B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, N. I. Abzalov, D. S. Vasilyev
{"title":"On the Nature of the Multidirectional Change in Combustion Velocity of Ti-based Powder Mixtures When Diluted with Inert Additives","authors":"B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, N. I. Abzalov, D. S. Vasilyev","doi":"10.3103/S1061386222050065","DOIUrl":"10.3103/S1061386222050065","url":null,"abstract":"<p>Macrokinetic parameters of combustion of powder and granular mixtures were studied upon dilution of Ti + C with various metal powders. The combustion velocities of powder mixtures (Ti + C) + 20% Me (Me = Ni, Cu) turned out to be higher than those of Ti + C blend, despite the lower temperature of combustion. When diluting Ti + C mixture with Ti or TiC powders, there was no such a contradiction. The convective-conductive model of combustion explains obtained data by a strong influence of impurity gas release from titanium particles ahead the combustion front. The time of combustion transfer between the granules, the combustion velocity inside the granules, and the quantitative assessment of the retarding effect of impurity gases in powder mixtures were determined. When comparing the combustion parameters of granular Ti + C mixtures diluted with various metal powders and titanium carbide, the efficiency of the combustion transfer between the granules in the presence of hot Ni melt was explained. In addition, the impurity gas reabsorption by titanium carbide was confirmed.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"283 - 287"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4381406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Boron Combustion in CO2 Atmosphere","authors":"T. G. Akopdzhanyan, I. A. Studenikin","doi":"10.3103/S1061386222040021","DOIUrl":"10.3103/S1061386222040021","url":null,"abstract":"","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"276 - 278"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4385913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. M. Pauls, J. C. Murphy, M. Drake, A. S. Rogachev, A. S. Mukasyan
{"title":"Cryo-Milled Nickel–Aluminum Nanostructured Composites: Bifurcated Ignition Mode","authors":"J. M. Pauls, J. C. Murphy, M. Drake, A. S. Rogachev, A. S. Mukasyan","doi":"10.3103/S1061386222040070","DOIUrl":"10.3103/S1061386222040070","url":null,"abstract":"<p>We report the use of high-energy cryo-milling for fabrication of reactive composite Ni/Al particles. Specifically, the CryoMill (Retsch) with liquid nitrogen was used with milling times in the range of 5 to 40 min. The microstructure of the obtained particles and their ignition characteristics were investigated. A novel bifurcated ignition mode for intermediate milling times was observed. The correlations between the microstructure of the Ni/Al particles and their reactivity were discussed.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"236 - 246"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4387596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. N. Kubanova, D. M. Ikornikov, V. N. Sanin, D. A. Martynov
{"title":"Centrifugal SHS of High Cr Composite Materials","authors":"A. N. Kubanova, D. M. Ikornikov, V. N. Sanin, D. A. Martynov","doi":"10.3103/S1061386222050041","DOIUrl":"10.3103/S1061386222050041","url":null,"abstract":"<div><div><h3>Keywords: </h3><p>composite materials, master alloy, chromium, centrifugal SHS</p></div></div>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"279 - 282"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4386253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of TiZrHfVNb Multi-Principal Element Alloy using SHS Hydrides by “Hydride Cycle” Method","authors":"D. G. Mayilyan, A. G. Aleksanyan","doi":"10.3103/S1061386222050053","DOIUrl":"10.3103/S1061386222050053","url":null,"abstract":"<p>Finding new energy effective methods for the production of refractory multi-principal element alloys (MPEAs) is a challenge for rapidly developing MPEA materials science. Formation of equimolar TiZrHfVNb MPEA and evaluation of alloy potential for use as hydrogen storage material were investigated. In this study, we demonstrated, for the first time to the best of our knowledge, that MPEA can be produced using SHS hydrides as precursor materials by “Hydride Cycle” (HC) method. The hydrogenation of obtained alloy by self-propagating high-temperature synthesis (SHS) method was studied. Crystal structure, surface microstructure, chemical composition, and thermal stability of synthesized materials were studied. It was shown that two-phase (α + β) alloy was synthesized. As a result of the SHS hydrogenation process, TiZrHfVNb alloy absorbed 1.8 wt % of hydrogen.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"268 - 272"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4386280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Ramprasad, G. V. J. Gowda, K. V. A. Gowda, K. S. Kantharaj, F. Tudorache, K. Abdulvakhidov, N. Lyanguzov, I. S. Yahia, H. Y. Zahran, H. Algarni, V. J. Angadi
