Trends in Environmental Analytical Chemistry最新文献

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Gas chromatography in analysis of different natural products: A comprehensive review on methods and applications 气相色谱法在不同天然产物分析中的应用综述
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2026-03-01 Epub Date: 2025-12-20 DOI: 10.1016/j.teac.2025.e00295
Saša D. Đurović , Ivan Kojić , Violeta M. Đurović , Yulia A. Smyatskaya , Angi E. Skhvediani , Julia G. Bazarnova , Yuri V. Shatalin , Andrey V. Vasin
{"title":"Gas chromatography in analysis of different natural products: A comprehensive review on methods and applications","authors":"Saša D. Đurović ,&nbsp;Ivan Kojić ,&nbsp;Violeta M. Đurović ,&nbsp;Yulia A. Smyatskaya ,&nbsp;Angi E. Skhvediani ,&nbsp;Julia G. Bazarnova ,&nbsp;Yuri V. Shatalin ,&nbsp;Andrey V. Vasin","doi":"10.1016/j.teac.2025.e00295","DOIUrl":"10.1016/j.teac.2025.e00295","url":null,"abstract":"<div><div>Gas chromatography (GC) is one of the most widely employed techniques for analysis today. It can be combined with various detectors, of which mass spectrometry (MS) and flame ionization detector (FID) are the most common. The MS is used for structure determination and conformation, while FID is more suitable for quantitative analysis. Therefore, these two detectors are often coupled together in one system. Depending on the nature of the sample and analyzed compounds, sample preparation and method conditions will be selected. Volatile and stable compounds, such as terpenes, can be analyzed directly after dissolving them in a suitable solvent. On the other hand, some less stable compounds (acidic forms of cannabinoids) and non-volatile (polyphenolic compounds) must be derivatized (usually silylation) before the analysis to increase their stability and volatility. The physico-chemical properties of the analyzed compounds will also influence the choice of column and temperature program on the GC. Based on the stationary phase, the capillary column may be non-polar, mid-polar, or polar. Compounds such as cannabinoids and polyphenolic compounds are analyzed on non-polar columns, while terpenes and alcohols are analyzed on mid-polar and polar columns. The nature of fatty acid methyl esters (FAMEs) allows their analysis on mid-polar and polar columns. However, for optimal separation, the most polar columns are used, where even <em>cis</em> and <em>trans</em> isomers can be separated. Selecting the method is not an easy task, and this article provides helpful information for method selection and sample preparation.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"49 ","pages":"Article e00295"},"PeriodicalIF":13.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145839972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in paper-based sensors for detecting and monitoring emerging organic contaminants 用于检测和监测新兴有机污染物的纸基传感器的最新进展
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2026-03-01 Epub Date: 2026-01-23 DOI: 10.1016/j.teac.2026.e00298
Shaikh Manirul Haque , Sirhan Al-Batty , Yunusa Umar , Elaref Ratemi , Syed Sauban Ghani , Masoom Raza Siddiqui , Adrián Fuente-Ballesteros
{"title":"Recent advances in paper-based sensors for detecting and monitoring emerging organic contaminants","authors":"Shaikh Manirul Haque ,&nbsp;Sirhan Al-Batty ,&nbsp;Yunusa Umar ,&nbsp;Elaref Ratemi ,&nbsp;Syed Sauban Ghani ,&nbsp;Masoom Raza Siddiqui ,&nbsp;Adrián Fuente-Ballesteros","doi":"10.1016/j.teac.2026.e00298","DOIUrl":"10.1016/j.teac.2026.e00298","url":null,"abstract":"<div><div>The widespread occurrence of emerging organic contaminants (EOCs), including pharmaceuticals, personal care products, pesticides, and industrial chemicals, is a growing concern for environmental and human health. Conventional analytical techniques, such as gas and liquid chromatography coupled to mass spectrometry, provide high sensitivity and reliability but remain costly, resource-intensive, and unsuitable for rapid or on-site monitoring. In this context, paper-based sensors are a promising alternative, offering low cost, portability, simple fabrication, and environmental sustainability. This review provides an overview of recent advances in paper-based sensors for the detection and monitoring of EOCs. Key fabrication strategies, including photolithography, wax printing, inkjet printing, screen printing, and laser-based approaches, are discussed with respect to device performance, scalability, and field deployability. Major transduction mechanisms, including electrochemical, colourimetric, fluorescence, and chemiluminescence approaches, are examined together with optimisation strategies based on nanomaterials, molecular recognition elements, and microfluidic design to improve sensitivity and selectivity. Applications in environmental monitoring, healthcare, and pharmaceutical and food analysis are reviewed, with emphasis on real-sample analysis and method validation. Current limitations related to matrix effects, reproducibility, environmental robustness, and large-scale manufacturing are identified, and future perspectives are outlined.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"49 ","pages":"Article e00298"},"PeriodicalIF":13.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146022386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal oxide electrodes: A new frontier in electrochemical microplastic detection 金属氧化物电极:电化学微塑性检测的新前沿
