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Biodegradation behaviour of pharmaceutical compounds and selected metabolites in activated sludge. A forecasting decision system approach 活性污泥中药物化合物和特定代谢物的生物降解行为。预测决策系统方法
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2024-01-08 DOI: 10.1007/s40201-023-00890-x
Carmen Fernández-López, Mariano González García, Andrés Bueno-Crespo, Raquel Martínez-España
{"title":"Biodegradation behaviour of pharmaceutical compounds and selected metabolites in activated sludge. A forecasting decision system approach","authors":"Carmen Fernández-López,&nbsp;Mariano González García,&nbsp;Andrés Bueno-Crespo,&nbsp;Raquel Martínez-España","doi":"10.1007/s40201-023-00890-x","DOIUrl":"10.1007/s40201-023-00890-x","url":null,"abstract":"<div><p>Society's support upon chemicals over the last few decades has led to their increased production, application and discharge into the environment. Wastewater treatment plants (WWTPs) contain a multitude of these chemicals such us; pharmaceutical compounds (PCs). Often, their biodegradability by activated sludge microorganisms is significant for their elimination during wastewater treatment. In this paper the focus is laid on two PCs carbamazepine (CBZ) and diclofenac (DCF) and their main transformation products (TPs). Laboratory degradation tests with these two pharmaceuticals using activated sludge as inoculum under aerobic conditions were performed and microbial metabolites were analyzed by liquid chromatography-mass spectrometry (LC/MS-MS). In two different Mixed liquid Suspended Solids (MLSS) concentrations the biodegradability by activated sludge of CBZ and DCF were evaluated. Also, this article proposes a decision support system to optimize the prediction process of this type of pharmacological compounds. A study and analysis of the techniques of Support Vector Machine, Random Forest, Decision Trees and Multilayer Perceptron Network is carried out to select the most reliable and accurate predictor for the decision system. There are not significant differences in the removal of DCF with 30 mg MLSS/L and 60 mg MLSS/L. DCF was better removed than CBZ in all experiments studied. The TP detected in the samples were mainly 4-OH-DCF for DCF and 10, 11 EPOXICBZ for CBZ. The results show that the best models are obtained with Random Forest and Multilayer Perceptron Network techniques, with a model fit of more than 95% for both carbamazepine and diclofenac metabolites. Obtaining a root means square errors of 0.80 µg/L for the metabolite 4-OH-DCF for DCF with the technique Random Forest and a root means square errors of 1.13 µg/L for the metabolite 10, 11 EPOXICBZ for CBZ with the Multilayer Perceptron Network technique.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"229 - 243"},"PeriodicalIF":3.0,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139412273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanisms of microbial resistance against cadmium – a review 微生物抗镉机制综述
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-12-11 DOI: 10.1007/s40201-023-00887-6
Monu Sharma, Sonu Sharma,  Paavan, Mahiti Gupta, Soniya Goyal, Daizee Talukder, Mohd. Sayeed Akhtar, Raman Kumar, Ahmad Umar, Abdulrab Ahmed M. Alkhanjaf, Sotirios Baskoutas
{"title":"Mechanisms of microbial resistance against cadmium – a review","authors":"Monu Sharma,&nbsp;Sonu Sharma,&nbsp; Paavan,&nbsp;Mahiti Gupta,&nbsp;Soniya Goyal,&nbsp;Daizee Talukder,&nbsp;Mohd. Sayeed Akhtar,&nbsp;Raman Kumar,&nbsp;Ahmad Umar,&nbsp;Abdulrab Ahmed M. Alkhanjaf,&nbsp;Sotirios Baskoutas","doi":"10.1007/s40201-023-00887-6","DOIUrl":"10.1007/s40201-023-00887-6","url":null,"abstract":"<div><p>The escalating cadmium influx from industrial activities and anthropogenic sources has raised serious environmental concerns due to its toxic effects on ecosystems and human health. This review delves into the intricate mechanisms underlying microbial resistance to cadmium, shedding light on the multifaceted interplay between microorganisms and this hazardous heavy metal. Cadmium overexposure elicits severe health repercussions, including renal carcinoma, mucous membrane degradation, bone density loss, and kidney stone formation in humans. Moreover, its deleterious impact extends to animal and plant metabolism. While physico-chemical methods like reverse osmosis and ion exchange are employed to mitigate cadmium contamination, their costliness and incomplete efficacy necessitate alternative strategies. Microbes, particularly