Journal of Inorganic and Organometallic Polymers and Materials最新文献

{"title":"Preparation of Delafossite CuMnO2 and Polyaniline Nanohybrid Electrode for Asymmetric Supercapacitor","authors":"Muhammad Arif,&nbsp;Aneela Bibi,&nbsp;Imen Safra,&nbsp;Abhinav Kumar,&nbsp;Jayanti Makasana,&nbsp;Suhas Ballal,&nbsp;RSK Sharma,&nbsp;Piyus Kumar Pathak,&nbsp;Rahul Raj Chaudhary","doi":"10.1007/s10904-025-03684-w","DOIUrl":"10.1007/s10904-025-03684-w","url":null,"abstract":"<div><p>The uninterruptible and renewable energy is a major challenge for this current era. It is therefore important to fabricate new energy storage devices to attained uninterruptible energy. Supercapacitors (SCs) is a well-known storage device which has greater stability, high charge and discharge rates, good power, and energy density. For SCs, its electrode is known as a vital part and here, delafossite CuMnO₂ and PANI nanohybrid electrode was fabricated via a simple hydrothermal technique. The generated hybrid material was characterized physically through various techniques like X-ray diffraction, Brunauer-Emmett-Teller, scanning electron microscopy, Fourier Transform infrared spectroscopy, and energy dispersive X-ray spectroscopy to confirm the crystallinity, high surface area, pore radius, morphological, functional group, and elemental composition respectively. The electrochemical investigation of CuMnO₂/PANI nanocomposite was invested via three electrodes and asymmetric in 3 M KOH. The analysis showed a noteworthy C_sp of 1411 F g⁻¹ at 1 A g⁻¹ and cyclic stability was 3000th cycles. The asymmetric device showed the ideal C_sp of 146.82 F g⁻¹ with a current density of 1 A g⁻¹ and E_d of 90 Wh kg⁻¹. SCs can also be utilized as dependable energy storage devices in urgent door-opening technologies for different air buses.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6643 - 6658"},"PeriodicalIF":4.9,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural Stability, Half-Metallic Ferromagnetism, Magneto-Optical, and Thermoelectric Properties of Europium-Based Ternary Zintl Compounds EuZn2C2(C = P, As): A Promising Alternative for Spintronics and Thermoelectric Applications","authors":"Sadia Yasin,&nbsp;Hayat Ullah,&nbsp;Khamael M. Abualnaja,&nbsp;Ghulam Murtaza","doi":"10.1007/s10904-025-03692-w","DOIUrl":"10.1007/s10904-025-03692-w","url":null,"abstract":"<div><p>For optimal spintronic device performance, high spin-polarized materials are crucial to facilitate efficient spin injection from ferromagnets to semiconductors. The EuZn₂C₂ (C = P, As) Zintl compounds have been predicted to exhibit half-metallic behavior based on first-principles investigations of their structural, magneto-optical, and thermoelectric properties using the full-potential linearized augmented plane wave (FP-LAPW) method. The PBE-GGA potential was employed to obtain theoretical results consistent with available experimental data for structural determination of europium compounds, while the GGA + U, mBJ, and SOC methods were utilized to improve the accuracy of electronic and magnetic properties. A comparative analysis of the compounds in their stable ferromagnetic, paramagnetic, and antiferromagnetic phases revealed that the ferromagnetic phase is more suitable for investigating magnetic properties. The calculated density of states (DOS) and band structures showed strong hybridization between the Eu-f state and the Zn-d and (P, As)-p states in the valence band, resulting in the formation of a half-metallic gap. The orbital hybridizations (d-f, p-d, and d-d) were found to contribute to the gap formation. Moreover, the strength of exchange splitting between the e.g. and t_2g states, determined by the occupation and distribution of electronic states, was found to influence the size of the gap. The calculated total magnetic moment of the EuZn₂ × ₂ compound confirmed strong ferromagnetism. Furthermore, the effects of spin-orbit coupling on the electronic structure were investigated, and the thermoelectric properties were computed using Boltzmann transport theory. The Curie temperatures were also determined. Notably, the EuZn₂C₂ (C = P, As) Zintl compounds exhibited Curie temperatures significantly higher than room temperature, making them promising candidates for spintronic applications due to their strong ferromagnetism and metallic nature.