P. A. Lazarev, A. S. Raznoschikov, M. L. Busurina, O. D. Boyarchenko, I. D. Kovalev, A. E. Sytschev
{"title":"Features of Selective Laser Melting of SHS-Prepared Intermetallic Alloy Ti20Al3Si9","authors":"P. A. Lazarev, A. S. Raznoschikov, M. L. Busurina, O. D. Boyarchenko, I. D. Kovalev, A. E. Sytschev","doi":"10.3103/S1061386224700328","DOIUrl":"10.3103/S1061386224700328","url":null,"abstract":"<p>Selective laser melting (SLM) was first used to deposit products made of SHS-produced intermetallic alloy Ti<sub>20</sub>Al<sub>3</sub>Si<sub>9</sub> powder on the Ti substrate. It was shown that formed Ti<sub>20</sub>Al<sub>3</sub>Si<sub>9</sub> alloy/Ti substrate composites have a strong bond. The influence of SLM parameters for processing SHS-produced powder on microstructure and phase composition of clad samples was studies.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"287 - 294"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. O. Kirillov, R. D. Kapustin, V. I. Uvarov, O. D. Boyarchenko
{"title":"Low-Temperature Sintering of SHS-Produced SiC-Based Porous Ceramics","authors":"A. O. Kirillov, R. D. Kapustin, V. I. Uvarov, O. D. Boyarchenko","doi":"10.3103/S1061386224700262","DOIUrl":"10.3103/S1061386224700262","url":null,"abstract":"<p>Porous ceramic materials were sintered from fine SiC filler powder produced via SHS with binders SiO<sub>2</sub> and MgO at temperatures of 800–1300°C. The effect of sintering temperature on the properties of the resulting ceramics such as pore size, open porosity, bending strength, and pure water permeability was investigated. SiC-based membrane rejected completely solid SiC particles with <i>D</i><sub>50</sub> = 0.5 μm while maintaining stable permeability and physical and mechanical characteristics after repeated filtration/regeneration cycles.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"280 - 286"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and Sintering of MgAlON: Influence of Sintering Additives","authors":"T. G. Akopdzhanyan, D. I. Abzalov","doi":"10.3103/S1061386224700286","DOIUrl":"10.3103/S1061386224700286","url":null,"abstract":"<p>MgAlON ceramics were prepared by combined use of self-propagating high-temperature synthesis of Al + Al<sub>2</sub>O<sub>3</sub> + MgO + Mg(ClO<sub>4</sub>)<sub>2</sub> mixtures doped with sintering agent LiF, CaCO<sub>3</sub> or La<sub>2</sub>O<sub>3</sub> + Y<sub>2</sub>O<sub>3</sub> + MgO and pressureless sintering. The effect of additives on the combustion process and phase formation of synthesized products, as well as their subsequent sintering was studied. Introduction of 10 wt % CaCO<sub>3</sub> was shown to lower the combustion temperature followed by stopping the combustion front. It was revealed that the density of sintered ceramic materials reaches 90% of the theoretical value. The sintered sample prepared by doping with 0.6 wt % CaCO<sub>3</sub> was found to possess the highest density (3.3 g/cm<sup>3</sup>) and light transmittance (16%).</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"303 - 307"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Combustion Synthesis of Titanium Nitride in a Controlled Reagent-Feed Reactor","authors":"A. V. Linde, V. V. Grachev","doi":"10.3103/S1061386224700316","DOIUrl":"10.3103/S1061386224700316","url":null,"abstract":"","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"324 - 326"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermal Ionization during SHS of Ti–Al–Mg System","authors":"P. A. Lazarev, V. Yu. Barinov, A. E. Sytschev","doi":"10.3103/S106138622470033X","DOIUrl":"10.3103/S106138622470033X","url":null,"abstract":"","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"327 - 329"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. N. Sanin, D. M. Ikornikov, A. O. Sivakova, D. Yu. Kovalev, O. A. Golosova
