ACS Applied Materials & Interfaces最新文献

{"title":"Attapulgite-Assisted In Situ Anchoring of Ultrasmall Ag Nanoparticles for Enhanced Eradication of Multidrug-Resistant Bacterial Biofilms and Accelerated Wound Healing","authors":"Yalong Li, Fangfang Yang, Bin Mu, Yulong Ma, Aiqin Wang, Xinyue Liu","doi":"10.1021/acsami.5c00906","DOIUrl":"https://doi.org/10.1021/acsami.5c00906","url":null,"abstract":"Silver nanoparticles (Ag NPs) have emerged as a promising solution to combat biofilm-related infections caused by multidrug-resistant bacteria. However, their practical application remains limited due to their tendency to aggregate and exhibit high toxicity at elevated concentrations. Here, we developed a <i>Citrus limon</i> peel water extract-mediated hydrothermal process to facilitate the heterogeneous nucleation of Ag NPs on attapulgite (APT) nanorods and prepared Ag/APT nanocomposites with ultrasmall Ag NPs (&lt;2 nm) uniformly anchored on APT nanorods. Ascorbic acid and polyphenols in <i>Citrus limon</i> peel extract acted as electron donors to reduce Ag⁺ to Ag⁰, while the interfacial interaction of APT nanorods induced heterogeneous nucleation and confined the growth of Ag nanocrystals, resulting in ultrasmall Ag NPs. As a result, due to the synergistic effect of the targeted biofilm-binding affinity of APT nanorods and the siginificantly increased specific surface area of Ag NPs conducive to the release of Ag⁺ ions, the obtained Ag/APT nanocomposites exhibited enhanced eradication activities on antimicrobial-resistant bacterial biofilms and accelerated wound healing in MRSA-infected wound models. Additionally, attributing to the low dosage of Ag, Ag/APT exhibited exceptional biocompatibility both in vitro and in vivo. This work provides a simple and green strategy for the preparation of highly active Ag-based antibacterial nanomaterials and sheds new light on the development of advanced antimicrobial agents for wound healing.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"253 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143862443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular Anchoring Strategies for Enhanced Thermal Stability in Organic Field-Effect Transistors","authors":"Xiwei Zheng, Meili Xu, Yanan Zhu, Hao Yan, Hongyang Li, Xiaopeng Zhang, Xiteng Li, Yueyue Wang, Zhouying Wu, Lingqiang Meng, Shuai Chang, Yaowu He, Hong Meng","doi":"10.1021/acsami.5c02381","DOIUrl":"https://doi.org/10.1021/acsami.5c02381","url":null,"abstract":"Thermally stable organic transistors are crucial for ensuring reliable performance in diverse applications, including high-temperature environments and thermally demanding electronic systems. However, developing thermally stable organic semiconductors with excellent charge transport capability remains a great challenge. Here, a thermally stable and high-performance organic semiconductor, [1]benzothieno[3,2-<i>b</i>][1]benzothiophene (BTBT) derivative BTBT-PO8OP, is designed by incorporating a phenyl-anchored unit in the side chain. The highly ordered molecular arrangements in the BTBT-PO8OP films promotes strong intermolecular π–π interactions and efficient charge transport, enabling BTBT-PO8OP-based organic transistors to achieve a high mobility of 2.68 cm² V^–1 s^–1 and remarkable performance uniformity. Under thermal stress, the anchor-shaped side chain restricts molecular curling and contraction, maintaining the structural integrity of the molecules. Even at 145 °C, the phenyl anchor structure in BTBT-PO8OP-based organic transistors effectively mitigates side-chain curling, preserving molecular order and effective charge transport property, leading to superior thermal stability compared to mainstream small molecular material C8-BTBT. This work presents a promising material for thermally stable and high-performance organic transistors and demonstrates the potential of anchor-structure strategies in addressing the challenges of developing thermally stable organic semiconductors toward transistor-based applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"33 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Probing the Effects of Dimethyl Aluminum Isopropoxide Surface Reaction Byproducts on Atomic Layer Deposition Nucleation","authors":"Jessica C. Jones, Jiayi Xu, Chang Yan, Chunxin Luo, Ashley R. Bielinski, Mark Muir, Adam S. Hock, Cong Liu, Alex B. F. Martinson","doi":"10.1021/acsami.5c00901","DOIUrl":"https://doi.org/10.1021/acsami.5c00901","url":null,"abstract":"Atomic layer deposition (ALD) processes that leverage a myriad of metal–organic and complementary reactant combinations have been identified to realize precise and conformal thin film growth. However, the effects of the ALD reaction byproducts on nucleation and growth mechanisms are rarely considered. Site-selective ALD processes provide an opportunity for the detailed investigation of uniform surface sites with atomistic accuracy. Intentional pretreatment with a known ALD reaction byproduct – isopropanol – enables a significant improvement in the nucleation rate reproducibility of dimethylaluminum isopropoxide and water ALD on rutile TiO₂(110). In situ spectroscopic ellipsometry reveals a partially reversible byproduct binding that is site-selective for TiO₂(110) surface oxygen vacancies. First-principles calculations reveal surface site-specific thermodynamics for adsorption of isopropanol and water that may influence ALD nucleation. The sensitivity of site-selective ALD motivates consideration of secondary surface reactions when designing precision deposition processes, including area- or site-selective ALD reactions.