S. L. Amaya Bustos, A. Gómez Zapata, J. D. Ortega Mesa, O. Morán, E. Chavarriaga
{"title":"燃料对凝胶燃烧合成钙钛矿型混合氧化物La0.7Ca0.3Mn1-xNixO3 (x = 0和0.07)结构、形态和电学性能的影响","authors":"S. L. Amaya Bustos, A. Gómez Zapata, J. D. Ortega Mesa, O. Morán, E. Chavarriaga","doi":"10.3103/S1061386224700390","DOIUrl":null,"url":null,"abstract":"<p>The solution combustion synthesis method was used to prepare samples with stoichiometric La<sub>0.7</sub>Ca<sub>0.3</sub>Mn<sub>1–x</sub>Ni<sub>x</sub>O<sub>3</sub> (<i>x</i> = 0 and 0.07) using glycine and tris(hydroxymethyl)aminomethane (TRIS) as fuels. X-ray diffraction showed that the samples crystallized into an orthorhombic structure of the <i>Pnma</i> space group with slight changes in the lattice parameters according to the type of fuel used, which can be attributed to their heat capacity. Likewise, using the transmission electron microscope technique, conglomerates of particles with relatively uniform morphology and crystallite sizes that varied in a range of 17–26 nm were observed. The electrical behavior exhibited a metal–semiconductor transition that displaced the temperature peak towards lower values, according to the Ni content. It was concluded that the properties of this type of complex inorganic oxide such as manganites can be varied with the use of different fuels in the synthesis process.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":"34 1","pages":"33 - 41"},"PeriodicalIF":0.5000,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fuel Effect on the Structural, Morphological, and Electrical Properties of Perovskite-Type Mixed Oxide La0.7Ca0.3Mn1–xNixO3 (x = 0 and 0.07) Synthesized through Gel Combustion\",\"authors\":\"S. L. Amaya Bustos, A. Gómez Zapata, J. D. Ortega Mesa, O. Morán, E. Chavarriaga\",\"doi\":\"10.3103/S1061386224700390\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The solution combustion synthesis method was used to prepare samples with stoichiometric La<sub>0.7</sub>Ca<sub>0.3</sub>Mn<sub>1–x</sub>Ni<sub>x</sub>O<sub>3</sub> (<i>x</i> = 0 and 0.07) using glycine and tris(hydroxymethyl)aminomethane (TRIS) as fuels. X-ray diffraction showed that the samples crystallized into an orthorhombic structure of the <i>Pnma</i> space group with slight changes in the lattice parameters according to the type of fuel used, which can be attributed to their heat capacity. Likewise, using the transmission electron microscope technique, conglomerates of particles with relatively uniform morphology and crystallite sizes that varied in a range of 17–26 nm were observed. The electrical behavior exhibited a metal–semiconductor transition that displaced the temperature peak towards lower values, according to the Ni content. It was concluded that the properties of this type of complex inorganic oxide such as manganites can be varied with the use of different fuels in the synthesis process.</p>\",\"PeriodicalId\":595,\"journal\":{\"name\":\"International Journal of Self-Propagating High-Temperature Synthesis\",\"volume\":\"34 1\",\"pages\":\"33 - 41\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2025-04-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Self-Propagating High-Temperature Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S1061386224700390\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Self-Propagating High-Temperature Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1061386224700390","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Fuel Effect on the Structural, Morphological, and Electrical Properties of Perovskite-Type Mixed Oxide La0.7Ca0.3Mn1–xNixO3 (x = 0 and 0.07) Synthesized through Gel Combustion
The solution combustion synthesis method was used to prepare samples with stoichiometric La0.7Ca0.3Mn1–xNixO3 (x = 0 and 0.07) using glycine and tris(hydroxymethyl)aminomethane (TRIS) as fuels. X-ray diffraction showed that the samples crystallized into an orthorhombic structure of the Pnma space group with slight changes in the lattice parameters according to the type of fuel used, which can be attributed to their heat capacity. Likewise, using the transmission electron microscope technique, conglomerates of particles with relatively uniform morphology and crystallite sizes that varied in a range of 17–26 nm were observed. The electrical behavior exhibited a metal–semiconductor transition that displaced the temperature peak towards lower values, according to the Ni content. It was concluded that the properties of this type of complex inorganic oxide such as manganites can be varied with the use of different fuels in the synthesis process.
期刊介绍:
International Journal of Self-Propagating High-Temperature Synthesis is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.