Frontiers of Chemical Science and Engineering最新文献_第9页

Synthetic auxotrophs accelerate cell factory development through growth-coupled models 合成辅助营养体通过生长耦合模型加速细胞工厂的发展

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-06-06 DOI: 10.1007/s11705-024-2454-9

Liangpo Li, Linwei Yu, Xinxiao Sun, Qipeng Yuan, Xiaolin Shen, Jia Wang

{"title":"Synthetic auxotrophs accelerate cell factory development through growth-coupled models","authors":"Liangpo Li, Linwei Yu, Xinxiao Sun, Qipeng Yuan, Xiaolin Shen, Jia Wang","doi":"10.1007/s11705-024-2454-9","DOIUrl":"10.1007/s11705-024-2454-9","url":null,"abstract":"<div><p>The engineering of microbial cell factories for the production of high-value chemicals from renewable resources presents several challenges, including the optimization of key enzymes, pathway fluxes and metabolic networks. Addressing these challenges involves the development of synthetic auxotrophs, a strategy that links cell growth with enzyme properties or biosynthetic pathways. This linkage allows for the improvement of enzyme properties by <i>in vivo</i> directed enzyme evolution, the enhancement of metabolic pathway fluxes under growth pressure, and remodeling of metabolic networks through directed strain evolution. The advantage of employing synthetic auxotrophs lies in the power of growth-coupled selection, which is not only high-throughput but also labor-saving, greatly simplifying the development of both strains and enzymes. Synthetic auxotrophs play a pivotal role in advancing microbial cell factories, offering benefits from enzyme optimization to the manipulation of metabolic networks within single microbes. Furthermore, this strategy extends to coculture systems, enabling collaboration within microbial communities. This review highlights the recently developed applications of synthetic auxotrophs as microbial cell factories, and discusses future perspectives, aiming to provide a practical guide for growth-coupled models to produce value-added chemicals as part of a sustainable biorefinery.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 9","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Enhanced bioethanol production from sugarcane bagasse: combination of liquid hot water and deep eutectic solvent pretreatment for optimized enzymatic saccharification 提高甘蔗渣的生物乙醇产量：结合液态热水和深层共晶溶剂预处理优化酶法糖化过程

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-06-04 DOI: 10.1007/s11705-024-2438-9

Xiaoling Xian, Biying Li, Shiyong Feng, Jiale Huang, Xinyuan Fu, Ting Wu, Xiaoqing Lin

{"title":"Enhanced bioethanol production from sugarcane bagasse: combination of liquid hot water and deep eutectic solvent pretreatment for optimized enzymatic saccharification","authors":"Xiaoling Xian, Biying Li, Shiyong Feng, Jiale Huang, Xinyuan Fu, Ting Wu, Xiaoqing Lin","doi":"10.1007/s11705-024-2438-9","DOIUrl":"10.1007/s11705-024-2438-9","url":null,"abstract":"<div><p>In the present study, a sustainable pretreatment methodology combining liquid hot water and deep eutectic solvent is proposed for the efficient fractionation of hemicellulose, cellulose, and lignin from sugarcane bagasse, thereby facilitating the comprehensive utilization of both C5 and C6 sugars. The application of this combined pretreatment strategy to sugarcane bagasse led to notable enhancements in enzymatic saccharification and subsequent fermentation. Experiment results demonstrate that liquid hot water-deep eutectic solvent pretreatment yielded 85.05 ± 0.66 g·L<sup>−1</sup> of total fermentable sugar (glucose: 60.96 ± 0.21 g·L<sup>−1</sup>, xylose: 24.09 ± 0.87 g·L<sup>−1</sup>) through enzymatic saccharification of sugarcane bagasse. Furthermore, fermentation of the pretreated sugarcane bagasse hydrolysate yielded 34.33 ± 3.15 g·L<sup>−1</sup> of bioethanol. These findings confirm the effectiveness of liquid hot water-deep eutectic solvent pretreatment in separating lignocellulosic components, thus presenting a sustainable and promising pretreatment method for maximizing the valuable utilization of biomass resources.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141387179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Interfacing biosynthetic CdS with engineered Rhodopseudomonas palustris for efficient visible light-driven CO2–CH4 conversion 将生物合成的 CdS 与工程化的古朴红假单胞菌（Rhodopseudomonas palustris）结合起来，实现可见光驱动的 CO2-CH4 高效转化

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-06-03 DOI: 10.1007/s11705-024-2460-y

