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Erratum to: Detecting Trace Amounts of Peroxides and Ammonium Nitrate in Fingerprints by Ion Mobility Spectrometry 离子迁移率光谱法检测指纹中痕量过氧化物和硝酸铵的勘误
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934825010022
T. I. Buryakov, I. A. Buryakov
{"title":"Erratum to: Detecting Trace Amounts of Peroxides and Ammonium Nitrate in Fingerprints by Ion Mobility Spectrometry","authors":"T. I. Buryakov, I. A. Buryakov","doi":"10.1134/S1061934825010022","DOIUrl":"10.1134/S1061934825010022","url":null,"abstract":"","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"196 - 196"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1061934825010022.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stripping Voltammetric Determination of the Antiviral Drug Ribavirin in Pharmaceutical Formulations and Human Serum 溶出伏安法测定制剂和人血清中抗病毒药物利巴韦林的含量
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S106193482470165X
Amr M. Beltagi, Gamal K. Gomaa, Aya R. Elgaml
{"title":"Stripping Voltammetric Determination of the Antiviral Drug Ribavirin in Pharmaceutical Formulations and Human Serum","authors":"Amr M. Beltagi,&nbsp;Gamal K. Gomaa,&nbsp;Aya R. Elgaml","doi":"10.1134/S106193482470165X","DOIUrl":"10.1134/S106193482470165X","url":null,"abstract":"<p>A highly sensitive square-wave adsorptive anodic stripping voltammetric method is described for the determination of ribavirin in its pharmaceutical formulations and human blood serum, utilizing a carbon paste electrode. The peak current was significantly enhanced due to the strong adsorptive properties of the drug at the electrode surface. The optimal procedural parameters were: frequency of 20 Hz, scan increment of 4 mV, pulse amplitude of 25 mV, and accumulation potential of –0.5 V versus Ag/AgCl/3 M KCl in Britton–Robinson buffer at pH 8.0. The described method was successfully applied for the assay of ribavirin in its pharmaceutical formulation (Ribavirin<sup>®</sup> capsules, 200 mg ribavirin), with mean percentage recoveries of (98.3 ± 1.3)%. Furthermore, the method was successfully applied for the assay of ribavirin in spiked human blood serum without the necessity for sample pretreatment or time-consuming extraction prior to analysis. The mean percentage recovery of ribavirin in human blood serum was (98.6 ± 1.1)% (<i>n</i> = 5), with a limit of detection of 1 × 10<sup>–9</sup> M (0.24 ng/mL). Due to this extremely low limit of detection, the proposed method can be applied in pharmacokinetic and pharmacodynamic studies of the drug.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"169 - 181"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Principles of the Injection of Organic Substances into a Gas Chromatographic Column by Thermal Desorption Depending on the Volatility of the Mixture Components 根据混合物成分的挥发性，通过热脱附将有机物注入气相色谱柱的原理
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S106193482470148X
M. N. Baldin, V. M. Gruznov, V. V. Fedotov
{"title":"Principles of the Injection of Organic Substances into a Gas Chromatographic Column by Thermal Desorption Depending on the Volatility of the Mixture Components","authors":"M. N. Baldin,&nbsp;V. M. Gruznov,&nbsp;V. V. Fedotov","doi":"10.1134/S106193482470148X","DOIUrl":"10.1134/S106193482470148X","url":null,"abstract":"<p>A review of methods for thermal desorption from concentrators in portable rapid gas chromatographs of the EKhO series for injecting samples of organic substances into a gas chromatographic column depending on the volatility range of substances in the samples is presented. Sample injection techniques without manual operations in EKhO instruments are considered. The principles of sample injection with incomplete gas-dynamic isolation of the injection chamber and the column when introducing explosive and arene vapor samples with different volatility of substances in the sample and with complete isolation of the injection chamber and the column when introducing samples of C<sub>1</sub>−C<sub>5</sub> saturated hydrocarbons with sharply different volatility are described.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"15 - 23"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rapid Assessment of Urine Samples by Atmospheric Pressure Laser Plasma Ionization Mass Spectrometry 利用大气压激光等离子体电离质谱法快速评估尿液样本
