Fe-MOF were prepared by a coprecipitation method followed by an in situ graft copolymerization. When they employed as heterogeneous Fenton-catalysts to degrade phenol in waste water, their catalytic activity has the order of has the order of MIL-CMC (0.0873 min<sup>− 1</sup>) > MIL-MCC (0.0794 min<sup>− 1</sup>) > MIL-CTS (0.0712 min<sup>− 1</sup>) > MIL-88B (0.0675 min<sup>− 1</sup>). The reaction conditions were optimized, and found that the best reactions: MIL-CMC0.3 used as catalyst with catalyst load 20 mg/20ML, and the 25 ℃, pH = 3, and phenol of 100 ppm, could be removed completely in 5 min. Most important, Fe ions leakage of MIL: CMC is very small (0.02–0.03 mg/L), significantly less than that of MIL-88B (2.00-2.85 mg/L). The enhanced catalytic activity of Fe-MOF@flocculent could be attributed to flocculent protective action.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1743 - 1750"},"PeriodicalIF":3.9,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Silambarasan, R. Boopathiraja, Surekha Podili, V. Kavitha, Nouf H. Alotaibi, Saikh Mohammad, B. Sethuraman, K. Sakthipandi
{"title":"Facile Hydrothermal Synthesis of ZnCo2O4 Hexagonal Plate-Like Electrode for Supercapacitor Applications: Capacitive and Diffusive Mechanism of Trassati Method","authors":"M. Silambarasan, R. Boopathiraja, Surekha Podili, V. Kavitha, Nouf H. Alotaibi, Saikh Mohammad, B. Sethuraman, K. Sakthipandi","doi":"10.1007/s10904-024-03358-z","DOIUrl":"10.1007/s10904-024-03358-z","url":null,"abstract":"<div><p>The Zinc cobaltite (ZnCo<sub>2</sub>O<sub>4</sub>), with its extensive redox reactions involving many ions and oxidation states, is an emerging electrode material for supercapacitors. The ZnCo<sub>2</sub>O<sub>4</sub> prepared by using easy hydrothermal method. The generated material’s structural, morphological, textural, and electrochemical behaviour were analysed using XRD, FESEM, XPS, Raman, FTIR, BET, CV, GCD, and EIS. The prepared ZnCo<sub>2</sub>O<sub>4</sub> material exhibits bundle of hexagonal plates (HPs) like structure. The prepared ZnCo<sub>2</sub>O<sub>4</sub> HPs electrode delivers high specific capacitance of 950 Fg<sup>− 1</sup> at 5 mA. The prepared ZnCo<sub>2</sub>O<sub>4</sub> HPs electrode exhibits capacity retention of 74.2% after 6500 cycles. ZnCo<sub>2</sub>O<sub>4</sub> HPs electrode exhibits energy density of 21.1 Whkg<sup>− 1</sup> and power density of 446.8 Wkg<sup>− 1</sup>at 5 mA. The findings show that ZnCo<sub>2</sub>O<sub>4</sub> HPs have a great deal of promise for application as an effective supercapacitive electrode material because of their higher specific capacitance and increased cycle stability.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1751 - 1763"},"PeriodicalIF":3.9,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergetic Photocatalytic Performance of Reusable Ag2S/ZnS/Fe3O4 Magnetic Nanocomposite for Impressive Degradation of Methyl Orange over Visible Light","authors":"M. Beigmoradi, P. Iranmanesh, S. Saeednia","doi":"10.1007/s10904-024-03367-y","DOIUrl":"10.1007/s10904-024-03367-y","url":null,"abstract":"<div><p>In this research, a novel ternary Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> magnetic nanocomposite was successfully synthesized using the facile co-precipitation method. Different characterization equipments were used to study the structure, morphology, and optical properties of the Ag<sub>2</sub>S/ZnS and Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> nanocomposites, which will be used as a photocatalyst for methyl orange degradation. X-ray diffraction analyses showed that ZnS and Fe<sub>3</sub>O<sub>4</sub> have a cubic crystal structure, while Ag<sub>2</sub>S has a monoclinic structure at room temperature. TEM images revealed that the average particle size of the Ag<sub>2</sub>S/ZnS and Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> nanocomposites is approximately 9 nm and 26 