Environmental Science and Pollution Research最新文献

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Stacked Ensemble with Machine Learning Regressors on Optimal Features (SMOF) of hyperspectral sensor PRISMA for inland water turbidity prediction. 高光谱传感器 PRISMA 的最佳特征机器学习回归器堆叠集合(SMOF)用于内陆水域浊度预测。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-25 DOI: 10.1007/s11356-024-35481-2
Rajarshi Bhattacharjee, Shishir Gaur, Shard Chander, Anurag Ohri, Prashant K Srivastava, Anurag Mishra
{"title":"Stacked Ensemble with Machine Learning Regressors on Optimal Features (SMOF) of hyperspectral sensor PRISMA for inland water turbidity prediction.","authors":"Rajarshi Bhattacharjee, Shishir Gaur, Shard Chander, Anurag Ohri, Prashant K Srivastava, Anurag Mishra","doi":"10.1007/s11356-024-35481-2","DOIUrl":"https://doi.org/10.1007/s11356-024-35481-2","url":null,"abstract":"<p><p>Leveraging hyperspectral data across various domains yields substantial benefits, yet managing many spectral bands and identifying the essential ones poses a formidable challenge. This study identifies the most relevant bands within a hyperspectral data cube for turbidity prediction in inland water. Nine machine learning regressors Cat Boost, Decision Trees, Extra Trees, Gradient Boost, Light Gradient Boost (LightGBM), Recursive Feature Elimination (RFE), Random Forest, Support Vector Regressor (SVR), and Xtreme Gradient Boost (XGBoost) have been used to compute the feature importance of the hyperspectral bands for predicting turbidity. Random Forest has outperformed the other models with a mean absolute percentage error (MAPE) of 1.61%, and the R<sup>2</sup> of the linear fit is 0.96. Band 77, with a central wavelength of 1067.61 nm, is the most dominating band regarding feature importance. We have also developed a novel framework for turbidity prediction: Stacked Ensemble with Machine Learning Regressors on Optimal Features (SMOF). It employs a stacking ensemble of the nine regressors mentioned above with Random Forest as both base and meta-model, leveraging feature selection outputs. With this framework, the MAPE (%) reached 1.21, while the R<sup>2</sup> stood at 0.95. The present study also presents a simple statistical algorithm to detect noisy bands in the Hyperspectral Precursor of the Application Mission (PRISMA) data cube. The approach assesses quadrat-wise intra-band spatial coherence using Renyi's entropy thresholding for noisy band segregation. Radiometric calibration error and absorption due to water vapour are the two primary sources of noise within the data cube. Moreover, this research implements the open-source Water Colour Simulator (WASI) to simulate inland water spectra with varied proportions of turbidity. Overall, the study presents an approach to identify noisy bands and integrates the potential wavelengths for turbidity prediction of inland waters.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142708506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The method of radiation risk assessment based on physico-geographical regionalisation: a case study of Carpathians, Poland. 基于物理地理区域化的辐射风险评估方法:波兰喀尔巴阡山脉案例研究。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-25 DOI: 10.1007/s11356-024-35518-6
Filip Jędrzejek, Katarzyna Szarłowicz, Marcin Stobiński
{"title":"The method of radiation risk assessment based on physico-geographical regionalisation: a case study of Carpathians, Poland.","authors":"Filip Jędrzejek, Katarzyna Szarłowicz, Marcin Stobiński","doi":"10.1007/s11356-024-35518-6","DOIUrl":"https://doi.org/10.1007/s11356-024-35518-6","url":null,"abstract":"<p><p>Radiological assessment of the environment in expansive territories poses significant challenges due to the complexity of spatial and environmental variables. The aim of this study was to use and present the advantages of a physico-geographical regionalisation methodology to improve the precision and effectiveness of radiological assessments in large areas. The study area was a region of the Polish Carpathian mountains with a territory of 19,600 km<sup>2</sup>. By integrating geographic information systems (GIS) and radiological data, this research analysed a similarity of environmental attributes (soil type, lithology, mineralogy) and absorbed dose rate (ADR) level from the terrestrial origin for populations. Consistency in terms of the nature and origin of the relief and lithological diversity was a key aspect that distinguished the radiological characteristics. Therefore, consistency was observed at the macroregional level according to physiographic mapping. The study demonstrates the utility of macroregionalisation in capturing spatial ADR heterogeneity and provides a new strategy in radiological monitoring.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142708534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatiotemporal distribution and source analysis of PM2.5 and its chemical components in national industrial complexes of Korea: a case study of Ansan and Siheung. 韩国国家工业园区 PM2.5 及其化学成分的时空分布和来源分析:安山和始兴案例研究。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-24 DOI: 10.1007/s11356-024-35537-3
