Trends in Environmental Analytical Chemistry最新文献

{"title":"Green analytical procedure index assessment for total petroleum hydrocarbons determination methods in soil and sediments. A review","authors":"Bauyrzhan Abdykarimov ,&nbsp;Mereke Alimzhanova ,&nbsp;Rebeca López-Serna ,&nbsp;Yerkanat Syrgabek","doi":"10.1016/j.teac.2025.e00262","DOIUrl":"10.1016/j.teac.2025.e00262","url":null,"abstract":"<div><div>Accurate determination of total petroleum hydrocarbons in soil and sediment is crucial for assessing pollution levels and guiding remediation efforts. This review looks at various analytical techniques for total petroleum hydrocarbons determination, such as gas chromatography with different detection methods, infrared based and fluorescence spectroscopic methods, in addition to gravimetric analysis. Green Analytical Procedure Index was used to investigate the environmental impact of the techniques along with different coupled extraction methods. Green Analytical Procedure Index individually evaluates the sample preparation, the type of instrumental technique, the reagents and solvents employed, the health and safety hazard, occupational hazard, and waste of each proposed analytical tool. This literature review showed that Soxhlet extraction, although ranked lower in greenness, is still one of the most widely used techniques for total petroleum hydrocarbons determination due to its completeness. Techniques like gas chromatography - mass spectrometer coupled with solid-phase microextraction, and infrared based tools with direct application are greener because the use of solvent is negligible, and the preparation of the sample is minimal. At the same time infrared based techniques showed lower prediction accuracy compared to gas chromatography - mass spectrometer coupled with solid-phase microextraction. This review highlights the critical need to balance analytical performance with environmental sustainability, offering insights into future developments in forensic and environmental monitoring. It shows pathways toward increasing the greenness of widely used techniques and future use in forensic investigations and environmental monitoring. Overall, this review is among the first to systematically assess total petroleum hydrocarbons analytical methods using Green Analytical Procedure Index, bridging the gap between analytical efficiency and green chemistry principles.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"46 ","pages":"Article e00262"},"PeriodicalIF":11.1,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Redefining nanobiosensors in rapid detection of viral infections: Where are we now?","authors":"Muhammad Asif ,&nbsp;Jari S. Algethami ,&nbsp;Mohsen A.M. Alhamami ,&nbsp;Peng Lie ,&nbsp;Shunag Shaomin ,&nbsp;Ayesha Aziz","doi":"10.1016/j.teac.2025.e00263","DOIUrl":"10.1016/j.teac.2025.e00263","url":null,"abstract":"<div><div>The development of nanobiosensors has conquered immense attention of the scientific community owing to the recent events of outbreaks. Highly targeted and responsive detection of viruses plays a crucial role in accurate and timely diagnosis of viral infections. Regardless of the numerous efforts to detect viruses, the diagnosis of viral diseases yet relay on costly and time-consuming assays. Currently, PCR based assays are frequently used methods for the detection of viral illnesses further allowing the precise diagnosis of various diseases but these techniques still suffer several limitations including long time to get results and the need for experts to run. As alternative approaches, low-cost nanobiosensors are rapid and trustworthy diagnostic systems for point-of-care diagnosis because of their high sensitivity and selectivity. Biosensing methodologies ensure sensitive and specific detection, recognition, and quantification of pathogens. Viruses can have severe economic repercussions due to its high transmissibility and rapid proliferation, which can have a significant impact on both individual and collective health. Herein, after introduction, we have summarized key contributions regarding the development in nanobiosensors for detection of viral infections induced by respiratory viruses including MERS-CoV, SARS-CoV-2 and hepatitis viruses, zika virus, dengue virus, and human papilloma virus. Moreover, vitality of rapid and emerging biosensing technologies including electrochemical, optical, and piezoelectric biosensors has been discussed in details. This review underscores the recent advances in assembling the efficient sensing devices with their figures of merits. Finally, we have outlined the benefits and drawbacks of diagnostic methods, as well as potential future research avenues.