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2026-03-01 Epub Date: 2025-12-02 DOI: 10.1016/j.teac.2025.e00289
Eun-Bi Kim , Ing Kong , M. Shaheer Akhtar , Sadia Ameen , Hu Li
{"title":"Metal oxide electrodes: A new frontier in electrochemical microplastic detection","authors":"Eun-Bi Kim ,&nbsp;Ing Kong ,&nbsp;M. Shaheer Akhtar ,&nbsp;Sadia Ameen ,&nbsp;Hu Li","doi":"10.1016/j.teac.2025.e00289","DOIUrl":"10.1016/j.teac.2025.e00289","url":null,"abstract":"<div><div>Microplastic pollution has become a significant problem due to its widespread presence in aquatic ecosystems and its possible negative impacts on human beings and marine life. Traditional detection methods are often time-consuming, and their sensing activity still needs accurate quantification. Electrochemical sensing methods offer a promising alternative for the highly sensitive and quick detection of microplastics. This review explains the outlines of recent advancements in electrochemical sensing methods, with a focus on metal oxide electrodes. These electrodes have been recognized as promising platforms for microplastic detection owing to their relatively high chemical stability, large surface area, and superior conductivity. Various metal oxides, such as zinc oxide (ZnO), titanium dioxide (TiO<sub>2</sub>), and iron oxide (Fe<sub>3</sub>O<sub>4</sub>), have been investigated for their suitability in these applications. This review discusses the principles and mechanisms underlying electrochemical sensing, including voltammetric and amperometric techniques. Key factors influencing the performance of metal oxide-based sensors, such as electrode morphology, surface functionalization, and sensor configuration, are examined. Recent developments in sensors, fabrication techniques, and strategies for enhancing sensitivity and selectivity are also highlighted. In addition, the review confronts the challenges, hurdles, and future directions in electrochemical sensing for microplastic detection, including the need for standardized protocols, validation of sensor performance in real-world samples, and integration into monitoring networks for environmental surveillance. Overall, metal oxide-based electrochemical sensing methods hold great promise for detecting microplastics in environmental samples. Continued research efforts aimed at optimizing sensor performance and addressing practical challenges will contribute to the development of reliable and cost-effective tools for microplastic monitoring and remediation.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"49 ","pages":"Article e00289"},"PeriodicalIF":13.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145738030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in nanomaterials for water and wastewater treatment and monitoring 纳米材料在水和废水处理和监测方面的进展
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2026-03-01 Epub Date: 2026-01-23 DOI: 10.1016/j.teac.2026.e00299
Niloofar Salehpour , Parisa Mahdavi , Saeed Nojavan
{"title":"Advancements in nanomaterials for water and wastewater treatment and monitoring","authors":"Niloofar Salehpour ,&nbsp;Parisa Mahdavi ,&nbsp;Saeed Nojavan","doi":"10.1016/j.teac.2026.e00299","DOIUrl":"10.1016/j.teac.2026.e00299","url":null,"abstract":"<div><div>The persistent release of emerging contaminants into water and wastewater poses escalating ecological and public health risks, highlighting limitations of conventional treatment systems. Nanomaterials offer a transformative approach by combining efficient contaminant removal with sensitive and real-time analytical monitoring. This review critically evaluates diverse nanomaterial classes including polymeric nanostructures, metal-organic frameworks (MOFs), metal and metal oxide nanoparticles, and multifunctional nanocomposites, focusing on their mechanisms in adsorption, photocatalysis, filtration, and sensing. The distinctive contribution of this review lies in its integrated, application-oriented evaluation of nanomaterials that simultaneously address wastewater remediation and analytical detection, a perspective largely absents in existing literature, which treats these functions separately. Practical considerations including scalability, environmental safety, and regulatory relevance are also addressed. By unifying remediation and monitoring functionalities, this review provides a structured roadmap for designing next-generation nanomaterial-based strategies for sustainable water management.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"49 ","pages":"Article e00299"},"PeriodicalIF":13.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green solutions for clean water: Natural materials in contaminant detection and removal 清洁水的绿色解决方案:污染物检测和去除中的天然材料
