ACS Applied Materials & Interfaces最新文献

{"title":"","authors":"Zhipeng Liao, Haiqin Liao, Yi Luo, Sijie Chen, Mingyu Chen, Jiarong He, Yan Xu, Long Wang and Chengcheng Niu*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsami.5c07008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"","authors":"Changxin Dong, Samya Sen, Zhennan Ru, Athena Kolli, Paxton S. Appel, Jonathan A. Fan and Eric A. Appel*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsami.5c05534","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"","authors":"Xiaodong He*,  and , Qilong Zhao, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsami.5c08242","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"","authors":"Xinyu Zhang, Jun Ma, Hanyin Hu, Zhuoming Xu, Jintao Liu, Jiayi Chen, Bin Chen, Lili Shi, Huanhuan Luo*, Gang Chen* and Hongwei Xu*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 29","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsami.5c12875","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chemochromic Damage-Detecting and Recovery System Using Affordable Hydrogel.","authors":"Hyun Jae Lee, Ryuma Niiyama","doi":"10.1021/acsami.5c08719","DOIUrl":"10.1021/acsami.5c08719","url":null,"abstract":"<p><p>A multipurpose chemochromic protector is proposed with a hydrogel made from a mixture of sodium chloride, starch, and water, and the deposition of a copper layer on the nylon polyethylene film surrounding the hydrogel. This hydrogel is found to be chemically stable, water-retaining, shock-absorbent, biocompatible, cost-effective, and highly reactive with copper enough to realize its chemochromic characteristics. The varying chemical compositions of the hydrogel show that the presence of poly(acrylic acid) (PAA) inside can enhance the damage-detecting and recovery capabilities of the protector. The compressive strength measurement reveals that the hydrogel becomes effectively solidified with the formation of copper chloride and the evaporation of water molecules to cover the damaged areas. In the shear strength experiment, the PAA-included hydrogel is proven to have the high adhesiveness necessary for the recovery of the protector. The damage-detecting and recovery experiment successfully presents the copper-specific chemochromic properties of the protector, implying that the addition of PAA intensifies the color changes of the hydrogel as well as its increased stiffness in the damaged areas. The chemochromically operating surface protector with a simple fabrication process, intuitive measurement, and an alternative working mechanism would be able to promote related studies and contribute to the development of additional protective measures such as for diverse protective clothing, miscellaneous robotic structures, and numerous space applications.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42407-42419"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144590014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Colloidally Synthesized Near-Infrared-Emitting Perovskite Nanocrystals for Optoelectronics.","authors":"Amit K Guria, Shivangi Jain, Nidhi Dubey, Suresh Sarkar","doi":"10.1021/acsami.5c02928","DOIUrl":"10.1021/acsami.5c02928","url":null,"abstract":"<p><p>Near-infrared (NIR) light emitting nanocrystals possess spectacular optoelectrical properties, which play pivotal roles in photonics, optical devices, and nanomedicine. The advent of halide perovskites (HPs) has marked a significant development in the applications of NIR-emitting nanocrystals in optoelectrical devices. Given the potential of NIR-perovskite in photovoltaics applications, there has been a growing focus on developing colloidal HP nanostructures for both fundamental study and commercial applications. These optoelectronic applications require the solution-processability and compatibility of these nanocrystal (NC) emitters in various organic and inorganic matrices. Colloidal synthesis of NCs facilitates these requirements, ushering in a new era of research on the architecture of HP nanostructures, which has yet to unfold many unresolved fundamental mysteries. This review examines recent studies on NIR-light-emitting undoped and doped all-inorganic and hybrid HP colloidal NCs with or without toxic lead and meticulously analyzes the role of surface ligands in the synthesis, crystallographic phase, and colloidal stability of these HP nanocrystals. The review particularly focuses on the recent progress in the synthesis, photophysics, excited-state carrier dynamics, and environmental stability of these NIR-perovskite NCs and their applications in the fabrication of optoelectronic devices, including NIR-LEDs, solar cells, photodetectors, and luminescent solar concentrators.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"41403-41441"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of Polyionic Liquid Coating Layer Enables High Cyclic Stability of 4.5 V LiCoO₂ Cathode by In Situ Polymerization.","authors":"Dejun Li, Haifeng Tu, Shiqi Zhang, Yuyue Guo, Jiawei Zhao, Xianshu Cai, Jiang-Yan Xue, Suwan Lu, Lingwang Liu, Xin Zhang, Keyang Peng, Jingjing Xu, Xiaodong Wu","doi":"10.1021/acsami.5c06988","DOIUrl":"10.1021/acsami.5c06988","url":null,"abstract":"<p><p>The pursuit of high-energy-density portable electronic applications has intensified the development of high-voltage LiCoO₂ (LCO) cathodes. However, the LCO cathode undergoes severe side reactions with the electrolyte at elevated cutoff voltages, leading to significant interface degradation and structural collapse. Modifying the cathode/electrolyte interface is a very good strategy to restrain interfacial side reactions and stabilize the structure. Herein, we proposed a high-voltage-stable polyionic liquid (PIL) as an artificial solid electrolyte interface, achieved by in situ bulk polymerization of a diallyldimethylammonium bis(trifluoromethanesulfonyl)imide (DMDA) monomer to form a polymer-containing cross-linked structure on the LCO cathode surface. The polymerized DMDA (PDMDA) coating layer forms a thin, dense cathode-electrolyte interphase (CEI) that effectively isolates the LCO from direct contact with the electrolyte and suppresses side reactions. Consequently, the PDMDA-modified LCO cathode retains 80% of its initial capacity over 500 cycles at 1C within a voltage range of 3 to 4.5 V, significantly outperforming the bare-LCO cathode. Additionally, the PDMDA layer also enhances the thermal stability of the LCO cathode, offering substantial value for safe lithium battery applications. This PDMDA modification strategy provides a promising pathway for practical deployment of high-voltage LCO cathodes.