ACS Applied Materials & Interfaces最新文献

{"title":"Modulating the Cavity Size of Carbon Nanobelts for Enhanced Oxygen Reduction Reaction.","authors":"Tingting Xu, Xiaofei Zhang, Zao Wang, Pei Wen Ng, Liuying Jiao, Shi-Qiang Wang, Khoong Hong Khoo, Zhengtao Xu, Jishan Wu, Jun Zhu","doi":"10.1021/acsami.4c23016","DOIUrl":"10.1021/acsami.4c23016","url":null,"abstract":"<p><p>The preactivation of reactants within the cavities of carbon nanotubular materials has remained largely unexplored due to the scarcity of materials with well-defined sizes and precisely engineered doping sites. Herein, we demonstrate that the catalytic activity toward the oxygen reduction reaction (ORR) is primarily governed by the cavity sizes of well-defined nanobelt materials with precisely doped <i>sp</i>²-nitrogen atoms. Our results show that the confinement effect induced by cavity size and the electron-rich chemical environment within the cavity are crucial for O₂ adsorption and preactivation, leading to enhanced catalytic activity. <b>Belt2</b>, with its medium-sized cavity (6.3 Å), exhibits superior ORR catalytic performance compared to <b>Belt1</b> with its narrower cavity and <b>Belt3</b>/<b>Belt4</b> with its larger cavities. Notably, <b>Belt2</b> achieves high half-wave and onset potentials of 0.84 and 0.97 V, respectively, along with an open-circuit voltage of 1.32 V and a peak power density of 181 mW cm^-2 in a zinc-air battery. This work not only provides a deeper understanding of the geometric factors influencing the ORR electrocatalysis of nanocarbon materials but also offers insights into the future design of nanocarbon electrocatalysts for enhancing catalytic efficiency. These findings may also be beneficial for other energy conversion and catalytic materials.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"20096-20104"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143690393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Poly-T-Modified Gold Nanorods Suppress Macrophage-Mediated Inflammation for Periodontitis Therapy","authors":"Wanghong He, Wei Wei, Yifan Zhao, Yanxue Wang, Chang Liu, Yi Wei, Xueting Lu, Lei Zhao, Chengxin Wang, Junge Chen, Xinfeng Tan, Minli You, Yi Liu","doi":"10.1021/acsami.5c00470","DOIUrl":"https://doi.org/10.1021/acsami.5c00470","url":null,"abstract":"Traditional treatments for periodontitis are limited by their inability to adequately modulate the immune response and control inflammation. Recently, nucleic acid-modified nanomaterials have attracted significant attention for their potential in regulating inflammation. Among these, most nanomaterials, such as spherical nucleic acids, tend to exhibit pro-inflammatory effects. In this study, we identified for the first time that poly-T sequence-modified gold nanorods (PTM AuNRs) possess significant anti-inflammatory properties. The PTM AuNRs demonstrated excellent biocompatibility and efficacy in treating ligation-induced periodontitis. PTM AuNRs modulate immune responses by inhibiting the differentiation of pro-inflammatory M1 macrophages and reducing pro-inflammatory cytokine levels through promoting AMPK activation. When administered via local injection, PTM AuNRs effectively suppress inflammatory response and inflammatory cell infiltration, downregulate inflammatory cytokine levels, and mitigate collagen fiber degradation and alveolar bone loss. Together, these findings highlight PTM AuNRs as a promising and innovative therapeutic strategy for periodontitis management.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"89 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143758459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Silicoaluminophosphate SAPO-56 Molecular Sieves for Efficient CO₂ Adsorption and Separation.","authors":"Yi Li, Yining Liao, Yue Wang, Zheng Niu, Zhenggong Wang, Qiming Sun","doi":"10.1021/acsami.4c22638","DOIUrl":"https://doi.org/10.1021/acsami.4c22638","url":null,"abstract":"<p><p>Capturing CO₂ from flue gas and natural gas is crucial for energy production and environmental protection, and the development of efficient adsorbents is the key. In this study, we systematically investigated the factors influencing the hydrothermal synthesis of silicoaluminophosphate SAPO-56 molecular sieve, including the molar ratio of raw materials, crystallization time, and temperature. A seed-assisted synthesis strategy was employed to significantly reduce the crystal size of SAPO-56 from over 30 μm to below 1 μm. The resulting submicron-sized SAPO-56 exhibited a markedly enhanced CO₂ uptake (5.94 mmol g^-1 at 0 °C) compared to conventional SAPO-56 samples (4.77 mmol g^-1), surpassing most previously reported zeolitic adsorbents. Significantly, the submicron-sized SAPO-56 was utilized for the first time as a filler to prepare mixed matrix membranes (MMMs) with benzimidazole-based polyimide (BIMPI) as the polymer matrix for natural gas purification. The membrane with 50% SAPO-56 loading demonstrated a promising CO₂ permeability of 151.23 Barrer, significantly higher than that of the pure BIMPI membrane (18.00 Barrer). This work provides valuable insights into the ratio synthesis of SAPO-56 molecular sieves and advances their application in CO₂ adsorption and separation, as well as in MMMs for natural gas purification.