Weizuo Wang, Bingru Lu, Jinwen Shi, Qiuyang Zhao, Hui Jin
{"title":"Comparison of CO2 with H2O as the transport medium in a biomass supercritical water gasification system","authors":"Weizuo Wang, Bingru Lu, Jinwen Shi, Qiuyang Zhao, Hui Jin","doi":"10.1007/s11705-024-2472-7","DOIUrl":"10.1007/s11705-024-2472-7","url":null,"abstract":"<div><p>Supercritical water gasification is a clean technology for biomass conversion and utilization. In supercritical water gasification systems, H<sub>2</sub>O is often used as the transport medium. Decreases in the reaction temperature at the gasification area and in the heating rate of biomass may limit the gasification rate and efficiency. In this paper, CO<sub>2</sub> is used as the transport medium due to its relatively low critical point and specific heat capacity. Moreover, a corn stalk gasification system with different transport media is established in this paper, and the influences of various operating parameters, such as temperature, pressure and feedstock concentration, are investigated. The results show that the gas yield in the CO<sub>2</sub>-transport system decreases by no more than 5 wt %. In addition, thermodynamic analysis reveals that a system with CO<sub>2</sub> as transport medium consumes approximately 25% less electricity than a system with H<sub>2</sub>O as the transport medium. In addition, the reaction heat absorption decreases. The results show the superiority of CO<sub>2</sub> to H<sub>2</sub>O as a transport medium.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141921214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Bi, Qiong Wang, Jingzhang Liu, Fuxiang Cui, Maoyong Song
{"title":"Efficient removal and upcycling of pollutants in wastewater: a strategy for reconciling environmental pollution and resource depletion crisis","authors":"Lei Bi, Qiong Wang, Jingzhang Liu, Fuxiang Cui, Maoyong Song","doi":"10.1007/s11705-024-2486-1","DOIUrl":"10.1007/s11705-024-2486-1","url":null,"abstract":"<div><p>Due to the relentless exploitation of nonrenewable resources, humanity is faced with a resource depletion crisis in the coming decades and serious environmental issues. Achieving efficient removal and upcycling of pollutants (ERUP) may become a potential strategy to address these issues. Wastewater, characterized by its large production volume and fluidity, can easily cause widespread environmental pollution through natural water networks. Due to solubility constraints, pollutants in wastewater typically exhibit low concentrations and complex compositions, thereby impeding effective recovery. Therefore, achieving ERUP in wastewater is both highly significant and extremely challenging. Unlike conventional wastewater treatment strategies that are focused on removing pollutants, ERUP strategies can not only realize the efficient removal of pollutants from water but also convert pollutants into valuable and functional products. Herein, we enumerated the latest research progress on ERUP in wastewater and highlighted studies that demonstrate the simultaneous achievement of pollutant removal and the direct conversion of these contaminants into high-efficiency catalysts, hydrogen energy, electrical energy, and other high-value chemicals. Finally, we identified the problems and challenges in the development of ERUP in wastewater and outlined potential research directions for future studies.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142177498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shuangshuang Cao, Houjun Zhang, Haoyang Liu, Zhiyuan Lyu, Xiangyuan Li, Bin Zhang, You Han
{"title":"Optimization of kinetic mechanism for hydrogen combustion based on machine learning","authors":"Shuangshuang Cao, Houjun Zhang, Haoyang Liu, Zhiyuan Lyu, Xiangyuan Li, Bin Zhang, You Han","doi":"10.1007/s11705-024-2487-0","DOIUrl":"10.1007/s11705-024-2487-0","url":null,"abstract":"<div><p>The reduced mechanism based on the minimized reaction network method can effectively solve the rigidity problem in the numerical calculation of turbulent internal combustion engine. The optimization of dynamic parameters of the reduced mechanism is the key to reproduce the experimental data. In this work, the experimental data of ignition delay times and laminar flame speeds were taken as the optimization objectives based on the machine-learning model constructed by radial basis function interpolation method, and pre-exponential factors and activation energies of H<sub>2</sub> combustion mechanism were optimized. Compared with the origin mechanism, the performance of the optimized mechanism was significantly improved. The error of ignition delay times and laminar flame speeds was reduced by 24.3% and 26.8%, respectively, with 25% decrease in total mean error. The optimized mechanism was used to predict the ignition delay times, laminar flame speeds and species concentrations of jet stirred reactor, and the predicted results were in good agreement with experimental results. In addition, the differences of the key reactions of the combustion mechanism under specific working conditions were studied by sensitivity analysis. Therefore, the machine-learning model is a tool with broad application prospects to optimize various combustion mechanisms in a wide range of operating conditions.