nm, respectively. Furthermore, the photoluminescence peak intensity of the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> nanocomposite was lower than that of the Ag<sub>2</sub>S/ZnS nanocomposite, indicating a reduction in electron-hole recombination and an enhancement in photogenerated charge carrier transitions in the ternary nanocomposite. To optimize the photocatalytic performance of the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> magnetic nanocomposite for methyl orange degradation, different effective parameters such as pH, methyl orange concentration, photocatalyst dosage, and radiation type was varied. Under the optimized conditions, the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> nanocomposite exhibited higher photocatalytic efficiency than Ag<sub>2</sub>S/ZnS. Specifically, the photocatalytic degradation efficiency of the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> nanocomposite was approximately 92% and 99% under visible and ultraviolet light radiation, respectively. This excellent degradation performance can be attributed to the small band gap energy and low rate of electron-hole recombination in the ternary nanocomposite. Furthermore, we found that the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> photocatalyst could be easily separated with a simple magnet after the catalytic reaction. It also demonstrated a highly stable performance after recycling, indicating advanced reusability and stability. Therefore, the Ag<sub>2</sub>S/ZnS/Fe<sub>3</sub>O<sub>4</sub> magnetic nanocomposite, which is both biocompatible and reusable, can be considered an effective and high-efficiency photocatalyst for methyl orange degradation under visible light radiation.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1779 - 1794"},"PeriodicalIF":3.9,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shobha Musmade, Dinesh Hase, Kailas Kadam, Gajanan Pandhare, Kanhaiyalal Bhavsar, Mohd Shahnawaz Khan, Mohd Rashid Khan, Shailendra Gurav, Vaishali Murade
{"title":"Integrating ZnO/BiOCl@rGO Derived S-Scheme Photocatalyst: Characterization and Mechanistic Insight for Environmental Remediation","authors":"Shobha Musmade, Dinesh Hase, Kailas Kadam, Gajanan Pandhare, Kanhaiyalal Bhavsar, Mohd Shahnawaz Khan, Mohd Rashid Khan, Shailendra Gurav, Vaishali Murade","doi":"10.1007/s10904-024-03389-6","DOIUrl":"10.1007/s10904-024-03389-6","url":null,"abstract":"<div><p>With the contemporary phenomenon of excessive industrialization, safeguarding and conserving the environment has ascended to the forefront of humanity’s most critical challenges. This investigation delineates the successful synthesis of a novel S-scheme ternary ZnO/BiOCl@rGO photocatalyst via a straightforward hydrothermal method. It is employed to proficiently degrade the carcinogenic dyes of methylene blue and malachite green in industrial effluents. The synthesized photocatalysts were characterized utilizing advanced analytical methodologies to examine their crystallinity, vibrational modes of bonds, surface morphology, elemental composition, chemical oxidation states, optical absorption characteristics, the recombination dynamics of photogenerated charge carriers, specific surface area, and structural attributes. The absorbance of visible light and the catalytic performance of the ternary ZnO/BiOCl@rGO (5% RBZ) photocatalyst exhibited a substantial enhancement in comparison to both the pure ZnO and the ZnO/BiOCl composite. The degradation efficiency of ZnO/BiOCl@rGO (5% RBZ) (93.73%, k = 0.0318 min<sup>−1</sup>) was found to be 1.7 times superior to that of ZnO/BiOCl and 4.4 times greater than that of pure ZnO in the degradation of methylene blue after 60 min. In a similar vein, the degradation efficiency of ZnO/BiOCl@rGO (5% RBZ) (99.68%, k = 0.0503 min<sup>−1</sup>) was 1.9 times more effective than ZnO/BiOCl and 3.8 times higher than pure ZnO in the degradation of malachite green after 60 min. The photocatalytic efficacy of ZnO/BiOCl@rGO (5% RBZ) was augmented due to the superior electron transport properties of the rGO layers, which proficiently facilitate the separation of electron–hole pairs. The findings substantiate that the novel S-scheme ternary ZnO/BiOCl@rGO (5% RBZ) photocatalyst represents a cost-efficient solution for the remediation of contaminated water and has the potential to serve as an exemplary material for the reduction of water pollution.