Journal of Inorganic and Organometallic Polymers and Materials最新文献

{"title":"A Comprehensive Analysis of CoHfX (X = As, Bi) Half Heusler Alloys: Implications for High-Performance Thermoelectric and Photovoltaic Devices","authors":"Bharti Gurunani,&nbsp;Dinesh C. Gupta","doi":"10.1007/s10904-024-03279-x","DOIUrl":"10.1007/s10904-024-03279-x","url":null,"abstract":"<div><p>The linearized full-potential augmented plane wave method within the framework of density functional theory (DFT) was employed to investigate the structural, elastic, electronic, optical and thermoelectric properties of the cobalt-based half-Heusler alloy CoHfX (X = As, Bi). The exchange-correlation functional was treated using the generalized gradient approximation of Perdew-Burke-Ernzerhof (GGA-PBE) and the Tran-Blaha-modified Becke-Johnson (TB-mBJ) approach as implemented in the WIEN2k package. The results indicate that the studied material is mechanically stable, suggesting its potential for experimental synthesis. Noteworthy findings include Debye temperatures of 317.42 K for CoHfAs and 343.26 K for CoHfBi, highlighting distinct thermal behaviors. The electronic band structures and density of states confirm the semiconductor nature of these compounds, with indirect band gaps of 1.36 eV for CoHfAs and 1.12 eV for CoHfBi, as determined using the TB-mBJ approximation. To examine the thermoelectric properties, including the Seebeck coefficient (S), electrical conductivity (σ), thermal conductivity (κ), and figure of merit (ZT), Boltzmann transport equations within the DFT framework were employed. The significant values obtained for the figure of merit and Seebeck coefficient indicate that CoHfX alloys are promising candidates for thermoelectric applications. The materials under investigation also exhibit exceptional absorption coefficients (α(ω)) in the ultraviolet and visible regions of the light spectrum, making them suitable for photovoltaic and optical equipment manufacturing. To date, no experimental or theoretical studies have been conducted on the half-Heusler alloy CoHfX. Consequently, the theoretical findings regarding the structural, elastic, electronic, magnetic, and thermoelectric properties are likely to be corroborated by future experimental investigation.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2327 - 2343"},"PeriodicalIF":3.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of Graphene Oxide on the Physical Properties of the Inorganic 2D Semiconductor Material Based Indium(III) Sulfide","authors":"A. Timoumi,&nbsp;W. Belhadj,&nbsp;N. Bouguila,&nbsp;Y. Raviprakash,&nbsp;Ziad Moussa,&nbsp;Hatem M. Altass,&nbsp;Saleh A. Ahmed","doi":"10.1007/s10904-025-03640-8","DOIUrl":"10.1007/s10904-025-03640-8","url":null,"abstract":"<div><p>Thin-film-based solar cell research is a critical focus for materials scientists due to its rapid growth as a sustainable energy solution. Indium sulfide (In₂S₃) has emerged as a promising material in the development of CdTe-based photovoltaic devices. In₂S₃; an inorganic two-dimensional semiconductor, has attracted significant interest for its potential in thin-film photovoltaics, photoelectrochemical cells, and other energy-related applications. Despite this growing interest, the commercial form of In₂S₃ remains under characterized. In this study, we systematically investigate the physical characteristics of graphene oxide (GO) incorporated into powdered β-phase In₂S₃. The samples were analyzed using X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and impedance spectroscopy (IS). XRD analysis confirmed that all samples were polycrystalline and crystallized in the tetragonal β-phase, with a reduction in crystalline size as the GO content increased. XPS analysis indicated the formation of oxygen vacancies without significant changes in elemental composition. TEM images showed that GO was well dispersed across the surface of In2S3, resulting in a reduced particle size. Electrical characteristics, measured via impedance spectroscopy, showed semiconducting behavior with a decrease in resistance as temperature increased, indicating enhanced conductivity. The results suggest that GO-doped In₂S₃ pellets could serve as promising materials for photovoltaic systems, especially as optical windows in solar cells. The study offers valuable insights into the role of GO in modulating the properties of In₂S₃ and highlights its potential for optimizing materials used in solar applications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2767 - 2775"},"PeriodicalIF":3.9,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Z-Scheme Heterojunction-based Rod-shaped g-C3N5/ZIF-8: Enhancing Photocatalytic, Antibacterial and Hemolytic Activity","authors":"Asima Subhadarshini,&nbsp;Sangram Keshari Samal,&nbsp;Binita Nanda","doi":"10.1007/s10904-024-03432-6","DOIUrl":"10.1007/s10904-024-03432-6","url":null,"abstract":"<div><p>A simple, cost-effective one-pot synthesis route has been implemented to prepare a rod-shaped nitrogen-rich g-C₃N₅-modified ZIF-8 (Zeolitic Imidazolate Framework-8) as a Z-scheme heterojunction-based photocatalyst. The formation of nanocomposite g-C₃N₅/ZIF-8 was confirmed through various characterization techniques like XRD, FTIR, SEM, CHNS, UV-Vis DRS, XPS, BET, GC-MS, TOC, and EIS. To evaluate the photocatalytic performance, tetracycline hydrochloride was taken as the target pollutant. After successful characterization, photocatalytic and antibacterial activity was being checked. g-C₃N₅/ZIF-8 exhibited the highest photocatalytic activity (98% in 120 min with K_app 0.032 min^− 1 towards tetracycline hydrochloride degradation as compared to pristine ZIF-8 and g-C₃N₅). The improved photocatalytic performance is mainly attributed to the broadening of light absorption capacity, formation of Z-scheme heterojunction, creation of a charge transport pathway, and reduced electronic charge recombination, which reduces the degradation time. The composite proved its stability and sustainability through five consecutive cycles. After 120 min of light exposure, total organic carbon (TOC) level reach 73.7%, with the remainder attributed to the presence of other minor intermediates. Furthermore, the composite showed better antibacterial activity against 2 Gram-stained bacterial pathogens, <i>E. coli</i> and <i>S. aureus</i>, and was found to have no hemolytic behaviour towards blood cells, proving it an efficient catalyst for water purification and biomedical application.</p><p>.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div><div><p>Graphical portray of CN5/ZIF-8’s photocatalytic, hemolytic and antibacterial activity</p></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2889 - 2903"},"PeriodicalIF":3.9,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Retraction Note: Two Mn(II)-Organic Frameworks: Selective Detection of Fe3+ Ion and Treatment Activity on Alcohol-Induced Cerebellar Atrophy by Reducing ROS Accumulation in Brain","authors":"En-Jie Guan,&nbsp;Yan Xia,&nbsp;Jian Hu","doi":"10.1007/s10904-024-03497-3","DOIUrl":"10.1007/s10904-024-03497-3","url":null,"abstract":"","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"34 11","pages":"5665 - 5665"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142789185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ternary Carbon Spheres/PAA-Al2O3 Nanoparticles as an Efficient Catalyst for RhB Dye Degrader and Bactericidal Agent; Molecular Docking Analysis","authors":"Malaika Batool,&nbsp;Muhammad Ikram,&nbsp;Ali Haider,&nbsp;Anum Shahzadi,&nbsp;Ahmed M. Fouda,&nbsp;Anwar Ul-Hamid","doi":"10.1007/s10904-024-03390-z","DOIUrl":"10.1007/s10904-024-03390-z","url":null,"abstract":"<div><p>Ternary CSs/PAA-Al₂O₃ NPs (carbon spheres/polyacrylic acid-aluminum oxide nanoparticles) were prepared using the sol-gel method. The main purpose of the current investigation is to increase the catalytic and antibacterial performance of CSs/PAA-doped Al₂O₃ NPs. PAA and CSs are used as doping agents as they increase the charge kinetics by reducing the e⁻/h⁺ pair recombination rate of Al₂O₃. The as-prepared samples were examined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV-vis spectra. According to the XRD pattern, Al₂O₃ was crystalline with orthorhombic structure and measured crystallite size was found to be decreased upon doping. Conversely, dopants effectively increased the band gap energy from 5.09 to 5.25 eV of prepared samples. Nanoparticles were observed in the TEM micrographs and particle size decreases with the incorporation of dopants. The experimental findings proved that the CSs doped specimens provided better catalytic and antibacterial activity than binary ones (PAA- Al₂O₃) and pure Al₂O₃. 4% CSs/PAA-Al₂O₃ demonstrated a maximal degradation 86.3% (neutral medium) 83.3% (acidic and basic environments) within eight min. 4% CSs/PAA-Al₂O₃ revealed the inhibitory diameter against <i>E. coli</i> was about 9.15 ± 0.02 mm. Furthermore, in silico molecular docking studies verified the postulated microbicidal mechanism, which showed that these nanostructures may block the enzymes FabH and FabI responsible for the fatty acid pathway.