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6739 - 6760"},"PeriodicalIF":4.9,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"PEO Based Nanocomposite With Improved Structural and Optical Properties","authors":"Siyamand S. Khasraw,&nbsp;Dyari M. Mamand,&nbsp;Salah R. Saeed,&nbsp;Peshawa O. Hama,&nbsp;Abdollah Hassanzadeh,&nbsp;Dara M. Aziz,&nbsp;Pshko A. Mohammed,&nbsp;Rebar T. Abdulwahid,&nbsp;Shujahadeen B. Aziz","doi":"10.1007/s10904-025-03656-0","DOIUrl":"10.1007/s10904-025-03656-0","url":null,"abstract":"<div><p>The development of advanced UV protective materials is crucial for human health and enhancing the longevity of electronic devices, especially through transparent UV shielding coatings that block harmful UV radiation without compromising visibility. This study presents a novel approach by developing polyethylene oxide (PEO)-based nanocomposites doped with vanadium pentoxide (V₂O₅) nanoparticles, which exhibit enhanced structural, optical, and dielectric properties. Nanocomposite films were synthesized using the solvent-casting method with V₂O₅ doping concentrations ranging from 1 to 7 wt%. Key techniques, including ATR-FTIR, XRD, FESEM, UV-vis spectroscopy, and dielectric analysis, were employed to investigate the material properties. ATR-FTIR analysis demonstrated significant interactions between PEO and V₂O₅, while XRD revealed reduced crystallinity and crystallite size. FESEM showed morphological changes, including the formation of smaller spherulites and a porous structure at lower doping concentrations, which transitioned to aggregation and larger spherulites at higher V₂O₅ concentrations. Optical studies indicated a reduction in the optical bandgap from 5.44 eV for pure PEO to 1.89 eV for PEO doped with 7 wt% V₂O₅, due to enhanced polarization and localized electronic states. Dielectric studies highlighted a marked increase in the high-frequency dielectric constant from 3.31 to 6.12. These findings present a promising pathway for the design of advanced UV shielding materials with improved light absorption, polarizability, and optical performance, contributing to the development of novel applications in nonlinear optical devices, sensors, and photonic systems.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6290 - 6316"},"PeriodicalIF":4.9,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Comprehensive Analysis of CoHfX (X = As, Bi) Half Heusler Alloys: Implications for High-Performance Thermoelectric and Photovoltaic Devices","authors":"Bharti Gurunani,&nbsp;Dinesh C. Gupta","doi":"10.1007/s10904-024-03279-x","DOIUrl":"10.1007/s10904-024-03279-x","url":null,"abstract":"<div><p>The linearized full-potential augmented plane wave method within the framework of density functional theory (DFT) was employed to investigate the structural, elastic, electronic, optical and thermoelectric properties of the cobalt-based half-Heusler alloy CoHfX (X = As, Bi). The exchange-correlation functional was treated using the generalized gradient approximation of Perdew-Burke-Ernzerhof (GGA-PBE) and the Tran-Blaha-modified Becke-Johnson (TB-mBJ) approach as implemented in the WIEN2k package. The results indicate that the studied material is mechanically stable, suggesting its potential for experimental synthesis. Noteworthy findings include Debye temperatures of 317.42 K for CoHfAs and 343.26 K for CoHfBi, highlighting distinct thermal behaviors. The electronic band structures and density of states confirm the semiconductor nature of these compounds, with indirect band gaps of 1.36 eV for CoHfAs and 1.12 eV for CoHfBi, as determined using the TB-mBJ approximation. To examine the thermoelectric properties, including the Seebeck coefficient (S), electrical conductivity (σ), thermal conductivity (κ), and figure of merit (ZT), Boltzmann transport equations within the DFT framework were employed. The significant values obtained for the figure of merit and