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"67 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143862446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on the Action Mechanism of a Nontraditional Thioamide-Based Leveler of 1-Phenyl 2-Thiourea for Microvia Void-Free Filling","authors":"Zhao-Yun Wang, Li-Xin Yu, Yu-Qing Feng, Lei Jin, Jia-Qiang Yang, Yi Zhao, Tao Song, DongPing Zhan, Daquan Yu, Fang-Zu Yang, Shi-Gang Sun","doi":"10.1021/acsami.5c04034","DOIUrl":"https://doi.org/10.1021/acsami.5c04034","url":null,"abstract":"Leveler is the key additive for achieving microvia void-free filling in the high-density integration of electronic components for miniaturization, lightweighting, and intelligent development of electronic devices. Traditional organic levelers are mostly quaternary ammonium salts and nitrogen-containing heterocyclic compounds. In this study, thiosemicarbazide (TA) and 1-phenyl 2-thiourea (PTA), which are the thioamino compounds with different substituents of amino and phenyl, are used for the first time as levelers for microvia filling in an acidic copper sulfate bath of Cu electroplating (Cu-EP). The results demonstrate that only the PTA, when used as the leveler in combination with poly(ethylene glycol) (PEG) as the suppressor and bis(sodium sulfopropyl)-disulfide (SPS) as the accelerator, can achieve microvia void-free filling. Chronopotentiometric analyses reveal that both TA and PTA accelerate the reduction of cupric ions. The accelerator of SPS with TA synergistically enhances accelerating effect, while with PTA, it behaves with competitive adsorption to weaken this effect. The suppressor of PEG can cooperate with PTA to show a strong inhibiting effect on cupric ion reduction but presents competitive adsorption with TA, weakening the inhibiting effect of PEG. Under such complex interactions of these additives, it has been found that only the combination of PTA, SPS, and PEG exhibits convection-dependent adsorption behavior, which results in a more negative reduction potential of cupric ions at the mouth of the microvia than that at the bottom of the microvia, indicating a theoretical feasibility of achieving microvia void-free filling. Cyclic voltammetry experiments further demonstrate that the PTA can accelerate the reduction of cupric ions, but this acceleration effect is weakened by SPS due to competitive adsorption. PTA synergizes with PEG to greatly enhance the inhibiting effect on cupric ions reduction. According to electrochemical properties and interactions of the additives, the essence of the PTA-based acidic Cu sulfate bath for achieving microvia void-free filling is elucidated through electroplating simulations. When the three additives coexist, the adsorption coverage of PTA–PEG gradually decreases from the mouth to the bottom. As PTA–PEG exhibits a synergistic inhibition effect, such a gradient significantly inhibits Cu deposition at the mouth; simultaneously, the adsorption coverage of SPS, which behaves with an accelerating effect, gradually increases from the mouth to the bottom, facilitating the reduction of cupric ions at the bottom. The dual gradient effects enable the microvia void-free filling.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"262 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143862453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unexpected MoO3/Al Interfacial Reaction Lowering the Performance of Organic Solar Cells upon Thermal Annealing and Methods for Suppression","authors":"Xuelai Yu, Qian Xi, Jian Qin, Na Wu, Bowen Liu, Tianyu Liu, Zhiyun Li, Ronald Österbacka, Qun Luo, Chang-Qi Ma","doi":"10.1021/acsami.5c05122","DOIUrl":"https://doi.org/10.1021/acsami.5c05122","url":null,"abstract":"Understanding the degradation mechanism and improving the thermal stability of organic solar cells are essential for this new photovoltaic technology. In this work, we found that the high-performance polymer solar cells suffer from significant performance decay upon thermal annealing at 150 °C owing to the fast decay of <i>V</i>_OC and FF. We demonstrated that the thermal annealing process leads to a severe chemical reaction of MoO₃ with Al, forming an Al₂O₃ barrier layer at the MoO₃/Al interface, which