Journal of Inorganic and Organometallic Polymers and Materials最新文献_第6页

Ecofriendly Synthesis of Silver Nanoparticle for Phytochemical Screening, Photocatalytic and Biological Applications 用于植物化学筛选、光催化和生物应用的银纳米粒子的生态友好合成

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-23 DOI: 10.1007/s10904-024-03326-7

Nayab Nadeem, Aqsa Habib, Shabeeb Hussain, Abu Sufian, Ishaq Ahmad, Fozia Noreen, Arslan Mehmood, Furqan Ali, Khalid Mujasam Batoo, Muhammad Farzik Ijaz

{"title":"Ecofriendly Synthesis of Silver Nanoparticle for Phytochemical Screening, Photocatalytic and Biological Applications","authors":"Nayab Nadeem, Aqsa Habib, Shabeeb Hussain, Abu Sufian, Ishaq Ahmad, Fozia Noreen, Arslan Mehmood, Furqan Ali, Khalid Mujasam Batoo, Muhammad Farzik Ijaz","doi":"10.1007/s10904-024-03326-7","DOIUrl":"https://doi.org/10.1007/s10904-024-03326-7","url":null,"abstract":"Herein this manuscript we demonstrate phytochemical screening results of different parts of common medicinal plants including Acacia nilotica buds, Acacia nilotica leaf, Syzgium aromaticum buds, Syzgium cumini leaf, Terminalia chebula dried fruit and Azadirachta indica leaves. Based on largest TPC and TFC, bud extract of Acacia nilotica was selected for microwave-assisted biological fabrication of silver nanoparticles (Ag-NPs). UV-Vis spectroscopy confirmed silver nanoparticles with a surface plasmon resonance between 410 and 460 nm. FTIR analysis indicated the existence of various bioactive compounds from extract capped the Ag-NPs which increased their stability. Crystallinity, lattice parameters, symmetry and average crystallite size (about 8.73 nm) of prepared Ag-NPs were examined by powder XRD. The spherical shaped Ag-NPs observed in TEM images further supported the size and crystallinity calculated on the basis of of powder XRD analysis. The Ag-NPs efficiently degraded IC dye (about 86.12%) at pH 3 and exhibited strong antibacterial activity against S. aureus and E. coli. This approach offers a quick, energy-efficient method for producing high-yield and uniformly sized nanoparticles. Thus, microwave-assisted synthesis proves advantageous due to its reduced reaction time, lower energy consumption and the production of stable, non-aggregated green nanoparticles with narrow size distribution and high yield.<h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"1 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

DFT Analysis of Ba2NbRhO6: A Promising Double Perovskite for Sustainable Energy Applications Ba2NbRhO6 的 DFT 分析：一种有望用于可持续能源应用的双过氧化物

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-22 DOI: 10.1007/s10904-024-03336-5

Soufyane Belhachi, Samah Al-Qaisi, Saidi Samah, Habib Rached, Abid Zaman, Tahani A. Alrebdi, Abderrazak Boutramine, Nazia Erum, R. Ahmed, Ajay Singh Verma

