Bruno I E Heredia, Brenda V Canizo, Ana L Diedrichs, Jorgelina C Altamirano, Ruth Clausen, Estefanía M Martinis, Pamela Y Quintas
{"title":"Air quality monitoring in Mendoza, Argentina: machine learning approaches for PM<sub>10</sub> prediction.","authors":"Bruno I E Heredia, Brenda V Canizo, Ana L Diedrichs, Jorgelina C Altamirano, Ruth Clausen, Estefanía M Martinis, Pamela Y Quintas","doi":"10.1007/s11356-025-36657-0","DOIUrl":"https://doi.org/10.1007/s11356-025-36657-0","url":null,"abstract":"<p><p>In this study, different statistical methodologies were combined to assess the relationship between PM<sub>10</sub> concentrations and meteorological variables (temperature, relative humidity, wind direction and speed, and atmospheric pressure) and their associations with other pollutants (CO, NO<sub>2</sub>, NO, and O<sub>3</sub>) recorded during the period 2021-2024 at Mendoza City, Argentina. The results indicate that increased humidity and temperature might reduce PM<sub>10</sub> levels by enhancing particle dispersion and deposition. Positive correlations between PM<sub>10</sub>, NO, and NO<sub>2</sub> suggest a shared origin, likely from vehicle emissions. To further analyze PM<sub>10</sub> behavior, prediction models were developed to categorize PM<sub>10</sub> levels as \"good\" (≤ 45 μg/m<sup>3</sup>) or \"bad\" (>45 μg/m<sup>3</sup>) based on a air quality guidelines from WHO. The performance of the random forest (RF) and logistic regression (LR) algorithms were evaluated and compared. Additionally, the influence of atmospheric variables and pollutant concentrations was also assessed to determine their impact on PM<sub>10</sub> predictions. RF model demonstrated the highest predictive performance for PM<sub>10</sub> level. Results indicate that NOx (NO<sub>2</sub> and NO) significantly contribute to PM<sub>10</sub> formation, likely due to shared anthropogenic sources. Temperature, humidity, and wind speed also impact PM<sub>10</sub> predictions, though to a lesser extent than pollutant concentrations. The inclusion of these variables highlights the role in the dispersion and transformation of air pollutants. Implementing such models could provide policymakers with real-time data to enhance pollution control and public health protection.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144537641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergistic photocatalysis: enhanced degradation of organic dyes using a heterojunction nanocomposite of high-surface-area g-C<sub>3</sub>N<sub>4</sub> and TiO<sub>2</sub> - WO<sub>3</sub> - Bi<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub>.","authors":"Rezvan Abdollahpour, Amin Bazyari","doi":"10.1007/s11356-025-36664-1","DOIUrl":"https://doi.org/10.1007/s11356-025-36664-1","url":null,"abstract":"<p><p>High-performance nanocomposites of high-surface-area (HSA) g-C<sub>3</sub>N<sub>4</sub> and TiO<sub>2</sub>-WO<sub>3</sub>-Bi<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> (g-C<sub>3</sub>N<sub>4</sub>/TSBW) were successfully synthesized and evaluated for their photocatalytic degradation of organic dyes in aqueous solution under visible light irradiation. The photocatalysts were characterized using XRD, N<sub>2</sub> adsorption-desorption, FE-SEM, EDS, HR-TEM, FTIR, Raman spectroscopy, UV-Vis DRS, and PL spectroscopy. The study investigated the effects of g-C<sub>3</sub>N<sub>4</sub> content, photocatalyst loading, dye concentration and type, solution pH, scavengers, and oxidants on the photocatalytic degradation process. The g-C<sub>3</sub>N<sub>4</sub> photocatalyst, with a high surface area of approximately 100 m<sup>2</sup>/g, exhibited a combined adsorption and photocatalytic degradation effect for rhodamine B (RhB) removal. Notably, nearly 100% RhB degradation was achieved using 1 g/L of the optimized 50% g-C<sub>3</sub>N<sub>4</sub>/TSBW heterojunction photocatalyst with an initial RhB concentration of 10 mg/L after only 20 min of visible light exposure. This high performance resulted from the synergistic effect of combining g-C<sub>3</sub>N<sub>4</sub> with TSBW, facilitated by the formation of a type II heterojunction between TiO<sub>2</sub> and g-C<sub>3</sub>N<sub>4</sub>, which effectively suppressed the recombination of photoinduced charge carriers. Trapping experiments provided mechanistic insights into RhB photocatalytic degradation, revealing the significant contribution of superoxide radicals (•O<sub>2</sub><sup>-</sup>). Based on these trapping experiments, a plausible photocatalytic reaction mechanism was proposed. Finally, the recyclability of the 50% g-C<sub>3</sub>N<sub>4</sub>/TSBW heterojunction photocatalyst was also demonstrated.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144537668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Asma Siddiqa, Most Halima Khatun, Md Golam Mostafa