{"title":"Gravity-Assisted SHS Metallurgy of Cast High-Entropy Mo–Nb–Ta–(Cr,V,Zr,Hf) Alloys","authors":"V. N. Sanin, D. M. Ikornikov, A. O. Sivakova, D. Yu. Kovalev, O. A. Golosova","doi":"10.3103/S1061386224700298","DOIUrl":"10.3103/S1061386224700298","url":null,"abstract":"<p>Cast Mo–Nb–Ta–(Cr,V,Zr,Hf) refractory high-entropy alloys were first prepared via gravity-assisted SHS metallurgy. It was shown that the ingots crystallize from the liquid state, in which a homogeneous distribution of constituting elements is provided. The phase composition of synthesized RHEA ingots was revealed to be doped component dependent. Combined reduction of metals of V (Nb, Ta, V) and VI (Cr, Mo) groups formed single-phase alloys with a bcc crystal structure. MoNbTaCr alloys doped with Zr or Hf having hexagonal crystal structure were found to consist of fcc and hcp phases in addition to bcc solid solution.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"308 - 318"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Self-Propagating High-Temperature Synthesis of SiC-Doped Cu2Se Compound: Thermoelectric Properties","authors":"G. R. Nigmatullina, D. Yu. Kovalev, A. V. Karpov","doi":"10.3103/S1061386224700304","DOIUrl":"10.3103/S1061386224700304","url":null,"abstract":"<p>Cu<sub>2</sub>Se thermoelectric compound containing up to 5 wt % SiC was prepared via self-propagating high-temperature synthesis. Doping SiC was shown to improve the thermoelectric properties and get 20% increase in the electrical conductivity and 60% increase in the Seebeck coefficient. The thermoelectric power factor of Cu<sub>2</sub>Se–5 wt % SiC was found to be 14.4 μW cm<sup><i>–</i>1</sup> K<sup><i>–</i>2</sup> at 900 K, which is 3 times higher than that of Cu<sub>2</sub>Se.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"319 - 323"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"SHS of V2AlC Ceramics Using VO2 as a Starting Material","authors":"D. Yu. Kovalev, V. I. Vershinnikov","doi":"10.3103/S1061386224700249","DOIUrl":"10.3103/S1061386224700249","url":null,"abstract":"<p>V<sub>2</sub>AlC powder was prepared through self-propagating high-temperature synthesis of VO<sub>2</sub>/Mg/Al/C mixture in molten NaCl followed by leaching in dilute hydrochloric acid. The synthesized product included V<sub>2</sub>AlC, vanadium aluminides and carbides, as well as MgO and MgAl<sub>2</sub>O<sub>4</sub>. The phase composition was found to be magnesium and carbon content dependent. Optimum component ratios and acid leaching conditions were determined for the successful synthesis of V<sub>2</sub>AlC MAX phase.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"266 - 272"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. M. Ikornikov, O. A. Golosova, S. L. Silyakov, V. N. Sanin
{"title":"Effect of Doping with Si–B on the Structure of Cast Mo–Nb–Cr–V–Ti–Al High-Entropy Alloy Produced by Gravity-Assisted SHS Metallurgy","authors":"D. M. Ikornikov, O. A. Golosova, S. L. Silyakov, V. N. Sanin","doi":"10.3103/S1061386224700341","DOIUrl":"10.3103/S1061386224700341","url":null,"abstract":"","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"330 - 335"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Ti–55531 Multicomponent Alloy by the Energy-Efficient Hydride Cycle Method","authors":"A. Aleksanyan, D. Mayilyan","doi":"10.3103/S1061386224700237","DOIUrl":"10.3103/S1061386224700237","url":null,"abstract":"<p>This investigation aimed to synthesize Ti–5Al–5V–5Mo–3Cr–1Zr (Ti–55531) alloy by energy-efficient “hydride cycle” (HC) method. From X-ray powder diffraction it was found that the synthesized alloy consists of two phases: HCP α and BCC β. Scanning electron microscopy (SEM) unveiled discernible surface characteristics on the Ti–55531 alloy, delineating two predominant phases with distinct variations in light and dark shades. These observed phases corresponded to microstructural compositions attributed to the α and β phases. The interaction of obtained Ti–55531 alloy with hydrogen in self-propagating high-temperature synthesis (SHS) mode was studied. It was demonstrated that the compacted alloy without preliminary crushing or mechanical treatment could absorb 3.4 wt % of hydrogen during the SHS process. Additionally, it was determined that the synthesized hydride of multicomponent alloy consists of two phases: TiH<sub>2</sub> phase with FCC structure and β-phase with BCC structure. The thermal stability of synthesized hydride was analyzed using differential thermal analysis (DTA) method, revealing a hydrogen desorption process characterized by two endo-peaks at 334 and 574°C.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"33 4","pages":"251 - 257"},"PeriodicalIF":0.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}