{"title":"非对称超级电容器用delafosite CuMnO2和聚苯胺纳米杂化电极的制备","authors":"Muhammad Arif, Aneela Bibi, Imen Safra, Abhinav Kumar, Jayanti Makasana, Suhas Ballal, RSK Sharma, Piyus Kumar Pathak, Rahul Raj Chaudhary","doi":"10.1007/s10904-025-03684-w","DOIUrl":null,"url":null,"abstract":"<div><p>The uninterruptible and renewable energy is a major challenge for this current era. It is therefore important to fabricate new energy storage devices to attained uninterruptible energy. Supercapacitors (SCs) is a well-known storage device which has greater stability, high charge and discharge rates, good power, and energy density. For SCs, its electrode is known as a vital part and here, delafossite CuMnO<sub>2</sub> and PANI nanohybrid electrode was fabricated via a simple hydrothermal technique. The generated hybrid material was characterized physically through various techniques like X-ray diffraction, Brunauer-Emmett-Teller, scanning electron microscopy, Fourier Transform infrared spectroscopy, and energy dispersive X-ray spectroscopy to confirm the crystallinity, high surface area, pore radius, morphological, functional group, and elemental composition respectively. The electrochemical investigation of CuMnO<sub>2</sub>/PANI nanocomposite was invested via three electrodes and asymmetric in 3 M KOH. The analysis showed a noteworthy C<sub>sp</sub> of 1411 F g<sup>−1</sup> at 1 A g<sup>−1</sup> and cyclic stability was 3000th cycles. The asymmetric device showed the ideal C<sub>sp</sub> of 146.82 F g<sup>−1</sup> with a current density of 1 A g<sup>−1</sup> and E<sub>d</sub> of 90 Wh kg<sup>−1</sup>. SCs can also be utilized as dependable energy storage devices in urgent door-opening technologies for different air buses.</p></div>","PeriodicalId":639,"journal":{"name":"Journal of Inorganic and Organometallic Polymers and Materials","volume":"35 8","pages":"6643 - 6658"},"PeriodicalIF":4.9000,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of Delafossite CuMnO2 and Polyaniline Nanohybrid Electrode for Asymmetric Supercapacitor\",\"authors\":\"Muhammad Arif, Aneela Bibi, Imen Safra, Abhinav Kumar, Jayanti Makasana, Suhas Ballal, RSK Sharma, Piyus Kumar Pathak, Rahul Raj Chaudhary\",\"doi\":\"10.1007/s10904-025-03684-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The uninterruptible and renewable energy is a major challenge for this current era. It is therefore important to fabricate new energy storage devices to attained uninterruptible energy. Supercapacitors (SCs) is a well-known storage device which has greater stability, high charge and discharge rates, good power, and energy density. For SCs, its electrode is known as a vital part and here, delafossite CuMnO<sub>2</sub> and PANI nanohybrid electrode was fabricated via a simple hydrothermal technique. The generated hybrid material was characterized physically through various techniques like X-ray diffraction, Brunauer-Emmett-Teller, scanning electron microscopy, Fourier Transform infrared spectroscopy, and energy dispersive X-ray spectroscopy to confirm the crystallinity, high surface area, pore radius, morphological, functional group, and elemental composition respectively. The electrochemical investigation of CuMnO<sub>2</sub>/PANI nanocomposite was invested via three electrodes and asymmetric in 3 M KOH. The analysis showed a noteworthy C<sub>sp</sub> of 1411 F g<sup>−1</sup> at 1 A g<sup>−1</sup> and cyclic stability was 3000th cycles. The asymmetric device showed the ideal C<sub>sp</sub> of 146.82 F g<sup>−1</sup> with a current density of 1 A g<sup>−1</sup> and E<sub>d</sub> of 90 Wh kg<sup>−1</sup>. SCs can also be utilized as dependable energy storage devices in urgent door-opening technologies for different air buses.</p></div>\",\"PeriodicalId\":639,\"journal\":{\"name\":\"Journal of Inorganic and Organometallic Polymers and Materials\",\"volume\":\"35 8\",\"pages\":\"6643 - 6658\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2025-03-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Organometallic Polymers and Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10904-025-03684-w\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Organometallic Polymers and Materials","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10904-025-03684-w","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
摘要
不间断和可再生能源是当今时代的主要挑战。因此,制造新型储能装置以获得不间断能源是非常重要的。超级电容器具有稳定性好、充放电率高、功率大、能量密度高等特点,是一种众所周知的存储器件。对于纳米碳化硅来说,其电极是至关重要的组成部分,本文采用简单的水热技术制备了delafosite CuMnO2和PANI纳米杂化电极。通过x射线衍射、布鲁诺尔-埃米特-泰勒、扫描电镜、傅里叶变换红外光谱、能量色散x射线光谱等技术对合成的杂化材料进行了物理表征,分别确定了其结晶度、高比表面积、孔半径、形态、官能团和元素组成。在3 M KOH条件下,采用三电极不对称方式对CuMnO2/PANI纳米复合材料进行了电化学研究。分析表明,在1 a g−1时,Csp值为1411 F g−1,循环稳定性为3000次循环。非对称器件的理想Csp为146.82 F g−1,电流密度为1 a g−1,Ed为90 Wh kg−1。SCs还可以作为可靠的储能装置用于不同空中客车的紧急开门技术。
Preparation of Delafossite CuMnO2 and Polyaniline Nanohybrid Electrode for Asymmetric Supercapacitor
The uninterruptible and renewable energy is a major challenge for this current era. It is therefore important to fabricate new energy storage devices to attained uninterruptible energy. Supercapacitors (SCs) is a well-known storage device which has greater stability, high charge and discharge rates, good power, and energy density. For SCs, its electrode is known as a vital part and here, delafossite CuMnO2 and PANI nanohybrid electrode was fabricated via a simple hydrothermal technique. The generated hybrid material was characterized physically through various techniques like X-ray diffraction, Brunauer-Emmett-Teller, scanning electron microscopy, Fourier Transform infrared spectroscopy, and energy dispersive X-ray spectroscopy to confirm the crystallinity, high surface area, pore radius, morphological, functional group, and elemental composition respectively. The electrochemical investigation of CuMnO2/PANI nanocomposite was invested via three electrodes and asymmetric in 3 M KOH. The analysis showed a noteworthy Csp of 1411 F g−1 at 1 A g−1 and cyclic stability was 3000th cycles. The asymmetric device showed the ideal Csp of 146.82 F g−1 with a current density of 1 A g−1 and Ed of 90 Wh kg−1. SCs can also be utilized as dependable energy storage devices in urgent door-opening technologies for different air buses.
期刊介绍:
Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.