{"title":"DFT Analysis of Ba2NbRhO6: A Promising Double Perovskite for Sustainable Energy Applications","authors":"Soufyane Belhachi, Samah Al-Qaisi, Saidi Samah, Habib Rached, Abid Zaman, Tahani A. Alrebdi, Abderrazak Boutramine, Nazia Erum, R. Ahmed, Ajay Singh Verma","doi":"10.1007/s10904-024-03336-5","DOIUrl":"https://doi.org/10.1007/s10904-024-03336-5","url":null,"abstract":"Our study employed the full-potential linearized augmented plane wave (FP-LAPW) approach within the density functional theory (DFT) framework to examine the fundamental characteristics of the Ba2NbRhO6 double perovskite. Our computed results align well with experimental measurements. The phonon dispersion relation confirmed the thermodynamic stability of Ba2NbRhO6, showing positive frequencies throughout. Structurally, the material is dominantly covalently bonded and mechanically predicted to be brittle. Electronic property analysis revealed an indirect band gap of 1.83 eV. The optical properties indicated a significant response in the ultraviolet and visible light spectra, with an absorption coefficient peaking at 200 × 104 cm−1 at 12 eV, an optical conductivity reaching up to 7575 ({Omega }^{-1}{text{cm}}^{-1}) at 5.35 eV, and a refractive index peaking at 3.3 at 3.4 eV. The material also exhibited a reflectivity of 0.74 at 13.5 eV. Thermoelectric properties, including power factor, electrical conductivity, and Seebeck coefficient, were also determined, with a notable Figure of Merit of 0.76 at room temperature and a power factor of 84.43 W K−2 m−1 s−1 at 700 K. These results suggest that Ba2NbRhO6 has considerable potential for application in thermoelectric devices.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"22 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing Solar Cell Efficiency: A Comparative Study of Lead-Free Double Halide Perovskites $$Rb_{2}CuAsBr_{6}$$ and $$Rb_{2}TlAsBr_{6}$$ using DFT and SLME Methods 提高太阳能电池效率：使用 DFT 和 SLME 方法对无铅双卤化物包光体 $$Rb_{2}CuAsBr_{6}$ 和 $$Rb_{2}TlAsBr_{6}$ 进行比较研究

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-22 DOI: 10.1007/s10904-024-03330-x

H. Fatihi, M. Agouri, H. Ouhenou, H. Benaali, A. Zaghrane, A. Abbassi, M. El Idrissi, S. Taj, B. Manaut

{"title":"Enhancing Solar Cell Efficiency: A Comparative Study of Lead-Free Double Halide Perovskites $$Rb_{2}CuAsBr_{6}$$ and $$Rb_{2}TlAsBr_{6}$$ using DFT and SLME Methods","authors":"H. Fatihi, M. Agouri, H. Ouhenou, H. Benaali, A. Zaghrane, A. Abbassi, M. El Idrissi, S. Taj, B. Manaut","doi":"10.1007/s10904-024-03330-x","DOIUrl":"https://doi.org/10.1007/s10904-024-03330-x","url":null,"abstract":"Recent advancements and developments in photovoltaic materials have made significant progress owing to the search for efficient and sustainable energy sources. Although lead halide perovskites have demonstrated impressive performance in solar cell applications, they face challenges such as environmental instability and lead toxicity. This study investigates several physical properties of two lead-free double halide perovskites, (Rb_{2}CuAsBr_{6}) and (Rb_{2}TlAsBr_{6}), and evaluates their potential for solar cell applications using density functional theory (DFT) within the Wien2k code and spectroscopic limited maximum efficiency (SLME) approach. The negative formation energy and Born criteria confirm the structural stability of both perovskites in the ideal cubic structure. Optoelectronic analyses reveal that (Rb_{2}TlAsBr_{6}), with a direct band gap of 1.51 eV, exhibits better photovoltaic characteristics compared to (Rb_{2}CuAsBr_{6}), which has an indirect band gap of 0.60 eV. Additionally, the SLME analysis shows that (Rb_{2}TlAsBr_{6}) achieves a higher SLME of approximately 31.4 %, compared to (Rb_{2}CuAsBr_{6}) which has a SLME of 7.44%. Moreover, the calculated thermoelectric properties show that (Rb_{2}TlAsBr_{6}) exhibits enhanced thermoelectric performance compared to (Rb_{2}CuAsBr_{6}). These findings highlight the potential of lead-free perovskites, particularly (Rb_{2}TlAsBr_{6}), for next-generation solar cell applications.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"48 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Zinc MOF and Melamine Sponge Composite: A Cutting-Edge Solution for Dose-Dependent Dye Degradation and Ultra-Sensitive Chemical Sensing of Nitro Derivatives and Sucrose 锌 MOF 和三聚氰胺海绵复合材料：用于硝基衍生物和蔗糖的剂量依赖性染料降解和超灵敏化学传感的尖端解决方案