bacteria and fungi, exhibit remarkable resilience to elevated cadmium concentrations through intricate resistance mechanisms. This paper elucidates the ingenious strategies employed by these microorganisms to combat cadmium stress, encompassing metal ion sequestration, efflux pumps, and enzymatic detoxification pathways. Bioremediation emerges as a promising avenue for tackling cadmium pollution, leveraging microorganisms' ability to transform toxic cadmium forms into less hazardous derivatives. Unlike conventional methods, bioremediation offers a cost-effective, environmentally benign, and efficient approach. This review amalgamates the current understanding of microbial cadmium resistance mechanisms, highlighting their potential for sustainable remediation strategies. By unraveling the intricate interactions between microorganisms and cadmium, this study contributes to advancing our knowledge of bioremediation approaches, thereby paving the way for safer and more effective cadmium mitigation practices.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"13 - 30"},"PeriodicalIF":3.0,"publicationDate":"2023-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00887-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138576838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous removal of phenoxy herbicides, 2-methyl-4-chlorophenoxyacetic acid and 2,4-dichlorophenoxyacetic acid from aqueous media by magnetized MgAl-LDH@Fe3O4 composite: application of partial least squares and Doehlert experimental design 磁化 MgAl-LDH@Fe3O4 复合材料同时去除水介质中的苯氧除草剂、2-甲基-4-氯苯氧乙酸和 2,4-二氯苯氧乙酸:偏最小二乘法和 Doehlert 试验设计的应用
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-12-08 DOI: 10.1007/s40201-023-00877-8
Abdolraouf Samadi-Maybodi, Hashem Ghezel-Sofla, Pourya BiParva
{"title":"Simultaneous removal of phenoxy herbicides, 2-methyl-4-chlorophenoxyacetic acid and 2,4-dichlorophenoxyacetic acid from aqueous media by magnetized MgAl-LDH@Fe3O4 composite: application of partial least squares and Doehlert experimental design","authors":"Abdolraouf Samadi-Maybodi,&nbsp;Hashem Ghezel-Sofla,&nbsp;Pourya BiParva","doi":"10.1007/s40201-023-00877-8","DOIUrl":"10.1007/s40201-023-00877-8","url":null,"abstract":"<div><p>Today, the excessive and increasing use of phenoxy family herbicides such as 2-methyl-4-chlorophenoxyacetic acid (MCPA) and (2,4- dichlorophenoxy) acetic acid (2,4-DCPA) for reasons such as indestructibility and pollution of groundwater resources is one of the most important environmental problems. Pesticide adsorbents like layered double hydroxides (LDHs) are commonly utilized due to their straightforward synthesis, substantial specific surface area resulting from their layered structure, and the potential for surface modification. These natural minerals serve as effective options for adsorption. In this study, a co-precipitation approach was used to create an MgAl-LDH@Fe<sub>3</sub>O<sub>4</sub> magnetic adsorbent for the simultaneous removal of MCPA and 2,4-DCPA herbicides from aqueous solution. Using different techniques such as TGA, XRD, FESEM, EDS and zeta potential, we investigated the properties of the prepared adsorbent. The partial least squares method measures the concentration of each herbicide in their mixture. The optimization of MCPA and 2,4-DCPA simultaneous adsorption by LDH was achieved through Doehlert experimental design and the response surface method. The optimal conditions for absorption were determined to be an adsorbent dose of 40.20 mg L<sup>-1</sup>, a pH of 6.8, and an initial concentration of 28.35 mg L<sup>-1</sup>. In this work, the equilibrium, kinetic, and thermodynamic absorption data of the absorption process were studied, and the obtained results were well described by the Freundlich model, and the pseudo-second-order model, respectively, and showed the spontaneity of the absorption process in this research. The highest absorption capacities of MCPA and 2.4-DCPA herbicides on the prepared adsorbent were 134.50 and 131.30 mg g<sup>-1</sup>, respectively.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"97 - 121"},"PeriodicalIF":3.0,"publicationDate":"2023-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00877-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138557077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of divalent mercury removal from synthetic wastewater using desirability function in central composite design of response surface methodology 在响应面方法的中央复合设计中使用可取函数优化合成废水中的二价汞去除率