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"46 ","pages":"Article e00263"},"PeriodicalIF":11.1,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent innovations in explosive trace detection: Advances and emerging technologies","authors":"Al-Fakih Ali Mohammed ,&nbsp;Karim Youssef Nabat ,&nbsp;Ting Jiang ,&nbsp;Lingyan Liu","doi":"10.1016/j.teac.2025.e00261","DOIUrl":"10.1016/j.teac.2025.e00261","url":null,"abstract":"<div><div>Detecting trace explosives is crucial for public safety in forensics, security, and environmental monitoring. This review analyzes recent advancements in four key explosive detection technologies: Ion Mobility Spectrometry (IMS), Gas Chromatography-mass spectrometry (GC-MS), Ambient Ionization Mass Spectrometry (AIMS), and Surface-Enhanced Raman Spectroscopy (SERS). IMS excels in detecting low-volatile explosives in complex environments, while GC-MS offers enhanced sensitivity and resolution for trace analysis. AIMS is noted for its rapid, non-invasive, high-throughput capabilities, ideal for real-time detection. Recent improvements in SERS have increased its sensitivity across a broader range of explosive compounds. Despite these advances, challenges such as low recovery rates, cross-sensitivity, and environmental interference remain. The paper highlights the need for continued innovation to improve sensitivity, selectivity, and accuracy, addressing evolving security, forensic, and environmental threats.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"46 ","pages":"Article e00261"},"PeriodicalIF":11.1,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessing emerging contaminants in soils using soil enzyme-based methods: A critical review","authors":"Ferdinand Ndikuryayo,&nbsp;Xue-Yan Gong,&nbsp;Xiuhai Gan,&nbsp;Wen-Chao Yang","doi":"10.1016/j.teac.2025.e00260","DOIUrl":"10.1016/j.teac.2025.e00260","url":null,"abstract":"<div><div>Emerging contaminants (ECs) in soils pose significant threat to human health and the environment, prompting an urgent need for innovative assessment methods. Soil enzymes (SEs) can serve as sensitive indicators of soil quality and pollution due to their responsiveness to various contaminants. Analytical methods have highlighted the crucial role of SEs in assessing soil contamination for plant protection. This review aims to critically evaluate current SE-based methods used to assess ECs in soils. By examining the strengths and weaknesses of these approaches in terms of complexity and analytical applicability, it highlights the most promising methods and SE-driven tools for EC assessment in soils. To enhance SE-proven methods, several innovative strategies have been suggested, ranging from sampling to analysis. These strategies include chemically modifying the products of SE-catalyzed reactions to enable the use of reliable analytical techniques such as fluorimetry and spectrophotometry, as well as utilizing biotechnology to enhance the activity of SEs in both EC assessment and <em>in situ</em> bioremediation. Finally, recommendations addressing existing gaps are presented, outlining future research directions for assessing ECs in soils and remediating EC-contaminated soils for food security.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"46 ","pages":"Article e00260"},"PeriodicalIF":11.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent trends in use of plant-derived carbon dot-based fluorescent probes for heavy metal ion detection and their biological applications","authors":"Geetha Venkatesan ,&nbsp;Govindasamy Sathiyan","doi":"10.1016/j.teac.2025.e00259","DOIUrl":"10.1016/j.teac.2025.e00259","url":null,"abstract":"<div><div>Plant-derived carbon dots (CDs) have drawn a lot of interest as superior nanomaterials because of their sustainable nature, biocompatibility, and environmentally friendly synthesis, which sets them apart from other CDs made from non-renewable resources. The synthesis of CDs from natural sources such as fruits, leaves, bark, stem, flower, seed and biowaste by hydrothermal, pyrolysis, and microwave-assisted method have been investigated to modify the size and features of CDs. The plant-derived CDs exhibit greater sensitivity and selectivity, and their high photoluminescent properties makes it possible to detect physiological and ecological significant metal ions like iron (Fe³⁺), copper (Cu²⁺), lead (Pb²⁺), and mercury (Hg²⁺). This study focuses mainly on crucial elements such as absorption, emission, sensitivity, selectivity, and limits of detection of metal ions, a thorough examination of their sensing characteristics is provided. This review article comprehensively summarizes plant-based CDs with different synthesis methods, characterization techniques, metal ion sensing and its mechanism, stability and biological imaging of CDs. Additionally, we discussed the plant derived CDs for the detection of pesticides and drugs. These CDs also find extensive applications in environmental remediation by offering a sustainable alternative for detecting harmful pollutants. Beyond these sensing, their biological uses of plant-derived CDs, such as bioimaging, antioxidant activity, and therapeutic potential, are finally addressed. This review emphasizes the bright future of plant-derived CDs in biomedicine and sustainable nanotechnology, with a focus on their biological applications and improved sensing capabilities in research development.