Preparation of Delafossite CuMnO2 and Polyaniline Nanohybrid Electrode for Asymmetric Supercapacitor

IF 4.9 3区 化学 Q2 POLYMER SCIENCE
Muhammad Arif, Aneela Bibi, Imen Safra, Abhinav Kumar, Jayanti Makasana, Suhas Ballal, RSK Sharma, Piyus Kumar Pathak, Rahul Raj Chaudhary
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Abstract

The uninterruptible and renewable energy is a major challenge for this current era. It is therefore important to fabricate new energy storage devices to attained uninterruptible energy. Supercapacitors (SCs) is a well-known storage device which has greater stability, high charge and discharge rates, good power, and energy density. For SCs, its electrode is known as a vital part and here, delafossite CuMnO2 and PANI nanohybrid electrode was fabricated via a simple hydrothermal technique. The generated hybrid material was characterized physically through various techniques like X-ray diffraction, Brunauer-Emmett-Teller, scanning electron microscopy, Fourier Transform infrared spectroscopy, and energy dispersive X-ray spectroscopy to confirm the crystallinity, high surface area, pore radius, morphological, functional group, and elemental composition respectively. The electrochemical investigation of CuMnO2/PANI nanocomposite was invested via three electrodes and asymmetric in 3 M KOH. The analysis showed a noteworthy Csp of 1411 F g−1 at 1 A g−1 and cyclic stability was 3000th cycles. The asymmetric device showed the ideal Csp of 146.82 F g−1 with a current density of 1 A g−1 and Ed of 90 Wh kg−1. SCs can also be utilized as dependable energy storage devices in urgent door-opening technologies for different air buses.

非对称超级电容器用delafosite CuMnO2和聚苯胺纳米杂化电极的制备
不间断和可再生能源是当今时代的主要挑战。因此,制造新型储能装置以获得不间断能源是非常重要的。超级电容器具有稳定性好、充放电率高、功率大、能量密度高等特点,是一种众所周知的存储器件。对于纳米碳化硅来说,其电极是至关重要的组成部分,本文采用简单的水热技术制备了delafosite CuMnO2和PANI纳米杂化电极。通过x射线衍射、布鲁诺尔-埃米特-泰勒、扫描电镜、傅里叶变换红外光谱、能量色散x射线光谱等技术对合成的杂化材料进行了物理表征,分别确定了其结晶度、高比表面积、孔半径、形态、官能团和元素组成。在3 M KOH条件下,采用三电极不对称方式对CuMnO2/PANI纳米复合材料进行了电化学研究。分析表明,在1 a g−1时,Csp值为1411 F g−1,循环稳定性为3000次循环。非对称器件的理想Csp为146.82 F g−1,电流密度为1 a g−1,Ed为90 Wh kg−1。SCs还可以作为可靠的储能装置用于不同空中客车的紧急开门技术。
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来源期刊
CiteScore
8.30
自引率
7.50%
发文量
335
审稿时长
1.8 months
期刊介绍: Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.
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