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-21 DOI: 10.1007/s10904-024-03350-7

Vibhav Shukla, Nazrul Haq, Kafeel Ahmad Siddiqui

{"title":"Zinc MOF and Melamine Sponge Composite: A Cutting-Edge Solution for Dose-Dependent Dye Degradation and Ultra-Sensitive Chemical Sensing of Nitro Derivatives and Sucrose","authors":"Vibhav Shukla, Nazrul Haq, Kafeel Ahmad Siddiqui","doi":"10.1007/s10904-024-03350-7","DOIUrl":"https://doi.org/10.1007/s10904-024-03350-7","url":null,"abstract":"This study investigates the innovative applications of the [Zn9(Cei)6(Bimb)*9]n(Zn-MOF) metal-organic framework and its composite with melamine sponge (Zn-MOF@MS) in the domains of photocatalytic degradation and fluorescence sensing. The Zn-MOF@MS composite demonstrates exceptional performance in the photocatalytic degradation of Rose Bengal (RB) dye, achieving a high degradation rate under optimized conditions (pH 5, 10 mg/L RB concentration, 6 mg photocatalyst dosage, and 120-minute reaction time). Additionally, Zn-MOF exhibits notable fluorescence sensing capabilities, enabling the detection of 2-nitrotoluene (2NT) and sucrose at low concentrations, with detection limits of 0.298 ppm and 1.129 ppm, respectively. These results highlight the novel integration of Zn-MOF with a melamine sponge matrix, showcasing significant advancements in both environmental remediation and analytical chemistry. The study underscores the potential of Zn-MOF@MS as a versatile material with substantial implications for improving dye degradation processes and enhancing chemical sensing precision. This work advances the field by demonstrating the dual functionality of Zn-MOF materials and providing a robust platform for future research and technological development in environmental and analytical applications.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"12 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

First-Principles Investigation of Optoelectronic Structure and Thermodynamic Properties of Ruddlesden-Popper Halide Perovskites for Optoelectronic Applications 用于光电应用的 Ruddlesden-Popper Halide Perovskites 的光电结构和热力学性质的第一性原理研究

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-21 DOI: 10.1007/s10904-024-03338-3

Izaz Ul Haq, A. Abdelkader, Yahia A. H. Obaidat, Refka Ghodhbani, A. Haj Ismail, Amnah Mohammed Alsuhaibani, Imad Khan

{"title":"First-Principles Investigation of Optoelectronic Structure and Thermodynamic Properties of Ruddlesden-Popper Halide Perovskites for Optoelectronic Applications","authors":"Izaz Ul Haq, A. Abdelkader, Yahia A. H. Obaidat, Refka Ghodhbani, A. Haj Ismail, Amnah Mohammed Alsuhaibani, Imad Khan","doi":"10.1007/s10904-024-03338-3","DOIUrl":"https://doi.org/10.1007/s10904-024-03338-3","url":null,"abstract":"The structure optimization, nuclear magnetic resonance (NMR) shielding, optoelectronic and thermodynamic properties of 2D layered Ruddlesden-Popper halide perovskites (RP-HPs) Cs2CdX4 (X = Cl, Br, I) are computed using first-principles simulations. The crystal structure is composed of 2D [CdX4]n2n− plane constructed by CdX6 octahedral vertices and inorganic spacer cation (Cs+) separates the octahedral layers. At the valence band (VB) edge, X-p and Cd-p orbitals are strongly hybridized, which play a key role in the optoelectronic applications of these compounds owing to the excitation of their valence electrons to the conduction band (CB) with minimum photon’s energy. The pseudo-direct and tunable band gaps of the understudy 2D layered RP-HPs are well-suited for optoelectronic applications. The numerical values of Debye temperature illustrates that each compound excites with different Debye frequency, corresponds to the unit cell size and phonon’s wavelength. The specific heat capacity curves are consistent with equipartition theorem of classical mechanics and obey the Dulong-Petit law at high temperature. The positive entropy change (ΔS) spirits negative change in Gibb’s free energy (ΔG), confirming the stability of these materials. The isotropic chemical shift depends on Cd and halides coordinates therefore, Cd-δiso is decreases and X-δiso increases with the halide increments. The Cs-p, Cd-d, and X-s orbital play a key role in NMR shielding owing to their existence in lower VB.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"22 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comprehensive Insights into SrCfO3: Unravelling Its Multifaceted Properties Through DFT Calculations 全面了解 SrCfO3：通过 DFT 计算揭示其多方面特性