Shin-Young Park, Hyeok Jang, Jaymin Kwon, Yong-Sung Cho, Jung-Il Lee, Cheol-Min Lee
{"title":"Spatiotemporal distribution and source analysis of PM<sub>2.5</sub> and its chemical components in national industrial complexes of Korea: a case study of Ansan and Siheung.","authors":"Shin-Young Park, Hyeok Jang, Jaymin Kwon, Yong-Sung Cho, Jung-Il Lee, Cheol-Min Lee","doi":"10.1007/s11356-024-35537-3","DOIUrl":"https://doi.org/10.1007/s11356-024-35537-3","url":null,"abstract":"<p><p>This study investigated the sources and distribution characteristics of PM<sub>2.5</sub> and its chemical components (ions, carbons, elements) at five locations within the Banwal and Sihwa National Industrial Complexes in Ansan and Siheung. These large-scale industrial clusters, comprising 7642 businesses across sectors such as petrochemicals, steel, machinery, and electronics, operate throughout the year. From 2020 to 2023, the average PM<sub>2.5</sub> concentration in the study area was 28.66 ± 16.72 μg/m<sup>3</sup>, with notable seasonal differences observed across the five measurement points. Ionic components were the primary contributors to PM<sub>2.5</sub>, while carbon and trace element concentrations fluctuated with the seasons. The coefficient of divergence (COD) analysis indicated that emission source differences between sites were insignificant, with COD values consistently below the threshold of 0.3. Hierarchical cluster analysis (HCA) and principal component analysis (PCA) identified secondary aerosols and vehicle emissions as the main sources of PM<sub>2.5</sub>, alongside additional contributions from Asian dust, industrial emissions, road dust, coal combustion, metal processing, biomass burning, and soil dust. These results highlight the need for systematic and economical air pollution control strategies in complex industrial areas, using COD to identify source differences and quantify contributions at different sites.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of inorganic component of biochar on lead adsorption performance and the enhancement by MgO modification. 生物炭中无机成分对铅吸附性能的影响以及氧化镁改性对铅吸附性能的增强。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-24 DOI: 10.1007/s11356-024-35556-0
Stephen Johnson Khamis Yesto, Hongru Shang, Xiaohong Lv, James Taban Abdalla, Tengfei Wang, Yanling Yu
{"title":"Effect of inorganic component of biochar on lead adsorption performance and the enhancement by MgO modification.","authors":"Stephen Johnson Khamis Yesto, Hongru Shang, Xiaohong Lv, James Taban Abdalla, Tengfei Wang, Yanling Yu","doi":"10.1007/s11356-024-35556-0","DOIUrl":"https://doi.org/10.1007/s11356-024-35556-0","url":null,"abstract":"<p><p>Biomass-derived biochar has enormous potential for sustainable and low-cost treatment of lead-contained wastewater. In this study, corncob and cow dung-derived biochar were prepared. The increase in pyrolysis temperature could improve the porous structures, surface area, functional groups and alkalinity, and further provide a higher Pb<sup>2+</sup> capacity in both biochars. Cow dung biochar performed better than corncob for its higher inorganic mineral content and more alkaline surface. Among them, CDB-600 performed the Langmuir maximum capacity of 357.1 mg/g, with a high surface area of 144.3 m<sup>2</sup>/g; ion exchange and precipitate were the main adsorption mechanisms. After further MgO modification, the M-CDB displayed a high surface area of 166 m<sup>2</sup>/g, and ion exchangeability and precipitate-promoting effects were improved. M-CDB performed a Langmuir maximum capacity of 833.3 mg/g. The pHpzc was found to be 10 and the adsorbents portray a very good Pb<sup>2+</sup> adsorption selectivity among coexisting ions in the solution. The adsorption process was found to be endothermic, feasible, spontaneous and chemisorption. The fixed lead on CDB-600 was stable in water. The immobilized lead could be desorbed by acid wash. CDB-600 performed better in terms of sustainability in use, which could support its continuous application ability.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seed priming with cold plasma, iron, and manganese nanoparticles modulates salinity stress in hemp (Cannabis sativa L.) by improving germination, growth, and biochemical attributes. 用冷等离子体、铁和锰纳米粒子进行种子处理,可通过改善大麻(Cannabis sativa L.)的发芽、生长和生化属性来调节其盐度胁迫。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35590-y
