Optical Materials: X最新文献

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CdTe quantum dots as fluorescent nanotools for in vivo glioblastoma imaging 碲化镉量子点作为荧光纳米工具用于体内胶质母细胞瘤成像
Optical Materials: X Pub Date : 2023-12-05 DOI: 10.1016/j.omx.2023.100282
Maria Aparecida Barreto Lopes Seabra , Luiz Gustavo Dubois , Eraldo Fonseca dos Santos-Júnior , Renata Virgínia Cavalcanti Santos , Antônio Gomes de Castro Neto , Alinny Rosendo Isaac , Adriana Fontes , Gunther Hochhaus , Belmira Lara da Silveira Andrade da Costa , Vivaldo Moura Neto , Beate Saegesser Santos
{"title":"CdTe quantum dots as fluorescent nanotools for in vivo glioblastoma imaging","authors":"Maria Aparecida Barreto Lopes Seabra ,&nbsp;Luiz Gustavo Dubois ,&nbsp;Eraldo Fonseca dos Santos-Júnior ,&nbsp;Renata Virgínia Cavalcanti Santos ,&nbsp;Antônio Gomes de Castro Neto ,&nbsp;Alinny Rosendo Isaac ,&nbsp;Adriana Fontes ,&nbsp;Gunther Hochhaus ,&nbsp;Belmira Lara da Silveira Andrade da Costa ,&nbsp;Vivaldo Moura Neto ,&nbsp;Beate Saegesser Santos","doi":"10.1016/j.omx.2023.100282","DOIUrl":"10.1016/j.omx.2023.100282","url":null,"abstract":"<div><p>Glioblastoma (GBM) is the most aggressive and infiltrating primary tumor of the central nervous system (CNS), showing a variety of mutations and a high degree of vascularity, cell polymorphism, and nuclear atypia. GBM treatment often recurs to surgical resection, but such protocol lacks efficacy since complete tumor removal is not entirely successful due to invasive cells that cannot be detected at the moment of the surgery. Here, we describe a new <em>in vivo</em> targeting and imaging method for GBM detection in an orthotropic mouse model using fluorescent CdTe quantum dots (CdTe QDs) conjugated to anti-glial fibrillary acidic protein (anti-GFAP). We conjugated and optimized red-emitting CdTe QDs to anti-GFAP to label GBM (U87 cell line) <em>in vivo</em>. The <em>in vivo</em> tumor growth was visualized by the hematoxylin and eosin staining and showed the successful delivery of GBM cells into the mouse brain parenchyma. CdTe/anti-GFAP QDs were injected into the tumor region, and their uptake by tumor cells was visualized by fluorescence microscopy, showing a specific dual labeling with vimentin-immunoreactive GBM. The results reported here provide new perspectives for using CdTe QDs in GBM detection, suggesting their potential application in imaging-guided surgery and a potential fluorescent tool to be applied in the monitoring of 3D tumor glial cultures.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147823000566/pdfft?md5=ce82416f54a125bd51405a5561426de3&pid=1-s2.0-S2590147823000566-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138626372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible photonics in carbon and glass fiber reinforced polymers for new multifunctionality: Exploring the advances, challenges, and opportunities 碳纤维和玻璃纤维增强聚合物中的柔性光子学,实现新的多功能性:探索进展、挑战和机遇
Optical Materials: X Pub Date : 2023-12-01 DOI: 10.1016/j.omx.2023.100277
Christopher Holmes , Janice Dulieu-Barton
{"title":"Flexible photonics in carbon and glass fiber reinforced polymers for new multifunctionality: Exploring the advances, challenges, and opportunities","authors":"Christopher Holmes ,&nbsp;Janice Dulieu-Barton","doi":"10.1016/j.omx.2023.100277","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100277","url":null,"abstract":"<div><p>Flexible photonics, characterized by their planar design and integrated features, have surfaced as a promising technology to unlock new possibilities for multifunctionality within fiber reinforced polymer composite materials. A comprehensive review of current progress, challenges, and opportunities associated with flexible photonic integration into carbon and glass fiber reinforced polymers is provided. A systematic examination of the literature has revealed several flexible photonic technologies that have demonstrated potential for integration in composite components to monitor performance in manufacture, service, and reuse. The review highlights the advantages and limitations of the current state-of-the-art in flexible integrated photonics for making assessments of compatibility with carbon and glass fiber reinforced polymer structures. By examining proof-of-concept demonstrations, the improved performance and novel functionalities that can be achieved for industrial applications are identified. The challenges associated with the integration process, such as durability and scalability are discussed in the context of the manufacturing processes required to create composite components. The concept of integrating flexible photonics in composite structures is relatively new, hence the paper closes by highlighting opportunities for further research and development in this field.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147823000517/pdfft?md5=f2ca35da6b3f4eefcc40c90237cd107b&pid=1-s2.0-S2590147823000517-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138582234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
