Journal of Inorganic and Organometallic Polymers and Materials最新文献

{"title":"Eco-friendly Synthesis of CuO/PMMA Nanocomposite Films for Efficient Rhodamine B Dye Photocatalytic Degradation","authors":"F. Gomaa,&nbsp;M. I. Mohammed","doi":"10.1007/s10904-025-03613-x","DOIUrl":"10.1007/s10904-025-03613-x","url":null,"abstract":"<div><p>The current study investigates the photocatalytic degradation of Rhodamine B (RhB) dye using polymethyl methacrylate (PMMA) doped with copper oxide (CuO) nanoparticles (NPs) under UVc light, synthesized via a casting technique. The structural, thermal, and morphological properties of the nanocomposites were examined using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The XRD analysis revealed an average crystallite size of nearly 45 nm for CuO NPs. FTIR spectroscopy confirmed the interaction between CuO and PMMA by observing shifts in PMMA’s infrared peaks. The incorporation of CuO NPs reduced the optical bandgap, suggesting the formation of intermediate energy bands. SEM images indicated significant PMMA surface morphology changes due to CuO NPs dispersion. Adding CuO enhanced the thermal stability of PMMA, while dielectric measurements showed a decrease in ε’ and the loss tangent (tan δ) with increasing frequency. Furthermore, increasing CuO content led to higher AC electrical conductivity. The CuO/PMMA nanocomposites exhibited a photocatalytic degradation efficiency of 97.4% and a reaction rate constant of 0.031 in the degradation of RhB dye, attributed to the increased surface area of the nanocomposites that aids in capturing dye molecules. These results demonstrate that CuO/PMMA films are effective, environmentally friendly catalysts for treating organic pollutants in water and wastewater, with enhanced photocatalytic activity driven by the synergy between CuO NPs and the PMMA matrix.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5651 - 5673"},"PeriodicalIF":4.9,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of Graphene Oxide on the Physical Properties of the Inorganic 2D Semiconductor Material Based Indium(III) Sulfide","authors":"A. Timoumi,&nbsp;W. Belhadj,&nbsp;N. Bouguila,&nbsp;Y. Raviprakash,&nbsp;Ziad Moussa,&nbsp;Hatem M. Altass,&nbsp;Saleh A. Ahmed","doi":"10.1007/s10904-025-03640-8","DOIUrl":"10.1007/s10904-025-03640-8","url":null,"abstract":"<div><p>Thin-film-based solar cell research is a critical focus for materials scientists due to its rapid growth as a sustainable energy solution. Indium sulfide (In₂S₃) has emerged as a promising material in the development of CdTe-based photovoltaic devices. In₂S₃; an inorganic two-dimensional semiconductor, has attracted significant interest for its potential in thin-film photovoltaics, photoelectrochemical cells, and other energy-related applications. Despite this growing interest, the commercial form of In₂S₃ remains under characterized. In this study, we systematically investigate the physical characteristics of graphene oxide (GO) incorporated into powdered β-phase In₂S₃. The samples were analyzed using X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and impedance spectroscopy (IS). XRD analysis confirmed that all samples were polycrystalline and crystallized in the tetragonal β-phase, with a reduction in crystalline size as the GO content increased. XPS analysis indicated the formation of oxygen vacancies without significant changes in elemental composition. TEM images showed that GO was well dispersed across the surface of In2S3, resulting in a reduced particle size. Electrical characteristics, measured via impedance spectroscopy, showed semiconducting behavior with a decrease in resistance as temperature increased, indicating enhanced conductivity. The results suggest that GO-doped In₂S₃ pellets could serve as promising materials for photovoltaic systems, especially as optical windows in solar cells. The study offers valuable insights into the role of GO in modulating the properties of In₂S₃ and highlights its potential for optimizing materials used in solar applications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2767 - 2775"},"PeriodicalIF":3.9,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Influence of Neodymium Oxide on the Physical, Dielectric, and Radiation-Shielding Properties of Glasses Composed of Bismuth Zinc Borosilicate","authors":"Aljawhara Almuqrin,&nbsp;Jamelah S. Al-Otaibi,&nbsp;Norah Alwadai,&nbsp;Badriah Albarzan,&nbsp;M. S. Shams,&nbsp;Yasser S. Rammah,&nbsp;R. A. Elsad","doi":"10.1007/s10904-025-03619-5","DOIUrl":"10.1007/s10904-025-03619-5","url":null,"abstract":"<div><p>The melt-quenching approach was used in this work to create several batches of bismuth zinc borosilicate glasses enriched with different amounts of neodymium (Nd₂O₃) oxides. Substituting B₂O₃ with Nd₂O₃ y increases the density of the resulting glass sample. Upon increasing the concentration of Nd₂O₃ from 0 to 1.2 mol%, the glass molar volume decreases. The structure of the glasses under study has been examined using a Fourier transform infrared spectrometer. Incorporating Nd-ions