Environmental Science and Pollution Research最新文献

{"title":"Optimization and reusability of photocatalytic g-C₃N₄/W-TiO₂/PVDF membranes for degradation of sulfamethazine.","authors":"Nourhan Hamdy, Mohammad El-Geundi, Mohram Fuoad, Mohamed Gar Alalm","doi":"10.1007/s11356-024-35445-6","DOIUrl":"https://doi.org/10.1007/s11356-024-35445-6","url":null,"abstract":"<p><p>Pharmaceuticals and personal care products (PPCPs) are prevalent emerging pollutants in the aquatic environment. The photocatalysis process has proven high efficiency in degrading PPCPs; however, the fate and repercussions of photocatalyst residuals are a major concern. To avoid that, we developed a composite from graphitic carbon nitride/tungsten doped with titanium dioxide (g-C₃N₄/W-TiO₂) and loaded it on polyvinylidene fluoride (PVDF) membranes by the phase-inversion method. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and other different analyses implied the successful synthesis of g-C₃N₄/W-TiO₂ composite and coating on PVDF membranes. A Box-Behnken design (BBD) was used to optimize the operational parameters, including pH, g-C₃N₄ ratio in the composite, and initial SMZ concentration by the response surface methodology (RSM). The highest SMZ degradation percentage was 98.60% after 240 min of irradiation. Liquid chromatography with tandem mass spectrometry (LC-MS/MS) along with suspect screening was used to identify the intermediate transformation products and propose the SMZ degradation pathway. The loss in membrane activity after five cycles of photocatalytic degradation was about 18%. According to the current study, the photocatalytic membrane g-C₃N₄/W-TiO₂/PVDF is promising for removing sulfonamide antibiotics from wastewater.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comments on \"Uranium standards in drinking water: an examination from scientific and socio-economic standpoints of India\".","authors":"Hardev Singh Virk","doi":"10.1007/s11356-024-35532-8","DOIUrl":"https://doi.org/10.1007/s11356-024-35532-8","url":null,"abstract":"","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing streamflow prediction in a mountainous watershed using a convolutional neural network with gridded data.","authors":"Zahra Hajibagheri, Mohammad Mahdi Rajabi, Ebrahim Asadi Oskouei, Ali Al-Maktoumi","doi":"10.1007/s11356-024-35482-1","DOIUrl":"https://doi.org/10.1007/s11356-024-35482-1","url":null,"abstract":"<p><p>In this research, we demonstrate the effectiveness of a convolutional neural network (CNN) model, integrated with the ERA5-Land dataset, for accurately simulating daily streamflow in a mountainous watershed. Our methodology harnesses image-based inputs, incorporating spatial distribution maps of key environmental variables, including temperature, snowmelt, snow cover, snow depth, volumetric soil water content, total evaporation, total precipitation, and leaf area index. The proposed CNN architecture, while drawing inspiration from classical designs, is specifically tailored for the task of streamflow prediction. The model's performance, assessed during both the training and testing phases, demonstrates high accuracy, reflected quantitatively in metrics such as RMSE, MAPE, R², and NSE. Notably, the model exhibits enhanced accuracy in predicting lower flow rates, particularly in autumn and winter, as evidenced by an average RMSE of 2.02 m³/s for flows below 13.8 m³/s. In contrast, the model's precision decreases in high flow rate scenarios, predominantly in spring and early summer. The implementation of forward feature selection (FFS) has further optimized the model, pinpointing total evaporation and volumetric soil water as key parameters, thus enabling a more efficient model with accuracy comparable to the initial, more complex version. This research underscores the practical utility of an image-based approach using CNN models for streamflow prediction. Moreover, the adoption of the freely available and universally accessible ERA5-Land dataset highlights its effectiveness as a valuable and cost-efficient tool for streamflow prediction.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Application of QuEChERS extraction and LC-MS/MS for determination of pharmaceuticals in sewage sludges sampled across the Czech Republic.","authors":"Pavlína Landová, Ludmila Mravcová, Šárka Poláková, Petra Kosubová","doi":"10.1007/s11356-024-35508-8","DOIUrl":"https://doi.org/10.1007/s11356-024-35508-8","url":null,"abstract":"<p><p>The use of pharmaceuticals entails a significant risk of environmental contamination. Wastewater treatment plants (WWTPs) are considered to be the main contributors to contamination as they ineffectively eliminate these compounds from wastewater. Simultaneously, they produce solid waste, sludge, which often contains a variety of retained