X-ray excited optical luminescence at Carnaúba, the Sirius X-ray nanoprobe beamline 天狼星 X 射线纳米探针光束线 Carnaúba 的 X 射线激发光学发光
Optical Materials: X Pub Date : 2023-12-01 DOI: 10.1016/j.omx.2023.100278
Verônica C. Teixeira , Joelson C. Silva , Francisco C.M. Silva , Rodrigo Szostak , Maria Gabriella D. Guaita , Leonardo M. Kofukuda , Antonio C. Piccino Neto , Anna P.S. Sotero , Itamar T. Neckel , Carlos A. Pérez , Douglas Galante , Hélio C.N. Tolentino
{"title":"X-ray excited optical luminescence at Carnaúba, the Sirius X-ray nanoprobe beamline","authors":"Verônica C. Teixeira ,&nbsp;Joelson C. Silva ,&nbsp;Francisco C.M. Silva ,&nbsp;Rodrigo Szostak ,&nbsp;Maria Gabriella D. Guaita ,&nbsp;Leonardo M. Kofukuda ,&nbsp;Antonio C. Piccino Neto ,&nbsp;Anna P.S. Sotero ,&nbsp;Itamar T. Neckel ,&nbsp;Carlos A. Pérez ,&nbsp;Douglas Galante ,&nbsp;Hélio C.N. Tolentino","doi":"10.1016/j.omx.2023.100278","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100278","url":null,"abstract":"<div><p>This work presents the developments and initial results obtained using X-ray excited optical luminescence (XEOL) at the Carnaúba, the nanoprobe beamline from Sirius, the Brazilian 4th generation synchrotron source. XEOL is a highly important tool to study luminescence mechanisms and identify optical channels in various types of materials under X-ray irradiation. Using this capability combined with a nanoprobe, one can probe optical channels, for example, in heterogenous materials, and directly correlate them with chemical composition, oxidizing state of absorbers, structure and/or morphology in simultaneous studies. Carnaúba is composed by two experimental station and at the Tarumã station, the first entering in operation, it has been possible to investigate XEOL in the integrated and emission modes, and 2D images in hyperspectral mapping with submicrometric resolution. Herein, it is showed some examples of studies combining excitation energy, emission wavelength and emission intensity in 3D spectra, 2D imaging, and XEOL emission on the study of very sensitive samples that can be easily damaged by the probe. This work also highlights some of the upcoming developments that include the time-resolved and <em>in situ</em> experiments, this last one using microfluidic cells, and the improvement of the covered emission wavelength up to 1700 nm, which will open new opportunities for studying optical materials.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147823000529/pdfft?md5=805fbd50fb7595d2ee456ddece4090d0&pid=1-s2.0-S2590147823000529-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138582247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the optical properties of monoclinic Na3AlF6 and Na3AlF6:Mn4+ 单斜晶型Na3AlF6和Na3AlF6:Mn4+的光学性质
Optical Materials: X Pub Date : 2023-11-13 DOI: 10.1016/j.omx.2023.100276
Thomas Jansen, David Böhnisch, Florian Baur, Thomas Jüstel
{"title":"On the optical properties of monoclinic Na3AlF6 and Na3AlF6:Mn4+","authors":"Thomas Jansen,&nbsp;David Böhnisch,&nbsp;Florian Baur,&nbsp;Thomas Jüstel","doi":"10.1016/j.omx.2023.100276","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100276","url":null,"abstract":"<div><p>Mn<sup>4+</sup> activated luminescent materials have attracted much attention as colour converters for light sources and displays. In particular, alkali metal hexafluorometallates, such as K<sub>2</sub>SiF<sub>6</sub>:Mn<sup>4+</sup> or K<sub>2</sub>TiF<sub>6</sub>:Mn<sup>4+</sup>, emit light in the red spectral region if pumped by phosphor converted LEDs (pcLED). In accordance with <em>Zhu</em> et al. we applied the cation-exchange method in order to synthesize Mn<sup>4+</sup> doped Na<sub>3</sub>AlF<sub>6</sub><strong>.