{"title":"Green-synthesized magnetite-maghemite nanocomposites for the removal of lead and cadmium from water: competitive adsorption behavior and mechanism studies.","authors":"Asma Siddiqa, Most Halima Khatun, Md Golam Mostafa","doi":"10.1007/s11356-025-36688-7","DOIUrl":"https://doi.org/10.1007/s11356-025-36688-7","url":null,"abstract":"<p><p>The environment and human health are at risk when industrial waste leaks into aquatic environments. Green-synthesized magnetite-maghemite nanocomposites (GSMMNs) were developed in this study as bio-synthesized adsorbents for removing heavy metals from water. The XRD, TEM, FT-IR, SEM-EDS, BET, VSM, and XPS analyses characterized the nanocomposites. The average particle size was 13.76 nm by TEM analysis with a surface area of 158 m<sup>2</sup>/g. The functional groups (C = O) and mixed Fe<sup>2</sup>⁺/Fe<sup>3</sup>⁺ states contribute to the adsorption confirmed by FT-IR and XPS. Batch studies showed optimal adsorption at pH 6.5, 1.5 g/L dose, 30 °C, and 20-30 min contact time (initial concentration 5 mg/L). Pb(II) and Cd(II) have maximal adsorption capacities of 35 mg/g and 15 mg/g, respectively, which decrease to 19 mg/g and 8.1 mg/g as a result of their antagonistic effects. The single and binary systems are followed by Langmuir and Sip models, respectively with a pseudo-second-order kinetic model (R<sup>2</sup> = 0.99). An antagonistic effect was observed in the binary solution of Pb(II) and Cd(II), based on mathematical modeling. Co-existing ions and ionic strength have an impact on the adsorption following the sequence (PO₄<sup>3</sup>⁻ > CO<sub>3</sub><sup>2</sup>⁻ > SO₄<sup>2</sup>⁻ > Ca<sup>2</sup>⁺ > NO₃⁻ > Cl⁻ > K⁺). In a real water matrix, the adsorbent showed performance following the sequence: deionized water > tube well water > tap water > river water. The GSMMNs showed promising potential as a cost-effective adsorbent with five regeneration cycles.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144537653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sadaf Saeed, Awais Manzoor, Arslan Haider, Tahrim Ramzan, Hafeez Ur Rehman, Muhammad Ahmad, Shahzad Bashir, Usman Zulfiqar, Muhammad Nazim, Muhammad Faisal Maqsood, Waleed A A Alsakkaf, Hayssam M Ali
{"title":"Alleviating cadmium-induced stress in maize: the role of zinc sulphate application on growth and biochemical responses.","authors":"Sadaf Saeed, Awais Manzoor, Arslan Haider, Tahrim Ramzan, Hafeez Ur Rehman, Muhammad Ahmad, Shahzad Bashir, Usman Zulfiqar, Muhammad Nazim, Muhammad Faisal Maqsood, Waleed A A Alsakkaf, Hayssam M Ali","doi":"10.1007/s11356-025-36568-0","DOIUrl":"https://doi.org/10.1007/s11356-025-36568-0","url":null,"abstract":"<p><p>Cadmium stress (Cd) damages plant growth and development by causing oxidative damage and plant physiological and biochemical attributes. However, zinc sulphate (ZnS) may act as an acute stress signal to alleviate the toxic effects of Cd stress by upregulating the antioxidant defense mechanism and enhancing nutrient absorption. This study aimed to evaluate the impact of ZnS foliar application on mitigating the toxic effects of Cd stress in maize seedlings. The treatments were a) ZnS applications (0 ppm, 20 ppm, and 40 ppm), b) maize varieties, V1 = Malka-16 and V2 = Sahiwal Gold, and Cd stress (0 mg kg<sup>-1</sup>, 20 mg kg<sup>-1</sup>, and 40 mg kg<sup>-1</sup>). Cadmium stress significantly reduced the growth and chlorophyll content in maize varieties as compared to the control. Results have revealed that plant growth and photosynthetic pigments were reduced under Cd stress as plant height and carotenoid contents decreased by 41.5 and 45.0% in Malka-16 and 12.7 and 50% in Sahiwal Gold compared to the control. Nutrient uptake was also significantly affected by Cd stress as calcium, phosphorus, potassium, and sodium were reduced in the roots, stems, and leaves in both maize varieties. However, ZnS treatments successfully reduced the toxicity of Cd stress in maize varieties and improved plant growth and development as compared to the control. Among the antioxidants, ascorbate (AsA), peroxidase (POD), catalase (CAT), and superoxide dismutase (SOD) were improved by 22.3, 12.8, 15.2, and 17.6% in Malka-16 and 18.0, 18.3, 16.2, and 18.8% in Sahiwal Gold by ZnS supplementations under Cd stress. Among both varieties of maize, Sahiwal Gold outperformed Malka-16 regarding plant morphophysiological, biochemical attributes, and nutrient uptake under Cd-stressed conditions. In crux, ZnS applications in maize decreased the toxicity of Cd stress by modifying the plant's antioxidant defense system. Zinc use is a promising strategy for sustainable agriculture since it enhances yield and quality and decreases cadmium deposition in edible plant parts.