pollutants, including pharmaceuticals. Since sewage sludge is frequently applied to agricultural soil due to its rich nutrient content, pollutants are introduced into the environment in this way. Only a few studies have been carried out on the topic of the analysis of pharmaceuticals in sludge. Therefore, information on the occurrence of pharmaceuticals in sludge is limited. The present study employed quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction and liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS) analysis to establish a simple and reliable procedure for determining 16 pharmaceuticals (antibiotics, anticonvulsants, antidepressants and β-blockers) in sewage sludge. The method has been thoroughly validated, and parameters such as linear range, accuracy, precision, matrix effects and detection and quantification limits were assessed. Our method achieved low limits of quantification (0.5-9.0 µg kg^-1) and satisfactory recoveries (51-101%). Forty sludge samples from different WWTPs across the Czech Republic were analysed. Fourteen compounds were detected and quantified in most samples, with antidepressants having the highest detection frequency and overall content. Sertraline, with a mean concentration of 521.0 µg kg^-1, was notably prevalent alongside its metabolite norsertraline (mean concentration 204.9 µg kg^-1). The antibiotic azithromycin was also found at higher levels (mean concentration 185.1 µg kg^-1).</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Can the pH-dependent adsorption of phenoxyalkanoic herbicides in soils be described with a single equation?","authors":"Tadeusz Paszko, Claudio A Spadotto, Miłosz Huber, Maria Jerzykiewicz, Joanna Matysiak, Alicja Skrzypek, Patrycja Boguta","doi":"10.1007/s11356-024-35413-0","DOIUrl":"https://doi.org/10.1007/s11356-024-35413-0","url":null,"abstract":"<p><p>The six phenoxyalkanoic acid herbicides currently used in the European Union have similar molecular structures. Therefore, we assumed the soil components involved in the adsorption mechanisms of these herbicides to be identical. The values of the adsorption distribution coefficient K_d, obtained via batch experiments involving typical Polish Arenosol, Luvisol, and Chernozem profiles with a native pH of 4.2-7.7, were examined using Lasso regression, as well as adsorption on isolated fractions of humic substances, Al₂O₃, and goethite. The neutral forms of the herbicides were adsorbed on the surface of fulvic acids available to them, covering soil mesopores with a size of > 2.5 nm. The models revealed that fulvic acids had a lognormal-like distribution in soil pores. Herbicide anions were adsorbed on the pH-dependent sites of Al oxyhydroxides and on the sites created by the Al⁺³ species adsorbed on the surface of fulvic acids (both sites were active up to pH 7.5), the sites of humic acids associated with the adsorbed Al³⁺ species, sites of Fe oxyhydroxides (active at pH < 5), and, to a limited extent, sites of humins. Two models describing the adsorption of phenoxyalkanoic acid herbicides in soils were created. A simpler model was based on humic substance fractions and the variables related to the potential acidity of soils. In the more extensive model, humic substance fractions and Al and Fe oxyhydroxide contents were used as predictors, and, where necessary, the predictors were combined with the modified Henderson-Hasselbalch formula to estimate the activity ranges of pH-dependent sorption sites. The study findings revealed that fulvic and humic acids were the main adsorbents of phenoxyalkanoic herbicides in soils, indicating that transporting of the herbicides with dissolved organic matter is an important mechanism of groundwater and surface water contamination with these chemicals.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pioneering technologies over time to rehabilitate crude oil-contaminated ecosystems: a review.","authors":"Netra Prova Baruah, Manisha Goswami, Nimisha Sarma, Devasish Chowdhury, Arundhuti Devi","doi":"10.1007/s11356-024-35442-9","DOIUrl":"https://doi.org/10.1007/s11356-024-35442-9","url":null,"abstract":"<p><p>The unremitting pollution of our environment induced by crude oil spillage and drilling site accidents has jeopardized every living species in the biological ecosystem. Removing heavy crude oil constituents with the help of traditional and mainstream oil sorbents because of their ingrained raised viscosities is a strenuous venture. Lighter distillates of crude oil, like condensate, do not aggregate with tremulous shine on the aquatic surface nor settle at the bottom sediment of the water bodies like the heavier components do with time. Fabricating optimally designed materials capable of capturing, degrading, or removing toxic chemical constituents of this fossil