Seebeck coefficient indicate that CoHfX alloys are promising candidates for thermoelectric applications. The materials under investigation also exhibit exceptional absorption coefficients (α(ω)) in the ultraviolet and visible regions of the light spectrum, making them suitable for photovoltaic and optical equipment manufacturing. To date, no experimental or theoretical studies have been conducted on the half-Heusler alloy CoHfX. Consequently, the theoretical findings regarding the structural, elastic, electronic, magnetic, and thermoelectric properties are likely to be corroborated by future experimental investigation.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 4","pages":"2327 - 2343"},"PeriodicalIF":3.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143900690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Integrative Approach and Computational Simulations of Hydrated Form of 5-Amino-1H-1,2,3,4-Tetrazole Single Crystal","authors":"M. G. Darsana,&nbsp;D. G. Arya,&nbsp;B. R. Bijini","doi":"10.1007/s10904-025-03683-x","DOIUrl":"10.1007/s10904-025-03683-x","url":null,"abstract":"<div><p>In this study, solvothermal synthesised CH₆N₅O single crystals were explored. The colourless crystals of ~ 0.5 × 0.4 × 0.3 mm dimensions were characterized comprehensively. SC-XRD provided atomic-level information, and PXRD demonstrated phase purity. Thermal stability and decomposition were analysed using TGA and DSC, revealing an activation energy of 2.04 kJ/mol derived from Kissinger’s plot. UV-Vis-NIR spectroscopy identified a bandgap of 4.5 eV, suitable for optoelectronic devices. Optical analyses further unveiled a reactivity index of 0.4976, polarizability of 8.6573 a.u, a transition dipole moment of 27.6707 Debye*eV, and a fraction of filled states of 0.9988, emphasising its high optical performance. The effective mass was calculated as 38.5716, contributing to the electronic transport properties. From Hirshfeld surface analysis, significant O-H/H-O interactions were identified, contributing to non-linear optical properties. DFT studies correlated theoretical findings with experiments, establishing a HOMO-LUMO gap of 4.45 eV and moderate electrophilicity, hinting at catalytic ability. The dose-response curve of biological evaluations revealed a maximum response of 0.97, a rate of 4.01, and a half-dose maximum of 0.60. Computational MolPredictX studies showed high activity probability against therapeutic targets such as COX2, iNOS, JNK-3, NADPH, and PDE5, positioning this material as a multi-target Alzheimer’s therapeutic agent. Toxicity studies hinted at possible side effects warranting further modifications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6611 - 6642"},"PeriodicalIF":4.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Improved OER Performance at High Current Density for the CuCo2S4@MIL-53(Fe) Composite Electrocatalyst","authors":"Qinyuan Yu,&nbsp;Jiahui Li,&nbsp;Yufen Wang,&nbsp;Xuedong Wei","doi":"10.1007/s10904-025-03659-x","DOIUrl":"10.1007/s10904-025-03659-x","url":null,"abstract":"<div><p>Transition metal sulfides (TMS) have drawn increasing research interest owing to their unique electronic structure. They hold broad prospects in accelerating the sluggish oxygen evolution reaction (OER) during water electrolysis. Metal-organic frameworks (MOFs) feature controllable electronic structures and specific surface areas, which facilitate the adsorption of reactants and expedite interfacial electron transfer. Leveraging the above-mentioned advantages of the two materials, a kind of composite electrocatalyst, CuCo₂S₄@MIL-53(Fe)/NF, was synthesized by growing MIL-53(Fe) in-situ onto CuCo₂S₄ nanowires supported on nickel foam. This composite electrocatalyst can accelerate charge transfer, significantly increase the number of active sites, and enhance both electrocatalytic activity and stability. The electrocatalyst CuCo₂S₄@MIL-53(Fe)/NF can drive the OER with an overpotential of 390 mV at a current density of 100 mA·cm⁻². Moreover, it still demonstrates excellent catalytic activity after 75 h of testing. This study not only broadens the avenues for sulfide composites but also provides an experimental basis and support for the direct combination of metal chalcogenides and Fe-based MOFs as electrocatalysts.