Yu Zhang, Yulei Qian, Zhenye Tong, Su Yan, Xiaoyu Yong, Yang-Chun Yong, Jun Zhou

{"title":"Interfacing biosynthetic CdS with engineered Rhodopseudomonas palustris for efficient visible light-driven CO2–CH4 conversion","authors":"Yu Zhang, Yulei Qian, Zhenye Tong, Su Yan, Xiaoyu Yong, Yang-Chun Yong, Jun Zhou","doi":"10.1007/s11705-024-2460-y","DOIUrl":"10.1007/s11705-024-2460-y","url":null,"abstract":"<div><p>Engineered photosynthetic bacterium <i>Rhodo-pseudomonas palustris</i> is excellent at one-step CO<sub>2</sub> biomethanation and can use near-infrared light sources, overcoming the limitations of conventional photosynthetic systems. The current study constructed a biohybrid system that deposited CdS nanoparticles on <i>R. palustris</i>. This biohybrid system broadens the capture of sustainable solar energy, achieving a 155 nmol·mL<sup>−1</sup> biological CH<sub>4</sub> production under full visible light irradiation, 13.4-fold of that by the pure <i>R. palustris</i>. The transcriptome profiles revealed that gene expression related to photosynthetic electron transfer chain, nitrogenase, nanofilaments, and redox stress defense was activated. Accordingly, we attributed the much-enhanced CO<sub>2</sub> biomethanation in the biohybrid system to the remarkable increase in the intracellular reducing power and the stronger rigidity of the cells assisted by photoexcited electrons from CdS nanoparticles. Our discovery offers insight and a promising strategy for improving the current CO<sub>2</sub>–CH<sub>4</sub> biomanufacturing system.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 10","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141388793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Inter-chromosomal insertions into wild-type chromosomes induced by SCRaMbLE SCRaMbLE 诱导的野生型染色体染色体间插入

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-06-03 DOI: 10.1007/s11705-024-2458-5

Sijie Zhou, Junyanrui Li, Xichen Cui, Ying Wang, Ying-Jin Yuan

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Construction of spinel/biochar film/honeycomb monolithic catalyst for photothermal catalytic oxidation of VOCs 构建用于 VOC 光热催化氧化的尖晶石/生物炭薄膜/蜂窝状整体催化剂

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-31 DOI: 10.1007/s11705-024-2453-x

Xikai Lu, Chunyan Zhang, Meng Wu, Wenjie Liu, Bin Xue, Chao Yao, Xiazhang Li

{"title":"Construction of spinel/biochar film/honeycomb monolithic catalyst for photothermal catalytic oxidation of VOCs","authors":"Xikai Lu, Chunyan Zhang, Meng Wu, Wenjie Liu, Bin Xue, Chao Yao, Xiazhang Li","doi":"10.1007/s11705-024-2453-x","DOIUrl":"10.1007/s11705-024-2453-x","url":null,"abstract":"<div><p>Photothermal catalytic oxidation emerges as a promising method for the removal of volatile organic compounds (VOCs). Herein, via sol-gel impregnation method, spinel CuMn<sub>2</sub>O<sub>4</sub> was coated on attapulgite honeycombs with integrating biochar (BC) film as the second carrier, using chestnut shell as complexation agent. Various mass ratios of CuMn<sub>2</sub>O<sub>4</sub> to chestnut shell was modulated to investigate the catalytic toluene degradation performance. Results indicated that the monolithic CuMn<sub>2</sub>O<sub>4</sub>/BC/honeycomb catalyst demonstrated superior photothermal catalytic toluene degradation with a low T<sub>90</sub> (temperature at 90% degradation) of 263 °C when the mass ratio of CuMn<sub>2</sub>O<sub>4</sub> to biomass was 1:4. The addition of BC film substantially increased the honeycomb’s specific surface area and improved the photothermal conversion of spinel, leading to enhanced photothermal catalytic activity. This study presents a cost-effective strategy for eliminating industrial VOCs using clay-biomass based monolithic catalyst.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 9","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141171498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Post-treatment of Ti-MWW zeolite with potassium fluoride for propylene epoxidation 用氟化钾对 Ti-MWW 沸石进行丙烯环氧化后处理

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-30 DOI: 10.1007/s11705-024-2441-1

