{"title":"Morphological Integrated Preparation Method and Implementation of Inorganic/Organic Dual-Phase Composite Gradient Bionic Bone Scaffold.","authors":"Haiguang Zhang, Yuping Wang, Qingxi Hu, Qiong Liu","doi":"10.1089/3dp.2022.0111","DOIUrl":"10.1089/3dp.2022.0111","url":null,"abstract":"<p><p>Large bone defects caused by congenital deformities and acquired accidents are increasing day by day. A large number of patients mainly rely on artificial bone for repair. However, artificial bone cannot fully imitate the structure and composition of human bone, resulting in a large gap with autologous bone function. Therefore, this article proposes a continuous preparation method for inorganic/organic biphasic composite gradient biomimetic bulk bone scaffolds. First, a controllable gradient hybrid forming platform for inorganic/organic dual-phase biomaterials was constructed, and the feeding control strategy was studied to achieve precise control of the feeding of sodium alginate/gelatin composite organic materials and hydroxyapatite inorganic materials. The speed is, respectively, sent from the corresponding feeding nozzle to the mixing chamber to realize the uniform mixing of the biphasic material and the extrusion of the composite material, and the inorganic/organic biphasic composite gradient biomimetic bone scaffold with gradual structure and composition is prepared. Second, to prove the superiority of the preparation method, the physicochemical and biological properties of the prepared scaffolds were evaluated. The test results showed that the morphological characteristics of the biphasic composite gradient bone scaffold showed good microscopic porosity and the structure and composition showed gradients. The mechanical properties are close to that of human bone tissue and <i>in vitro</i> cell experiments show that the scaffold has good biocompatibility and bioactivity. In conclusion, this article provides a new type of bone scaffold preparation technology and equipment for the field of tissue engineering, which has research value and application prospects.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057529/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43416580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Influence of Fused Deposition Modeling Parameters on the Properties of PA6/PA66 Composite Specimens by the Taguchi Method and Analysis of Variance.","authors":"Zhongbei Li, Youcai Liu, Zihai Liang, Yaochi Liu","doi":"10.1089/3dp.2022.0306","DOIUrl":"10.1089/3dp.2022.0306","url":null,"abstract":"<p><p>Fused deposition modeling (FDM) is widely used in the rapid prototyping of polymers. Polyamide (PA) has excellent mechanical properties, but its application in FDM is limited due to its high water absorption, warpage, and forming shrinkage. The material of the filament and the printing parameters of the printer are two critical aspects that affect the performance of a component. The prepared PA6/PA66 (composite polyamide [COPA], PA6:PA66 = 85:15) composite (COPA: acrylonitrile butadiene styrene [ABS]: maleic anhydride grafted acrylonitrile butadiene styrene [ABS-g-MAH]: polyethylene = 800:133:67:100) has low water absorption (0.39%) and high dimensional stability, which has a good application prospect in FDM. The influence of eight FDM parameters, including three rarely reported, on the properties of PA6/PA66 composite specimens was investigated by the Taguchi method. The significance of influencing factors was evaluated by analysis of variance (ANOVA) and the stability by signal-noise ratio. When the layer thickness was 0.15 mm, the infill pattern was zigzags, the build plate adhesion type was brim, and the distance from the nozzle to the printing platform and the layer thickness (ΔL) was 0.05 mm; the specimens' dimensional accuracy, surface quality, and mechanical properties were better than other levels. The layer thickness and infill pattern were the two most important factors. The switch of the cooling fan and the temperature printing platform played a significant role in the specimens' dimensional accuracy and surface quality. ΔL tremendously influenced the thickness and warping degree of the specimens. The preparation of high-performance PA composites and the investigation of multiparameters by the Taguchi method provide a possible solution for applying polyamide in FDM.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057551/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41869938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Roya Rezanavaz, Miruna Petcu, Marie-Joo Le Guen, Antoine Dubois