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6344 - 6354"},"PeriodicalIF":4.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tailoring the Adsorption and Sensing Properties of S Containing Molecules on the Novel Ag Cluster Decorated BSe Nanosheets: A Comparative DFT Study","authors":"M. A. Farag,&nbsp; Altalbawy,&nbsp;Pawan Sharma,&nbsp;Jayanti Makasana,&nbsp;I. A Ariffin,&nbsp;Mayank Bhushan,&nbsp;Shilpa Sharma,&nbsp;Shoira Formanova,&nbsp;Iman Samir Alalaq,&nbsp;Jasim Mohammed Abbas,&nbsp;Sadeq K Thajeel,&nbsp;Khursheed Muzammil,&nbsp;Marwea Al-hedrewy","doi":"10.1007/s10904-025-03657-z","DOIUrl":"10.1007/s10904-025-03657-z","url":null,"abstract":"<div><p>Two-dimensional nanomaterials, thanks to their exclusive physical properties and enhanced surface area, play a critical role in the molecular sensing technology, principally in the area of monitoring the concentrations of atmospheric pollutants. In this study, we have broadly scrutinized the interaction and sensing capabilities of modified BSe monolayers via introducing clusters composed of Ag metals based on utilizing density functional theory. Upon the modification of BSe with Ag clusters, the adsorption capacity and energy of BSe monolayers for S containing SO₂F₂, SOF₄, SO₂, thiophene and thiopyrylium meaningfully increased, indicating an evidently increased affinity. To further clarify the sensing phenomenon, we conducted a detailed investigation on the charge exchange, charge density difference between organic molecules and modified BSe, and the projected density of states (DOS). Diverse configurations for S containing molecules oriented above the decorated BSe monolayers were modeled and optimized using DFT. The conductivity and recovery time were also inspected for sensing substrates. The outstanding performance of Ag₄ cluster modified BSe monolayer towards the regarded molecules demonstrates its noteworthy value in practical applications for designing intelligent sensors.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6317 - 6326"},"PeriodicalIF":4.9,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Evaluation of Potential Usage of Ti4N3Tx MXene as Interface Layer Catalyst of Bipolar Membrane","authors":"Aytekin Çelik,&nbsp;Yunus Aksoy,&nbsp;Özge Hanay,&nbsp;Umay Halisdemir,&nbsp;Halil Hasar","doi":"10.1007/s10904-025-03669-9","DOIUrl":"10.1007/s10904-025-03669-9","url":null,"abstract":"<div><p>Modifications to the membrane and interface layer are crucial for enhancing bipolar membrane (BPM) performance. This study investigates the potential use of Ti₄N₃T_x in the BPM interface layer. Ti₄N₃Tₓ was synthesized from the Ti₄AlN₃ MAX phase via salt melting, and its successful synthesis was confirmed through X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetric analysis, atomic force microscopy, and water contact angle analyses. Incorporating Ti₄N₃T_x significantly increased BPM hydrophilicity. The water uptake capacity of BPM-1/PS (without Ti₄N₃Tₓ) and BPM-3/PS (containing 0.4 wt% Ti₄N₃Tₓ in polymer suspensions) was 10% and 17%, respectively. The Young’s modulus of BPM-1/PS was 634 MPa, whereas BPM-2/PS (with 0.2 wt% Ti₄N₃Tₓ in polymer suspension) exhibited 963 MPa, enhancing BPM stability. However, increasing the MXene content raised electrical resistance from 0.26 Ω·cm² (BPM-1/PS) to 2.00 Ω·cm². Compared to conventional BPM interface materials, such as metal oxides and carbon-based nanomaterials, Ti₄N₃Tₓ MXene offers a unique combination of tunable hydrophilicity, mechanical reinforcement, and surface charge modulation, providing an alternative strategy for optimizing BPM performance. These findings suggest that MXene-modified BPMs are promising for electrochemical water splitting, electrodialysis, and redox flow batteries, as well as wastewater treatment and energy storage applications.