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cherifa Mezhoud, Ali Berreksi, Rachid Sahnoune, Abdelhamid Bedjou, Faiza Bouchraki
{"title":"The combination of PROMETHEE II and FAHP methods for prioritizing maintenance work in a sanitation network.","authors":"Cherifa Mezhoud, Ali Berreksi, Rachid Sahnoune, Abdelhamid Bedjou, Faiza Bouchraki","doi":"10.1007/s11356-025-36690-z","DOIUrl":"https://doi.org/10.1007/s11356-025-36690-z","url":null,"abstract":"<p><p>Currently, the management of wastewater systems is both a complex and costly problem. Urban infrastructure failures have become an increasing concern over the last few decades, as many structures are approaching the end of their useful life. Our contribution concerns the development of a decision support tool intended for sanitation service managers. This model focuses on prioritizing maintenance work on sanitation networks based on their level of degradation. The methodology developed is based on the combination of two methods, namely the Fuzzy Analytic Hierarchy Process (FAHP) and the Preference Ranking Organization METHod for Enrichment Evaluations (PROMETHEE II). The results of the first method show that the collapse criterion is the most important, with a weight of 30.74%, followed by the structural defect criterion (STR = 17.27%). The second method shows that the highest maintenance priority is assigned to manifold number 2, with a priority of 29.14%, followed by manifold number 10, with a priority of 13.28%. By combining FAHP and PROMETHEE II, this research demonstrates a successful approach to designing efficient network management and maintenance systems.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Correction to: Effect of Acetamiprid on Spatial Memory and Hippocampal Glutamatergic System.","authors":"Mohsen Shamsi, Maliheh Soodi, Shirin Shahbazi, Ameneh Omidi","doi":"10.1007/s11356-025-36659-y","DOIUrl":"https://doi.org/10.1007/s11356-025-36659-y","url":null,"abstract":"","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jingni Zhang, Hongjuan Wang, Huan Chen, Yong Liu, An Wang, Hongwei Hou, Qingyuan Hu
{"title":"Correction to: Acetaldehyde induces similar cytotoxic and genotoxic risks in BEAS‑2B cells and HHSteCs: involvement of differential regulation of MAPK/ERK and PI3K/AKT pathways.","authors":"Jingni Zhang, Hongjuan Wang, Huan Chen, Yong Liu, An Wang, Hongwei Hou, Qingyuan Hu","doi":"10.1007/s11356-025-36686-9","DOIUrl":"https://doi.org/10.1007/s11356-025-36686-9","url":null,"abstract":"","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Are we eating microplastics with our staple food? A pioneering study of microplastic contamination in store-bought rice and cooked rice in Bangladesh.","authors":"Moriom Akter Urmi, Md Rokonujjaman Khan, Ayman Alrehaili, Md Mostafizur Rahman","doi":"10.1007/s11356-025-36671-2","DOIUrl":"https://doi.org/10.1007/s11356-025-36671-2","url":null,"abstract":"<p><p>Microplastics (MPs) pollution in food is becoming a rising concern around the world. In Bangladesh, previous studies found MPs in various food items including sugar, tea, salt, and fish. However, research on MPs contamination in Bangladesh is still missing. Therefore, for the first time, this study investigated the abundance, distribution and chemical composition of MPs in rice of Bangladesh. Rice was assessed in raw and traditionally cooked form to estimate potential human exposure of MPs via rice in Bangladesh. 