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142177522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kinetics of hydroxylation of phenol with SiC foam supported TS-1 structured catalyst","authors":"Yanzhao Sun, Zhitao Lv, Siyu Zhang, Guodong Wen, Yilai Jiao","doi":"10.1007/s11705-024-2481-6","DOIUrl":"10.1007/s11705-024-2481-6","url":null,"abstract":"<div><p>In light of the challenges associated with catalyst separation and recovery, as well as the low production efficiency resulting from intermittent operation for titanium silicalite-1 (TS-1) catalyzed phenol hydroxylation to dihydroxybenzene in the slurry bed, researchers keep on exploring the use of a continuous fixed bed to replace the slurry bed process in recent years. This study focuses on preparing a TS-1 coated structured catalyst on SiC foam, which exhibits significant process intensification in performance. We investigated the kinetics of this structured catalyst and compared it with those of extruded TS-1 catalyst; the dynamic equations of the two catalysts were obtained. It was observed that both catalysts followed E-R adsorption mechanism model, with an effective internal diffusion factor ratio between structured and extruded TS-1 of approximately 7.71. It was confirmed that the foamed SiC-based structured TS-1 catalyst exhibited significant improvements in phenol hydroxylation in fixed-bed reactor due to its well-developed pore structure, good thermal conductivity, excellent internal mass transfer performance, and short reactant diffusion distance, leading to higher utilization efficiency of active components. This finding also provides a foundation for designing and developing phenol hydroxylation processes in fixed-bed using structured catalysts through computational fluid dynamics calculations.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142177526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Interaction and characteristics of furfural residues and polyvinyl chloride in fast co-pyrolysis","authors":"Yue Zhang, Moshan Li, Erfeng Hu, Rui Qu, Shuai Li, Qingang Xiong","doi":"10.1007/s11705-024-2493-2","DOIUrl":"10.1007/s11705-024-2493-2","url":null,"abstract":"<div><p>This study investigated the interaction between the furfural residue and polyvinyl chloride co-pyrolysis using an infrared heating method. Various analytical techniques including production distribution analysis, thermal behavior, pyrolysis kinetic, simulated distillation and gas chromatography-mass spectrography (GCMS), and X-ray photoelectron spectroscopy were utilized to elucidate the pyrolysis characterization and reaction mechanism during the co-pyrolysis. Initially, the yield of co-pyrolysis oil increased from 35.12% at 5 °C·s<sup>−1</sup> to 37.70% at 10 °C·s<sup>−1</sup>, but then decreased to 32.07% at 20 °C·s<sup>−1</sup>. Kinetic and thermodynamic parameters suggested non-spontaneous and endothermic behaviors. GCMS analysis revealed that aromatic hydrocarbons, especially mono- and bi-cyclic ones, are the predominant compounds in the oil due to the presence of H radicals in polyvinyl chloride, suggesting an enhancement in oil quality. Meanwhile, the fixed chlorine content increased to 65.11% after co-pyrolysis due to the interaction between inorganic salts in furfural residues and chlorine from polyvinyl chloride.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 12","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Huimin Gao, Jinpeng Zhang, Fangyuan Zhang, Jieying Jing, Wen-Ying Li