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":""},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143762459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Morphology-Tunable Binary Transition Metal Oxide Heterostructure@Carbon Composites for Lithium-Ion Batteries","authors":"Jaeseong Kim, Sangyeop Kim, Chanyoung Lee, Seyoung Koo, Youngbok Lee, Hee Soo Kim, Hak-Sung Jung, Won Cheol Yoo","doi":"10.1021/acsami.5c01794","DOIUrl":"https://doi.org/10.1021/acsami.5c01794","url":null,"abstract":"Heterostructures of binary and unary transition metal oxides (B and UTMOs) have demonstrated excellent electrochemical performance in lithium-ion batteries (LIBs) due to synergistic effects; however, there remains a lack of research combining multiple strategies for synergy enhancement. Herein, we present the development of crystallinity-controlled heterostructures based on nickel and cobalt oxides (NiCo₂O₄/NiO and NiO/Co₃O₄) with different morphologies (urchin- and flower-like structures, e.g., U-NiCo₂O₄/NiO and F-NiCo₂O₄/NiO) to investigate the influence of heterostructure combinations and morphologies on electrochemical performance in LIBs. The morphologies of the heterostructures were controlled by adjusting the fluoride concentration during the synthesis of the nickel–cobalt (Ni–Co) precursor, while heterostructure combinations were regulated by heat treatment under specific conditions. When used as anodes for LIBs, electrochemical analyses revealed that the carbon-coated urchin-like U-NiCo₂O₄/NiO (U-NiCo₂O₄/NiO@C) sample provided more efficient charge transfer and a shorter Li-ion transport pathway compared to its counterpart (F-NiCo₂O₄/NiO@C) due to its high surface area and distinctive morphological features. In addition, U-NiCo₂O₄/NiO@C exhibited superior electrochemical performance as an anode in LIBs than U-NiO/Co₃O₄@C, indicating that the advantageous effects of BTMO over UTMO can effectively enhance LIB performance. This facile synthesis approach provides a foundation for morphology-controlled heterostructures in the development of high-performance anode materials for LIB applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"23 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143766946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flexible Waterborne Silicone-Based Coating with High Mechanical, Stretchable, and Durable Antismudge Properties.","authors":"Heng Li, Jianming Zhao, Menghua Feng, Haihang Luo, Tong Chen, Jun Xiang, Haojun Fan","doi":"10.1021/acsami.5c03648","DOIUrl":"10.1021/acsami.5c03648","url":null,"abstract":"<p><p>Eco-friendly, flexible, and fluorine-free antismudge coatings have broad applications in soft substrates such as fabrics, premium leather, synthetic leather, and flexible electronic devices. However, developing antismudge coatings possessing both excellent durability and desirable softness and stretchability remains a formidable challenge. Herein, two waterborne silicone-based emulsions were prepared via emulsion inversion point method, using high-molecular-weight divinyl-terminated poly(dimethylsiloxane) (^ViPDMS^Vi) and methyl vinyl MQ resin as raw materials, respectively, with polyether-modified silicone (D(PDMS)PE) compounding with sodium dodecyl sulfate (SDS) as emulsifiers. Subsequently, poly(methylhydrosiloxane) emulsion (PHSE) was utilized as a cross-linking agent, and a highly comprehensive waterborne silicone-based coating was successfully fabricated through hydrosilylation among the three types of emulsions. Owing to rational structural design and aqueous-based strategy, the coating achieves the integration of high mechanical properties (≥3.5 MPa tensile strength and 214% elongation) and stretchability, outstanding flexibility (the glass transition temperature below -105 °C), high transparency, excellent self-cleaning, and antismudge performance. Moreover, the exceptional durability of the coating is evidenced by maintaining antismudge properties after rigorous treatments, such as 24 h of UV irradiation, immersion in acid, alkali, and salt solutions for 24 h, 500 cycles of mechanical abrasion under a load of 1000 g, etc. This work provides a feasible pathway for manufacturing high-performance antismudge coatings suitable for soft substrates in a green and sustainable manner.