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1708 - 1729"},"PeriodicalIF":3.9,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gayathri Bindu Kurup, Prashanth Goud Banda, Swati Gubbala, E. S. Bindiya, Sarita G. Bhat, Raghasudha Mucherla
{"title":"Surface Nanoarchitectonics of Delafossite AgFeO2 with Chitosan Derived Nanodots: Innovative Catalyst for Phenol Access and Broad-Spectrum Antibacterial Applications","authors":"Gayathri Bindu Kurup, Prashanth Goud Banda, Swati Gubbala, E. S. Bindiya, Sarita G. Bhat, Raghasudha Mucherla","doi":"10.1007/s10904-024-03392-x","DOIUrl":"10.1007/s10904-024-03392-x","url":null,"abstract":"<div><p>In this work, we present a facile method for accessing phenols through the ipsohydroxylation of arylboronic acid using delafossite silver ferrite (AgFeO<sub>2</sub>) functionalized with chitosan-derived nanodots (CDs) as a reusable catalyst (AgFeO<sub>2</sub>@CD). The catalyst, synthesized via the wet impregnation method, was characterized by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and Brunauer–Emmett–Teller (BET) techniques. The ipsohydroxylation reaction conditions were optimized to achieve high catalytic efficiency, yielding up to 99% of the product at room temperature in an aqueous medium with hydrogen peroxide as a mild and environmentally friendly oxidant. The process generates water as the only by-product, ensuring cleanliness. The catalyst, recoverable with a simple external magnet, demonstrated no significant structural changes or loss in catalytic activity after five cycles, highlighting its reusability and recyclability. Furthermore, we investigated the potent antibacterial activity of AgFeO<sub>2</sub>@CD against Bacillus cereus, Escherichia coli, and Pseudomonas aeruginosa. The presence of Ag and CDs in the catalyst contributed to a significant reduction in pathogen growth, establishing it as an effective antibacterial agent. This multifunctional catalyst shows great promise in both catalysis and antibacterial applications, with its magnetic retrievability making it particularly valuable for ipsohydroxylation reactions.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1730 - 1742"},"PeriodicalIF":3.9,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ghulam Nabi, Hammad Ahmed, Wajid Ali, Mudassar Maraj, Mohammad Altaf, Khuram Shahzad Ahmad
{"title":"Nd-Ions Role in Structural Engineering and Capacitive Contributions of NiO Nanosheets Clusters as Excellent Pseudocapacitor Electrode Material","authors":"Ghulam Nabi, Hammad Ahmed, Wajid Ali, Mudassar Maraj, Mohammad Altaf, Khuram Shahzad Ahmad","doi":"10.1007/s10904-024-03391-y","DOIUrl":"10.1007/s10904-024-03391-y","url":null,"abstract":"<div><p>Neodymium (Nd) ions doping in NiO has a major impact on morphology tuning and electrochemical properties enhancement. Herein Un-doped and Nd-ions doped nickel oxide Nd<sub>x</sub>Ni<sub>1-x</sub>O (x = 0, 0.01, 0.03, 0.05) nanostructures have been synthesized by facile hydrothermal route. The SEM analysis exhibited that dopant plays crucial role in morphology optimization. The (XRD analysis exposed the cubic structures with average crystallite size of 28 nm. The CV measurements showed an improvement in the specific capacitance values with maximum value 1492.3 F/g at 5 mV/s for 3% Nd-doped electrode with 93.4% retention after 8000 cycles. The excellent performance is attributed to easy charge mobility and conductivity linked with nanosheets clusters. The power law (b = 0.65) and Dunn method (capacitive contribution 49.5%) exhibiting their pseudocapacitors capacitive nature. Current findings confirm the potential of Nd<sub>0.03</sub>Ni<sub>0.97</sub>O as an electrochemical material and open a new avenue for application in supercapacitor.