15 commonly consumed store-bought rice samples were analyzed for MPs contamination. Physical and chemical characteristics of MP's were detected using a stereomicroscope, and Fourier-transform infrared (FTIR) spectroscopy. MPs were detected in all samples, in raw rice the microplastic content was 67.20 ± 24.21 items/g and 32.47 ± 12.46 items/g in the cooked rice samples. Fragment shape, black and blue colour, and < 0.1 mm were the most prevalent characteristics observed. Nylon, nitrile, acrylonitrile butadiene styrene (ABS), polyvinyl chloride (PVC), and multiple other polymers were detected in both types of samples. This study found that traditional cooking process in Bangladesh can significantly reduce MPs from rice. But the presence of MPs in rice is high comparing to other countries. According to per capita rice consumption, an adult Bangladeshi intake approximately 15,226.87 ± 5843.59 items of MPs daily via rice. This finding of potential human exposure of MPs thorough rice intake in Bangladesh provides foundation for further research on health impacts associated with MPS and mitigation strategies.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Victoria Florencia Alcolea Ersinger, Daniela Lamas, Águeda Massa
{"title":"A review of marine collagens: approaches on extractions, applications, market, and future trends.","authors":"Victoria Florencia Alcolea Ersinger, Daniela Lamas, Águeda Massa","doi":"10.1007/s11356-025-36684-x","DOIUrl":"https://doi.org/10.1007/s11356-025-36684-x","url":null,"abstract":"<p><p>Collagen obtained from the fishing industry is a promising alternative source that utilizes by-products, representing a sustainable strategy for exploiting waste and raw materials within a circular economy. Numerous reviews have compiled data on the methodology of marine collagen extraction, its application, as well as market and future prospects. However, this information is scattered across various publications, providing also an incomplete picture of the geographical distribution of the research and the species used. Therefore, the aim of this review is to conduct a systematic search to compile all relevant information. Additionally, we emphasize update legislation, providing recommendations, and offering future perspectives. The analysis showed that the majority of studies (72%) were conducted in Asia, primarily in China, followed by Europe and South America. Almost 60% of the species studied are marine, followed by aquaculture ones. The studies cover a wide geographical area, mainly focusing on species under high fishing pressure, needing sustainable management measures. Of the traditional extraction methods, enzymatic extraction produces the best results. However, this method is time- and energy-consuming. Green alternatives using supercritical fluids and deep eutectic solvents have emerged, with the expectation of reducing extraction times and higher yields. Further development is crucial for industrial-level exploitation, addressing economic challenges. Collagen is used in a wide range of products, with dietary supplements being its main application, particularly in view of the aging population. Meanwhile, the global collagen market is expected to continue growing exponentially while legislation lags behind, failing to adapt to developments.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research on the law and mechanism of potential pollution of groundwater quality by grouting with cement-based materials.","authors":"Haobo Zheng, Ziwei Qian, Guowen Gao, Shenyang He, Gailing Zhang","doi":"10.1007/s11356-025-36676-x","DOIUrl":"https://doi.org/10.1007/s11356-025-36676-x","url":null,"abstract":"<p><p>In mining, the large amount of slurry used in grouting may harm groundwater quality and cause pollution. Therefore, researching the pollution effects of common grouting materials on regional groundwater is vital. A dynamic percolation reaction system was set up, and three sets of percolation tests were conducted for the ungrouted control (W), cement slurry (C), and cement-sodium silicate slurry (CS) groups. Their leachates were analyzed. The study found the following: (1) the slurry's hydration reactions greatly affect ionic contamination in the leachate. (2) After grouting, most ions in the leachate had high initial concentrations but decreased as percolation continued. The ionic concentration trends varied. Cement grouting caused metal ion contamination like Ca<sup>2+</sup>, while CS grouting led to high SO2- 4 levels. The main pollutants' degradation mostly follows an exponential decay model. (3) The leachate was alkaline after grouting, with increased total dissolved solids and reducing properties. Its hydrochemical type changed and gradually shifted towards that of the control group as percolation continued.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144511392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}