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"20348-20360"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Efficient Yolk-Shell Photocatalyst Constructed by Integration of Ni₂P and Cu₂O Nanoparticles to Defective Metal-Organic Frameworks for Visible-Light-Driven Amine Oxidation.","authors":"Zhaozhen Zhang, Xiying Zhang, Bin Zhang, Xiaomeng Hu, Jie Wu, Hongwei Hou","doi":"10.1021/acsami.5c00582","DOIUrl":"10.1021/acsami.5c00582","url":null,"abstract":"<p><p>Realizing the directional migration of photogenerated carriers plays an important role in improving the photocatalytic performance. Meanwhile, light-driven oxidative coupling of benzylamine under ambient conditions with an inexpensive catalyst is highly desirable for the industrial field. Herein, via in situ synthesis, defect engineering, and photodeposition, a yolk-shell nanostructured photocatalyst, Ni₂P@OH-NH₂-UiO-66@Cu₂O, featuring nickel phosphide (Ni₂P) nanoparticles (NPs) trapped inside a defect engineered metal-organic framework (MOF, namely OH-NH₂-UiO-66) and Cu₂O NPs adhering on the surface of MOFs, has been rationally fabricated for the achievement of spatial separation of oxidation/reduction cocatalyst in photocatalytic reaction systems. The yolk-shell structure can effectively avoid the aggregation of the Ni₂P and Cu₂O NPs. Remarkably, the separation of electron collector Ni₂P and hole collector Cu₂O regulates the directional movement of the photogenerated carriers and effectively improves the electron-hole separation efficiency to generate abundant reactive superoxide radicals (^•O₂^-) and hydroxyl radicals (^•OH). Ni₂P@OH-NH₂-UiO-66@Cu₂O achieves a conversion of 99% for the oxidative coupling of benzylamine into imine within 1 h at ambient temperature under visible-light irradiation. The present study provides an economical method to construct a MOF-based yolk-shell photocatalyst for the oxidative coupling of amines.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19722-19733"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Performance Electromagnetic Interference Shielding and Photothermal Superhydrophobicity Achieved by Nuclear Sheath Stacking in Three-Dimensional Honeycomb Structure and Multi-Level Heterogeneous Interfaces.","authors":"Jie Mei, Huimin Liao, Hongjian Huang, Hao Tu, Fang Yao, Shuai Zhao, Jian Wang","doi":"10.1021/acsami.5c01232","DOIUrl":"10.1021/acsami.5c01232","url":null,"abstract":"<p><p>The unpredictable and extremely cold weather conditions, combined with increasing electromagnetic pollution, have posed a serious threat to human health and socioeconomic well-being. However, existing deicing technologies and electromagnetic interference (EMI) materials lack adaptability to low-temperature, high-humidity environments. This study developed a lightweight asymmetric layered composite foam by integrating multilevel core-shell structures with heterogeneous core-shell fillers into a melamine foam (MF) matrix. Designed to leverage the differences in conductivity and dielectric constant between multiscale heterogeneous interfaces, this composite foam enhances the movement of free electrons and the relative displacement between electrons and atomic nuclei, thereby achieving efficient polarization and conduction losses. More than that, the unique feature of this composite lies in its ″absorption-absorption-reflection-reabsorption″ multilevel structure, enabling the composite to achieve an EMI shielding effectiveness of 70.7 dB in the X-band (8.2-12.4 GHz) and an absorption efficiency of 79.8%. Benefiting from the destructive interference of electromagnetic waves within the layered foam structure, the asymmetric composite foam (MHC-MNPF-ACN) exhibits superior absorption-dominated EMI shielding performance with excellent frequency selectivity. Additionally, by anchoring dual-size fillers onto the MF skeleton via impregnation adsorption to form a honeycomb-like 3D ″light-trapping″ network. This not only allows the composite foam to reach 93.6 °C under 1 sun, enabling rapid deicing within 160 s but also endows it with excellent superhydrophobicity and mechanical properties. These features provide a novel and multifunctional integrated approach to the fabrication of frequency-selective, absorption-dominated EMI shielding materials, proposing a new strategy for the protection of outdoor electromagnetic facilities in extremely low-temperature environments.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"20270-20283"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Leveraging Dual Resistive Switching in Quasi-2D Perovskite Memristors for Integrated Non-volatile Memory, Synaptic Emulation, and Reservoir Computing.","authors":"Zhenwang Luo, Weisheng Wang, Junhui Wu, Guohua Ma, Yanna Hou, Cheng Yang, Xu Wang, Fei Zheng, Zhenfu Zhao, Ziqi Zhao, Liqiang Zhu, Ziyang Hu","doi":"10.1021/acsami.4c21159","DOIUrl":"10.1021/acsami.4c21159","url":null,"abstract":"<p><p>The increasing computational demands of artificial intelligence (AI) algorithms are exceeding the capabilities of conventional computing architectures, creating a strong need for novel materials and paradigms. Memristors that integrate diverse resistive switching (RS) behaviors provide a promising avenue for developing novel computing architectures. In