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1695 - 1707"},"PeriodicalIF":3.9,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Environmentally Sustainable Techniques for rGO Synthesis: Focus on Spun Calcination and Clean Technology Advances","authors":"Neha Kumari, Sahil Kumar, Prerit Chauhan, Gun Anit Kaur, Itika Kainthla, Mamta Shandilya","doi":"10.1007/s10904-024-03385-w","DOIUrl":"10.1007/s10904-024-03385-w","url":null,"abstract":"<div><p>Recent advances in clean technologies have led to the development of environmentally sustainable methods for synthesizing reduced graphene oxide (rGO), a material crucial for several applications. This review explores various eco-friendly approaches, such as electrochemical, photochemical, photothermal, laser, and hydrothermal reduction, along with the innovative spun calcination method. Unlike conventional methods, which often use toxic chemicals and require high energy, these green methods reduce environmental impact while enhancing scalability and material properties. We particularly highlight the spun calcination method, which employs electrospinning, for its ability to produce high-purity rGO with minimal defects and waste. We also discuss the optimization of rGO synthesis through the use of different polymer precursors such as polyacrylonitrile (PAN) and polyvinyldene fluoride (PVDF). This review aims to guide future research toward more efficient, scalable, and sustainable rGO production, supporting broader advancements in green nanotechnology.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 2","pages":"699 - 723"},"PeriodicalIF":3.9,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Nanoscale ZSM-5 Zeolites for the Catalytic Cracking of Oleic Acid into Light Olefins and Aromatics","authors":"Hao Liu, Yanlin Wang, Hong Yuan, Wenbo Luo","doi":"10.1007/s10904-024-03404-w","DOIUrl":"10.1007/s10904-024-03404-w","url":null,"abstract":"<div><p>Nanoscale ZSM-5 zeolites (NZSM-5) having different crystal sizes and Si/tetrapropylammonium hydroxide (TPAOH) molar ratios were synthesized using a hydrothermal method. These materials were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and N<sub>2</sub> adsorption–desorption. The results showed that each zeolite was highly crystalline regardless of the Si/TPAOH ratio and that the Brunauer–Emmett–Teller surface areas were in the range of 329−392 m<sup>2</sup>/g. The random aggregation of these nanoparticles resulted in the formation of numerous intergranular mesopores. These NZSM-5 zeolites were applied to the catalytic cracking of oleic acid to prepare light olefins and light aromatics using a laboratory-scale fixed bed reactor. The zeolite having a Si/TPAOH ratio of 10/5 showed the best catalytic activity and provided light olefins yield of 55% and selectivity of BTX in liquid phase products of 18%, respectively, at 500 °C. The small crystal size and abundant intergranular mesopores in this specimen resulted in shorter diffusion paths and an increase in the external specific surface area that both inhibited coke deposition and ensured accessible acid sites.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1679 - 1694"},"PeriodicalIF":3.9,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ali S. Alshomrany, R. Bousbih, Muhammad Sajid, Muhammad Jamil, Junaid Munir, Mutasem Z. Bani-Fwaz, Majid S. Jabir, Hasan Majdi, Essam Elsayed Assem, Mohamed Shaban, Mubashir Nazar