into the glass’s network increases the number of non-bridging oxygen (NBO) ions in its internal molecular structure. A broad variety of frequencies was used to study the dielectric properties. The dielectric constant level (εʹ) increases steadily as the amount of Nd₂O₃ increases. Electrical conductivity (σ_ac) increases with applied frequency. The addition of Nd₂O₃ causes σ_ac and εʹ to rise due to the breakdown of the glass network’s structure and the rise in (NBO). The energy absorption (EABF) and exposure building factor (EBF) for the glasses under investigation have been determined at deep penetration levels of 0.5–40 mfp in photon energy extends between 0.015 and 10 MeV. Fast neutron removal sectionals (FNRCS) utilizing the G-P fitting method and a glasses’ equivalent atomic numbers Zeq, EBF, and EABF were computed using Phy-X/PSD software. The reported EBF and EABF have been displayed to rely on penetration depths, photon energy, and the glass sample’s Nd₂O₃ mol% content. Compared to other samples, Nd-1.2 glass has been found to offer better gamma-ray shielding. The results of this study may also be useful for radiation shielding applications in nuclear engineering, industry, and health.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5736 - 5750"},"PeriodicalIF":4.9,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Characterization, and Electrical Properties of CdO-Doped Polyaniline for Enhanced Hole Extraction and Performance in Inverted Perovskite Solar Cells","authors":"Ashraf Abozid,&nbsp;Ahmed Mourtada Elseman,&nbsp;Elsayed M. Elnaggar,&nbsp;Ali M. Hassan","doi":"10.1007/s10904-024-03551-0","DOIUrl":"10.1007/s10904-024-03551-0","url":null,"abstract":"<div><p>PEDOT: PSS is recognized as one of the most conductive polymers used as an organic hole transport layer (HTL) in inverted perovskite solar cell (PSC) structures. However, its acidic nature and valence band mismatch with the adjacent perovskite layer often led to reduced efficiency and lower open-circuit voltage (V_OC) in PSCs. To address these limitations, we incorporated polyaniline (PANI) doped with varying amounts of CdO (x = 0, 1, 5, and 10%), referred to as PANI-CdO (x%). The synthesized CdO samples were thoroughly characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Electrical measurements demonstrated that the addition of CdO enhanced the conductivity and mobility of PANI, contributing to the improved performance of the PSCs. Specifically, the device incorporating the CdO (5%)-doped PANI exhibited superior power conversion efficiency (PCE) of 14.71%, compared to 13.38% for the pristine PEDOT: PSS device. Additionally, V_OC increased from 1.02 V (pristine PEDOT: PSS) to 1.11 V (CdO 5% doped PANI), reflecting better energy band alignment and reduced recombination losses. Furthermore, the short-circuit current density (J_SC) also improved from 17.01 mA/cm² to 17.67 mA/cm², indicating enhanced charge extraction and transport efficiency.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 6","pages":"4692 - 4709"},"PeriodicalIF":4.9,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10904-024-03551-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145162193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessment of Thermodynamic Properties of SrSnO3 Perovskite for Enhanced Photocatalytic Applications","authors":"Shafia Kanwal,&nbsp;Ahmad K. Badawi,&nbsp;Asad Muhammad Khan,&nbsp;Rafaqat Ali Khan,&nbsp;Warda Shahzad,&nbsp;Bushra Ismail","doi":"10.1007/s10904-025-03621-x","DOIUrl":"10.1007/s10904-025-03621-x","url":null,"abstract":"<div><p>Textile wastewater contains hazardous dyes, chemicals, and heavy metals that threaten ecosystems. Perovskites, known for their strong photocatalytic and adsorption capabilities, present an innovative approach to breaking down pollutants and removing toxic substances effectively. Our research studies comprised the low-cost co-precipitation synthesis and modification of Sr_1 − xMn_xSnO₃ (x = 0, 0.4, and 0.6) perovskite, with cetyltrimethylammonium bromide (CTAB) for enhanced photocatalytic activity. The decrease in lattice constants calculated by X-ray diffraction data suggests that the manganese (Mn), doping distorts the strontium stannate, lattice. Energy dispersive X-ray spectroscopy, and scanning electron micrographs, show a stoichiometric distribution of elements and a uniform morphology which are crucial to efficient photocatalytic properties. Mn doping has been proven to decrease the band gap from 3.54 to 2.7 eV, which makes the material more efficient for visible light absorption by creating extra electronic states in the band structure of SrSnO₃. These extra states may overlap and interact with previously defined valance and conduction bands, shrinking the bandgap. Hence, Sr_0.4Mn_0.6SnO₃-CTAB proved an efficient visible light active photocatalyst to show degradation efficiency of 93% against anionic methyl orange dye.