this study, we achieve the coexistence of volatile and nonvolatile RS behaviors in quasi-2D perovskite memristor (Q-2DPM). The Q-2DPM exhibits competitive performance as a nonvolatile memory. Multiple synaptic functions have been successfully simulated on Q-2DPM, such as excitatory postsynaptic currents, paired-pulse facilitation, and long-term potentiation/depression. Furthermore, artificial neural networks using Q-2DPM synapses achieve high accuracy in MNIST image classification tasks. The Q-2DPM's inherent characteristics suitable for reservoir computing are also demonstrated through its application in a pulse-stream-based digital classification experiment, showcasing its impressive performance. The elucidation of the dual RS mechanisms within Q-2DPM provides fresh insights into memristor RS behavior and underscores the potential of achieving diverse computational units through a single device. This work paves the way for the implementation of physical neuromorphic hardware architectures and the advancement of sophisticated computational primitives, offering a significant step toward the next generation of computing technologies.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19879-19891"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Locally Ordered Graphitized Carbon Coating Enables Recycled Microsized Silicon as High-Performance Anodes.","authors":"Minghao Ma, Haimei Li, Yingtong Hu, Mathar Hamza, Weifeng Cao, Yingjie Ma, Lidong Li, Xianglong Li","doi":"10.1021/acsami.4c22721","DOIUrl":"10.1021/acsami.4c22721","url":null,"abstract":"<p><p>Microsized silicon (m-Si) emerges as a promising alternative anode material to graphite for lithium-ion batteries, offering high theoretical capacity, cost-effectiveness, and ease of handling. However, the inevitable particle fragmentation resulting from its bulk particle size challenges practical application. Despite the progress in carbon coating techniques that enhance the stability of mi-Si, there is still a demand for high-performance, scalable, and cost-effective m-Si anodes for industrial implementation. Herein, we propose a strategy to unleash the capacity of photovoltaic-waste-derived m-Si particles through locally ordered graphitized carbon coating, contributing to the large-scale production of superior m-Si silicon anodes. The obtained m-Si/carbon material exhibits a high capacity of 3203 mA h g^-1 at 0.2 A g^-1 and a superior rate capability (1532 mA h g^-1 at 4 A g^-1). The NCM811//Si@t-C full cell presents a capacity retention of 95.13% over 100 cycles. The carbon layer composed of locally ordered graphitized domains interconnected with disordered carbon is responsible for the remarkable performance. It effectively buffers the volume changes of m-Si, protects it from electrolyte, and promotes Li⁺ diffusion. Furthermore, this approach, combined with the utilization of m-Si, significantly reduces the overall cost of lithium-ion batteries, opening up opportunities for the application of m-Si.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19657-19668"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Co-Motif-Engineered RuO₂ Nanosheets for Robust and Efficient Acidic Oxygen Evolution.","authors":"Jiandong Hu, Le Tong, Yanlin Jia, Ziye Li, Haowei Yang, Yang Wang, Wenhui Luo, Yejun Li, Yong Pang, Shiyun Xiong, Zhi Liang Zhao, Qi Wang","doi":"10.1021/acsami.5c00773","DOIUrl":"10.1021/acsami.5c00773","url":null,"abstract":"<p><p>The development of efficient and reliable acidic oxygen evolution reaction (OER) electrocatalysts represents a crucial step in the process of water electrolysis. RuO₂, a benchmark OER catalyst, suffers from limited large-scale applicability due to its tendency toward the less stable lattice oxygen mechanism (LOM). This work reports the synthesis of Co-doped RuO₂ nanosheets with a unique porous morphology composed of interconnected grains via a facile molten salt method. Co doping modulates the grain size, effectively increasing the specific surface area and introducing oxygen vacancies. These oxygen vacancies, coupled with the Co dopants, form Co-O(V) motifs that tune the electronic configuration of Ru. This structural engineering promotes a shift in the OER mechanism from the detrimental LOM pathway to the more efficient adsorbate evolution mechanism (AEM), significantly enhancing the stability of the RuO₂ matrix in acidic environments. The optimized Co_0.108-RuO₂ catalyst exhibits a low overpotential of 214 mV at 10 mA cm^-2 and remarkable stability over commercial RuO₂ and undoped counterparts, owing to the synergistic effect of the increased surface area, Co-O(V) motifs, and favored AEM pathway. This strategy of utilizing Co doping to engineer morphology, electronic structure, and reaction mechanism offers a promising avenue for developing high-performance OER electrocatalysts.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19734-19744"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}