{"title":"Three-Dimensional Printing of Molecularly Imprinted Polymers by Digital Light Processing for Copper Ion Sequestration.","authors":"Roya Rezanavaz, Miruna Petcu, Marie-Joo Le Guen, Antoine Dubois","doi":"10.1089/3dp.2022.0107","DOIUrl":"10.1089/3dp.2022.0107","url":null,"abstract":"<p><p>Highly structured, molecularly imprinted polymer (MIP) networks for copper(II) ion sequestration have been realized using the additive manufacturing technology. Photopolymerizable formulations with acrylic functional monomers and two different porogens (water and methanol) in different ratios were studied to produce emulsions with 50 vol% of the internal phase. The results of morphological characterization indicate that all MIPs have cauliflower-like multiscale structures that change as a function of the solvent combination and fabrication process. X-ray fluorescence microscopy maps presented a layered structure and homogeneous distribution of copper in the printed MIP. Copper(II) ion adsorption-desorption tests were performed on MIPs prepared using a three-dimensional (3D) printing approach and MIPs prepared by bulk polymerization. Results indicate that the 3D printed MIP is able to absorb copper up to ten times more efficiently than the nonprinted one and the printed MIP with 100% water content has the highest imprint recognition.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057543/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42108831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Philipp Eyer, Sarah Enzler, Anna Trauth, Kay André Weidenmann
{"title":"Investigating the Mechanical Properties of Polymer Samples from Different Additive Manufacturing Processes Using Ultrasonic Phase Spectroscopy.","authors":"Philipp Eyer, Sarah Enzler, Anna Trauth, Kay André Weidenmann","doi":"10.1089/3dp.2022.0148","DOIUrl":"https://doi.org/10.1089/3dp.2022.0148","url":null,"abstract":"<p><p>Additive manufacturing processes have recently been used more frequently since they offer high design freedom and easy individualization of components. The processes have been optimized to improve mechanical performance of the manufactured parts. Nevertheless, properties of components made by means of injection molding could not be reached yet. In the study at hand, ultrasonic phase spectroscopy (UPS) is used to compare the elastic properties of acrylonitrile butadiene styrene specimens manufactured by injection molding, by fused filament fabrication, and the Arburg plastic freeforming process. UPS allows a nondestructive and prompt determination of the elastic modulus and allows evaluation of the mechanical properties in every direction in space. In the end, results of UPS are compared with properties derived by uniaxial tensile tests to validate UPS as a test method for the determination of the mechanical properties of polymers. Regardless of the manufacturing process, an approximately linear dependence of the elastic moduli on the density can be determined. Furthermore, the quasistatic properties of the injection molded samples consistently exhibit the mechanical properties of the other samples by at least 10%.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057542/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140861497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lixia Xi, Qiuyang Lu, Dongdong Gu, Shaoting Cao, Han Zhang, Ivan Kaban, Baran Sarac, Konda Gokuldoss Prashanth, Jürgen Eckert
{"title":"Circumventing Solidification Cracking Susceptibility in Al-Cu Alloys Prepared by Laser Powder Bed Fusion.","authors":"Lixia Xi, Qiuyang Lu, Dongdong Gu, Shaoting Cao, Han Zhang, Ivan Kaban, Baran Sarac, Konda Gokuldoss Prashanth, Jürgen Eckert","doi":"10.1089/3dp.2022.0207","DOIUrl":"10.1089/3dp.2022.0207","url":null,"abstract":"<p><p>Laser powder bed fusion (LPBF) of Al-Cu alloys shows high susceptibility to cracking due to a wide solidification temperature range. In this work, 2024 alloys were manufactured by LPBF at different laser processing parameters. The effect of processing parameters on the densification behavior and mechanical properties of the LPBF-processed 2024 alloys was investigated. The results show that the porosity increases significantly with increasing laser power, while the number of cracks and lack-of-fusion defects increase distinctly with increasing scan speed. The solidification cracking susceptibility of the LPBF-processed 2024 alloys prepared at different processing parameters was analyzed based on a finite element model, which was accurately predicted by theoretical calculations. Dense and crack-free 2024 samples with a high densification of over 98.1% were manufactured at a low laser power of 200 W combined with a low laser scan speed of 100 mm/s. The LPBF-processed 2024 alloys show a high hardness of 110 ± 4 HV<sub>0.2</sub>, an ultimate tensile strength of 300 ± 15 MPa, and an elongation of ∼3%. This work can serve as reference for obtaining crack-free and high-performance Al-Cu alloys by LPBF.