{"title":"Modification of Bitumen Properties Using Polyethylene Glycol: Towards Improved Outer Wrap Tapes for Gas Pipeline Coating in Cold Regions","authors":"Milad Asadnia, Mehdi Sadat-Shojai","doi":"10.1007/s40995-024-01759-w","DOIUrl":"10.1007/s40995-024-01759-w","url":null,"abstract":"<div><p>Coating gas pipelines is a crucial practice in the gas industry to enhance pipeline integrity, longevity, and safety. Recently, the outer wrap tape of bitumen impregnated glass fiber have been developed as the part of protective layers for the underground pipelines. Outer tapes prepared of pre-modified 10/20-grade bitumen by styrene–ethylene/butylene–styrene (SEBS), styrene–butadiene–styrene (SBS), and talk powder suffer from some problems such as brittleness at low temperatures, inadequate adhesion between the two glass fiber layers, and high weight. Therefore, the aim of this study was to survey the physical, rheological, and adhesion characteristics of pre-modified bitumen after addition of polyethylene glycol (PEG) 2000 and then to investigate the quality of the tape produced with this bitumen. Improvement of flexibility and decrease of susceptibility to deformation at low temperatures of PEG-modified samples were confirmed by penetration, softening point, and penetration index (PI) tests. The storage stability investigation showed that at higher PEG concentrations phase separation may happen. Dynamic shear rheological (DSR) test indicated that PEG-modified samples have lower complex modulus and complex viscosity. Tapes produced with PEG-modified bitumen displayed less brittleness and enhanced adhesion than those produced with unmodified bitumen. Generally, this study highlights the potential of PEG as a promising additive to prepare bitumen with desired properties. These findings contribute to the development of gas pipe coating technology in cold regions, specifically the production of outer wrap tapes.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 3","pages":"645 - 654"},"PeriodicalIF":1.4,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143938728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Extraction of Zemu Glacier’s Boundary Using a Multi-Parametric Approach","authors":"Devishri Kangjam, Kamaljit Singh Rajkumar, Mamata Maisnam, Pallipad Jayaprasad, Maganti Srinivasa Tarun, Putrevu Deepak, Misra Arundhati, Sharma Narpati, Shrestha Dhiren","doi":"10.1007/s40995-024-01769-8","DOIUrl":"10.1007/s40995-024-01769-8","url":null,"abstract":"<div><p>Though Zemu is the largest glacier in the Eastern Himalayas, it is one of the least monitored among the Himalayan glaciers. Thus, its sensitivity to global climate change should not be neglected. Glacier boundary delineation is a labor-intensive and time-consuming process. Therefore, the primary objective of this study is to create a semi-automatic processing chain that can recognize glacier boundaries using Synthetic Aperture Radar (SAR) data, Principal Component Analysis (PCA), and Connected components segmentation (CCS) techniques. SAR data processing provides weather-independent, high-resolution data that captures the surface characteristics of the glacier, including backscatter intensity and coherence, which are crucial for detecting glacier boundaries. PCA reduces data redundancy and enhances the spatial characteristics of the input data. CCS groups pixels with similar intensities into segments. Combining these methods results in a more accurate and reliable delineation of glacier boundaries. The parameters we have selected for the process are unique. Earlier researchers have used coherence and slope information. However, we have also considered the effect of radar backscattering intensity and curvature of the study area in addition to coherence and slope information. The use of CCS gives uniqueness to this study. A qualitative analysis of the study showed similarity with the GLIMS glacier outline, and the Intersection over Union (IoU) metric for segmentation accuracy was 0.67. Additionally, the two-pass Differential SAR Interferometry (DInSAR) technique was used for estimating the LOS velocity of the Zemu glacier. The significance is that LOS velocity measurements help track the movement of glaciers over time.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 3","pages":"681 - 695"},"PeriodicalIF":1.4,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143938676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Some approximation properties of Riemann-Liouville type fractional Bernstein-Stancu-Kantorovich operators with order of (alpha)","authors":"Reşat Aslan","doi":"10.1007/s40995-024-01754-1","DOIUrl":"10.1007/s40995-024-01754-1","url":null,"abstract":"<div><p>The main intent of this paper is to examine some approximation properties of Riemann-Liouville type fractional Bernstein-Stancu-Kantorovich operators with order of <span>(alpha)</span>. We derive some moment estimates and show the uniform convergence theorem, degree of convergence with respect to the usual modulus of continuity, class of Lipschitz-type continuous functions and as well as Peetre’s <i>K</i>-functional. Furthermore, we present various graphical and numerical examples to demonstrate and compare the effectiveness of the proposed operators. Also, we construct bivariate extension of the related operators and consider order of approximation by means of partial and complete modulus of continuity. Further, we provide a graphical representation and an error of approximation table to show the behavior order of convergence of bivariate form of discussed operators.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 2","pages":"481 - 494"},"PeriodicalIF":1.4,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shokooh Sadat Khaloo, Ali Jafari, Samaneh Jalali, Reza Gholamnia