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-09-30 DOI: 10.1016/j.teac.2025.e00285
Mithra Geetha, Reyhanath Pilakka Veettil, Kishor Kumar Sadasivuni
{"title":"Green solutions for clean water: Natural materials in contaminant detection and removal","authors":"Mithra Geetha,&nbsp;Reyhanath Pilakka Veettil,&nbsp;Kishor Kumar Sadasivuni","doi":"10.1016/j.teac.2025.e00285","DOIUrl":"10.1016/j.teac.2025.e00285","url":null,"abstract":"<div><div>The growing crisis of global water contamination, fueled by rapid industrialization, urban development, and intensified agriculture, has created an urgent need for sustainable, efficient, and environmentally friendly water treatment technologies. Conventional treatment approaches often fall short due to high operational costs, potential secondary pollution, and limited effectiveness against emerging pollutants. In response, green and natural materials have emerged as attractive alternatives for both contaminant removal and water quality monitoring, offering advantages such as biodegradability, ecological safety, cost-efficiency, and wide availability. This review provides a detailed overview of recent advancements in utilizing plant-based adsorbents, agricultural and industrial bio-wastes, natural polymers, clays, algae, microbial biomass, and eco-friendly nanomaterials for water purification. It explores key removal strategies including adsorption, photocatalytic degradation, membrane filtration, bio-based coagulation-flocculation, and bioremediation, demonstrating their effectiveness in targeting heavy metals, organic pollutants, biological contaminants, microplastics, and newly recognized environmental toxins. Furthermore, the integration of these natural materials into portable, low-cost sensing technologies—such as colorimetric, electrochemical, and fluorescent biosensors—is examined, offering innovative tools for real-time contaminant detection. The review also highlights emerging hybrid systems that combine green nanomaterials with biochar, biopolymers, and metal-based nanoparticles to enhance contaminant removal and multifunctional performance. Key practical considerations, including scalability, material uniformity, environmental impacts, biodegradability, and regulatory challenges, are addressed. A life cycle assessment (LCA) perspective is incorporated to compare the sustainability of these green alternatives with conventional materials. The article concludes by outlining future research opportunities focused on hybrid technologies, smart sensing integration, and circular economy frameworks to support scalable, sustainable, and decentralized water purification solutions.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00285"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145219792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular interactions in luminescent sensing of per- and polyfluoroalkyl substances (PFAS) 全氟烷基和多氟烷基物质(PFAS)发光传感中的超分子相互作用
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-11-03 DOI: 10.1016/j.teac.2025.e00286
Kun Zhang , Zhilin Guo , Ya Hu , Han Yan , Yanzhou Bao , Bintian Zhang
{"title":"Supramolecular interactions in luminescent sensing of per- and polyfluoroalkyl substances (PFAS)","authors":"Kun Zhang ,&nbsp;Zhilin Guo ,&nbsp;Ya Hu ,&nbsp;Han Yan ,&nbsp;Yanzhou Bao ,&nbsp;Bintian Zhang","doi":"10.1016/j.teac.2025.e00286","DOIUrl":"10.1016/j.teac.2025.e00286","url":null,"abstract":"<div><div>The detection of per- and polyfluoroalkyl substances (PFAS) is of critical environmental and public health importance due to their extreme persistence, bioaccumulative nature and toxicity. Luminescence-based sensing has emerged as a powerful alternative, offering faster response, higher sensitivity, and potential for on-site monitoring compared to traditional detection methods. In this paper, we summarised recent advances in luminescent PFAS sensors and systematically explored design strategies across diverse material platforms. Supramolecular interactions, including electrostatic attraction, hydrogen bonding, hydrophobic interaction and fluorine–fluorine (F–F) interactions between the recognition interface and PFAS molecules, play an important role in selectively capturing PFAS species and modulating the luminescent response. Despite the significant progress, we also discussed the current challenges and outlined key directions for future research. This review provides implications and guidance for the design and development of luminescent materials for selective and effective PFAS sensing.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00286"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145465298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lead(II) sensing in biological and environmental systems: A decade (2015–2024) of fluorescent probe innovations and emerging trends 生物和环境系统中的铅(II)传感:荧光探针创新和新兴趋势的十年(2015-2024)
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-09-16 DOI: 10.1016/j.teac.2025.e00283
Swagatika Mishra , Siddhesh Puri , Pragyan P. Dash , Patitapaban Mohanty , Suban K. Sahoo , Bigyan R. Jali