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-12-07 DOI: 10.1007/s40201-023-00888-5
Jonas Bayuo, Mwemezi J. Rwiza, Kelvin Mark Mtei
{"title":"Optimization of divalent mercury removal from synthetic wastewater using desirability function in central composite design of response surface methodology","authors":"Jonas Bayuo,&nbsp;Mwemezi J. Rwiza,&nbsp;Kelvin Mark Mtei","doi":"10.1007/s40201-023-00888-5","DOIUrl":"10.1007/s40201-023-00888-5","url":null,"abstract":"<div><p>Heavy metals exist in the ecosystem both naturally and due to anthropogenic activities and as recalcitrant pollutants; they are non-biodegradable and cause acute and chronic diseases to human beings and many lifeforms. A statistical experimental approach was applied in this current study to optimize the detoxification of mercury [Hg(II)] from mono-component biosorption system by a novel hybrid granular activated carbon (biosorbent) prepared from maize plant residues. The analysis of variance by the application of central composite design shows that all the studied independent factors greatly influence Hg(II) removal efficiency and uptake capacity. The optimum experimental condition of 30 min contact time, 0.5 g/L biosorbent dosage, and 15 mg/L initial Hg(II) concentration were achieved after seeking 20 optimization solutions at 0.903 desirability. The optimum percentage removal and uptake capacity of Hg(II) at the optimal experimental setup was 96.7% and 10.8 mg/g, respectively. To confirm the quadratic models developed for the prediction of the responses as a function of the independent factors, confirmatory laboratory experiments were performed at the optimum condition. The results show that at the established best experimental condition, the optimum Hg(II) removal efficiency of 98.3% and uptake capacity of 11.2 mg/g were attained, which were within the prediction intervals indicating the suitability of the quadratic models in predicting future cases. The TEM and XRD analyses show that the Hg(II) ions were adsorbed by the biosorbent successfully and this suggests the potential and applicability of this novel biosorbent in treating water contaminants, especially heavy metals.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"209 - 227"},"PeriodicalIF":3.0,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138545401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasma pyrolysis feasibility study of Spent Caustic waste to hydrogen production 废碱渣等离子体热解制氢可行性研究
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-11-29 DOI: 10.1007/s40201-023-00886-7
Rasoul Aghayee, Mohammadreza Khani, Farzaneh Ostovarpour, Mohammad Sadegh Abbassi Shanbehbazari, Mojtaba Shafiei, Mahtab Gharibi, Babak Mohammadhosseini, Babak Shokri
{"title":"Plasma pyrolysis feasibility study of Spent Caustic waste to hydrogen production","authors":"Rasoul Aghayee,&nbsp;Mohammadreza Khani,&nbsp;Farzaneh Ostovarpour,&nbsp;Mohammad Sadegh Abbassi Shanbehbazari,&nbsp;Mojtaba Shafiei,&nbsp;Mahtab Gharibi,&nbsp;Babak Mohammadhosseini,&nbsp;Babak Shokri","doi":"10.1007/s40201-023-00886-7","DOIUrl":"10.1007/s40201-023-00886-7","url":null,"abstract":"<div><p>Spent caustic is a used industrial caustic whose chemical content puts it in the special waste category. The disposal of this waste and the production of value-added products from it has attracted the attention of researchers not only to solve environmental problems but also to take advantage of its byproducts. This research has experimentally proved the transferred thermal plasma technology as a practical method feasible for the disposal of spent caustic. In this study, the applied voltage, electrical current, and feed rate are variable parameters, and others are kept constant. GC analysis showed H<sub>2</sub> as the main product, which is environmentally beneficial. The percentage of hydrogen production of approximately 74% is a promising result, considering the difficulty of achieving such a high percentage of hydrogen.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"197 - 208"},"PeriodicalIF":3.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Status of antibiotic residues in milk and dairy products of Iran: a systematic review and meta-analysis 伊朗牛奶和乳制品中抗生素残留的现状:系统回顾和荟萃分析
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-11-28 DOI: 10.1007/s40201-023-00889-4
Fatemeh Fatemi, Mahmood Alizadeh Sani, Seyyed Mohammad Ali Noori, Mohammad Hashemi