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-19 DOI: 10.1007/s10904-024-03329-4

Sakshi Gautam, Dinesh C. Gupta

{"title":"Comprehensive Insights into SrCfO3: Unravelling Its Multifaceted Properties Through DFT Calculations","authors":"Sakshi Gautam, Dinesh C. Gupta","doi":"10.1007/s10904-024-03329-4","DOIUrl":"https://doi.org/10.1007/s10904-024-03329-4","url":null,"abstract":"The current research utilized first-principles calculations to investigate the physical characteristics of SrCfO3 perovskite. These calculations were performed using the FP-LAPW method, which is a computational technique within the framework of Density Functional Theory. This method was implemented using the WIEN2k software package. In the study, the structural stability of the alloy was assessed using the Birch-Murnaghan equations of state. The key indicator used from these equations is the ground-state energy, which is a measure of the minimum energy configuration of the material’s atomic structure. In this research, it was found that the ground-state energy levels for the alloy was negative which indicates that the material is energetically stable in its current structural form. Electronic properties reveal the half-metallic nature of the alloy. We used the Debye quasi-harmonic model to investigate the thermodynamic properties of the alloy. The Boltz Trap code, integrated with WIEN2k software, was used to analyse the thermoelectric properties of the alloy. This analysis highlights SrCfO3 as a promising candidate for thermoelectric applications, thanks to its high-power factor. This suggests it could potentially contribute to advancements in energy harvesting and waste heat recovery technologies.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"14 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Novel Cellulose-Based Composite Hydrogel Microsphere Material: for Efficient Adsorption of Co(II) and Ni(II) Ions in Water 一种新型纤维素基复合水凝胶微球材料：用于高效吸附水中的钴（II）和镍（II）离子

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-19 DOI: 10.1007/s10904-024-03323-w

Jingru Zhao, Zifei Wei, Linan Sun, Ying Wang, Xiaodan Wu, Tao Wang, Zihan Wang, Yujie Fu