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5767 - 5789"},"PeriodicalIF":4.9,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Plasticizer modulation of dynamic mechanical properties and dielectric performance in sodium alginate-based biopolymer films","authors":"Heba Kandil,&nbsp;Fawzy G. El Desouky","doi":"10.1007/s10904-025-03623-9","DOIUrl":"10.1007/s10904-025-03623-9","url":null,"abstract":"<div><p>This work focuses on the effects of various plasticizers, such as glycerol (GLY), polyethylene glycol (PEG), and dioctyl phthalate (DOP) at 0%, 25%, and 50% concentrations, on the structure, dynamic mechanical behavior, and relaxation dynamics of charge carriers of sodium alginate (SA) film. The investigation of the structure was conducted using attenuated total reflectance fourier transform infrared (ATR-FTIR) and X-ray diffraction (XRD). The AT-FTIR analysis indicated changes in the OH and C–O bands of plasticized SA films, suggesting potential intermolecular interactions between the SA matrix and the plasticizers. Moreover, XRD revealed that GLY and PEG enhanced the amorphous phase of SA, promoting flexibility, while DOP increased crystallinity. Dynamic mechanical testing revealed that the pristine SA biofilm displayed a high storage modulus (<span>(:E^{prime})</span>) of 11 GPa at − 50 °C, indicating a stiff structure. The plasticization process with GLY, PEG, and DOP resulted in a decrease in the values to 0.09, 0.1, and 7.11 GPa, respectively, as well as a decrease in the glass transition temperature, which was attributed to weakened polymer chain interactions. The drastic reduction in storage modulus upon plasticization indicates enhanced flexibility. Dielectric measurements revealed significantly higher dielectric constants ranging from 1.65 × 10⁶ to 0.12 × 10⁶ at 0.1 Hz and direct current conductivity at lower frequencies, also decreasing in relaxation time for films plasticized with GLY and PEG linked to increased hydroxyl groups and higher amorphous content. These findings highlight the potential of SA films plasticized with GLY and PEG as advanced materials for electrochemical and conductive polymer electrode applications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5790 - 5804"},"PeriodicalIF":4.9,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10904-025-03623-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of Hydrophobic and Hydrophilic Functional Groups in Silica Nanoparticles on the Properties of Polypropylene","authors":"Elton José Sehnem,&nbsp;Bruna Louise Silva,&nbsp;Carla Dalmolin,&nbsp;Luiz Antonio Ferreira Coelho","doi":"10.1007/s10904-025-03633-7","DOIUrl":"10.1007/s10904-025-03633-7","url":null,"abstract":"<div><p>This study evaluates the hydrophobicity of silica nanoparticles and their role, at varying mass fractions, on the thermal, mechanical, and electrical properties of polypropylene (PP). Nanocomposites with mass fractions of 1.5%, 3%, and 6% were prepared via melt dispersion. Instrumental nanoindentation was employed to determine Young’s modulus and nanohardness. Thermal properties were analyzed using differential scanning calorimetry (DSC) and thermogravimetry (TG), while electrical properties were assessed through Electrochemical Impedance Spectroscopy (EIS). Phase morphology was characterized using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Across all samples, regardless of silica fraction and type, no significant changes were observed in the melting behavior of PP. However, higher silica fractions for both types showed increased thermal stability. EIS results indicated a 15% decrease in dielectric conductivity for nanocomposites containing hydrophobic nanoparticles compared to neat PP. Regarding mechanical properties, all nanocomposites exhibited a higher elastic modulus than the matrix, with an increase of up to 67.3% observed in samples containing 3% hydrophilic silica. These findings are interpreted based on the nanoparticle phase’s dispersion state and hydrophobic nature.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5954 - 5964"},"PeriodicalIF":4.9,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable Nanocomposite Fabrication from Pistachio Shells and Aluminum Cans: Alumina-Activated Carbon with Silver Ferrite Nanoparticles for High-Performance Supercapacitors","authors":"Soad Zahir Alsheheri,&nbsp;Reda S. Salama","doi":"10.1007/s10904-025-03620-y","DOIUrl":"10.1007/s10904-025-03620-y","url":null,"abstract":"<div><p>Recently, the valorization of agricultural and industrial wastes has gained significant attention for the synthesis of high-value nanomaterials. In this study, we investigate the synthesis and characterization of composite materials comprising activated carbon (AC) derived from pistachio shells, alumina nanoparticles (Al₂O₃) sourced from recycled aluminum cans, and silver ferrite nanoparticles (AgFeO₂) for potential energy storage applications. The nanocomposites were characterized using XPS, FTIR, BET, SEM, TEM, and EDX techniques to analyze their structural, chemical, and morphological properties. XPS analysis revealed the oxidation states and chemical interactions between the components, confirming the successful integration of AgFeO₂ into the AC and alumina matrix. FTIR spectra indicated the presence of hydroxyl, carbonyl, and ferrite functional groups. Textural analysis demonstrated that the composites possessed a hybrid microporous-mesoporous structure, with significant surface area retention and optimized pore sizes. TEM and SEM imaging showed uniform nanoparticle dispersion, highlighting the composites’ high structural integrity. Electrochemical evaluation indicated superior capacitive performance, with the 10 wt% AgFeO₂-Alum-AC composite achieving the highest specific capacitance (480 F/g at 0.7 A/g) and excellent cycling stability. These findings establish the AgFeO₂-modified Alum-AC composite as a viable material for high-performance supercapacitors.