{"title":"Synthesis and Study of Highly Porous Nature Gadolinium Doped CoCr2O4: Focus on the Structural, Microstructural, Electric, and Humidity Sensing Properties","authors":"N. Ramprasad, G. V. J. Gowda, K. V. A. Gowda, K. S. Kantharaj, F. Tudorache, K. Abdulvakhidov, N. Lyanguzov, I. S. Yahia, H. Y. Zahran, H. Algarni, V. J. Angadi","doi":"10.3103/S1061386222040094","DOIUrl":"10.3103/S1061386222040094","url":null,"abstract":"<p>In this paper, we presented structural, Fourier infrared spectroscopic, and dielectric analysis of cobalt chromate (Co<sup>2+</sup><span>({text{Cr}}_{2}^{{3 + }})</span>O<sub>4</sub>) with 2 mol % of gadolinium (Gd<sup>3+</sup>) rare earth metal additions under humidity and non-humidity circumstances. The Gd<sup>3+</sup> doped Co<sup>2+</sup><span>({text{Cr}}_{2}^{{3 + }})</span>O<sub>4</sub> samples were prepared by solution combustion method and sintered for 2 h at 650°C to get single phase. Doped and undoped samples were characterized by X-ray powder diffraction (XRD) analysis providing the detailed information of the Co<sup>2+</sup><span>({text{Cr}}_{2}^{{3 + }})</span>O<sub>4</sub> phase and crystallinity. Furthermore, the average crystallite sizes were found to be in the range of 18 to 7 nm. The general nature of ferrite materials was revealed via FTIR analysis. The octahedral and tetrahedral stretching band in FTIR spectra were confirmed a ferrite structure without impurity. Scanning electron microscopic images exhibited that samples are highly porosity. We investigated the relevant conductivity of the samples, the reaction time of the capacitive sensor, and the humidity influence on the relative permittivity characteristics at a constant frequency of 1 kHz. Our findings indicate that Gd<sup>3+</sup> doped Co<sup>2+</sup><span>({text{Cr}}_{2}^{{3 + }})</span>O<sub>4</sub> could be exploited as an active material in humidity sensor applications.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"169 - 178"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4386282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. A. Lazarev, M. L. Busurina, A. N. Gryadunov, A. E. Sytschev, A. F. Belyakova
{"title":"SHS Pressing of (Ti–Al–Mn)/Ti Metal–Intermetallic Layered Material","authors":"P. A. Lazarev, M. L. Busurina, A. N. Gryadunov, A. E. Sytschev, A. F. Belyakova","doi":"10.3103/S1061386222040057","DOIUrl":"10.3103/S1061386222040057","url":null,"abstract":"<p><b>(</b>Ti–Al–Mn)/Ti metal–intermetallic layered material was prepared by SHS pressing. It was found that the combustion product obtained in Ti–Al–Mn layer consists of hexagonal Ti(Mn<sub>0.755</sub>Al<sub>1.246</sub>) and cubic Ti<sub>0.25</sub>Al<sub>0.67</sub>Mn<sub>0.08</sub> phases. The transition zone forming between the Ti–Al–Mn layer and the Ti foil was shown to have a thickness of 10–15 µm and to be represented by Ti<sub><i>x</i></sub>Al phase with variable composition.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"164 - 168"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4691910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"On the Nature of the Pyrophoricity of Metal Nanopowders","authors":"M. I. Alymov, B. S. Seplyarskii","doi":"10.3103/S1061386222050016","DOIUrl":"10.3103/S1061386222050016","url":null,"abstract":"","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"288 - 291"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4386255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. S. Yousef, I. S. Yahia, H. Y. Zahran, V. J. Angadi
{"title":"Synthesis and Study of Structural, Microstructural, and Magnetic Properties of Europium and Scandium 1 Mol % Doped CuFe2O4 Prepared by Self-Propagating High Temperature Synthesis Method","authors":"E. S. Yousef, I. S. Yahia, H. Y. Zahran, V. J. Angadi","doi":"10.3103/S1061386222040148","DOIUrl":"10.3103/S1061386222040148","url":null,"abstract":"<p>In the present work, CuEu<sub>0.01</sub>Fe<sub>1.99</sub>O<sub>4</sub> and CuEu<sub>0.01</sub>Sc<sub>0.01</sub>Fe<sub>1.98</sub>O<sub>4</sub> nanoparticles were prepared by self-propagating high-temperature synthesis method for reporting the structural, microstructural, and magnetic properties of prepared samples. X-ray diffraction (XRD) patterns confirmed the spinel cubic structure with space group <i>Fd</i>3<i>m</i>. An average crystallite size was found in the range of 20–40 nm. Scanning electron microscopy (SEM) investigations indicated the porous nature and particles agglomeration. The elemental composition of samples was studied by using energy-dispersive X-ray spectroscopy (EDS). The magnetic hysteresis loop revealed the soft ferromagnetic nature. Magnetic parameters such as saturation magnetization, coercivity, and remanence magnetization decrease with an increase in Eu<sup>3+</sup> and Sc<sup>3+</sup> concentration.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"31 4","pages":"159 - 163"},"PeriodicalIF":0.6,"publicationDate":"2023-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4385905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}