Xintong Li, Xianchen Gong, Jilong Wang, Shengbo Jin, Hao Xu, Peng Wu

{"title":"Post-treatment of Ti-MWW zeolite with potassium fluoride for propylene epoxidation","authors":"Xintong Li, Xianchen Gong, Jilong Wang, Shengbo Jin, Hao Xu, Peng Wu","doi":"10.1007/s11705-024-2441-1","DOIUrl":"10.1007/s11705-024-2441-1","url":null,"abstract":"<div><p>Epoxidation of propylene to propylene oxide (PO) with hydrogen peroxide (HPPO) is an environmentally friendly and cost-efficient process in which titanosilicates are used as catalysts. Ti-MWW is a potential industrial catalyst for this process, which involves the addition of HPPO to PO. The silanol groups generated during secondary crystallization unavoidably result in ring-opening of PO and inefficient decomposition of HPPO, which diminish the PO selectivity and the lifespan of Ti-MWW. To address this issue, we conducted post-treatment modifications of the structured Bf-Ti-MWW catalyst with potassium fluoride aqueous solutions. By quenching the silanol groups with potassium fluoride and implanting electron-withdrawing fluoride groups into the Ti-MWW framework, both the catalytic activity and HPPO utilization efficiency were increased. Moreover, the ring opening reaction of PO was prohibited. In a continuous fixed-bed liquid-phase propylene epoxidation reaction, the KF-treated structured Ti-MWW catalyst displayed an exceptionally long lifespan of 2700 h, with a PO yield of 590 g·kg<sup>−1</sup>·h<sup>−1</sup>.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141171439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enzymatic C1 reduction using hydrogen in cofactor regeneration 利用氢在辅助因子再生中进行酶促 C1 还原

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-30 DOI: 10.1007/s11705-024-2431-3

Ruishuang Sun, Chenqi Cao, Qingyun Wang, Hui Cao, Ulrich Schwaneberg, Yu Ji, Luo Liu, Haijun Xu

{"title":"Enzymatic C1 reduction using hydrogen in cofactor regeneration","authors":"Ruishuang Sun, Chenqi Cao, Qingyun Wang, Hui Cao, Ulrich Schwaneberg, Yu Ji, Luo Liu, Haijun Xu","doi":"10.1007/s11705-024-2431-3","DOIUrl":"10.1007/s11705-024-2431-3","url":null,"abstract":"<div><p>Carbon dioxide fixation presents a potential solution for mitigating the greenhouse gas issue. During carbon dioxide fixation, C1 compound reduction requires a high energy supply. Thermodynamic calculations suggest that the energy source for cofactor regeneration plays a vital role in the effective enzymatic C1 reduction. Hydrogenase utilizes renewable hydrogen to achieve the regeneration and supply cofactor nicotinamide adenine dinucleotide (NADH), providing a driving force for the reduction reaction to reduce the thermodynamic barrier of the reaction cascade, and making the forward reduction pathway thermodynamically feasible. Based on the regeneration of cofactor NADH by hydrogenase, and coupled with formaldehyde dehydrogenase and formolase, a favorable thermodynamic mode of the C1 reduction pathway for reducing formate to dihydroxyacetone (DHA) was designed and constructed. This resulted in accumulation of 373.19 µmol·L<sup>−1</sup> DHA after 2 h, and conversion reaching 7.47%. These results indicate that enzymatic utilization of hydrogen as the electron donor to regenerate NADH is of great significance to the sustainable and green development of bio-manufacturing because of its high economic efficiency, no by-products, and environment-friendly operation. Moreover, formolase efficiently and selectively fixed the intermediate formaldehyde (FALD) to DHA, thermodynamically pulled formate to efficiently reduce to DHA, and finally stored the low-grade renewable energy into chemical energy with high energy density.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 7","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141171359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ultralong hydroxyapatite-based forward osmosis membrane for freshwater generation 用于淡水发电的超长羟基磷灰石正渗透膜

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-24 DOI: 10.1007/s11705-024-2450-0

Mohamed Gamal Gomaa, Hamdy Maamoun Abdel-Ghafar, Francesco Galiano, Francesca Russo, Alberto Figoli, El-Sayed Ali Abdel-Aal, Abdel-Hakim Taha Kandil, Bahaa Ahmed Salah

{"title":"Ultralong hydroxyapatite-based forward osmosis membrane for freshwater generation","authors":"Mohamed Gamal Gomaa, Hamdy Maamoun Abdel-Ghafar, Francesco Galiano, Francesca Russo, Alberto Figoli, El-Sayed Ali Abdel-Aal, Abdel-Hakim Taha Kandil, Bahaa Ahmed Salah","doi":"10.1007/s11705-024-2450-0","DOIUrl":"10.1007/s11705-024-2450-0","url":null,"abstract":"<div><p>Increasing global water shortages are accelerating the pace of membrane manufacturing, which generates many environmentally harmful solvents. Such challenges need a radical rethink of developing innovative membranes that can address freshwater production without generating environmentally harmful solvents. This work utilized the synthesized ultra-long hydroxyapatite (UHA) by the solvothermal method using the green solvent oleic acid in preparing UHA-based forward osmosis membranes. The membranes were developed using different loading ratios of graphene oxide (GO) by vacuum-assisted filtration technique. The prepared GO/UHA membranes were identified using X-ray diffraction, scanning electron microscope, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy. Water contact angle and pore size distribution were determined for the obtained GO/UHA membranes. The obtained hierarchical porous structure in the prepared membranes with interconnected channels results in a stable water flux with reverse salt flux. The best water flux rate of 42 ± 2 L·m<sup>−2</sup>·h<sup>−1</sup> was achieved using the 50 mg GO/UHA membrane, which is 3.3 times higher than the pristine membrane, and a reverse salt flux of 67 g·m<sup>−2</sup>·h<sup>−1</sup>. The obtained results showed a promising capability of a new generation of sustainable inorganic-based membranes that can be utilized in freshwater generation by energy-efficient techniques such as forward osmosis.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 9","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11705-024-2450-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141171358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Continuous flow pyrolysis of virgin and waste polyolefins: a comparative study, process optimization and product characterization 原生聚烯烃和废弃聚烯烃的连续流热解：比较研究、工艺优化和产品特性分析