{"title":"Removal of Dimethoate Pesticide Using Double Layer Hydroxide@Graphene Oxide: Optimization Via Response Surface Methodology and Neural Networks","authors":"Shokooh Sadat Khaloo, Ali Jafari, Samaneh Jalali, Reza Gholamnia","doi":"10.1007/s40995-024-01771-0","DOIUrl":"10.1007/s40995-024-01771-0","url":null,"abstract":"<div><p>Removing pesticides from water is essential to protect ecosystems and preserve water sources from pollutants. The use of nanocomposites for adsorption removal has gained attention in the last decade. In this work, Mg-Al double-layer hydroxide coated on graphene oxide (Mg-Al-LDH@GO) was synthesized and characterized using FESEM, EDS, and XRD techniques. The removal of dimethoate from aqueous solution using Mg-Al-LDH@GO as an adsorbent was optimized and modeled. The response surface method (RSM) was employed to design the experiments based on the central composite design (CCD). Four parameters affecting the adsorption removal efficiency of dimethoate, including pH, contact time, adsorbent dose, and pollutant concentration, were optimized using RSM-CCD. The results indicate that the removal process can be accurately predicted by the quadratic model. Numerical optimization results showed that when the concentration of dimethoate is 83.7 mg/L, the optimal conditions are pH 2.6, contact time 15.3 h, and adsorbent dose 27.5 mg/100 mL. Under these conditions, the removal efficiency reached 86.08%. A feed-forward neural network (ANN) model with the Levenberg-Marquardt backpropagation training algorithm was adapted to model the removal process. The performance of the ANN model showed adequate response prediction with R² values of 0.9989, 0.9803, 0.9984, and 0.9936 for training, validation, testing, and overall, respectively. The results obtained in this work demonstrate that Mg-Al-LDH@GO is a potential adsorbent for the removal of dimethoate from water.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 4","pages":"913 - 926"},"PeriodicalIF":1.4,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145168063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Description of the Energy Spectrum of Cosmic Rays Using Superstatistics and Gamma Distribution","authors":"Mahsa Iranmanesh, Hamid Arjomand Kermani","doi":"10.1007/s40995-024-01770-1","DOIUrl":"10.1007/s40995-024-01770-1","url":null,"abstract":"<div><p>Although the origin of cosmic rays and spectral breaks remains a controversial issues, it is evident that the energy spectrum of cosmic rays does not follow a Gaussian distribution and therefore, cannot be described using ordinary statistical mechanics. In this study, we apply Beck-Cohen superstatistics, a generalized framework of statistical mechanics. In this model, the main idea is that the energy spectrum of cosmic rays results from many high-energy scattering processes, each with a different local temperature <span>(beta)</span> in the local scattering volume. By considering the temperature fluctuations, one can not only obtain Tsallis statistics but also an infinite set of statistics. In this paper, we utilize a gamma distribution to describe these temperature fluctuations, employing shape and scale parameters as essential tools. Our approach facilitates the derivation of a novel relationship for the entropy index <i>q</i> as a function of energy, which has not been previously explored in the context of cosmic rays. The effective temperature is estimated to be 100 MeV, aligning with the generalized Hagedorn temperature. Importantly, our theoretical results show strong agreement with available experimental data.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 4","pages":"1145 - 1151"},"PeriodicalIF":1.4,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145167838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and Characterization of Microporous Nanomaterial from ZIF-8 for Efficient Loading and Controlled Release of Dapsone in Aqueous Media","authors":"Zahra Khalili, Negar Moatakef Kazemi, Zahra Jafari Azar, Zahra Mosavi, Mehdi Hasanzadeh","doi":"10.1007/s40995-024-01750-5","DOIUrl":"10.1007/s40995-024-01750-5","url":null,"abstract":"<div><p>This study focuses on the synthesis, characterization, and application of a microporous nanomaterial made from a metal-organic framework called ZIF-8. The material was successfully prepared and used to investigate its ability to load and release dapsone in water-based solutions. This prepared ZIF-8 exhibited promising drug loading from aqueous environments through hydrogen bonding, π-π, and electrostatic interactions. The synthesized ZIF-8 was characterized through Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, Elemental