lowers the built-in potential (<i>V</i>_bi) of the cells and consequently reduces charge collection efficiency. Inserting a thin C₆₀ interlayer between MoO₃/Al slows the chemical reaction of MoO₃ with Al, which ensures a high <i>V</i>_bi and charge collection efficiency for the annealed MoO₃/C₆₀/Al cells. Such a protection effect of the C₆₀ layer in improving device performance against thermal annealing was also confirmed for cells with different polymer photoactive layers and metal electrodes, demonstrating the generality of the interfacial degradation of the cells and the protection effect of the C₆₀ layer. Finally, we demonstrated that the inverted polymer solar cells with the C₆₀-modified anode showed almost no performance decay upon high-temperature hot-press encapsulation, demonstrating excellent heat tolerance of this new device structure.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"18 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrogen-Free Explosive of N-Azo-Bridged 1,2,4-Triazole: A Novel Nitrogen-Chain-Extended Compound with Exceptional Energy Performance","authors":"Meiqi Xu, Wen-Shuai Dong, Qamar-un-Nisa Tariq, Zu-Jia Lu, Deng-Ke Li, Qiyao Yu, Jian-Guo Zhang","doi":"10.1021/acsami.5c02609","DOIUrl":"https://doi.org/10.1021/acsami.5c02609","url":null,"abstract":"The design of high-energy-density materials (HEDMs) and the investigation of energy limits have consistently represented a focal point and a significant challenge in research. This study prepared a hydrogen-free compound, <b>BLG-102</b>, with high nitrogen content (66.6%) using an energetic block design based on a long nitrogen chain (N6). <b>BLG-102</b> has a high crystal density of 1.85 g·cm^–3, with a measured crystal density of 1.82 g·cm^–3. It also achieves zero oxygen balance (based on CO), excellent enthalpy of formation, and good conjugate planarity and aromaticity. <b>BLG-102</b> demonstrates exceptional detonation performance with a high detonation velocity (<i>V</i>_D = 9311 m·s^–1) and detonation pressure (<i>P</i> = 38.5 GPa). These values are superior to the well-known energetic compound RDX (<i>V</i>_D = 8991 m·s^–1, <i>P</i> = 35.2 GPa), and are comparable to HMX (<i>V</i>_D = 9144 m·s^–1, <i>P</i> = 39.2 GPa). Nevertheless, BLG-102 exhibits slightly higher but acceptable sensitivity (IS = 5 J, FS = 54 N). BLG-102 demonstrates remarkable capabilities in laser initiation. Notably, a 10 mg charge of BLG-102 can effectively detonate 20 mg of RDX, producing a pore diameter of 11.44 mm in the lead plate (2 mm thick). The integrated design approach using the block design concept─combining nitro, azide, and long nitrogen chain structures with a 1,2,4-triazole framework─significantly enhances the energy performance of 1,2,4-triazole compounds. It breaks through the energy limit of already known 1,2,4-triazole-based compounds and provides a new idea for the design and synthesis of HEDMs with high performance.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"51 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bidirectional Bending Soft Actuator with Multistimuli Responsiveness for Environmental Pollutant Monitoring","authors":"Meihao Chen, Chenchen Ding, Yixiong Feng, Weiyu Yan, Junjie Song, Zhifeng Zhang, Xi Xiao, Jianrong Tan, Xiuju Song","doi":"10.1021/acsami.5c02577","DOIUrl":"https://doi.org/10.1021/acsami.5c02577","url":null,"abstract":"Soft actuators have emerged as promising tools for environmental monitoring; however, most existing actuators suffer from multistimuli cross-sensitivity and limited adaptability across various environments. Herein, we propose a bilayer soft actuator composed of a graphene-doped polydimethylsiloxane (G@PDMS) layer and a poly(vinylidene fluoride) (PVDF) layer, capable of effective deformation in both air and aqueous environments while exhibiting selective responsiveness. The actuator demonstrates multistimuli responsiveness to organic solvents/vapors, thermal radiation, and infrared (IR) radiation in air, achieving bidirectional deformation under organic stimuli with a remarkable bending angle of 630° and a load capacity of 180 times its self-weight. In aqueous environments, the actuator exhibits minimal response to thermal and IR light stimuli but shows high selectivity and rapid response to specific organic pollutants, with a response time of just 1.77 s to dichloromethane. Leveraging these properties, we developed a series of functional actuators─including <i>Miura</i> origami, airfoil, and artificial muscle configurations─demonstrating their capability to replicate complex movements. Moreover, a water lily-inspired multienvironmental actuator was designed to effectively shield against underwater temperature fluctuations, IR light, and nontarget organic solvent interference, showing its cross-insensitivity and potential for real-time environmental monitoring applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"46 