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5751 - 5766"},"PeriodicalIF":4.9,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A2AlInI6 (A = K, Rb, Cs) Double Perovskite Halides for Renewable Energy Applications: A DFT Study on Stability, Light Absorption, and Thermoelectric Performance","authors":"Nabeel Israr,&nbsp;Asma A. Alothman,&nbsp;Saikh Mohammad,&nbsp;Shamim Khan,&nbsp;G. Murtaza,&nbsp;Muhammad Saeed","doi":"10.1007/s10904-025-03634-6","DOIUrl":"10.1007/s10904-025-03634-6","url":null,"abstract":"<div><p>Double perovskite halides are promising candidates for addressing energy scarcity and hold significant potential for renewable energy applications. In this study, the physical properties of A₂AlInI₆ (A = K, Rb, or Cs) compounds were investigated using density functional theory (DFT) and the all-electron FP-LAPW method. The optimized structural parameters and negative formation energies confirm that these halides are structurally and thermodynamically stable in their cubic phase. Mechanical analysis reveals that K₂AlInI₆ exhibits a ductile nature, as indicated by its Pugh and Poisson ratios, while Rb₂AlInI₆ and Cs₂AlInI₆ demonstrate brittle characteristics. Electronic band structure calculations yield energy bandgaps of 2.10 eV, 2.08 eV, and 1.98 eV for K₂AlInI₆, Rb₂AlInI₆, and Cs₂AlInI₆, respectively, suggesting strong potential for light absorption in the visible spectrum. Optical properties, including the complex dielectric function, indicate superior absorption in the UV and visible ranges, further supporting their application in solar energy systems. Solar cell efficiency, evaluated using the Spectroscopic Limited Maximum Efficiency (SLME) approach via Jarvis software, confirms their suitability for photovoltaic devices. Additionally, thermoelectric properties were analyzed using semi-classical Boltzmann theory. At room temperature, the figure of merit (ZT) values for the compounds were found to be 0.74, 0.72, and 0.71, respectively. These values highlight their potential for integration into hybrid renewable energy systems, combining photovoltaic and thermoelectric functionalities.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 7","pages":"5965 - 5980"},"PeriodicalIF":4.9,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144868681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Copper Catalyzed Formation of Carbon–Silicon Bond: A Review","authors":"Rafid Jihad Albadr,&nbsp;Waam Mohammed Taher,&nbsp;Mariem Alwan,&nbsp;Mahmood Jasem Jawad,&nbsp;Hiba Mushtaq,&nbsp;Basim Mohammed Saadi,&nbsp;Aseel Smerat,&nbsp;Mosstafa Kazemi,&nbsp;Ramin Javahershenas","doi":"10.1007/s10904-024-03558-7","DOIUrl":"10.1007/s10904-024-03558-7","url":null,"abstract":"<div><p>Organosilicon chemistry is a valuable branch of chemistry science, particularly in organic synthesis, because compounds containing carbon–silicon (C–Si) bonds are valuable in various fields such as pharmaceuticals, agrochemicals, and materials science. Copper catalysts have emerged as a pivotal tool in the formation of carbon–silicon bonds, offering a sustainable and efficient alternative to traditional methods. The use of copper in catalyzing these reactions is advantageous due to its abundant availability and cost-effectiveness compared to other precious metals. Recent advancements have demonstrated that copper-catalyzed reactions are not only versatile but also exhibit high degrees of regio- and enantioselectivity, making them highly desirable for complex organic synthesis. The ability of copper to facilitate the formation of C(sp³)–Si bonds is particularly noteworthy, as these bonds are integral in the development of pharmaceuticals and in the synthesis of silicon-containing organic compounds, which are valuable in materials science. Moreover, the mild reaction conditions, coupled with the low toxicity of copper catalysts, align well with the principles of green chemistry, further underscoring the benefits of this approach. This review outlines the recent applications of copper catalysts (from 2010 to 2024) in the preparation of organosilicon compounds by substitution reactions and by addition reactions to imine, aldehyde and C=C double bonds.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 5","pages":"3197 - 3221"},"PeriodicalIF":4.9,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}