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057541/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41554519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Impact of Beam Shape on Print Accuracy in Digital Light Processing Additive Manufacture.","authors":"Andrew Reid, James Windmill","doi":"10.1089/3dp.2022.0193","DOIUrl":"10.1089/3dp.2022.0193","url":null,"abstract":"<p><p>Photopolymerization-based additive manufacturing requires selectively exposing a feedstock resin to ultraviolet (UV) light, which in digital light processing is achieved either using a digital micromirror device or a digital mask. The minimum tolerances and resolution for a multilayer process are separate for resolution through the Z-axis, looking through the thickness of a printed part, and resolution in the XY-axes, in the plane of the printed layer. The former depends wholly on the rate of attenuation of the incident UV light through the material relative to the mechanical motion of the build layer, while the latter is determined by a two-dimensional pattern of irradiance on the resin formed by the digital micromirror device or the digital mask. The size or the spacing of elements or pixels of this digital mask is frequently given by manufacturers as the \"resolution\" of the device, however, in practice the achievable resolution is first determined by the beam distribution from each pixel. The beam distribution is, as standard, modeled as a two-parameter Gaussian distribution but the key parameters of peak intensity and standard deviation of the beam are hidden to the user and difficult to measure directly. The ability of models based on the Gaussian distribution to correctly predict the polymerization of printed features in the microscale is also typically poor. In this study, we demonstrate an alternative model of beam distribution based on a heavy-tailed Lorentzian model, which is able to more accurately predict small build areas for both positive and negative features. We show a simple calibration method to derive the key space parameters of the beam distribution from measurements of a single-layer printed model. We propose that the standard Gaussian model is insufficient to accurately predict a print outcome as it neglects higher-order terms, such as beam skew and kurtosis, and in particular failing to account for the relatively heavy tails of the beam distribution. Our results demonstrate how the amendments to the beam distribution can avoid errors in microchannel formation, and better estimates of the true XY-axes resolution of the printer. The results can be used as the basis for voxel-based models of print solidification that allow software prediction of the photopolymerization process.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057548/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44103631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai Scherer, Adrian Huwer, Roland Ulber, Michael Wahl
{"title":"Optimizing Luminous Transmittance of a Three-Dimensional-Printed Fixed Bed Photobioreactor.","authors":"Kai Scherer, Adrian Huwer, Roland Ulber, Michael Wahl","doi":"10.1089/3dp.2022.0136","DOIUrl":"10.1089/3dp.2022.0136","url":null,"abstract":"<p><p>The development of innovative production processes and the optimization of photobioreactors play an important role in generating industrial competitive production technologies for phototrophic biofilms. With emerse photobioreactors a technology was introduced that allowed efficient surface attached cultivation of terrestrial cyanobacteria. However, the productivity of emerse photobioreactors depends on the available cultivation surface. By the implementation of biocarriers to the bioreactor volume, the cultivation surface can be increased which potentially improves productivity and thus the production of valuable compounds. To investigate the surface attached cultivation on biocarriers new photobioreactors need to be developed. Additive manufacturing (AM) offers new opportunities for the design of photobioreactors but producing the needed transparent parts can be challenging using AM techniques. In this study an emerse fixed bed photobioreactor was designed for the use of biocarriers and manufactured using different AM processes. To validate the suitability of the photobioreactor for phototrophic cultivation, the optical properties of three-dimensional (3D)-printed transparent parts and postprocessing techniques to improve luminous transmittance of the components were investigated. We found that stereolithography 3D printing can produce parts with a high luminous transmittance of over 85% and that optimal postprocessing by sanding and clear coating improved the clarity and transmittance to more than 90%. Using the design freedom of AM resulted in a bioreactor with reduced part count and improved handling. In summary, we found that modern 3D-printing technologies and materials are suitable for the manufacturing of functional photobioreactor prototypes.