Samaneh Ghasempour, Marzieh Ghanbari Jahromi, Amir Mousavi, Alireza Iranbakhsh
{"title":"Seed priming with cold plasma, iron, and manganese nanoparticles modulates salinity stress in hemp (Cannabis sativa L.) by improving germination, growth, and biochemical attributes.","authors":"Samaneh Ghasempour, Marzieh Ghanbari Jahromi, Amir Mousavi, Alireza Iranbakhsh","doi":"10.1007/s11356-024-35590-y","DOIUrl":"https://doi.org/10.1007/s11356-024-35590-y","url":null,"abstract":"<p><p>Using cutting-edge technologies such as non-thermal plasma and metallic nanoparticles has shown promise in ameliorating salinity-induced stress in plants. However, there are still knowledge gaps concerning the most effective strategies for mitigating salinity stress in hemp (Cannabis sativa L.) plants. Consequently, this study was undertaken to investigate the impact of seed priming with cold plasma (CP), iron (Fe), and manganese (Mn) nanoparticles (NPs) on salinity modulation in hemp plants, aiming to improve seed germination, plant growth, and biochemical attributes. A pot experiment was conducted with salinity at three levels (0, 60, and 120 mM NaCl) and seed priming at five levels (control, 60 s CP, 90 s CP, 50 mg L<sup>-1</sup> Fe NPs, and 50 mg L<sup>-1</sup> Mn NPs). The results showed that salinity at 120 mM decreased germination percentage (GP, 34%), germination speed (GS, 61%), seedling vigor index (SVI, 47%), shoot weight (38%), root weight (15%), chlorophyll (Chl) a + b (31%), and relative water content (RWC, 24%) while increasing malondialdehyde (MDA, 48%) and proline (39%). Seed priming with CP, Fe NPs, and Mn NPs increased plant weight, GP, GS, SVI, RWC, and Chl but decreased MDA accumulation. Fe NPs and salinity at 60 mM led to high levels of total phenolic content and total flavonoid content, which represent 29 and 44% increases, respectively, compared to the control. The heat map showed that among the treatments, GS and SVI had the highest degrees of variability. Fe NPs at 50 mg L<sup>-1</sup> and CP at 90 s produced the best plant tolerance to salt stress.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Translocation mechanism and the role of aerenchyma in nanoplastic translocation in Myriophyllum sp. "Roraima" and physiological responses. "Roraima "叶绿藻的转运机制和气孔在纳米塑料转运中的作用以及生理反应。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35606-7
Zhaozhi Liu, Mudalige Don Hiranya Jayasanka Senavirathna, Takeshi Fujino, Yasuko Kaneko
{"title":"Translocation mechanism and the role of aerenchyma in nanoplastic translocation in Myriophyllum sp. \"Roraima\" and physiological responses.","authors":"Zhaozhi Liu, Mudalige Don Hiranya Jayasanka Senavirathna, Takeshi Fujino, Yasuko Kaneko","doi":"10.1007/s11356-024-35606-7","DOIUrl":"https://doi.org/10.1007/s11356-024-35606-7","url":null,"abstract":"<p><p>Nanoplastics have become a growing concern due to their potential impact on freshwater vegetation. The uptake, translocation, and effects of 0.05-µm nanoplastics on Myriophyllum sp. \"Roraima\" were investigated, along with the role of aerenchyma in nanoplastic transport. Microscopic observations revealed nanoplastic particle adsorption to the plant surface and entry into the roots and stems, with higher abundance and more dispersed distribution by direct contact. Nanoplastic particles were detected in the plant stem, primarily concentrated in regions adjacent to the aerenchyma. No morphological effects were observed. Induced changes in photosynthesis, including increased maximum quantum efficiency of photosystem II (Fv/Fm), decreased non-photochemical quenching (NPQ), decreased photosynthetic pigments, and increased photoprotective pigments, were recognized. Additionally, hydrogen peroxide levels and antioxidant enzyme activities varied in response to nanoplastic exposure. This study provides insights into the impact of nanoplastics on Myriophyllum sp. \"Roraima\" and has reviewed the underlying mechanisms, highlighting the role of aerenchyma in nanoplastic transport within the plant. Moreover, this study contributes to the understanding of the potential impacts of nanoplastic pollution on freshwater macrophytes while acknowledging the influence of phyto-anatomical structure on nanoplastic translocation.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of RT-LAMP assay for detection of lead and cadmium toxicity using HepG2 cells. 利用 HepG2 细胞开发 RT-LAMP 检测铅和镉毒性的方法。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35544-4
Sanjay Sharma, Ankita Kapri, Mansi Joshi, Suneel Kumar Onteru, Dheer Singh