{"title":"Status of antibiotic residues in milk and dairy products of Iran: a systematic review and meta-analysis","authors":"Fatemeh Fatemi,&nbsp;Mahmood Alizadeh Sani,&nbsp;Seyyed Mohammad Ali Noori,&nbsp;Mohammad Hashemi","doi":"10.1007/s40201-023-00889-4","DOIUrl":"10.1007/s40201-023-00889-4","url":null,"abstract":"<div><h3>Background</h3><p>Today, antibiotics are widely used for treatment and feed additives to enhance livestock growth. Antibiotic residues may be found in food of animal origin for various reasons, including ignoring the withdrawal period after treatment, overuse for animals, and contamination of feed with treated animals in animal products. Among animal products, dairy products have a special place in the human diet, and antibiotic residues in them have caused a great deal of concern among consumers.</p><h3>Objective</h3><p>This systematic review and meta-analysis aimed to evaluate and compare studies conducted in Iran on antibiotic residues in dairy products during 2000–2022.</p><h3>Methods</h3><p>In this review, 52 eligible studies were collected by searching the Scientific Information Database (SID), Magiran, Google Scholar, Science-Direct, Scopus, and PubMed using the English or Persian keywords such as an antibiotic or antimicrobial residue, Beta-lactam residue, Tetracycline residue, Sulfonamide residue, Chloramphenicol residue, Aminoglycosides residue, Macrolide residue, Quinolones residue, Milk, Raw milk, Pasteurized milk, UHT milk, Powder milk, Cheese, Yogurt, Butter, Cream, Doogh, Kashk, Ice cream, and Iran.</p><h3>Results</h3><p>According to the reviewed studies, the total prevalence of antibiotic residues in dairy products was 29% (95% CI: 15–43%). Among the seven evaluated antibiotic groups, most studies have been conducted on tetracycline, beta-lactam, and sulfonamide groups, with 16, 10, and 7 respectively, and the highest level of contamination with 663 ± 1540 μg/l is related to tetracycline. Most studies on antibiotic dairy product residues in Iran with 12, 11, and 8 studies are associated with East Azarbaijan province, then Tehran and Khorasan Razavi respectively, and no study has been conducted in 11 provinces of the country. According to the studies, Gilan, Qazvin and Razavi Khorasan provinces had the highest amount of antibiotic residue in milk with an average value of 56.415 ± 33.354, 45.955 ± 4.179 and 45.928 ± 33.027, respectively. Most of the methods used in the studies to measure antibiotic residues in milk were the Copan test kit and the HPLC method, which were used in 19 and 14 studies, respectively.</p><h3>Conclusions</h3><p>Studies have shown that the prevalence of antibiotic residue in dairy products in Iran is high, so applying an effective strategy and developing the necessary standards in this field to control milk quality is a public health necessity. The findings of this study show that further evaluation of fermented dairy products, especially non-fermented ones such as butter and cream, is needed to prevent adverse health reactions.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"31 - 51"},"PeriodicalIF":3.0,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00889-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent 二氧化钛纳米颗粒改性纤维素:潜在的太阳能驱动光催化剂和吸附剂
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-11-23 DOI: 10.1007/s40201-023-00884-9
Deepti Sharma, Jai Prakash Mishra, Veena Dhayal
{"title":"Modification of cellulose with TiO2 nanoparticles: Potential solar driven photocatalyst and adsorbent","authors":"Deepti Sharma,&nbsp;Jai Prakash Mishra,&nbsp;Veena Dhayal","doi":"10.1007/s40201-023-00884-9","DOIUrl":"10.1007/s40201-023-00884-9","url":null,"abstract":"<div><p><i>In-situ</i> modification of cellulose fibers with titania nanoparticles (TiO<sub>2</sub> NPs) (TiO<sub>2</sub> NPs-cellulose) was carried out via the sol–gel process using titania sol and fibers of cellulose. Cellulose fibers were extracted from wheat straw, an agricultural waste material, whereas titania sol was prepared from titanium(IV) acetoximate, [Ti{ONC(CH<sub>3</sub>)<sub>2</sub>}<sub>4</sub>]. The synthesized TiO<sub>2</sub> NPs-cellulose composite was characterized by FT-IR, SEM–EDX, and XRD analyses. The obtained results exposed that TiO<sub>2</sub> NPs were homogeneously dispersed over the surface of cellulose fibers. A study was conducted to compare the photocatalytic activities of TiO<sub>2</sub> NPs-cellulose composite and TiO<sub>2</sub> NPs towards the degradation of methylene blue and methyl orange dyes under sunlight, and it was observed that the photo-degradation of methylene