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2574 - 2588"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Retraction Note: Biocompatibility and Antimicrobial Investigation of Agar-Tannic Acid Hydrogel Reinforced with Silk Fibroin and Zinc Manganese Oxide Magnetic Microparticles","authors":"Fatemeh Ganjali,&nbsp;Reza Eivazzadeh-Keihan,&nbsp;Hooman Aghamirza Moghim Aliabadi,&nbsp;Ali Maleki,&nbsp;Saeedeh Pouri,&nbsp;Reza Ahangari Cohan,&nbsp;Seyed Masoud Hashemi,&nbsp;Mohammad Mahdavi","doi":"10.1007/s10904-024-03468-8","DOIUrl":"10.1007/s10904-024-03468-8","url":null,"abstract":"","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"34 11","pages":"5664 - 5664"},"PeriodicalIF":3.9,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142789250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the Aqueous Battery-Type Energy Storage Systems Through UiO-66/Se/PANI Composite","authors":"Reda M. Nageib,&nbsp;Saad G. Mohamed,&nbsp;Mohamed Gaber,&nbsp;Ramadan M. Salm,&nbsp;Ayman A. EL Amin,&nbsp;Xuejin Li","doi":"10.1007/s10904-024-03426-4","DOIUrl":"10.1007/s10904-024-03426-4","url":null,"abstract":"<div><p>In pursuing efficient energy storage systems, extensive research has focused on novel materials and composites. Metal-organic frameworks (MOFs), particularly UiO-66, have emerged as attractive prospects due to their unique properties. In this study, we used solvothermal techniques to synthesize UiO-66, UiO-66/Se, and UiO-66/Se/PANI materials, which were subsequently characterized using various methods. X-ray photoelectron spectroscopy and Raman spectroscopy were used to identify the nature of the defects and the surface functional groups present in the UiO-66/Se/PANI composite. X-ray diffraction analysis revealed a significant degree of crystallinity, while transmission electron microscopy (TEM) and field-emission scanning electron microscopy (FE-SEM) provided additional insights into the structural characteristics of the materials. When utilized as the battery-type supercapacitors’ electrode material, the UiO-66/Se/PANI composite demonstrated exceptional capacity performance, reaching 607.3 C g^− 1 (168.7 mAh g^− 1) at 1 A g^− 1, along with outstanding coulombic efficiency and capacity retention even at a high current of 5 A g^− 1. An asymmetric device was constructed to investigate practical applications. In this device, UiO-66/Se/PANI was utilized as the positive electrode, while commercial activated carbon was the negative electrode. This device exhibited remarkable performance metrics, including a specific energy of 35.2 Wh kg^− 1, a specific power of 977.02 W kg^− 1, and a capacity retention rate of 79% after 5000 cycles, with a high coulombic efficiency of 99.5%. For application in zinc alkaline battery, UiO-66/Se/PANI demonstrated a 126 mAh g^− 1 capacity and demonstrated a high cycling lifespan, with 95.5% capacity retention after 1000 cycles and 93.6% rate properties. It also revealed a tremendous specific energy of 65.5 Wh kg^− 1 at the current density of 0.5 A g^− 1. This work encourages the development of novel cathode materials for alkaline zinc batteries and high-performance aqueous battery-type supercapacitors.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2792 - 2813"},"PeriodicalIF":3.9,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Dispersed Magnetic Fe3O4 Nanohydrogel Based on Gelatine by Gamma Irradiation for Toxic Heavy Metals Removal","authors":"Asmaa E. Elsayed,&nbsp;Sayed K. Attia,&nbsp;Ahmed M. Rashad,&nbsp;Ghada A. Mahmoud,&nbsp;Doaa I. Osman","doi":"10.1007/s10904-024-03387-8","DOIUrl":"10.1007/s10904-024-03387-8","url":null,"abstract":"<div><p>Heavy metals are among the problematic groups of contaminants. They are discharged from various industries. The wastewater disposed by heavy metals is causing major hazards to the environment. Different hydrogels based on Gelatin (gelt/AAm/EDTA) and nano- (Fe₃O₄/gelt/AAm/EDTA) were prepared by gamma radiation at 60 KGy and employed for heavy metals elimination. The structure and surface morphology of the manufactured hydrogels were confirmed with FTIR, X-ray, surface area, and SEM. The prepared hydrogels were characterized in terms of their gel content. The swelling properties were studied as a function of time. This research aims to investigate the adsorption properties of diverse hydrogels concerning heavy metal ions, specifically copper, cobalt, and nickel. The impact of key experimental factors, including initial metal concentration, temperature, time, and pH, was inspected via batch adsorption experiments utilizing atomic absorption spectroscopy. It was found that the adsorption of Cu⁺²‏, Co^+2‏ and Ni⁺²‏ ions is pH-dependent, and the optimal pH for adsorption of Cu⁺² is pH 4‏, Co⁺² ‏is 5, and Ni⁺²‏ is 4. The highest metals removal was copper, nickel, and cobalt ions by nano (Fe₃O₄/gelt/AAm/EDTA) hydrogel with removal percent 98.5% for Cu⁺², 96.8%for Ni⁺², and 93.9%for Co⁺².