{"title":"Lead(II) sensing in biological and environmental systems: A decade (2015–2024) of fluorescent probe innovations and emerging trends","authors":"Swagatika Mishra ,&nbsp;Siddhesh Puri ,&nbsp;Pragyan P. Dash ,&nbsp;Patitapaban Mohanty ,&nbsp;Suban K. Sahoo ,&nbsp;Bigyan R. Jali","doi":"10.1016/j.teac.2025.e00283","DOIUrl":"10.1016/j.teac.2025.e00283","url":null,"abstract":"<div><div>Lead (Pb²⁺) contamination in environmental and biological systems causes a significant risk to human health and ecosystems because of its high toxicity, persistence, and bioaccumulation potential. Even at trace levels, exposure to lead can result in severe neurological, developmental, and organ-related disorders. Hence, the development of highly sensitive and selective detection methods for Pb²⁺ is crucial. This review provides an overview of recent advancements in lead chromofluorogenic sensors (2015–2024), including Schiff bases, homocyclic and heterocyclic aromatic compounds, molecular organic frameworks (MOFs), macrocyclic ligands and nanomaterial-based approaches. The sensing mechanisms, detection limits, response times, and analytical applications in biological and environmental monitoring of the reviewed Pb<sup>2 +</sup> sensors have been discussed. Additionally, the challenges and future perspectives of Pb²⁺ sensing technologies are discussed to guide further research in this critical field.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00283"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145120851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Latest advances in environmental applications of COFs and their derivatives towards marine biotoxins COFs及其衍生物在海洋生物毒素方面环境应用的最新进展
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-09-16 DOI: 10.1016/j.teac.2025.e00282
Tianxing Wang , Zhou Qin , Nini Liang , Yucheng Zou , Yongqiang Shi , Junjun Zhang , Tingting Shen , Jian Zhu
{"title":"Latest advances in environmental applications of COFs and their derivatives towards marine biotoxins","authors":"Tianxing Wang ,&nbsp;Zhou Qin ,&nbsp;Nini Liang ,&nbsp;Yucheng Zou ,&nbsp;Yongqiang Shi ,&nbsp;Junjun Zhang ,&nbsp;Tingting Shen ,&nbsp;Jian Zhu","doi":"10.1016/j.teac.2025.e00282","DOIUrl":"10.1016/j.teac.2025.e00282","url":null,"abstract":"<div><div>Marine biotoxins pose persistent threats to aquatic ecosystems and food safety, calling for advanced monitoring and remediation strategies. This review highlights covalent organic frameworks (COFs) as multifunctional materials for toxin sensing, adsorption, and catalytic degradation under marine conditions. Key advances in framework design, including pore engineering, surface functionalization, and hybridization, are summarized to illustrate how structural control enhances toxin-specific recognition. Representative applications targeting saxitoxin, domoic acid, okadaic acid, and microcystins are highlighted. COF adsorbents show high capacities for lipophilic shellfish toxins (e.g., okadaic acid/dinophysistoxin-1 up to 812/830 mg g⁻¹) and ultrafast adsorption for polar analytes (e.g., domoic acid reaching 66.5 mg g⁻¹ within 7 min), while retaining &gt; 80 % efficiency after multiple regeneration cycles. COF-based sensors achieve detection limits as low as pg mL⁻¹ in seawater and 0.005 µg kg⁻¹ in shellfish. Moreover, mechanistic insights into pseudo-second-order adsorption kinetics, Freundlich/Langmuir isotherms, binding forces (π–π conjugation, hydrogen bonding, electrostatic, and hydrophobic interactions), and key signal transduction pathways (photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET)) are critically discussed, together with COF-based photocatalytic systems enabling ROS (•OH, <sup>1</sup>O<sub>2</sub>, and O<sub>2</sub>•⁻)-driven degradation of recalcitrant toxins. Despite these advances, challenges remain regarding scalability, long-term stability, and field deployment. Future opportunities include machine learning-guided COF design, integrated sensing–remediation systems, and alignment with regulatory standards, providing a roadmap toward next-generation solutions for marine toxin management.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00282"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145105608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artificial intelligence and machine learning for colorimetric detections: Techniques, applications, and future prospects 人工智能和机器学习用于比色检测:技术、应用和未来前景
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-09-06 DOI: 10.1016/j.teac.2025.e00280
Arpita Parakh , Ashish Awate , Sampa Manoranjan Barman , Rakesh K. Kadu , Dhiraj P. Tulaskar , Madhusudan B. Kulkarni , Manish Bhaiyya