mapping analysis, thermogravimetric analysis, and Brunauer–Emmett–Teller analysis to investigate its structure and morphology. The study investigated several factors that could influence the dapsone loading procedure, including pH, ZIF-8 dosage, and loading time, to optimize the process. Using the non-linear simplex optimization methodology, it was found that the efficiency of loading dapsone exceeded 92.5 ± 3.9% when the concentration of the dapsone drug was 50 mg.L<sup>-1</sup>. The most effective parameters for achieving the highest possible loading of dapsone were loading pH = 7.0, ZIF-8 dosage = 6.0 mg.mL<sup>-1</sup>, and loading time = 120 min. Investigative studies on release mechanisms demonstrated that when the dapsone-loaded ZIF-8 was submerged in phosphate buffer saline (at pH = 7.4 and temperature = 37 °C), it displayed an optimal efficiency surpassing 80% following a duration of 120 h.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 2","pages":"331 - 344"},"PeriodicalIF":1.4,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Transformation, Kinetic and Thermodynamic Behaviors of Ni4Ti3 Precipitated/Un-Precipitated Ni-Rich NiTi SMA","authors":"Boutheina Ben Fraj, Slim Zghal","doi":"10.1007/s40995-024-01756-z","DOIUrl":"10.1007/s40995-024-01756-z","url":null,"abstract":"<div><p>In this study, it is aimed to experimentally investigate the transformation and the thermodynamic behaviors of the Ni-rich NiTi Shape Memory Alloy (SMA) at various thermal conditions. Based on XRD and SEM analyses, Ni<sub>4</sub>Ti<sub>3</sub> precipitated/un-precipitated structures were identified as function of annealing temperature (450 °C and 650 °C). Through the calorimetric study, by varying the DSC scanning rate, it was proved that transformation temperatures, transformation rate and thermal hysteresis are highly sensitive to the presence of the precipitation phase. Furthermore, thermodynamic properties and kinetic behavior were assessed highlighting the impact of microstructural alteration on changes in enthalpy, entropy, Gibbs free energy and elastic energy. Activation energies of Ni<sub>4</sub>Ti<sub>3</sub> precipitated and un-precipitated samples were determined according to Kissinger and Takhor approaches revealing a notable negative activation energy for the un-precipitated sample and considerably high values for the precipitated one. This result implies that, with the presence of Ni<sub>4</sub>Ti<sub>3</sub> precipitates, the NiTi SMA requires higher activation energy to conduct the martensitic transformation.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 2","pages":"547 - 558"},"PeriodicalIF":1.4,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Complex Symmetry of Slant H-Toeplitz Operators","authors":"Anuradha Gupta, Deepika Singh","doi":"10.1007/s40995-024-01745-2","DOIUrl":"10.1007/s40995-024-01745-2","url":null,"abstract":"<div><p>In this paper complex symmetry of slant H-Toeplitz operator is studied. Necessary conditions for complex symmetry of restrictions of slant H-Toeplitz operator, namely slant Toeplitz operator and the slant Hankel operator, with respect to a weighted composition operator are explored along with counterexamples for insufficient conditions. The upper bound for the spectral radius of the slant H-Toeplitz is also obtained.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 3","pages":"781 - 788"},"PeriodicalIF":1.4,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143938609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Action Principle for Equilibrium Thermodynamics","authors":"Sikarin Yoo-Kong","doi":"10.1007/s40995-024-01747-0","DOIUrl":"10.1007/s40995-024-01747-0","url":null,"abstract":"<div><p>The action principle is introduced to describe the thermodynamic processes of the state functions from the initial equilibrium state to the final equilibrium state. To capture the path-independent property of the state functions through the thermodynamic processes, one requires an integrability condition called the Lagrangian 1-form closure relation as a direct result of the least action principle with respect to the independent variables.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 2","pages":"541 - 546"},"PeriodicalIF":1.4,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Note on Hopfian and Co-Hopfian S-Acts","authors":"Mohammad Roueentan, Roghaieh Khosravi","doi":"10.1007/s40995-024-01753-2","DOIUrl":"10.1007/s40995-024-01753-2","url":null,"abstract":"<div><p>The main purpose of this work is to investigate of the notions Hopfian (co-Hopfian) acts in which their surjective (injective) endomorphisms are isomorphisms. While we study conditions that are relevant to these classes of acts, their interrelationship with some other concepts for example quasi-injective and Dedekind-finite acts is studied. Using Hopfian and co-Hopfian concepts, we provide several conditions for a quasi-injective act to be Dedekind-finite.</p></div>","PeriodicalId":600,"journal":{"name":"Iranian Journal of Science and Technology, Transactions A: Science","volume":"49 3","pages":"789 - 794"},"PeriodicalIF":1.4,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143938578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}