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"46 ","pages":"Article e00259"},"PeriodicalIF":11.1,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143463733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chitosan-based sorbents for the micro-solid-phase extraction of pesticides","authors":"Ahmad Reza Bagheri,&nbsp;Ardeshir Shokrollahi","doi":"10.1016/j.teac.2025.e00258","DOIUrl":"10.1016/j.teac.2025.e00258","url":null,"abstract":"<div><div>The widespread use of pesticides and their hazardous impacts on humans and animals have made their detection and determination a critical issue. However, due to the low concentration of pesticides and the complexity of the entire sample, it is essential to use sample preparation approaches before determining pesticides. Among sample preparation approaches, micro-solid-phase extraction (µ-SPE), as a miniaturized extraction technique, has garnered much attention. This technique decreases the use of materials, reagents, and solvents. Additionally, µ-SPE applies micro- and/or nano-based sorbents and employs miniaturized extraction gadgets and devices. The attributes of µ-SPE, plus the concepts of green analytical chemistry, have encouraged analytical scientists to introduce and use green and environmentally friendly materials in µ-SPE techniques. Chitosan (CS) is a biocompatible, low- or negligible-toxic, environmentally friendly, and cost-effective material. Another valuable property of CS is its capability for modification and combination with different compounds. CS-based materials not only address the problems of traditional sorbents but also introduce new ones with excellent features such as high stability, high adsorption capacity, etc. These factors motivated us to assess the recent development in using CS-based sorbents for the µ-SPE of pesticides from 2016 to 2025. In this article, the properties of CS are illustrated. Different CS composites and the possible mechanisms for extracting pesticides are reviewed. Finally, the current trends and prospects related to using CS-based sorbents in the µ-SPE of pesticides are summarized. This review article investigates the properties and utilizations of CS-based materials as sorbents in µ-SPE, highlighting their potential to revolutionize pesticide determination.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"45 ","pages":"Article e00258"},"PeriodicalIF":11.1,"publicationDate":"2025-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143378101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Trace element determination using mass spectrometry coupled detection methods","authors":"Dotse Selali Chormey ,&nbsp;Elif Öztürk Er ,&nbsp;Sezin Erarpat Bodur ,&nbsp;Buse Tuğba Zaman ,&nbsp;Süleyman Bodur ,&nbsp;Tülay Borahan Kustanto ,&nbsp;İnci Kayın ,&nbsp;Sezgin Bakırdere","doi":"10.1016/j.teac.2024.e00257","DOIUrl":"10.1016/j.teac.2024.e00257","url":null,"abstract":"<div><div>About half a century ago, trace elements in the environment were restricted at upper parts per billion levels due to limited information on their toxicological effects on humans and other organisms in the environment. In this present day, stricter restrictions are being enforced by several regulatory authorities to curb the continuous release of trace elements into the environment through anthropogenic activities that have resulted from the demand to meet the global population increase. The severity of health disorders related to trace elemental exposure from different sources and doses seem to overshadow their relevance for several biological functions. Thus, toxicological studies that elucidate the harmful effects of chemicals and help regulators to set limits of restriction require very sensitive analytical instruments that offer selectivity and specificity for accurate and precise determinations. Mass spectrometry is a unique technique that suits the purpose of identifying, confirming and quantifying elements that emanate from various chemical species. Inductively coupled plasma mass spectrometry is a superior analytical technique used for the simultaneous determination of trace elements in various samples. This superior technique is further augmented by solid phase and liquid phase microextraction methods, which help separate trace elements from complex matrices into clean, readable and enriched forms for the instrument.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"45 ","pages":"Article e00257"},"PeriodicalIF":11.1,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Combination of miniature electrode systems via nanomaterials: Pesticide analysis","authors":"Murat Çelik ,&nbsp;Ipek Kucuk ,&nbsp;Selenay Sadak ,&nbsp;Bengi Uslu","doi":"10.1016/j.teac.2024.e00251","DOIUrl":"10.1016/j.teac.2024.e00251","url":null,"abstract":"<div><div>Pesticides are vital in modern agriculture for controlling pests and diseases, thereby enhancing crop yields and food security. However, their extensive use has raised environmental and health concerns due to their persistence and toxicity. Conventional detection methods, such as high-performance liquid chromatography and gas chromatography, are effective but often costly and time-consuming, prompting