{"title":"A Novel Cellulose-Based Composite Hydrogel Microsphere Material: for Efficient Adsorption of Co(II) and Ni(II) Ions in Water","authors":"Jingru Zhao, Zifei Wei, Linan Sun, Ying Wang, Xiaodan Wu, Tao Wang, Zihan Wang, Yujie Fu","doi":"10.1007/s10904-024-03323-w","DOIUrl":"https://doi.org/10.1007/s10904-024-03323-w","url":null,"abstract":"Heavy metal ions contain highly toxic and non-biodegradable wastewater pollutants seriously contaminating the environment and affecting human health. Removal of heavy metal ions from the environment is a vital step towards the elimination of water pollution on a global scale. Therefore, in this study, cellulose was modified with L-cysteine, sodium alginate and polyethyleneimine to produce cellulose/sodium alginate /polyethyleneimine/L-cysteine composite hydrogel microspheres (WCMs/SA/PEI/L-Cys) in order to efficiently adsorb heavy metal ions. Co(II) and Ni(II) are successfully removed from water. After their production, the sorbents underwent examination using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy (FT-IR), and Scanning electron microscopy (SEM). In addition, the investigation of the mechanism and adsorption characteristics of cellulose-modified gel microspheres WCMs/SA/PEI/L-Cys has been completed. The majority of the adsorption of contaminants by cellulose-modified gel microspheres WCMs/SA/PEI/L-Cys adhered to the Langmuir isothermal adsorption model and quasi-secondary kinetic model. The intra-particle diffusion model was adopted for improving the fitting of the adsorption process in the materials. It was indicated that the internal and external diffusion acted together to eliminate the contaminants from the materials. When exploring the decontamination mechanism of the materials using XPS, it was shown that the functional groups containing nitrogen, oxygen and sulfur play a key role in removing contaminants. For Co(II) and Ni(II), the highest adsorption capacities of the sorbent were 358 and 373 mg/g, respectively. The material exhibited robust stability and recyclability based on the regeneration experiment results, remaining stable after six adsorption cycles and retaining over 80% of the initial adsorption amount.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Visual-Based Platform Using Sustainable Intrinsic Fluorescent Zn-Based Metal–Organic Framework for Detection of Folic Acid in Pharmaceutical Formulations 利用可持续本征荧光锌基金属有机框架的可视化平台检测药物制剂中的叶酸

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-19 DOI: 10.1007/s10904-024-03322-x

Idrees B. Qader, Sameera Sh. Mohammed Ameen, Hemn A. Qader, Khalid M. Omer

{"title":"Visual-Based Platform Using Sustainable Intrinsic Fluorescent Zn-Based Metal–Organic Framework for Detection of Folic Acid in Pharmaceutical Formulations","authors":"Idrees B. Qader, Sameera Sh. Mohammed Ameen, Hemn A. Qader, Khalid M. Omer","doi":"10.1007/s10904-024-03322-x","DOIUrl":"https://doi.org/10.1007/s10904-024-03322-x","url":null,"abstract":"In the present work, intrinsic fluorescent zinc-based metal–organic framework (FMOF-5) was prepared and used for folic acid (FA) detection. The intrinsic emission of zinc-based MOFs without encapsulation and/or functionalization of the ligand and/or the MOF is not very common. Here, the intrinsic emission of FMOF-5 is triggered by the coordination-induced emission of weakly fluorescent organic ligand in the framework structure. FMOF-5 showed fluorescence emission at 440 nm when excited at 300 nm. Common characterization techniques were used to investigate the size, morphology, and optical properties of the FMOF-5. The fluorescence emission of the prepared MOF was quenched by the internal filter effect, which gives us an opportunity to design a novel on-off mode sensor for the detection of FA. The conventional fluorometric-based assay and the smartphone-assisted visual detection mode were developed and validated. The visual-mode linearity was from 30 to 270 µM with limit of detection about 4.3 µM. The on-off sensor was successfully applied for detection of FA in pharmaceutical formulations with excellent recovery and reproducibility. The visual on-off mode using intrinsic fluorescent MOFs is highly appealing for pint of care testing applications.<h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"4 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced Cd2+ Adsorption Using Engineered Hydroxyapatite Nanoparticles 利用工程羟基磷灰石纳米颗粒增强对 Cd2+ 的吸附能力

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-18 DOI: 10.1007/s10904-024-03259-1

Sandeep Eswaran Panchu, Sarojini Jeeva Panchu, Vijayaraj Venkatachalam, Hendrik C. Swart, Moorthy Babu Sridharan, Narayana Kalkura Subbaraya

