ACS Applied Materials & Interfaces最新文献

{"title":"A Generalizable Machine Learning Framework for Identifying Sustainable Multi-Ion Garnet Electrolytes.","authors":"Jinjin Dong, Wenjun Yang, Haolin Liu, Jingwen Wu, Zongguo Wang","doi":"10.1021/acsami.5c03645","DOIUrl":"10.1021/acsami.5c03645","url":null,"abstract":"<p><p>Lithium-ion (Li-ion) solid-state batteries (SSBs) are highly regarded for their exceptional energy density and prolonged operational lifespan. However, concerns regarding their sustainability have arisen due to the uneven global distribution of Li resources and Li's relatively low abundance in the Earth's crust. Consequently, significant interest has shifted toward developing alternative SSBs, such as sodium (Na), magnesium (Mg) and Aluminum (Al)-ion batteries. A key challenge in this pursuit is efficiently identifying viable solid-state electrolytes (SEs) from the vast chemical space, particularly for Na and Mg ions. This study introduces a generalized framework based on machine learning for effectively screening high-performance garnet-type SEs. Utilizing specifically designed chemical descriptors, ML models predict the thermal stability and electrical conductivity of garnet-type SEs, achieving predictive accuracies of 94% and 89%, respectively. The chemical factors influencing stability and conductivity are identified and validated through interpretability analysis. Leveraging these models, 1764 garnet-type SEs exhibiting high thermal stability and wide band gaps were screened from a database of 43,732 compounds. Furthermore, 44 garnet-type SEs with favorable environmental and economic advantages were selected, and verified through first-principles calculations using density functional theory. Given their cost-effectiveness and high performance, these SEs hold great potential for application in Na, Mg, and Al ion SSBs. This study provides crucial insights into developing SSB materials, advances sustainable energy storage, and offers key perspectives for exploring material systems within specific space groups.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"41868-41882"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144590012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Simple Proton-Driven Allosteric Aptamer Nanorobot for Receptor Tyrosine Kinase Degradation and Behavior Modulation in Cancer Cells.","authors":"Lanlin Qi, Yuchen Wu, Bin Zhang, Yan Zhou, Lin He, Min Zhang, Kemin Wang, Mingjian Chen, Xiaoxiao He","doi":"10.1021/acsami.5c09210","DOIUrl":"10.1021/acsami.5c09210","url":null,"abstract":"<p><p>The aptamer-based strategy for selective protein degradation demonstrates broad application prospects in the field of biomedicine, particularly holding significant therapeutic potential for tumors and other protein dysregulation-related diseases. However, it faces substantial challenges due to on-target off-tumor effects arising from nonspecific expression of target proteins. To address this issue efficiently, we report here a pH-responsive allosteric DNA nanorobot (named A/I) that enhances the precision of aptamer-mediated target protein degradation through tumor microenvironment-specific activation. The allosteric nanorobot is comprised of two modules: the recognition module (A-strand) and the response module (I-strand). To be specific, the A-strand integrates both target recognition and degradation-inducing capabilities, while the I-strand blocks the recognition sites of the A-strand through complementary base pairing and confers pH sensitivity. Under physiological pH conditions, the A/I nanorobot exists stably in the form of a double-stranded structure. When the acidic tumor microenvironment is encountered, the pH-triggered conformational change of the I-strand induces the duplex disassembly, releasing the A-strand, which can specifically bind to the target protein and subsequently induce its degradation. Our findings demonstrate that the activatable allosteric nanorobot achieves targeted protein degradation, significantly inhibiting the proliferative and migratory abilities of tumor cells. In general, the activatable allosteric nanorobot has innovatively overcome the bottleneck of insufficient selectivity in traditional aptamer-based protein degradation strategies, providing a molecular tool for precision tumor therapy technologies. In addition, the allosteric nanorobot features a simple design and enables specific degradation of diverse target proteins by flexible replacement of the recognition module, demonstrating significant potential for constructing a universal protein precise degradation platform.