{"title":"DFT-Based Tailoring of the Thermoelectric and Photovoltaic Response of the Halide Double Perovskite Cs2TlYF6 (Y = Ag, Co)","authors":"Ali S. Alshomrany, R. Bousbih, Muhammad Sajid, Muhammad Jamil, Junaid Munir, Mutasem Z. Bani-Fwaz, Majid S. Jabir, Hasan Majdi, Essam Elsayed Assem, Mohamed Shaban, Mubashir Nazar","doi":"10.1007/s10904-024-03187-0","DOIUrl":"10.1007/s10904-024-03187-0","url":null,"abstract":"<div><p>The novel material halide double perovskites Cs<sub>2</sub>TlYF<sub>6</sub> (Y = Ag, Co) are the potential candidates for thermoelectric and photovoltaic devices. The ground state and temperature dependent electronic transport properties are computed for Cs<sub>2</sub>TlYF<sub>6</sub> (Y = Ag, Co) by utilizing density functional theory as employed within WIEN2k package. The negative energy of formation and obtained optimization plots validated the stability of studied halides. The computed electronic properties (band structure, DOS) reveal the semiconductor behavior with band gap value of 1.95 eV and 3.55 eV for Cs<sub>2</sub>TlAgF<sub>6</sub> and Cs<sub>2</sub>TlCoF<sub>6</sub>, correspondingly. The optical features are illustrated in terms of dielectric function <span>(varepsilon left(omega right))</span>, coefficient of optical absrobance, extinction coefficient, refractive index, and reflectivity. The optimal absorbance in the visible and UV spectrum of light, affirms the materials availability for optoelectronic devices. Thermoelectric characteristics exhibit maximum ZT value, higher Seebeck coefficients and lower thermal conductivity. A ZT of 1.46 at 300 K is attained for Cs<sub>2</sub>TlCoF<sub>6</sub>, while 0.74 is achieved for Cs<sub>2</sub>TlAgF<sub>6</sub>. Presented theoretical simulations indicate that the explored materials can of potential usage in renewable energy fields.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1591 - 1602"},"PeriodicalIF":3.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biogenic Production of Silver Nanoparticles Using Neocosmospora Solani Endophytic Fungal Extract: Their In Vitro Antibacterial and Anticancer Properties","authors":"Kistu Singh Nongthombam, Surendirakumar Kannaiah, Prabhu Raju, Lakshmanan Govindan, Shyamkesho Singh Mutum, Radha Raman Pandey","doi":"10.1007/s10904-024-03226-w","DOIUrl":"10.1007/s10904-024-03226-w","url":null,"abstract":"<div><p>The biogenic synthesis of nanomaterials has great advantages, biocompatible, and valuable material production. In this study, we demonstrated a sustainable and biocompatible approach for the synthesis of Ag nanoparticles (Ag NPs) using the endophytic fungi <i>Neocosmospora solani</i> (NS) extract isolated from the <i>Anaphalis contorta</i> stem. The anticancer and antibacterial potential of bioactive NS mediated AgNPs was evaluated by in vitro studies. The physicochemical characteristics of synthesized NS-AgNPs were systematically investigated by UV-vis, XRD, FTIR, FE-SEM, DLS and Zeta potential analyzer. In details, UV-visible spectroscopy confirmed the presence of biosynthesized NS-AgNPs at 432 nm, while XRD analysis confirmed their crystal nature. The FTIR spectrum confirmed the presence of functional groups in biomolecules that act as a capping agent for the nanoparticles. SEM was used to evaluate the shape of AgNPs. Dynamic light scattering (DLS) indicated that the average particle size is 362.3 nm, a zeta potential was − 0.168 mV with a single peak. The biosystem technique produced stable AgNPs up to 2 months following synthesis. In addition, the NS-AgNPs were exposed to excellent antibacterial efficacy against human pathogenic bacterial strains. The results of the anticancer assessment of NS-AgNPs against A549 lung cancer cells revealed that the dose-dependent cytotoxic and morphological changes have been reported in both AO/EB and Hoechst’s staining assays. In the future, it might be an excellent antibiotic and anticancer material for biomedical applications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 3","pages":"1603 - 1614"},"PeriodicalIF":3.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}