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934824701582
S. I. Timakova, Ya. I. Simakina, K. Yu. Kravets, A. A. Grechnikov
{"title":"Rapid Assessment of Urine Samples by Atmospheric Pressure Laser Plasma Ionization Mass Spectrometry","authors":"S. I. Timakova,&nbsp;Ya. I. Simakina,&nbsp;K. Yu. Kravets,&nbsp;A. A. Grechnikov","doi":"10.1134/S1061934824701582","DOIUrl":"10.1134/S1061934824701582","url":null,"abstract":"<p>The method of atmospheric pressure laser plasma ionization (APLPI) was investigated to address the task of the rapid detection of physiologically active substances in urine. Urine samples were collected from patients undergoing treatment in hospitals in Moscow. The study demonstrated that the APLPI method, combined with high-resolution mass spectrometry, enables the detection of all analytes previously identified in urine extract samples using the standard LC–MS/MS method. Analysis duration for a single sample does not exceed 1 min. Calibration curves were constructed, and the analytical characteristics of the method were determined using the “dilution in matrix” approach. The LC–MS/MS and APLPI methods exhibit comparable signal-to-noise ratios. The advantages of the APLPI method include its rapidity, retrospective analysis capability, and the requirement for only small sample volumes. The study demonstrated the feasibility of using the APLPI method for screening physiologically active substances in urine without sample preparation.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"104 - 111"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sorption–Spectroscopic Determination of Dimedrol as Ion Associates with Anionic Azo Dyes 离子与阴离子偶氮染料的吸附光谱测定地美罗
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934824701545
M. M. Osmanova, T. I. Tikhomirova, Kh. A. Mirzaeva
{"title":"Sorption–Spectroscopic Determination of Dimedrol as Ion Associates with Anionic Azo Dyes","authors":"M. M. Osmanova,&nbsp;T. I. Tikhomirova,&nbsp;Kh. A. Mirzaeva","doi":"10.1134/S1061934824701545","DOIUrl":"10.1134/S1061934824701545","url":null,"abstract":"<p>The sorption of ion associates of acidic azo dyes, sulfonazo and Congo red, with Dimedrol on polyurethane foams is studied depending on pH, phase contact time, and component ratio. A method for determining Dimedrol in medicinal products is developed based on its sorption as ion associates with dyes and subsequent detection on the sorbent surface by diffuse reflectance spectroscopy.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"70 - 75"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to: New Trends in Chemical Identification Methodology 《化学鉴定方法的新趋势》的勘误
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S106193482501006X
B. L. Milman, I. K. Zhurkovich
{"title":"Erratum to: New Trends in Chemical Identification Methodology","authors":"B. L. Milman,&nbsp;I. K. Zhurkovich","doi":"10.1134/S106193482501006X","DOIUrl":"10.1134/S106193482501006X","url":null,"abstract":"","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"200 - 200"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S106193482501006X.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to: Membrane Chromatographic Test System for Determining Bisphenol A in Drinking Water Based on the Use of an Aptamer 勘误：基于 Aptamer 的测定饮用水中双酚 A 的膜色谱测试系统
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934825010058
N. S. Komova, K. V. Serebrennikova, A. N. Berlina, A. V. Zherdev, B. B. Dzantiev
{"title":"Erratum to: Membrane Chromatographic Test System for Determining Bisphenol A in Drinking Water Based on the Use of an Aptamer","authors":"N. S. Komova,&nbsp;K. V. Serebrennikova,&nbsp;A. N. Berlina,&nbsp;A. V. Zherdev,&nbsp;B. B. Dzantiev","doi":"10.1134/S1061934825010058","DOIUrl":"10.1134/S1061934825010058","url":null,"abstract":"","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"199 - 199"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1061934825010058.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Sulphonated Styrene and Divinylbenzene Copolymers with Various Degrees of Crosslinking to Ion Exclusion Chromatography 不同交联度磺化苯乙烯和二乙烯基苯共聚物在离子排除色谱中的应用
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934824701612
A. Yu. Laptev, N. B. Rozhmanova, A. V. Sevko, P. N. Nesterenko