the need for alternative approaches. Electrochemical methods emerge as promising solutions for pesticide analysis owing to their affordability, simplicity, and suitability for field applications. The incorporation of nanomaterials into electrochemical sensors significantly enhances their sensitivity and selectivity. Nanomaterials, including noble metals, carbon nanotubes, and metal oxide nanoparticles, improve sensor performance through their unique physical, chemical, and biological properties. This review examines recent advancements in miniature electrochemical sensors for pesticide detection, including contemporary literature. It discusses the structure, applications, and impacts of pesticides, and highlights the advantages of electrochemical sensors enhanced by nanomaterials. Various electrode types and their modifications with nanomaterials are evaluated. Additionally, the integration of smartphone technology and innovative approaches such as lab-on-a-chip and portable sensors are explored. By incorporating recent studies, this review provides a comprehensive reference for developing advanced, portable, and in situ analyzers utilizing nanomaterials, aiming to enhance food safety, human health, and environmental monitoring.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"45 ","pages":"Article e00251"},"PeriodicalIF":11.1,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microplastics in road dust and surrounding environment: Sources, fate and analytical approaches","authors":"K.S.D. Premarathna ,&nbsp;Anushka Upamali Rajapaksha ,&nbsp;Meththika Vithanage","doi":"10.1016/j.teac.2024.e00256","DOIUrl":"10.1016/j.teac.2024.e00256","url":null,"abstract":"<div><div>Microplastic pollution is a growing environmental concern worldwide, and roadsides have been recognized as a reservoir for microplastic accumulation. The main sources of microplastics on the road dust and roadside are tire and road wear particles and plastic litter. Once released to the road surface, these are combined with other contaminants released via vehicle exhausts and particulate matter on the road surfaces. This review aimed to assess roadside microplastics' sources, abundance, characteristics, and dispersion pathways. Further, this review critically discusses existing analytical techniques for identifying roadside microplastics and their limitations. Microplastics in the roadside are mainly identified using spectroscopic techniques; however, using specific markers to identify microplastics in roadside soil is rather common and effective due to additive-based interferences with infrared radiation. The health impacts of roadside microplastics are under-studied, necessitating more studies and standardized methods for their monitoring and analysis.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"45 ","pages":"Article e00256"},"PeriodicalIF":11.1,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanoparticles-assisted lateral flow immunoassays for mycotoxins: A state-of-the-art review","authors":"Nan Long ,&nbsp;Qingbin Xu ,&nbsp;Pengyue Song ,&nbsp;Ying Li ,&nbsp;Yujiao Hou ,&nbsp;Jiabo Wang ,&nbsp;Weijun Kong","doi":"10.1016/j.teac.2024.e00254","DOIUrl":"10.1016/j.teac.2024.e00254","url":null,"abstract":"<div><div>The global concerns on mycotoxins contamination in different matrices have accelerated the development of analytical techniques. Of them, nanoparticles (NPs)-assisted lateral flow immunoassays (LFIAs) have attracted increasing interests for the on-site point-of-care detection of mycotoxins. The introduction of anti-bodies as recognition elements and NPs with unique structures and properties as the active elements has greatly improved the analytical performance of LFIAs. The real applications for mycotoxins detection and corresponding publications have grown exponentially over the past decades. Therefore, in this review, we first summarize the detection principle, development trend, and novel fabrication strategy of NPs-assisted LFIAs for single-target detection and multiplexed analysis of mycotoxins. Then, we concentrate on the recent real applications and played roles of NPs and their nanocomposites as signal labels, encapsulating materials, catalysts, magnetic absorption and separation materials, and fluorescence quenchers in constructing diverse LFIA platforms through the elaborate evaluation of different proof-of-concept cases. A special highlight is given to colored-, fluorescent-, photothermal-, and SERS-active-type NPs as nano-labels. Beyond a comprehensive commentary of advantages and potential limitations of the emerging NPs-assisted LFIAs for mycotoxins monitoring, we critically discuss their current challenges and future perspectives. It is anticipated that this systematically-presented review will provide essential insights into the development of NPs-assisted LFIA and their extensive applications in different fields to safeguard food safety and public health.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"45 ","pages":"Article e00254"},"PeriodicalIF":11.1,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}