{"title":"Enhanced Cd2+ Adsorption Using Engineered Hydroxyapatite Nanoparticles","authors":"Sandeep Eswaran Panchu, Sarojini Jeeva Panchu, Vijayaraj Venkatachalam, Hendrik C. Swart, Moorthy Babu Sridharan, Narayana Kalkura Subbaraya","doi":"10.1007/s10904-024-03259-1","DOIUrl":"https://doi.org/10.1007/s10904-024-03259-1","url":null,"abstract":"The hydroxyapatite (HAp) nanoparticles were effectively engineered through a combination of ultrasonication and microwave techniques. This process significantly enhances the adsorbent’s specific surface area and particle size compared to microwave and other combinational techniques. The particle size of the adsorbent was effectively reduced to 30 ± 3 nm (length) and 10 ± 3 nm (width), with a crystallite size of 10 nm, an enhanced specific surface area of 105 m2/g. These modifications led to a significant acceleration in Cd2+ adsorption capacity, 195 mg/g at pH 7 in 20 min. The pseudo-second-order kinetic and Langmuir isotherm fitting confirm that Cd2+ adsorption occurs through chemisorption and that the adsorption is monolayer, respectively. The positive value of ΔH and the negative value of ΔG indicate that the adsorption of Cd2+ ions was endothermic and spontaneous, respectively. Very high and sustained regeneration efficiency was observed for HAp-UM (ultrasound and microwave treated HAp), 95% after seven regeneration cycles. The simple and rapid synthesis of HAp-UM demonstrates a drastic enhancement in Cd2+ ion removal capacity, making it a promising option for wastewater treatment.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"71 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biopolymer-CMTG and m-BPDM Based Hydrogel Composite for Promising Sensing of Zinc, Cadmium, and Mercury in Aqueous Medium 基于生物聚合物-CMTG 和 m-BPDM 的水凝胶复合材料可用于水介质中锌、镉和汞的检测

IF 4 3区化学

Journal of Inorganic and Organometallic Polymers and Materials Pub Date : 2024-08-17 DOI: 10.1007/s10904-024-03224-y

Priyanka Yadav, Sudhir G. Warkar, Anil Kumar

{"title":"Biopolymer-CMTG and m-BPDM Based Hydrogel Composite for Promising Sensing of Zinc, Cadmium, and Mercury in Aqueous Medium","authors":"Priyanka Yadav, Sudhir G. Warkar, Anil Kumar","doi":"10.1007/s10904-024-03224-y","DOIUrl":"https://doi.org/10.1007/s10904-024-03224-y","url":null,"abstract":"The detection of spectroscopically silent metal ions is challenging due to their electronic configuration (d10). A practical approach to overcome this issue is the use of complex-based sensing platforms for metal ion detection. However, sensing using these ligand-based complexes occurs only in organic media, hindering their large-scale applications. Therefore, the current study aims to develop a biopolymer-based hydrogel composite for colorimetric sensing in aqueous medium. The meta-benziporphodimethene (m-BPDM)-modified carboxymethyl tamarind gum (CMTG)/polyacrylamide (PAM) hydrogel was developed via in situ incorporation of m-BPDM into hydrogel matrix. Solid-state UV-visible spectroscopy, FTIR, MXRD, and SEM characterized the m-BPDM-modified CMTG-based hydrogel composite. The as-synthesized m-BPDM-modified hydrogel was applied as a sensor for the colorimetric sensing of Zn+ 2, Hg+ 2, and Cd+ 2 metal ions. It demonstrated a color change from pinkish red to dark blue in the aqueous solution of metal salts. The change in color of hydrogel upon contact with the metal solution was also validated by Solid UV-visible spectroscopy. Further, the impact of temperature, the concentration of heavy metal ions, solution pH on sensing time, and sensing of zinc ions in E. coli cells were investigated. The sensor’s performance was also assessed in industrial effluents to check its applicability in real-time applications. The quantitative determination of Zn+ 2, Hg+ 2, and Cd+ 2 from industrial effluents was confirmed using atomic absorption spectroscopy (AAS). This suggests that synthesized hydrogel can be utilized as a sensor for the visual on-site detection of zinc, cadmium, and mercury metal ions in an aqueous medium.","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"3 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0