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-20 DOI: 10.1007/s11705-024-2429-x

Ecrin Ekici, Güray Yildiz, Magdalena Joka Yildiz, Monika Kalinowska, Erol Şeker, Jiawei Wang

{"title":"Continuous flow pyrolysis of virgin and waste polyolefins: a comparative study, process optimization and product characterization","authors":"Ecrin Ekici, Güray Yildiz, Magdalena Joka Yildiz, Monika Kalinowska, Erol Şeker, Jiawei Wang","doi":"10.1007/s11705-024-2429-x","DOIUrl":"10.1007/s11705-024-2429-x","url":null,"abstract":"<div><p>Under optimal process conditions, pyrolysis of polyolefins can yield ca. 90 wt % of liquid product, i.e., combination of light oil fraction and heavier wax. In this work, the experimental findings reported in a selected group of publications concerning the non-catalytic pyrolysis of polyolefins were collected, reviewed, and compared with the ones obtained in a continuously operated bench-scale pyrolysis reactor. Optimized process parameters were used for the pyrolysis of waste and virgin counterparts of high-density polyethylene, low-density polyethylene, polypropylene and a defined mixture of those (i.e., 25:25:50 wt %, respectively). To mitigate temperature drops and enhance heat transfer, an increased feed intake is employed to create a hot melt plastic pool. With 1.5 g·min<sup>−1</sup> feed intake, 1.1 L·min<sup>−1</sup> nitrogen flow rate, and a moderate pyrolysis temperature of 450 °C, the formation of light hydrocarbons was favored, while wax formation was limited for polypropylene-rich mixtures. Pyrolysis of virgin plastics yielded more liquid (maximum 73.3 wt %) than that of waste plastics (maximum 66 wt %). Blending polyethylenes with polypropylene favored the production of liquids and increased the formation of gasoline-range hydrocarbons. Gas products were mainly composed of C<sub>3</sub> hydrocarbons, and no hydrogen production was detected due to moderate pyrolysis temperature.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 6","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Petroleum pitch derived hard carbon via NaCl-template as anode materials with high rate performance for sodium ion battery 通过氯化钠模板提取的石油沥青硬碳作为钠离子电池的高倍率负极材料

IF 4.3 3区工程技术

Frontiers of Chemical Science and Engineering Pub Date : 2024-05-20 DOI: 10.1007/s11705-024-2430-4

Baoyu Wu, Hao Sun, Xiaoxue Li, Yinyi Gao, Tianzeng Bao, Hongbin Wu, Kai Zhu, Dianxue Cao

{"title":"Petroleum pitch derived hard carbon via NaCl-template as anode materials with high rate performance for sodium ion battery","authors":"Baoyu Wu, Hao Sun, Xiaoxue Li, Yinyi Gao, Tianzeng Bao, Hongbin Wu, Kai Zhu, Dianxue Cao","doi":"10.1007/s11705-024-2430-4","DOIUrl":"10.1007/s11705-024-2430-4","url":null,"abstract":"<div><p>Sodium-ion batteries (SIBs) have garnered significant interest in energy storage due to their similar working mechanism to lithium ion batteries and abundant reserves of sodium resource. Exploring facile synthesis of a carbon-based anode materials with capable electrochemical performance is key to promoting the practical application of SIBs. In this work, a combination of petroleum pitch and recyclable sodium chloride is selected as the carbon source and template to obtain hard carbon (HC) anode for SIBs. Carbonization times and temperatures are optimized by assessing the sodium ion storage behavior of different HC materials. The optimized HC exhibits a remarkable capacity of over 430 mA·hg<sup>−1</sup> after undergoing full activation through 500 cycles at a density of current of 0.1 A·g<sup>−1</sup>. Furthermore, it demonstrates an initial discharge capacity of 276 mAh·g<sup>−1</sup> at a density of current of 0.5 A·g<sup>−1</sup>. Meanwhile, the optimized HC shows a good capacity retention (170 mAh·g<sup>−1</sup> after 750 cycles) and a remarkable rate ability (166 mAh·g<sup>−1</sup> at 2 A·g<sup>−1</sup>). The enhanced capacity is attributed to the suitable degree of graphitization and surface area, which improve the sodium ion transport and storage.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 7","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141511888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0