{"title":"Enhanced formic acid production for CO2 photocatalytic reduction over Pd/H-TiO2 catalyst","authors":"Huimin Gao, Jinpeng Zhang, Fangyuan Zhang, Jieying Jing, Wen-Ying Li","doi":"10.1007/s11705-024-2485-2","DOIUrl":"10.1007/s11705-024-2485-2","url":null,"abstract":"<div><p>The photocatalytic reduction of CO<sub>2</sub> into formic acid is a feasible approach to alleviate the effects of global climate change and achieve chemical energy storage. It is important to design highly active photocatalysts to improve the selectivity and yield of formic acid. In this study, TiO<sub>2</sub>-based catalysts were prepared and loaded with Pd nanoparticles via an impregnation process. The Pd/H-TiO<sub>2</sub> catalyst demonstrated superior CO<sub>2</sub> reduction activity and a high formic acid production rate of 14.14 mmol<sub>cat</sub>·g<sup>−1</sup>·h<sup>−1</sup>. The excellent catalytic performance observed in the presence of a Pd/H-TiO<sub>2</sub> catalyst is ascribed to the synergy between O<sub>v</sub> and Pd. The presence of O<sub>v</sub> led to increase in CO<sub>2</sub> adsorption while Pd loading enhanced the photogenerated electron-hole pair separation. Electron transfer from H-TiO<sub>2</sub> to Pd also contributed to CO<sub>2</sub> activation.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fan Zhang, Yanzhu Guo, Xianhong Wu, Ce Gao, Qingda An, Zhongjian Tian, Runcang Sun
{"title":"Preparation of a novel lactose-lignin hydrogel catalyst with self-reduction capacity for nitrogenous wastewater treatment","authors":"Fan Zhang, Yanzhu Guo, Xianhong Wu, Ce Gao, Qingda An, Zhongjian Tian, Runcang Sun","doi":"10.1007/s11705-024-2451-z","DOIUrl":"10.1007/s11705-024-2451-z","url":null,"abstract":"<div><p>A novel carboxylated lactose/sodium lignosulfonate/polyacrylic acid hydrogel composites with self-reduction capacity was successfully synthesized by self-assembly method. The hydrogel with well-developed porous structure provided abundant anchoring points and reduction capacity for transforming Ag<sup>+</sup> into silver nanoparticles. Silver nanoparticles dispersed among the network of hydrogel and the composites exhibited catalytic capacity. The catalytic performance was evaluated via degradation of <i>p</i>-nitrophenol, rhodamine B, methyl orange and methylene blue, which were catalyzed with corresponding reaction rate constants of 0.04338, 0.07499, 0.04891, and 0.00628 s<sup>–1</sup>, respectively. In addition, the catalyst exhibited stable performance under fixed-bed condition and the corresponding conversion rate still maintained more than 80% after 540 min. Moreover, the catalytic performance still maintained effective in tap water and simulated seawater. The catalytic efficiency still remained 99.7% with no significant decrease after 8 cycles.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 9","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yi Cheng, Qiong Pan, Jie Li, Nan Zhang, Yang Yang, Jiawei Wang, Ningbo Gao
{"title":"Machine learning facilitated the modeling of plastics hydrothermal pretreatment toward constructing an on-ship marine litter-to-methanol plant","authors":"Yi Cheng, Qiong Pan, Jie Li, Nan Zhang, Yang Yang, Jiawei Wang, Ningbo Gao","doi":"10.1007/s11705-024-2468-3","DOIUrl":"10.1007/s11705-024-2468-3","url":null,"abstract":"<div><p>An onboard facility shows promise in efficiently converting floating plastics into valuable products, such as methanol, negating the need for regional transport and land-based treatment. Gasification presents an effective means of processing plastics, requiring their transformation into gasification-compatible feedstock, such as hydrochar. This study explores hydrochar composition modeling, utilizing advanced algorithms and rigorous analyses to unravel the intricacies of elemental composition ratios, identify influential factors, and optimize hydrochar production processes. The investigation begins with decision tree modeling, which successfully captures relationships but encounters overfitting challenges. Nevertheless, the decision tree vote analysis, particularly for the H/C ratio, yielding an impressive <i>R</i><sup>2</sup> of 0.9376. Moreover, the research delves into the economic feasibility of the marine plastics-to-methanol process. Varying payback periods, driven by fluctuating methanol prices observed over a decade (ranging from 3.3 to 7 yr for hydrochar production plants), are revealed. Onboard factories emerge as resilient solutions, capitalizing on marine natural gas resources while striving for near-net-zero emissions. This comprehensive study advances our understanding of hydrochar composition and offers insights into the economic potential of environmentally sustainable marine plastics-to-methanol processes.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 10","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11705-024-2468-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141772932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Prince Joby, Yesaiyan Manojkumar, Antony Rajendran, Rajadurai Vijay Solomon