{"title":"Development of RT-LAMP assay for detection of lead and cadmium toxicity using HepG2 cells.","authors":"Sanjay Sharma, Ankita Kapri, Mansi Joshi, Suneel Kumar Onteru, Dheer Singh","doi":"10.1007/s11356-024-35544-4","DOIUrl":"https://doi.org/10.1007/s11356-024-35544-4","url":null,"abstract":"<p><p>Heavy metals such as lead and cadmium are prevalent in the environment. These are harmful to living beings even at lower concentrations as they persist in the body for years and lead to the development of severe diseases. Therefore, the present work was designed to develop a rapid and field-applicable cell-based assay for quick detection of lead and cadmium in biofluids using an RNA biomarker. The RNA biomarker was identified by analyzing the impact of these heavy metals on the gene expression of candidate genes using HepG2 cells. The results showed that the gene expression of AhR pathway-related genes, apoptosis-related genes, MAPK1, and HMOX1 were significantly increased after lead and cadmium treatments (P < 0.05). Interestingly, the gene expression of HMOX1 was increased linearly up to fivefold in a dose and time-dependent manner in the case of both heavy metals which also correlated with an increased secretion of bilirubin from the cells after 6 h treatment. Therefore, the RT-LAMP assay was developed for lead and cadmium toxicity using HMOX1. The positive amplification was visualized in the form of color change of HNB dye from violet to blue in 30 min. Additionally, standard curves were also prepared for the RT-LAMP color change after treatment with different concentrations of lead and cadmium for their quantification in unknown samples. The developed RT-LAMP assay was also validated using lead and cadmium-spiked milk samples. The ROC curve analysis showed 100% sensitivity and specificity for both heavy metals above their MRL value in infant milk substitutes and infant foods. This assay can be utilized for early detection of heavy metals in common food items such as milk.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142692501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Small intestine structural and functional responses to environmental heavy metal stress in tree sparrow Passer montanus nestlings. 树麻雀雏鸟对环境重金属胁迫的小肠结构和功能反应
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35587-7
Fei Jin, Yue Shen, Zhaocun Lin, Yuquan Miao, Yu Liu, Rui Su, Wenya Zhang, Yingmei Zhang
{"title":"Small intestine structural and functional responses to environmental heavy metal stress in tree sparrow Passer montanus nestlings.","authors":"Fei Jin, Yue Shen, Zhaocun Lin, Yuquan Miao, Yu Liu, Rui Su, Wenya Zhang, Yingmei Zhang","doi":"10.1007/s11356-024-35587-7","DOIUrl":"https://doi.org/10.1007/s11356-024-35587-7","url":null,"abstract":"<p><p>Tree sparrow nestlings predominantly consume protein-rich insect larvae, making them vulnerable to environmental heavy metal contamination through the food web, potentially affecting their growth. Understanding the effects of heavy metals on the structure and function of the small intestine, the principal organ responsible for protein digestion and absorption, is therefore crucial. This study investigated tree sparrow nestlings at three developmental stages (3, 6, and 12 days old) in Liujiaxia (LJX), a comparatively unpolluted area, and Baiyin (BY), a heavy metal polluted area, to elucidate the factors and mechanisms by which heavy metals affect nutrient absorption. We compared heavy metal accumulation levels, structural integrity, and protein digestion and absorption functions of the duodenum, jejunum, and ileum. The increase of fluctuating asymmetry and decrease in body condition in tree sparrow nestlings were found to be associated with environmental heavy metal accumulation in the small intestine. Structural impairments of villi and crypts were observed in the duodenum and jejunum of tree sparrow nestlings at 3-, 6-, and 12-day-old in the polluted site BY. Conversely, structures related to the ileum were elevated, and the small intestine of nestlings at all stages exhibited abnormally elevated protein digestibility but diminished absorption of amino acids. However, there was no significant difference in small peptide absorption. These findings indicate that environmental heavy metal pollution impacts the structure of the small intestine in tree sparrow nestlings through the food chain and further affects their digestion and absorption function of proteins.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of VOC vapors on ZnPc: sensing and kinetic studies. ZnPc 对挥发性有机化合物蒸汽的吸附:传感和动力学研究。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35576-w
Vildan Yılmaz, Nursel Can, Ahmet Altındal