fuel is critical in this modern era. This review comprehensively discusses the evolution of scientific technologies developed to separate these constituents from land and aquatic bodies. We provide an overview of the latest physical and chemical strategies and prevalent biological remediation schemes for removing these pollutants from soils and water for environmental protection. The article highlights the urgency of preventing oil spill accidents, whose anticipation is challenging to harness. A spectrum of advanced functional methodologies is also discussed to adequately treat discharged hydrocarbon contaminants, establish public safety, and pave the path to enhancing the circular economy metrics linked with oil industries.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Empirical insights into India's energy demand: unveiling elasticity dynamics for strategic policy initiatives.","authors":"Aamir Ahmad Teeli, Mudaser Ahad Bhat, Mohammad Subhan","doi":"10.1007/s11356-024-35423-y","DOIUrl":"https://doi.org/10.1007/s11356-024-35423-y","url":null,"abstract":"<p><p>Policymakers and stakeholders can use insights from price elasticity and income elasticities of energy demand to devise targeted interventions that promote energy efficiency, reduce reliance on fossil fuels, and drive the transition to more sustainable and resilient energy systems. This study seeks to examine how changes in income elasticity and price elasticity affect energy consumption over time using the ARDL model and a time-varying parameter technique, state-space Kalman filter. The study's findings reveal that energy prices have a negative and significant impact on energy consumption, whereas GDP per capita and population growth have a positive and significant impact on energy consumption in both the short and long run. The findings underline the importance of economic growth and increasing population in driving growing energy demand in India, which is consistent with the country's energy-intensive development aspirations. The time-varying analysis shows that the price elasticity of energy consumption follows a U-shaped pattern across time. However, from the onset of the new millennium decade, the elasticity of energy consumption with regard to its price has continually decreased, reaching - 0.54 by 2020. Furthermore, the findings imply that the income elasticity of India's energy demand has stabilized around unity, indicating that the country is currently near the middle of the energy intensity-GDP inverted-U trajectory. Given these evolving elasticities, policymakers should take a flexible and forward-thinking strategy to achieve optimal energy consumption levels.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Removal of hexavalent chromium and pentavalent arsenic from aqueous solutions by adsorption on polyethylenimine-modified silica nanoparticles.","authors":"Maria Xanthopoulou, Dimitrios Gkiliopoulos, Konstantinos S Triantafyllidis, Margaritis Kostoglou, Ioannis A Katsoyiannis","doi":"10.1007/s11356-024-35473-2","DOIUrl":"https://doi.org/10.1007/s11356-024-35473-2","url":null,"abstract":"<p><p>Chromium and arsenic are commonly found in water and wastewater as hexavalent chromium, Cr(VI), and inorganic arsenic species, such as pentavalent arsenic, As(V). In aqueous media, both Cr(VI) and As(V) exist predominantly in the form of oxy-anions. In our study, we prepared a polyethylenimine-silica composite material (SiO₂-PEI) as an adsorbent to study the adsorption capacity for chromate and arsenate ions. Polyethylenimine (PEI) can effectively bind negatively charged species through electrostatic interactions. The parameters that were evaluated, regarding the adsorption capacity were the effect of pH, the effect of the initial concentration of Cr(VI) and As(V), and the presence of other anions. Also, we examined the effect of Cr(VI) and As(V) on each other by studying the simultaneous removal of chromate and arsenate ions. Isotherm, kinetic, and thermodynamic analyses on the experimental data obtained were conducted. The results showed that the pH of the solution is affecting the charge density of PEI, and at pH 4, the lower value that was examined, the SiO₂-PEI exhibited higher adsorption capacity. The presence of other anions, such as phosphate, nitrate, and sulfate ions, had an adverse effect on the adsorption capacity of the SiO₂-PEI material for both chromate and arsenate ions. The adsorption capacity of arsenate was more affected by the presence of other anions compared to the chromate, and the higher impact was observed by the sulfate ions at pH 4, on the contrary for the chromate ions the higher impact was observed by the sulfate ions at pH 7 and by the phosphate ions at pH 4. Concerning the effect of temperature, the adsorption is an exothermic process and it was more favorable at lower environmental temperature. The study of simultaneous removal of Cr(VI) and As(V) declares the material's ability to accommodate both types of ions without requiring separate treatment steps. Addressing the simultaneous removal is essential for reducing the complexity of water treatment systems, lowering operational costs, and improving the safety of treated water.