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057691/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43351836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nondestructive Assessment of Quality Characteristics of As-Built Additive Manufacturing Aeronautical AlSi10Mg and Inspection of Offset.","authors":"Pengcheng Ding, Zhiwei Zeng","doi":"10.1089/3dp.2022.0293","DOIUrl":"10.1089/3dp.2022.0293","url":null,"abstract":"<p><p>AlSi10Mg is widely used in additively manufacturing aeronautical lattice and honeycomb structures. The unclear complex quality characteristics has been an obstacle of nondestructive testing of additive manufacturing (AM) AlSi10Mg, especially at its as-built state. This article attempts to reveal the quality characteristics of as-built AM aeronautical AlSi10Mg based on its conductivity characteristics. Experimental results show that the quality of manufacturing is nonuniform. The nonuniformity of each sample surface is systematically evaluated. Along the building direction, the quality is best in the initial few layers and decreases as the built height increases. On this basis, a reference curve is obtained and used to describe the quality characteristics of as-built AM component along the building direction. Based on the quality characteristics, the inspection of small offsets caused by accidental failures during the manufacturing process is carried out. The offsets not <37 μm are detected with the help of the reference curve, whereas they are not discovered by the radiography testing. It proves that the proposed method of offset inspection is highly sensitive.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057533/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46524309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chunxin Liu, Taras Oriekhov, Cherrie Lee, Clarissa M Harvey, Michael Fokine
{"title":"Rapid Fabrication of Silica Microlens Arrays via Glass 3D Printing.","authors":"Chunxin Liu, Taras Oriekhov, Cherrie Lee, Clarissa M Harvey, Michael Fokine","doi":"10.1089/3dp.2022.0112","DOIUrl":"10.1089/3dp.2022.0112","url":null,"abstract":"<p><p>Rapid manufacturing of high purity fused silica glass micro-optics using a filament-based glass 3D printer has been demonstrated. A multilayer 5 × 5 microlens array was printed and subsequently characterized, showing fully dense lenses with uniform focal lengths and good imaging performance. A surface roughness on the order of <i>R<sub>a</sub></i> = 0.12 nm was achieved. Printing time for each lens was <10 s. Creating arrays with multifocal imaging capabilities was possible by individually varying the number of printed layers and radius for each lens, effectively changing the lens height and curvature. Glass 3D printing is shown in this study to be a versatile approach for fabricating silica micro-optics suitable for rapid prototyping or manufacturing.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057534/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"60697351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yitian Chi, Narayanan Murali, Tianqi Zheng, Jingke Liu, Xiaochun Li
{"title":"Wire-Arc Additive Manufacturing of Nano-Treated Aluminum Alloy 2024.","authors":"Yitian Chi, Narayanan Murali, Tianqi Zheng, Jingke Liu, Xiaochun Li","doi":"10.1089/3dp.2022.0150","DOIUrl":"10.1089/3dp.2022.0150","url":null,"abstract":"<p><p>With high strength and good fatigue resistance, Al-Cu alloys such as AA2024 are widely used in the aerospace and automotive industries. However, the system's susceptibility to hot cracking and other solidification defects hinders its development in metal additive manufacturing (AM). A nano-treated AA2024 deposition, with the addition of TiC nanoparticles, is successfully additively manufactured without cracks. Microstructural analysis suggests nanoparticles not only mitigate the hot cracking sensitivity but also significantly refine and homogenize grains, resulting in an average size of 23.2 ± 0.4 μm. Microhardness profiles show consistent mechanical performance along the build direction, regardless of cyclic thermal exposure. Finally, excellent tensile strength and elongation up to 428 MPa and 7.4% were achieved after heat treatment. The combined results show a great promise of nano-treating in high-strength aluminum AM.</p>","PeriodicalId":54341,"journal":{"name":"3D Printing and Additive Manufacturing","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11057550/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42559814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}