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"41781-41791"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144598872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Decoupling Nonlinear Motion of the Self-Propelled Disk Sensitive to the Metal Salts.","authors":"Yu Xu, Mingming Sun, Luwei Zhang, Wei Guo, Qiuyu Zhang","doi":"10.1021/acsami.4c22995","DOIUrl":"10.1021/acsami.4c22995","url":null,"abstract":"<p><p>Despite advances in inanimate motors, challenges remain in creating novel motors to demonstrate tailorable motion and understanding the complex synergistic mechanisms in biological systems. Consequently, there is an urgent demand for a deeper understanding of programmable motions and stimulus responsiveness in self-propelled motors based on interface science. Herein, a self-propelled camphor system sensitive to additive metal ions is presented, and the key role of metal ion type and concentration in determining the kinematic characteristics of the camphor disk is revealed. The results show that high valence metal ions have a stronger self-propulsion effect, which is attributed to the interaction of the charged metal ions with surfactants and camphor molecules. In addition, the dependence of motion behaviors (including motion speed, mode bifurcation, and oscillation characteristics) on the metal species has been demonstrated. Especially, the motion speed, mode change, and motion characteristics of the self-propelled camphor system in this study, which are sensitive to various metal ions, are expected to be applied to metal ion detection in the environmental field.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42372-42379"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Proton-Conductive Solid-State Electrolyte Based on Covalent Organic Framework for Proton Battery Application.","authors":"Bing Tang, Sheng-Ting Liu, Xin-Rui Ma, Feng-Jia Zhao, Guo-Qin Zhang, Xu-Sheng Gao, Jiazhi Yang, Hong-Bin Luo, Xiao-Ming Ren","doi":"10.1021/acsami.5c09195","DOIUrl":"10.1021/acsami.5c09195","url":null,"abstract":"<p><p>Solid-state proton batteries are emerging as promising technologies for energy storage. However, efficient solid-state protonic electrolyte development remains in its early stages. Herein, we report the preparation and potential application of a high-performance covalent organic framework (COF)-based protonic electrolyte for solid-state proton batteries. Using a mechanochemical method, H₃PO₄ was incorporated into the channels of a sulfonated COF (COF-SO₃H) to produce the composite solid-state electrolyte, H₃PO₄@COF-SO₃H. This composite was thoroughly characterized using techniques such as powder X-ray diffraction, ¹³C NMR spectroscopy, X-ray photoelectron spectroscopy, and nitrogen adsorption/desorption analysis. Impedance spectroscopy revealed that H₃PO₄@COF-SO₃H exhibited superprotonic conductivity exceeding 10^-2 S cm^-1 under ambient conditions, alongside remarkable long-term stability and a broad electrochemical stability window. A solid-state proton battery assembled using H₃PO₄@COF-SO₃H as the electrolyte demonstrated exceptional performance, including excellent rate capability, high specific capacity of 101.8 mAh g^-1 at 1.0 A g^-1, and good cycling stability with a capacity retention of 80.6% after 1000 cycles at 1.0 A g^-1, outperforming previously reported solid-state proton batteries. These findings suggest that COF-based composite solid-state electrolytes hold significant promise for future applications in solid-state proton batteries.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42004-42010"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Stretchable Transparent Electrodes for Wearable Near-Infrared Organic Photodetectors Enabling Vital Monitoring, Imaging, and Communication.","authors":"Yupu Wang, Mengfan Li, Ruochen Wang, Hanzhe Shi, Feng Li, Yu Zhu, Guanghui Li, Wang Ni, Yongsheng Chen, Miaomiao Li, Yanhou Geng","doi":"10.1021/acsami.5c06999","DOIUrl":"10.1021/acsami.5c06999","url":null,"abstract":"<p><p>Stretchable near-infrared organic photodetectors (NIR OPDs) are crucial for the development of wearable and implantable electronics. However, these devices commonly underperform compared to their rigid counterparts, primarily due to the lack of high-quality stretchable transparent electrodes. Here, we develop silver nanowires (AgNWs)/thermoplastic polyurethane (TPU) composite electrodes by introducing 3-[<i>N</i>-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic acid sodium salt (HOS). The resulting AgNWs-HOS/TPU electrodes show impressive optical transmittance and low sheet resistance (12 Ω·sq^-1), comparable to ITO/glass electrodes. Notably, the incorporation of HOS significantly improves the adhesion between AgNWs and TPU, ensuring a low sheet resistance (21.3 Ω·sq^-1) even under mechanical deformation of 80%. Consequently, the AgNWs-HOS/TPU-based stretchable OPDs exhibit a record-high shot-noise-limited specific detectivity (<i>D</i>*_shot) of 5.58 × 10¹³ Jones at 800 nm, comparable to rigid devices. Moreover, these stretchable devices maintain a <i>D</i>*_shot > 10¹³ Jones after 500 stretching cycles at 50% strain and sustain a <i>D</i>*_shot over 10¹³ Jones under continuous stretching at 30% strain for over 80 min, ranking as the highest value among stretchable OPDs in photovoltaic mode reported so far. Furthermore, the stretchable NIR OPDs are successfully applied in pulse signal detection, imaging, and optical communication, and they are capable of accurate signal detection after cyclic stretching, which demonstrates great potential in wearable and implantable devices.