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6466 - 6478"},"PeriodicalIF":4.9,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10904-025-03669-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Spinach to the Rescue: Unveiling the Antibacterial and Anticancer Potential of Biogenic Zinc-Doped Hydroxyapatite Nanoparticles","authors":"K. Arun,&nbsp;G. Shobana,&nbsp;V. Gayathri,&nbsp;E. Ranjith Kumar,&nbsp;M. Saravanakumar,&nbsp;Perwez Alam,&nbsp;Vasudeva Reddy Minnam Reddy,&nbsp;Woo Kyoung Kim","doi":"10.1007/s10904-025-03660-4","DOIUrl":"10.1007/s10904-025-03660-4","url":null,"abstract":"<div><p>This study reports the green synthesis of zinc-doped hydroxyapatite nanoparticles (ZnHANPs) using spinach extract as a novel bio-template. The synthesized ZnHANPs were characterized using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). XRD analysis confirmed the crystalline nature of the ZnHANPs with an average crystallite size of 100 nm. FT-IR spectra revealed the presence of characteristic functional groups associated with hydroxyapatite. SEM and TEM images showed predominantly rod-shaped nanoparticles, a morphology advantageous for bone regeneration and targeted drug delivery. Elemental mapping confirmed the presence of Zn, Ca, P, and O. The synthesized ZnHANPs exhibited significant antioxidant activity, demonstrating a concentration-dependent increase in DPPH radical scavenging. Furthermore, the ZnHANPs displayed potent antibacterial activity against both Gram-positive (<i>Bacillus subtilis</i>) and Gram-negative (<i>Escherichia coli</i>) bacteria, with greater efficacy observed against <i>B. subtilis</i>. Importantly, the ZnHANPs demonstrated significant anticancer activity against MCF-7 breast cancer cells. MTT assays revealed an IC₅₀ value of 46 mg/mL. Dual staining (AO/EtBr) and DAPI assays confirmed that ZnHANPs induced apoptosis in MCF-7 cells by increasing ROS production and causing DNA damage. These findings highlight the potential of green-synthesized ZnHANPs as promising candidates for biomedical applications, including bone regeneration, antibacterial agents, and cancer therapy.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6355 - 6365"},"PeriodicalIF":4.9,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145021686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Comprehensive Review on Application of Different Natural and Chemically Modified Nanomaterials Adsorbents for Heavy Metals Removal","authors":"R. L. Nibe,&nbsp;R. W. Gaikwad","doi":"10.1007/s10904-024-03469-7","DOIUrl":"10.1007/s10904-024-03469-7","url":null,"abstract":"<div><p>The present study is a comprehensive review of environmental problems raised by various heavy metal ions. Due to various heavy metal ions such as Cd (II), Pb (II), Cr (VI), Hg (II), Sr (II), and many more in the environment harm people’s health because they are poisonous and persistent. Also, it spreads toxicity and carcinogenicity to ecosystems and living things. Various hazardous effects of heavy metals are such as toxicity, bioaccumulation, and environmental pollution. The heavy metals basically cause the neurological disorders, kidney damage, liver damage, cardiovascular disease and sometimes cancer. To address the issue of heavy metal ions using various nanomaterials and natural resources through efficient and effective ways is reported in the present review. The use of natural zeolites and their derivatives used for heavy metal removal were systematically discussed. The characteristics of the heavy metal after the surface modification were investigated using various analytical techniques such as FTIR, XRD, BET, TEM, AFM, SEM–EDX, Raman spectroscopy, etc. The higher adsorption efficiencies of various inorganic nanomaterials were observed because of their solid and active sites, interactions, complexation, and reduction mechanisms. Natural zeolite and other inorganic nanomaterials such as GO, MXene, MoS₂, hBN, and TiO₂ were found to be effective and efficient adsorbents with surface-modified chemicals for the degradation and removal of heavy metal ions from different industrial wastewater streams.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 5","pages":"3222 - 3242"},"PeriodicalIF":4.9,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}