{"title":"Adsorption of VOC vapors on ZnPc: sensing and kinetic studies.","authors":"Vildan Yılmaz, Nursel Can, Ahmet Altındal","doi":"10.1007/s11356-024-35576-w","DOIUrl":"https://doi.org/10.1007/s11356-024-35576-w","url":null,"abstract":"<p><p>Thin film of sensing unit, 2,3,9,10,16,17-hexakis(3-dietylaminophenoxy)-23-etynylphenyl-(2-ferrocenyl-o-carborane)phthalocyaninato zinc(II) (ZnPc), have been deposited by spray pyrolysis technique on the quartz crystal surface with a fundamental resonance frequency of 10 MHz. The surface morphology of the film has been studied using the contact mode atomic force microscope (AFM) technique and the average surface roughness was determined to be 36.4 nm. Then, this film was exposed to the vapors of methanol, ethanol, 2-propanol, and 1-butanol with various concentrations varying between 50 and 400 ppm. In addition, studies on response time and repeatability of the sensors have also been carried out. Films exhibit maximum sensing response to methanol vapor while the lowest sensitivity of the film towards 1-butanol has been observed. After an exposure time of 10 min, the frequency shift of 415 Hz was recorded for 400 ppm methanol vapor concentration, while a frequency shift of 215 Hz was observed for the same concentration of 1-butanol. The sensor was 1.30 times more sensitive to methanol vapor than ethanol and 2.00 times more sensitive to methanol than to 1-butanol. Variations in the sensitivity of the sensor have been correlated with the number of carbon groups in analyte vapors. The effect of the number of carbon groups in analyte molecule on adsorption kinetics of the film has also been investigated and compared. Adsorption isotherms of four volatile organic compounds on ZnPc were investigated at room temperature and the experimental data obtained were correlated with different existing adsorption isotherm models such as the Langmuir, the Freundlich, and Temkin model. An overall evaluation of the obtained results showed that the sensing performance, adsorption kinetic, and adsorption isotherms are dependent on the molecular size of the analyte molecules.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of PAEs in some dairy products (yogurt and kashk) using method of MSPE-GC/MS: a health risk assessment study. 利用 MSPE-GC/MS 方法调查某些乳制品(酸奶和卡什克)中的 PAEs:一项健康风险评估研究。
IF 5.8 3区 环境科学与生态学
Environmental Science and Pollution Research Pub Date : 2024-11-23 DOI: 10.1007/s11356-024-35543-5
Mojtaba Moazzen, Amir Mohammad Mortazavian, Nabi Shariatifar, Sara Sohrabvandi, Elham Khanniri, Majid Arabameri
{"title":"Investigation of PAEs in some dairy products (yogurt and kashk) using method of MSPE-GC/MS: a health risk assessment study.","authors":"Mojtaba Moazzen, Amir Mohammad Mortazavian, Nabi Shariatifar, Sara Sohrabvandi, Elham Khanniri, Majid Arabameri","doi":"10.1007/s11356-024-35543-5","DOIUrl":"https://doi.org/10.1007/s11356-024-35543-5","url":null,"abstract":"<p><p>In this study, MSPE-GC/MS method (magnetic solid phase extraction-gas chromatography/mass spectrometry) was applied to analyze six PAEs in yogurt and kashk samples. According to our findings, in all samples, the mean of Bis (2-ethylhexyl)phthalate (DEHP) was 2.00 ± 0.87, and the mean total PAEs was 8.33 ± 2.26 µg/kg, which the mean of all phthalates was less than the existing standards (EFSA (The European Food Safety Authority) and US EPA (U.S. Environmental Protection Agency)). Also, the mean of DEHP and total PAEs in kashk samples were 2.43 ± 1.02 and 10.07 ± 1.06 µg/kg, respectively, and in yogurt samples were 1.57 ± 0.36 and 6.59 ± 1.26 µg/kg, respectively. Furthermore, the mean of total PAEs at the time of expiration date (9.09 ± 2.36 µg/kg) was higher than the production date (7.57 ± 1.92 µg/kg), and the samples with a higher volume of the container had a higher amount of total PAEs (8.88 ± 2.48 µg/kg) than the samples with a smaller volume of the container (7.78 ± 1.92 µg/kg). Various indices (CDI (chronic daily intake), THQ (target hazard quotient), and ILCR (incremental lifetime cancer risk)) were applied to estimate risks of human health. Likewise, the technique of Monte Carlo was employed for probabilistic non-carcinogenic and carcinogenic risk assessment via oral exposure in adults and children. The CDI of PAEs detected via yogurt and kashk consumption was less than the tolerable daily intake. Eventually, a probabilistic model with Monte Carlo simulation showed that the THQ and the ILCR were far less than the unacceptable risk (1 > THQ and 10<sup>-6</sup> > ILCR). Finally, according to the results obtained, it can be concluded the consumption of yogurt and kashk does not pose any threat to Iranian consumers (children and adults).</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142695053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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