柔性超级电容器用可拉伸导电木质素水凝胶电解质

IF 4.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
He-Fei Wan, Xin Zhao, Qian Guo, Ce Gao, Run-Cang Sun
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引用次数: 0

摘要

虽然木质素是第二丰富的森林生物质聚合物,但由于其不溶性和不灵活性,在水凝胶电解质中一直被忽视。本研究以天冬氨酸改性木质素和海藻酸钠为原料制备了双交联水凝胶,其力学性能得到显著改善。该水凝胶的应变为3008%,抗拉强度为0.03 MPa,表现出优异的力学性能。此外,由于水凝胶中大量亲水性基团的存在,获得了高离子电导率(11.7 mS·cm−1)。水凝胶组装的超级电容器表现出令人印象深刻的比电容39.46 F·g−1。值得注意的是,该超级电容器具有0-1.5 V的宽电位窗口,在499.9 W·kg−1的功率密度下,最大能量密度达到5.48 Wh·kg−1。在10000次充放电循环后,电容保持率保持在115%。最后,在循环过程中库仑效率接近100%。当弯曲角达到90°时,比电容保持率仍然高达94%。这些结果表明,超级电容器可以在极端恶劣的条件下保持正常的电化学性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Stretchable and conductive lignin hydrogel electrolyte for flexible supercapacitor

Although lignin is the second most abundant forest biomass polymer, it has been largely neglected in hydrogel electrolytes due to its insolubility and inflexibility. In this study, a double-crosslinked hydrogel was prepared using aspartic acid-modified lignin and sodium alginate, significantly improving the mechanical properties. The hydrogel exhibited an exceptional strain of 3008% and a tensile strength of 0.03 MPa, demonstrating its remarkable mechanical properties. In addition, high ionic conductivity (11.7 mS·cm−1) was obtained due to the abundant presence of hydrophilic groups in the hydrogel. The hydrogel-assembled supercapacitor manifested an impressive specific capacitance of 39.46 F·g−1. Notably, the supercapacitor showed a wide potential window of 0–1.5 V and achieved a maximum energy density of 5.48 Wh·kg−1 at the power density of 499.9 W·kg−1. The capacitance retention remained at 115% after 10000 charge-discharge cycles. Finally, the coulombic efficiency was almost 100% during the cycles. Upon reaching a bending angle of 90°, the specific capacitance retention remained impressively high at 94%. These results suggest that the supercapacitor cans maintain normal electrochemical performance under extremely harsh conditions.

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来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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