blue (99.99%) and methyl orange (80.73%) within 160 min is higher in the presence of TiO<sub>2</sub> NPs-cellulose composite than TiO<sub>2</sub> NPs. The adsorption capabilities of TiO<sub>2</sub> NPs-cellulose composite towards Pb<sup>2+</sup>, Cd<sup>2+</sup>, and Cr<sup>3+</sup> toxic metal ions were also examined, and it was found 44.73 mg. g<sup>−1</sup> (89.46%), 38.82 mg. g<sup>−1</sup> (77.65%), and 4.42 mg. g<sup>−1</sup> (8.85%), respectively. Removal of pollutants from textile industrial effluent were also investigated using TiO<sub>2</sub> NPs-cellulose composite under sun light. The results obtained were very promising which shows potential of TiO<sub>2</sub> NPs-cellulose composite as an efficient photocatalyst and absorbent for real time applications.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"167 - 178"},"PeriodicalIF":3.0,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Human health risk assessment of toxic heavy metals in summer crops and vegetables: a study in Ilam Province, Iran 夏季作物和蔬菜中有毒重金属对人类健康的风险评估:伊朗伊拉姆省的一项研究
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-11-01 DOI: 10.1007/s40201-023-00881-y
Ali Amarloei, Seyed Abbas Mirzaei, Zahra Noorimotlagh, Shahrokh Nazmara, Heshmatollah Nourmoradi, Neamatollah Jaafarzadeh Haghighi Fard, Mohsen Heidari, Fazel Mohammadi-Moghadam, Sajad Mazloomi
{"title":"Human health risk assessment of toxic heavy metals in summer crops and vegetables: a study in Ilam Province, Iran","authors":"Ali Amarloei,&nbsp;Seyed Abbas Mirzaei,&nbsp;Zahra Noorimotlagh,&nbsp;Shahrokh Nazmara,&nbsp;Heshmatollah Nourmoradi,&nbsp;Neamatollah Jaafarzadeh Haghighi Fard,&nbsp;Mohsen Heidari,&nbsp;Fazel Mohammadi-Moghadam,&nbsp;Sajad Mazloomi","doi":"10.1007/s40201-023-00881-y","DOIUrl":"10.1007/s40201-023-00881-y","url":null,"abstract":"<div><h3>Purpose</h3><p>The presence of toxic heavy metals (HMs) in agricultural crops ‎can be considered as a noteworthy threat for consumers. The aim of this study was to assess the content of HMs ‎(Pb, As, Cr, Cd, Co, Hg, and Ag) and their potential health risk in summer crops and vegetables (watermelon, cantaloupe, cucumber, melon, tomato, onion, ‎potato, raw and stewed vegetables) in Ilam province, Iran.</p><h3>Methods</h3><p>Totally, 31 crop samples were collected from local farms during the 2019 harvest ‎season and the elements ‎ content were evaluated using inductively coupled plasma-mass spectrometry (ICP-MS). The non-carcinogenic health risk of HMs to the adults and children was estimated by Monte Carlo simulation method and target hazard quotients (THQs).</p><h3>Results</h3><p>In general, the results showed that the concentration of Cr in the studied ‎agricultural crops was higher than other HMs. As well as, the carcinogenic risk (CR) obtained for adults and children were more than the acceptable range for As. Also, CR for As in raw vegetable was the most (‎8.19E-1) and violated the threshold risk limit. The total carcinogenic risk of HMs in children was higher than that in adults.</p><h3>Conclusion</h3><p>These results suggest that the agricultural crops were not safe for human consumption with potential risks associated. Due to the possible health effects of such products consumption, proper action should be taken to avoid chronic exposure, prevention of further pollution and consequent adverse health implications.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"139 - 148"},"PeriodicalIF":3.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135272304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanosorbent based on coprecipitation of ZnO in goethite for competitive sorption of Cd(II)-Pb(II) and Cd(II)-Pb(II)-Ni(II) systems 基于氧化锌在网沸石中共沉淀的纳米吸附剂,用于竞争性吸附镉(II)-铅(II)和镉(II)-铅(II)-镍(II)体系
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-10-26 DOI: 10.1007/s40201-023-00882-x
John Godwin, Jacques Romain Njimou, Nasalam Abdus-Salam, Haleemat Iyabode Adegoke, Prasanna Kumar Panda, Bankim Chandra Tripathy, Sanda Andrada Maicaneanu