</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2546 - 2564"},"PeriodicalIF":3.9,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10904-024-03387-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nano-Synthesis of Crystalline 3D-Zr-Cluster-Porous Coordinated Polymer for CO2-Capture","authors":"Khaled M. Elsabawy,&nbsp;Ahmed M. Fallatah,&nbsp;Zeid O. Owidah","doi":"10.1007/s10904-024-03394-9","DOIUrl":"10.1007/s10904-024-03394-9","url":null,"abstract":"<div><p>Novel crystalline Zr(IV)-syn-3,4,6,7-tetramethyl-1,5-diazabicyclo(3.3.0)-octa-3,6-diene-2,8-dione porous coordinated polymers (PCPs) were successfully synthesized via advanced microwave assisted hydrothermal technique in 33 min. The present studies are aiming to optimize experimental conditions of the newly Zr(IV)- complex formation which is the initial monomeric precursor for Zr-PCPs. The molecular modeling studies of the principle ligand predicted by a two different stabilized geometrical positions can present together inside the crystal lattice of the produced 3D-Zr-PCPs. One of these two orientation models (Zigzag-like structure) which has strong priority to form disordered Zr-PCPs. The theoretical calculations of bond distances, indicated by existence of zirconium ions with average ionic radii of ~ 1.09Å (i.e. bond length of Zr⁴⁺-O = 2.18Å) which is very near to the (octa-coordinated zirconium with ionic redii ~ 0.98Å), due to presence of elongated bond distances between Zr-O inside unit cell. Furthermore, the synthesized crystalline Zr-complex was carefully characterized via micro-elemental analysis (C, H, O, N and M), XRD, SEM, 3D-AFM, Uv-Vis. as well as BET-specific surface area which was found relatively high of ~ 2125m²g^− 1. The synthesized Zr- PCPs exhibited substantially stronger CO₂ adsorption with maximum adsorption capacity of 2.61mmol/g at 273 K and 1 bar.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2589 - 2596"},"PeriodicalIF":3.9,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mucoadhesive Polymer Tangeretin Loaded Chitosan Nanoparticles to Combat the Resistance of Mycobacterium Tuberculosis","authors":"Yu-chen Zheng,&nbsp;Run-ze Qiu,&nbsp;Xin Da,&nbsp;Guang-chuan Dai,&nbsp;Xiang-rong Zhang","doi":"10.1007/s10904-024-03428-2","DOIUrl":"10.1007/s10904-024-03428-2","url":null,"abstract":"<div><p>Present methods of care the recommended course of treatment for <i>Mycobacterium tuberculosis</i> (MTB) resistance involves taking first-line medications orally for 4–6 months. Nonetheless, serious negative consequences result from this strategy. For the purpose of treating MTB resistance, chitosan nanoparticles (CSNPs) have been the subject of extensive research into controlled release drug delivery systems. A chitosan nanoparticle encapsulated O-polymethoxylated flavone called tangeretin was used in this investigation. Several approaches were used to characterize this nanoparticle (TN-CSNPs) that were successfully obtained. <i>Acinetobacter baumannii</i>, <i>Pseudomonas aeruginosa</i>, <i>Enterobacter</i> spp., <i>Staphylococcus aureus</i>, <i>Klebsiella pneumoniae</i>, and TB resistant strains were tested for antimicrobial activity in both planktonic and biofilm development phases. Utilizing the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) test in treated cells, the bioavailability of the nanoparticles has been evaluated. The TN-CSNPs demonstrated enhanced inhibitory effectiveness against both planktonic and adhering MTB strains, as well as resistant strains compared to chitosan alone treated groups. Additionally, the nanoparticles that were tested were found to be biocompatible with MRC-5 fibroblast cells. This suggests that they could be used to create novel therapeutic agents that are effective against MTB and other multidrug-resistant infections.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2827 - 2838"},"PeriodicalIF":3.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}