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42162-42173"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Performance 4D Printed ABS/Conductive TPU Electrothermal Actuator Devices with SWCNT Segregated Structures: A Gripper Demonstrator toward Soft Robotics Applications.","authors":"Miron Krassas, Emmanouil Porfyrakis, Fivos Simopoulos, Georgios Kampourakis, Papadakis Ch Nikolaos, Stavros Katsiaounis, Konstantinos Papagelis, George Karalis, John D Kechagias, Evangelos K Evangelou, Panagiotis Polygerinos, Lazaros Tzounis","doi":"10.1021/acsami.5c09083","DOIUrl":"10.1021/acsami.5c09083","url":null,"abstract":"<p><p>A high-performance U-shaped bimetallic polymer-based \"soft\" electrothermal actuator (ETA) device is reported utilizing a versatile fused filament fabrication (FFF) three-dimensional printing (3DP) process. A dual-head multimaterial 3D printer is employed to fabricate the ETA devices, consisting of an acrylonitrile butadiene styrene (ABS)/conductive thermoplastic polyurethane (cTPU) bilayer architecture. The cTPU layer is intentionally printed with a gyroid microporous structure, facilitating the infiltration of a single-walled carbon nanotube (SWCNT) aqueous ink, deposited through \"direct ink writing\" (DIW). The final 4D printed ABS/cTPU/SWCNT ETA could reach orders of magnitude lower internal resistance compared to the \"cTPU only\" layer, namely, from ca. 9 kΩ to ∼20 Ω. Scanning electron microscopy (SEM), Raman spectroscopy, thermogravimetric analysis (TGA), and electrical resistance measurements highlight the morphological and physicochemical properties of the obtained electrothermally active materials and structures. 4DP ETAs are characterized for their actuation bending performance upon being exposed to different applied bias voltages (<i>V</i>_bias) and \"ON-OFF\" alternating cycles, measuring in real time the tip displacement through a high-resolution camera. Finite element analysis (FEA) corroborates the ETA device performance for a specific <i>V</i>_bias. The force generated by the ETAs is quantified via a digital microbalance, while infrared thermography (IR-T) images are captured upon device operation to validate the electrothermal Joule-heating effect. Three ETA devices are electrically connected in parallel to a three-finger \"soft\" gripper demonstrator. Our 4DP ETAs could have a modular design for variable applications, while the fast and reliably responsive gripper prototype could open new avenues in the field of soft robotics.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42331-42347"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Liquid Metal-Based Capacitive Strain Sensor with Self-Shielding and Low-Hysteresis.","authors":"Bowen Bai, Jiayi Yang, Tingting Yu, Jing Guo, Lihao Song, Guoxiang Dong","doi":"10.1021/acsami.5c10267","DOIUrl":"https://doi.org/10.1021/acsami.5c10267","url":null,"abstract":"<p><p>Soft capacitive strain sensors with soft conductive electrodes are advantageous for their ability to decouple resistance from the flexible electrodes, offering excellent repeatability, low hysteresis, low energy consumption, and good temperature stability. However, existing soft capacitive strain sensors utilize intrinsically stiff conductors as soft electrodes, limiting the sensitivity, repeatability, and hysteresis. To address these issues, this work proposes a soft capacitive strain sensor based on liquid metal. The soft electrodes are composed of a liquid metal-nickel particle conductive paste, which combines fluidity and low surface tension, thereby eliminating the elastic modulus mismatch between the soft electrodes and the elastomers. This design achieves high sensitivity, excellent repeatability, and low hysteresis. The sensor employs a three-electrode structure, which enhances resistance to parasitic and stray capacitance without applying shielding layers. The measurement and the self-shielding of the three-electrode structure are investigated through simulation analyses. Additionally, the influence of the elastic modulus compatibility between the soft electrodes and the elastomers is investigated through experiments and simulations. Furthermore, the application of this sensor in the field of wearable devices is demonstrated.