{"title":"Nanosorbent based on coprecipitation of ZnO in goethite for competitive sorption of Cd(II)-Pb(II) and Cd(II)-Pb(II)-Ni(II) systems","authors":"John Godwin,&nbsp;Jacques Romain Njimou,&nbsp;Nasalam Abdus-Salam,&nbsp;Haleemat Iyabode Adegoke,&nbsp;Prasanna Kumar Panda,&nbsp;Bankim Chandra Tripathy,&nbsp;Sanda Andrada Maicaneanu","doi":"10.1007/s40201-023-00882-x","DOIUrl":"10.1007/s40201-023-00882-x","url":null,"abstract":"<div><p>Amongst the various water pollutants, heavy metal ions require special attention because of their toxic nature and effects on humans and the environment. Preserving natural resources will have positive impacts on living conditions by reducing diseases and water treatment by nanotechnology is effective in solving this problem owing to the properties of nanomaterials. In this study, a goethite nanoparticle was prepared by hydrothermal method, while ZnO/goethite nanocomposite by co-precipitation was developed. The nanoparticles were characterized using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Transform Electron Microscopy (TEM), Thermogravimetric Differential Thermal Analysis (TGA-DTA), Dynamic Light Scattering (DLS), and Breunner-Emmet-Teller (BET) surface area analysis. The adsorption of Cd(II)-Pb(II) and Cd(II)-Pb(II)-Ni(II) ions systems on ZnO/goethite nanocomposite was investigated in a batch mode. The findings of the study showed that nanoparticles ZnO/goethite composite were mixed of spherical and rod-like shapes. The BET results revealed average particle sizes of 41.11 nm for nanoparticles for ZnO/goethite while TGA/DTA confirmed the stability of the adsorbents. The optimum adsorption capacities of the nanocomposite for Pb(II), Cd(II), and Ni(II) ions from the Pb-Cd-Ni ternary system were 415.5, 195.3, and 87.13 mg g<sup>−1</sup>, respectively. The adsorption isotherm data fitted well with the Langmuir isotherm model. The study concluded that the nanoparticle adsorbents are efficient for the remediation of toxic pollutants and are, therefore, recommended for wastewater treatment.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"149 - 165"},"PeriodicalIF":3.0,"publicationDate":"2023-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134910441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessment of the environmental performance of sugarcane companies based on waste disposed of on the soil 根据土壤废弃物评估甘蔗公司的环境绩效
IF 3 4区 环境科学与生态学
Journal of Environmental Health Science and Engineering Pub Date : 2023-10-14 DOI: 10.1007/s40201-023-00880-z
Erik Geraldo da Silva Souza, Marcelo Girotto Rebelato
{"title":"Assessment of the environmental performance of sugarcane companies based on waste disposed of on the soil","authors":"Erik Geraldo da Silva Souza,&nbsp;Marcelo Girotto Rebelato","doi":"10.1007/s40201-023-00880-z","DOIUrl":"10.1007/s40201-023-00880-z","url":null,"abstract":"<div><h3>Purpose</h3><p>This study aimed to present an index (<i>IEP</i>) to evaluate the environmental performance of the sugar-energy industrial process based on the waste generated in manufacturing operations. The residues considered in this study were: vinasse, filter cake, ash and soot, residual waters, and sewage sludge.</p><h3>Methods</h3><p>The index created was developed to take into account, and to be directly proportional to the environmental impact of each residue generated by the sugar-energy production, to the relative spatial dispersion that each waste can reach, and to the environmental fragility of the hydrographic basin where the plant under evaluation is inserted and works. The lower IEP, the better the company valuation.</p><h3>Results</h3><p>The index was tested in a real company and exhibited an <i>IEP Total</i> = 1,4.10<sup>13</sup> km<sup>2</sup>.p/yr, which shows weak waste management by the enterprise. Vinasse was responsible for 50% of the <i>IEP Total, </i>while filter cake contributed 45% to it. Ash and soot, residual waters, and sewage sludge were together responsible for 5% of the <i>IEP Total</i>.</p><h3>Conclusion</h3><p>The theoretical conception used in this study is inspiring for the development of new studies on environmental assessment measurement. The study showed that vinasse is the most problematic waste in environmental terms, a conclusion that is in line with academic studies. Nevertheless, the waste with the greatest potential impact on the environment is filter cake. Despite this, filter cake presented a lower <i>IEP(i) </i>than vinasse, given that its negative impact on the basin is smaller. Both wastes contributed 95% of the <i>IEP Total</i>, which places them among the residues to be managed with greater attention.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"22 1","pages":"123 - 137"},"PeriodicalIF":3.0,"publicationDate":"2023-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00880-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135803391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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