{"title":"Application of Sulphonated Styrene and Divinylbenzene Copolymers with Various Degrees of Crosslinking to Ion Exclusion Chromatography","authors":"A. Yu. Laptev,&nbsp;N. B. Rozhmanova,&nbsp;A. V. Sevko,&nbsp;P. N. Nesterenko","doi":"10.1134/S1061934824701612","DOIUrl":"10.1134/S1061934824701612","url":null,"abstract":"<p>The chromatographic retention of neutral polar compounds (alcohols, ketones, carboxylic acids, carbohydrates, and sweeteners) and compounds in the ionized form (mono- and dibasic organic acids) on cation exchange columns packed with sulfonated poly(styrene-divinylbenzene) having crosslinking degrees of 8% (Nautilus-IE) and 10% (Sevko AA) is studied in ion exclusion chromatography. Using 5 mM sulfuric acid, the retention parameters of the compounds are determined and new patterns are obtained, clarifying the mechanism of retention of organic acids in ion-exclusion chromatography. It is found that the retention of all the studied compounds (log<i>k</i>') is directly proportional to hydrophobicity values (log <i>P</i><sub>exp</sub>). In this case, the electrostatic repulsion of organic acids from the sulfo groups of the cation exchanger shifts the log <i>k</i>'–log <i>P</i><sub>exp</sub> dependences by a constant value, proportional to the number of carboxyl groups. A possibility of using the Sevko AA column not only for amino acid analysis, but also for the determination of organic acids and alcohols in complex samples by ion exclusion chromatography with spectrophotometric and refractometric detection is shown.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"134 - 147"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physically Adsorbed Chitosan-Based Coatings for the Electrophoretic Separation of Biologically Active Substances 物理吸附壳聚糖基涂层用于生物活性物质的电泳分离
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934824701594
E. A. Kolobova, E. R. Ziangirova, E. V. Solovyova, L. A. Kartsova
{"title":"Physically Adsorbed Chitosan-Based Coatings for the Electrophoretic Separation of Biologically Active Substances","authors":"E. A. Kolobova,&nbsp;E. R. Ziangirova,&nbsp;E. V. Solovyova,&nbsp;L. A. Kartsova","doi":"10.1134/S1061934824701594","DOIUrl":"10.1134/S1061934824701594","url":null,"abstract":"<p>Coatings for the inner walls of quartz capillaries were obtained using cationic high-molecular-weight chitosan with a degree of deacetylation of 95%. The dependence of the electroosmotic flow velocity on the pH of the background electrolyte was studied and the stability of the coatings under the influence of various solvents was assessed. The results were compared with those for another cationic coating based on poly(diallyldimethylammonium chloride) (PDADMAC). In separating amino acids, catecholamines, and organic acids, the chitosan-based coatings showed slightly lower efficiency compared to PDADMAC coatings, but provided higher resolution for the biologically active analytes studied. Chitosan on the inner walls of the quartz capillary enhanced enantioselectivity in the separation of enantiomers of β-blockers (carvedilol, propranolol, and sotalol) in the presence of (2-hydroxypropyl)-β-cyclodextrin in the background electrolyte, as well as nonsteroidal anti-inflammatory substances (ketoprofen and ketorolac) using vancomycin as a second chiral selector.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"112 - 123"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to: Voltammetric DNA Sensors for the DNA Damage Detection Using Poly (Acridine Orange) Coatings Deposited from Reline and Glyceline 对伏安DNA传感器的勘误：DNA损伤检测使用聚（吖啶橙）涂层沉积从线和甘氨酸
IF 1 4区 化学
Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI: 10.1134/S1061934825010071
A. V. Porfireva, Z. F. Khusnutdinova, G. A. Evtyugin
{"title":"Erratum to: Voltammetric DNA Sensors for the DNA Damage Detection Using Poly (Acridine Orange) Coatings Deposited from Reline and Glyceline","authors":"A. V. Porfireva,&nbsp;Z. F. Khusnutdinova,&nbsp;G. A. Evtyugin","doi":"10.1134/S1061934825010071","DOIUrl":"10.1134/S1061934825010071","url":null,"abstract":"","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"201 - 201"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1061934825010071.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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