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polyethersulfone mixed matrix membranes modified with pore formers and Ag-titanate nanotubes: physicochemical characteristics and (bio)fouling study.","authors":"Amanda Sałacińska, Paulina Sienkiewicz, Kacper Szymański, Sylwia Mozia","doi":"10.1007/s11356-024-35461-6","DOIUrl":"https://doi.org/10.1007/s11356-024-35461-6","url":null,"abstract":"<p><p>In the presented studies it was hypothesized that the modification of a polymeric membrane with a pore former and a hybrid nanomaterial composed of titanate nanotubes with deposited Ag nanoparticles (Ag-TNTs NPs) can protect the membrane from the microbial growth, and thus enhance its resistance to biofouling. Polyethersulfone (PES) membranes were prepared by the wet phase inversion, and polyvinylpyrrolidone (PVP) and poly(ethylene glycol) (PEG) were used as pore formers. The membranes were characterized in terms of morphology, topography, permeability, separation characteristics, and anti-(bio)fouling properties as well as antibacterial activity. The membranes modified with porogens and Ag-TNTs revealed improved hydrophilicity and water permeability compared to the unmodified membrane, from 58 to 66%. Moreover, the improvement in rejection of model dextrans and PEG upon application of the NPs was found. However, the use of PVP or PEG had a negative influence on the resistance to fouling by bovine serum albumin, i.e., ca. 35% of decline of permeate flux was noticed after 2 h of ultrafiltration of BSA. On the contrary, both porogens and NPs contributed to biofouling mitigation. The introduction of pore formers had a positive effect on the inhibition of Escherichia coli growth by the membrane containing Ag-TNTs. The log reduction of bacteria varied from 3.17 to 3.3 in case of stirred and filtration system.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photoelectrocatalytic degradation of organophosphate esters using tio₂ electrodes produced from 3d-printed ti substrates.","authors":"Gustavo C Tedesco, Belisa L Soares, Enelton Fagnani, Joyce Cristale, Cynthia A Joll, David J Henry","doi":"10.1007/s11356-024-35465-2","DOIUrl":"https://doi.org/10.1007/s11356-024-35465-2","url":null,"abstract":"<p><p>3D printed electrode substrates with novel geometries may significantly improve the efficacy of photoelectrocatalysis for degradation of recalcitrant pollutants such as organophosphate flame retardants (OPFRs). However, the 3D printed substrates often have an irregular topology that can lead to a less uniform arrangement of nanotubes following anodisation. This study investigated the effect of polishing 3D-printed Ti substrates prior to anodisation to form TiO₂ nanotube array electrodes, and their subsequent applicability for photoelectrocatalytic treatment of OPFRs in water matrices. Polished and non-polished electrodes exhibited differences in morphology in terms of average roughness, (0.38 and 3.10 µm, respectively), leading to more uniform TiO₂ nanotubes of the former. Water contact angle measurements revealed the non-polished electrode was super-hydrophilic and the polished electrode hydrophilic (water contact angles of 6.4˚ and 16.1˚, respectively). Despite these differences, the polished and non-polished electrodes exhibited very similar electrochemical responses. In fact, the purity and electrical conductivity of water matrices affected the photoelectrocatalytic performance more than the electrode morphology. The purified water (PW) matrix facilitated the highest degradation/removal of OPFRs, compared to tap water matrices. In particular, individual OPFR degradation levels in PW were 74% ± 9, 37% ± 10, 33% ± 9, 31% ± 11 and 3% ± 5 for triphenyl phosphate, tris(butyl) phosphate, tris(isobutyl) phosphate, tris(2-butoxyethyl) phosphate and tris(2-chloroisopropyl) phosphate, respectively. The removal of OPFRs was relative to their reactivity to hydroxyl radicals, which was higher for the aryl then alkyl straight-chain and then chlorinated compounds. This study reveals that polishing of electrode substrates is not required for the preparation of effective photoelectrocatalytic reactors to treat recalcitrant pollutants (e.g. OPFRs), Importantly, future development of novel high-profile 3D printed electrode will not be hindered by the requirement to polish the substrates prior to anodisation.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}