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":""},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"2D-Seed-Induced Crystallization Strategy Contributes to Blade-Coating FAPbI3-Based Perovskite Solar Cells.","authors":"Yumeng Zhang,Kexin Zhang,Ruikai Zhang,Xinbo Shi,Guofu Zhou,Jun-Ming Liu,Yue Jiang,Zhen Wang,Jinwei Gao","doi":"10.1021/acsami.5c12738","DOIUrl":"https://doi.org/10.1021/acsami.5c12738","url":null,"abstract":"Formamidinium lead iodide (FAPbI3)-based perovskites are promising photoabsorber materials owing to their optimal bandgap and excellent photothermal stability. However, their complex crystallization behavior during blade-coating presents challenges for scalable fabrication, leading to poor perovskite film morphology and uniformity, which adversely affect the performance and stability of perovskite solar cells (PSCs). Herein, a two-dimensional (2D) perovskite seed layer was introduced onto the SnO2 electron transport layer within a conventional n-i-p device architecture. This seed layer was employed to provide heterogeneous nucleation sites for and to induce the bottom-up-oriented growth of [PbI6]4- octahedra, thereby facilitating the formation of the photoactive α-FAPbI3 phase with enhanced crystallinity and film uniformity. As a result, PSCs with an active area of 2.5 × 2.5 cm2 were fabricated, achieving a power conversion efficiency (PCE) of 22.03% and an open-circuit voltage (VOC) of 1.10 V. Furthermore, over 80% of the initial efficiency was retained after 2000 h of ambient storage (relative humidity ≈ 5%, temperature ≈ 25 °C) without encapsulation, indicating excellent long-term stability. Through this approach, a viable and scalable pathway has been established for the fabrication of high-quality α-FAPbI3 films, offering significant potential for the advancement of efficient and stable PSCs.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"12 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lignin-Derived Hierarchically Porous Carbon Nanofibers via Deep Eutectic Solvent Electrospinning and Silica-Templated Etching for High-Performance Supercapacitors.","authors":"Yuchen Wang,Shuangli Wu,Shanlei Chang,Kai Rong,Shaojun Dong","doi":"10.1021/acsami.5c10539","DOIUrl":"https://doi.org/10.1021/acsami.5c10539","url":null,"abstract":"The valorization of lignin, an abundant and renewable resource, remains pivotal to advancing sustainable material innovation. Herein, we propose a green and cost-effective strategy for synthesizing lignin-derived hierarchically porous carbon nanofibers (HPCFs). This approach utilized choline chloride-lactic acid deep eutectic solvent (ChCl-LA DES) for lignin dissolution, followed by wet-electrospinning to fabricate lignin-based fiber aerogels. SiO2 nanospheres were uniformly embedded within electrospun fibers as sacrificial templates to create macropores, and the lignin carbonization generated abundant mesopores and micropores, ultimately producing carbon nanofibers with multiscale pore architectures. Furthermore, the hierarchical pore distribution can be tuned by modulating the SiO2 nanosphere content, which in turn optimized the textural properties and electrochemical performance of the carbon nanofibers. The optimized carbon nanofibers doped with 100 mg of SiO2 nanospheres (100-HPCF) exhibited distinct improvement in specific surface area (779.515 m2/g) and specific capacitance (237.1 F/g at 0.5 A/g), representing a marked improvement over nontemplated lignin-derived electrospun carbon fibers (LESCFs). Moreover, 100-HPCF demonstrated exceptional cycling stability, retaining 97.7% of its peak capacitance after 15000 cycles. The integration of lignin valorization, DES-enabled processing, and hierarchical pore-structure optimization establishes a sustainable and viable pathway for developing advanced carbon materials with exceptional supercapacitor performance.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"25 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Dithienopyrazine-Based Wide Band Gap Polymer Donor for Efficient Organic Solar Cells.","authors":"Zongtao Wang,Hao Wang,Lijun Tu,Qiang Guo,Weiwei He,Yongqiang Shi,Erjun Zhou","doi":"10.1021/acsami.5c10609","DOIUrl":"https://doi.org/10.1021/acsami.5c10609","url":null,"abstract":"Developing a wide band gap polymer donor is highly important for realizing high-performance organic solar cells (OSCs). Herein, we are the first to utilize the dithienopyrazine (DTPz) electron-accepting (A) unit to construct novel D-A type copolymers, namely, DTPz-1 and DTPz-2, using benzodithiophene (BDT) and benzodifuran (BDF) as the copolymerizing electron-donating (D) units, respectively. Compared with DTPz-1, DTPz-2 exhibits a cascade energy level with nonfullerene acceptors (NFAs) of L8-BO, proper phase separation scale, strong molecular packing, and high charge mobility. As a result, the device based on DTPz-2/L8-BO achieves a higher power conversion efficiency (PCE) of 15.03% compared with DTPz-1/L8-BO, which has a PCE of 8.14%. This study not only provides a new A structural unit for fabricating high-efficiency D-A type polymer donors but also proves that BDF may be more suitable than classic BDT when designing certain D-A type photovoltaic donors.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"4 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144684315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}