{"title":"Computational catalysis on the conversion of CO2 to methane—an update","authors":"Prince Joby, Yesaiyan Manojkumar, Antony Rajendran, Rajadurai Vijay Solomon","doi":"10.1007/s11705-024-2484-3","DOIUrl":"10.1007/s11705-024-2484-3","url":null,"abstract":"<div><p>The reliance on fossil fuels intensifies CO<sub>2</sub> emissions, worsening political and environmental challenges. CO<sub>2</sub> capture and conversion present a promising solution, influenced by industrialization and urbanization. In recent times, catalytic conversion of CO<sub>2</sub> into fuels and chemical precursors, particularly methane, are gaining traction for establishing a sustainable, carbon-neutral economy due to methane’s advantages in renewable energy applications. Though homogeneous and heterogeneous catalysts are available for the conversion of CO<sub>2</sub> to methane, the efficiency is found to be higher in heterogeneous catalysts. Therefore, this review focuses only on the heterogeneous catalysts. In this context, the efficient heterogeneous catalysts with optimum utility are yet to be obtained. Therefore, the quest for suitable catalyst for the catalytic conversion of CO<sub>2</sub> to CH<sub>4</sub> is still continuing and designing efficient catalysts requires assessing their synthetic feasibility, often achieved through computational methods like density functional theory simulations, providing insights into reaction mechanisms, rate-limiting steps, catalytic cycle, activation of C=O bonds and enhancing understanding while lowering costs. In this context, this review examines the conversion of CO<sub>2</sub> to CH<sub>4</sub> using seven distinct types of catalysts, including single and double atom catalysts, metal organic frameworks, metalloporphyrins, graphdiyne and graphitic carbon nitrite and alloys with some case studies. The main focus of this review is to offer a detailed and extensive examination of diverse catalyst design approaches and their utilization in CH<sub>4</sub> production, with a specific emphasis on computational aspects. It explores the array of design methodologies used to identify reaction pathways and investigates the critical role of computational tools in their refinement and enhancement. We believe this review will help budding researchers to explore the possibilities of designing catalysts for the CO<sub>2</sub> to CH<sub>4</sub> conversion from computational framework.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142177501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hassan Alhassawi, Edidiong Asuquo, Shima Zainal, Yuxin Zhang, Abdullah Alhelali, Zhipeng Qie, Christopher M. A. Parlett, Carmine D’Agostino, Xiaolei Fan, Arthur A. Garforth
{"title":"Formulation of zeolite-mesoporous silica composite catalysts for light olefin production from catalytic cracking","authors":"Hassan Alhassawi, Edidiong Asuquo, Shima Zainal, Yuxin Zhang, Abdullah Alhelali, Zhipeng Qie, Christopher M. A. Parlett, Carmine D’Agostino, Xiaolei Fan, Arthur A. Garforth","doi":"10.1007/s11705-024-2480-7","DOIUrl":"10.1007/s11705-024-2480-7","url":null,"abstract":"<div><p>Framework materials such as zeolites and mesoporous silicas are commonly used for many applications, especially catalysis and separation. Here zeolite-mesoporous silica composite catalysts (employing zeolite Y, ZSM-5, KIT-6, SBA-15 and MCM-41 mesoporous silica) were prepared (with different weight percent of zeolite Y and ZSM-5) and assessed for catalytic cracking (using <i>n</i>-heptane, as the model compound at 550 °C) with the aim to improve the selectivity/yield of light olefins of ethylene and propylene from <i>n</i>-heptane. Physicochemical properties of the parent zeolites and the prepared composites were characterized comprehensively using several techniques including X-ray diffraction, nitrogen physisorption, scanning electron microscopy, fourier transform infrared spectroscopy, pulsed-field gradient nuclear magnetic resonance and thermogravimetric analysis. Catalytic cracking results showed that the ZY/ZSM-5/KIT-6 composite (20:20:60 wt %) achieved a high <i>n</i>-heptane conversion of 85% with approximately 6% selectivity to ethylene/propylene. In contrast, the ZY/ZSM-5/SBA-15 composite achieved a higher conversion of 95% and an ethylene/propylene ratio of 8%, indicating a more efficient process in terms of both conversion and selectivity. Magnetic resonance relaxation analysis of the ZY/ZSM-5/KIT-6 (20:20:60) catalyst confirmed a micro-mesoporous environment that influences <i>n</i>-heptane diffusion and mass transfer. As zeolite Y and ZSM-5 have micropores, <i>n</i>-heptane can move and undergo hydrogen transfer reactions, whereas KIT-6 has mesopores that facilitate <i>n</i>-heptane’s accessibility to the active sites of zeolite Y and ZSM-5.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 11","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11705-024-2480-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142177521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}