{"title":"Artificial intelligence and machine learning for colorimetric detections: Techniques, applications, and future prospects","authors":"Arpita Parakh ,&nbsp;Ashish Awate ,&nbsp;Sampa Manoranjan Barman ,&nbsp;Rakesh K. Kadu ,&nbsp;Dhiraj P. Tulaskar ,&nbsp;Madhusudan B. Kulkarni ,&nbsp;Manish Bhaiyya","doi":"10.1016/j.teac.2025.e00280","DOIUrl":"10.1016/j.teac.2025.e00280","url":null,"abstract":"<div><div>Rapid, low-cost detection of contaminants and quality markers is critical across healthcare, food safety, environmental monitoring, and industrial applications. While traditional laboratory methods remain accurate, they are often slow, expensive, and unsuitable for point-of-care or field use. Colorimetric biosensing offers a simple, affordable, and visually intuitive alternative; however, its dependence on subjective human interpretation introduces bias and limits reproducibility, particularly when subtle color variations arise under different lighting conditions or device types. Recent advances in artificial intelligence (AI), machine learning (ML), and especially deep learning (DL) have transformed these limitations into opportunities by enabling automated, robust, and highly precise analysis. Models such as convolutional neural networks (CNNs) and specialized architectures like ColorNet can directly interpret raw images, extract complex features, and adapt across varied environments, thereby enhancing accuracy and scalability. Through smartphone integration, edge computing, and explainable AI, these systems are now being deployed in diverse real-world scenarios, including biomedical diagnostics, wound and tissue health monitoring, food spoilage and adulteration detection, environmental pollutant sensing, and smart packaging. This review critically examines AI/ML/DL-assisted colorimetric systems, highlights domain-specific applications, and addresses challenges such as dataset generalizability, model interpretability, and regulatory validation, offering practical solutions and future directions for smarter, portable, and accessible biosensing platforms.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00280"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145019638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Copper-based nanozymes for environmental analytical applications: A review 铜基纳米酶在环境分析中的应用综述
IF 13.4 2区 化学
Trends in Environmental Analytical Chemistry Pub Date : 2025-12-01 Epub Date: 2025-09-09 DOI: 10.1016/j.teac.2025.e00281
Qing Han , Xixingchi Chen , Ke Li , Hui Huang , Yongxin Li
{"title":"Copper-based nanozymes for environmental analytical applications: A review","authors":"Qing Han ,&nbsp;Xixingchi Chen ,&nbsp;Ke Li ,&nbsp;Hui Huang ,&nbsp;Yongxin Li","doi":"10.1016/j.teac.2025.e00281","DOIUrl":"10.1016/j.teac.2025.e00281","url":null,"abstract":"<div><div>The analysis and detection of pollutants is one of the important steps in solving environmental problems. Natural enzymes, as efficient catalysts produced in living organisms, can be applied to the detection and sensing of pollutants through their mediated enzymatic reactions. However, the poor environmental stability, complex purification techniques, and high costs of natural enzymes have limited their large-scale application in environmental analysis. Nanozymes, as a class of nanomaterials with enzyme-like activity, are characterized by high catalytic activity, good stability, low cost, and easy production and preparation. Most nanozymes use transition metals as catalytic active sites. Since copper has multiple oxidation states, nanozymes with copper as the active center typically exhibit multiple activities, particularly some copper-based nanozymes that possess oxidase-like activity, whose catalytic action relies on oxygen. This characteristic has enabled their broader application in environmental analysis (e.g., rapid detection and identification of environmental pollutants). This review discusses the classification of enzyme-like activities of copper-based nanozymes and their design strategies, composition types, and various applications in the field of environmental analysis (rapid detection and identification of environmental pollutants) based mainly on the research of copper-based nanozymes for the analysis of environmental pollutants in the last three years, and summarizes the current status of copper-based nanozymes in environmental analysis (their effectiveness in detecting and identifying environmental pollutants), challenges (low sensitivity, poor selectivity, lack of rational design), and future trends (integration with electrocatalysis, molecular imprinting technology, and rational design based on target substance characteristics). We link the activity of copper-based nanozymes with their corresponding design strategies and discuss approaches to yield copper-based nanozymes with a range of activities. The interactions between the target substances and the signal output generated by copper-based nanozymes are summarized. We believe this will facilitate the further development of practical applications for copper-based nanozymes in environmental analysis.</div></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":"48 ","pages":"Article e00281"},"PeriodicalIF":13.4,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145049484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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