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"AURORA - An Automatic Robotic Platform for Materials Discovery","authors":"Bingyu Lei, Per H. Svensson, Pavel Yushmanov, Lars Kloo","doi":"10.1021/acsami.5c02605","DOIUrl":"https://doi.org/10.1021/acsami.5c02605","url":null,"abstract":"The urgent need for renewable energy solutions requires rapid advancements in materials discovery. In response, we present AURORA, an innovative robotic platform that enhances this process by integrating automated synthesis, characterization, and evaluation into a single unit, thereby improving efficiency and reducing errors. Its modular design allows for adaptable screening of diverse materials, including metal halide perovskites, and their application in solar cell devices. Our study demonstrates the ability of AURORA to autonomously synthesize and evaluate polycrystalline, mixed halide perovskites, including a novel mesoscopic solar cell array with improved data reliability and throughput. AURORA also conducts postsynthesis treatments and dynamic analyses under stress, setting it apart from traditional methods. These features make AURORA a transformative tool for the discovery of novel materials, with potential machine learning integration for optimization. Our results highlight the application of AURORA as a robust and adaptable platform for future developments in automated materials research.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143862556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Self-Powered and Self-Healing Underwater Sensors with Functions of Intelligent Drowning Warning and Rescuing by Using a Nonswelling Hydrogel","authors":"Zhongyuan Tian, Shilin Luo, Shangzhi Yue, Zheng Li, Dan Yang","doi":"10.1021/acsami.5c04162","DOIUrl":"https://doi.org/10.1021/acsami.5c04162","url":null,"abstract":"Hydrogels have attracted increasing attention in wearable sensors, but preparing underwater hydrogel sensors with excellent anti-swelling and self-healing properties is still challenging. Herein, an anti-swelling and self-healing hydrogel is prepared by grafting poly(acrylic acid) with hydrophobic lauryl methacrylate, as well as constructing a second network and multiple molecular interactions (abbreviated as PALCF). The introduced hydrophobic long alkyl chains and the increased cross-linking density of the hydrogel result in a swelling ratio of only 0.04% after immersion in water for 15 days. Due to abundant metal coordination and hydrogen bonds, the PALCF hydrogel exhibits a high tensile stress of 0.60 MPa and a self-healing efficiency reaching 96.0% after self-healing at 60 °C for 2 min. Based on the piezoresistive effect, the PALCF hydrogel is directly used as an underwater strain sensor with a high sensitivity (GF = 2.24) to control underwater vehicles for rescue implementation. Furthermore, two self-powered triboelectric nanogenerator sensors with contact and non-contact models are constructed based on PALCF hydrogels for underwater communication, capable of sending out SOS messages and drowning alarms in emergency. The proposed underwater sensors with drowning warning and rescuing functions have the potential for use in drowning prevention, human–machine interfaces, and underwater communication system.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"6 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"One-Step Sintering Coating toward Air-Stable O3-Type Layered Oxide Cathodes for Sodium-Ion Batteries","authors":"Yibo Pan, Xing Zhou, Deda Peng, Run Liu, Yongyuan Zhou, Jin Han, Tiefeng Liu, Ya You","doi":"10.1021/acsami.5c01356","DOIUrl":"https://doi.org/10.1021/acsami.5c01356","url":null,"abstract":"Layered oxides are one of the most promising cathode materials for sodium-ion batteries due to their high theoretical capacity, high voltage platform, and low manufacturing cost. However, the poor air stability severely limits the practical application of the O3-type layered oxide. In this study, a simple one-step sintering coating method is explored to construct a uniform and dense heavy metal oxide (Sb₂O₃) coating layer on Na(Ni_1/3Fe_1/3Mn_1/3)O₂ (NFM333), and the coating layer effectively improved the air stability of NFM333 by mitigating the contact of H₂O and CO₂ in the air. Consequently, NFM333–0.5 wt % Sb₂O₃ obtains a specific capacity of 92.1 mAh g^–1 with a capacity retention of 84.6% after 200 cycles at 1C after exposure in air with 60% humidity for 2 days, while NFM333 without a coating layer has a specific capacity of just 85.4 mAh g^–1 with a capacity retention of 65.3% after 200 cycles at 1C after the same exposure handling. This study presents a facile coating method to improve the air stability of O3-type NFM33, which provides insights for the development of air-stable NFM333.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"33 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143862560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}