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42268-42277"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic ZnS Windows Fabricated by Femtosecond Laser Optical Field Modulation Assisted with Wet Etching for High-Performance Infrared Monitoring of EV Charging.","authors":"Yulong Ding, Cong Wang, Xianshi Jia, Linpeng Liu, Zheng Gao, Xiang Jiang, Shiyu Wang, Dejin Yan, Nai Lin, Ji-An Duan","doi":"10.1021/acsami.5c09910","DOIUrl":"10.1021/acsami.5c09910","url":null,"abstract":"<p><p>Femtosecond laser micromachining, a remarkable technology for fabricating various micro/nanostructures, struggles to balance processing efficiency and quality. Here, a method is proposed that combines femtosecond laser optical field modulation technology with the wet chemical etching process to efficiently fabricate high-quality microhole arrays on zinc sulfide (ZnS). Utilizing Bessel beams and subpulse sequences for fabrication, a machining error of less than 0.3 μm (defocus amount of 1 to 16 μm) and a significant improvement in the aspect ratio are achieved. Inspired by the antireflective properties of stink bug compound eyes, approximately 25 million biomimetic microholes with an aspect ratio of 0.75 are fabricated on the ZnS surface in under 42 min. Biomimetic ZnS demonstrates broadband transmission (average of 81.3% from 8 to 12 μm) and excellent transmittance (83.2% at 9.2 μm). The utilization of the biomimetic window for monitoring an outdoor electric vehicle charging station demonstrates an improvement of 6.7% to 12.4% in target discrimination, detail capture, texture rendering, and edge resolution in the captured infrared images, thereby highlighting the potential application advantages of high-quality biomimetic microholes.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42462-42473"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiple Dynamic Anticounterfeiting Using Photochromic Luminescence Organic Cocrystals.","authors":"Li Li, Shu-Hao Li, Hui-Yuan Jiang, Jian-Ge Zeng, Chun-Jie Liu","doi":"10.1021/acsami.5c08514","DOIUrl":"10.1021/acsami.5c08514","url":null,"abstract":"<p><p>Photochromic and luminescent complexes are easy to imitate due to their single-signal output, resulting in a low encryption and anticounterfeiting level. Photochromic luminescence (PCL) complexes exhibit fluorescence and color-changing dual output, which provides additional safety and greatly improves anticounterfeiting security. However, it is challenging to overcome the competition between luminescence and the quenching effect of the photoinduced electron transfer (PET) process. This work proposes that introducing a highly conjugated luminescent unit into a photochromic molecule and using hydrogen bond interactions to construct highly rigid organic cocrystals is an effective strategy to overcome the quenching effect of PET in the construction of PCL compounds. By this strategy, two viologen-based cocrystals with fluorescence and color-changing dual output were synthesized, and high-security anticounterfeiting was demonstrated. The mechanistic analysis indicates that the highly conjugated compound not only significantly enhances the luminescent intensity but also prolongs the lifetime of the charge separated state, with its influence dominating over the quenching effect of the PET process. This work presents a strategy for constructing PCL complexes for high security anticounterfeiting.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42293-42302"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrochemical Liquid-Liquid-Solid Electrodeposition of Ge Nanowire Films with Low Reflectance for Light Management Coatings and High Mass-Loading for High Areal Capacity Li+ Battery Anodes.","authors":"Tung T Nguyen,Christopher P Woodley,Dijia Zou,Joshua P Hazelnis,Mohammad Ali,Lauren C Rich,L Jay Guo,Bart M Bartlett,Stephen Maldonado","doi":"10.1021/acsami.5c07519","DOIUrl":"https://doi.org/10.1021/acsami.5c07519","url":null,"abstract":"A simple method for the electrodeposition of dense semiconductor nanowire films on metal foils via the electrochemical liquid-liquid-solid (ec-LLS) method has been demonstrated. Thin liquid InBiCd coatings on metal foil electrodes were used to seed the Ge nanowire growth in an aqueous electrolyte. The resultant Ge nanowire films were characterized via scanning electron microscopy, X-ray diffraction, angle-resolved reflectance spectra, and cyclic voltammetry both outside and within a coin cell by using a Li counter electrode. High magnification electron microscopy indicated that the nanowire sizes and densities depended on the nature of the underlying metal foil. The highest density and thinnest nanowires were obtained with the Cu foil substrates. The as-deposited Ge nanowires were highly crystalline and exhibited a coiled microstructure. The mass density of the films linearly tracked with a longer electrodeposition time. At the highest mass loadings, the films were visibly dull black and exhibited a wavelength-independent total reflectance of ∼10% across visible and near-infrared wavelengths. Separate specular reflectance measurements confirmed that the total reflectance was dominated by diffuse scattering. Optical simulation corroborated the premise that a high density of randomly oriented Ge nanowires with large-angle orientations significantly reduces the total reflectance of such films. Voltammetric measurements indicated that Li+ insertion took place predominantly in the Ge nanowires, with a high initial areal (gravimetric) discharge capacity of 4.12 mA h cm-2 (1359 mA h g-1). An areal (gravimetric) capacity of 2.10 mA h cm-2 (691 mA h g-1) was retained after 50 cycles while maintaining 98.7% Coulombic efficiency. This work significantly advances the use of ec-LLS as a synthesis approach for functional nanowire film for a high-mass loading anode for Li-ion batteries and low reflectance coatings.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"109 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144684313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}