</strong> Na<sub>3</sub>AlF<sub>6</sub>:Mn<sup>4+</sup> exhibits efficient red photoluminescence peaking at 627 nm, which can be assigned to the <sup>2</sup><em>E</em><sub><em>g</em></sub> → <sup>4</sup><em>A</em><sub>2<em>g</em></sub> intraconfigurational transition of Mn<sup>4+</sup> ([Ar]3<em>d</em>.<sup>3</sup> configuration) within the [MnF<sub>6</sub>]<sup>2-</sup> octahedra on the aluminum site in the cryolite host structure. Photoluminescence properties, such as temperature dependence of the PL intensity and luminescence lifetime are presented. Additionally, the band structure of the undoped host material has been treated with Density Functional Theory (DFT). The theoretical results have been evaluated experimentally with diffuse UV reflectance spectroscopy. Finally, luminous efficacy and color rendering values of simulated warm white emitting pcLEDs comprising a dichromatic phosphor blend employing Na<sub>3</sub>AlF<sub>6</sub>:Mn<sup>4+</sup> as the red emitting component are calculated and compared to the performance of warm white emitting pcLEDs comprising K<sub>2</sub>SiF<sub>6</sub>:Mn<sup>4+</sup> as red emitting component.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147823000505/pdfft?md5=9a93d8c05fee2a6ff79ffa8780bddcc5&pid=1-s2.0-S2590147823000505-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134656133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adaptive guided stochastic optimization: A novel approach for fitting the theoretical intensity parameters for lanthanide compounds 自适应引导随机优化:拟合镧系化合物理论强度参数的新方法
Optical Materials: X Pub Date : 2023-10-18 DOI: 10.1016/j.omx.2023.100275
Carlos V. Santos-Jr. , Eduardo C. Aguiar , Albano N. Carneiro Neto , Renaldo T. Moura Jr.
{"title":"Adaptive guided stochastic optimization: A novel approach for fitting the theoretical intensity parameters for lanthanide compounds","authors":"Carlos V. Santos-Jr. ,&nbsp;Eduardo C. Aguiar ,&nbsp;Albano N. Carneiro Neto ,&nbsp;Renaldo T. Moura Jr.","doi":"10.1016/j.omx.2023.100275","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100275","url":null,"abstract":"<div><p>In this study, we introduce a state-of-the-art approach to enhance the fitting accuracy of theoretical intensity parameters in lanthanide spectroscopy. Lanthanide-based compounds play a pivotal role in a wide range of applications due to their distinctive photophysical characteristics. Theoretical understanding and computational descriptions are essential for advancing these applications. The Judd-Ofelt theory stands as a fundamental stone, offering insights into the luminescence exhibited by lanthanide compounds. Our methodology addresses the procedure of fitting charge factors (<span><math><mi>g</mi></math></span> in the Simple Overlap Model) and ligand effective polarizabilities (<span><math><msup><mrow><mi>α</mi></mrow><mrow><mo>′</mo></mrow></msup></math></span> in the Bond Overlap Model), quantities used for the determination of the intensity parameters (<span><math><msub><mrow><mi>Ω</mi></mrow><mrow><mi>λ</mi></mrow></msub></math></span>). We propose Adaptive Guided Stochastic Optimization (AGSO), a method that employs randomized initial points within predefined bounds for each variable. By iteratively updating variable bounds based on population statistics, AGSO systematically minimizes the error function with respect to experimental data. Extensive tests were conducted comparing AGSO with the well-established simulated annealing (SA) method. Remarkably, AGSO consistently outperformed SA, demonstrating its efficacy in fitting intensity parameters for various lanthanide compounds. Through AGSO, we offer a robust and efficient tool for the accurate study of lanthanide-based compounds, with broad implications for diverse applications.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590147823000499/pdfft?md5=d22d8835b1345dd5b4291414ad0bac07&pid=1-s2.0-S2590147823000499-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92024618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Femtosecond laser induced damage threshold and incubation in l-threonine aminoacid crystal 飞秒激光诱导l-苏氨酸氨基酸晶体损伤阈值及培养
Optical Materials: X Pub Date : 2023-10-13 DOI: 10.1016/j.omx.2023.100274
L.K. Nolasco , G.A. Flores , S.N.C. Santos , M.B. Andrade , J.J. Rodrigues Jr. , C.R. Mendonça
{"title":"Femtosecond laser induced damage threshold and incubation in l-threonine aminoacid crystal","authors":"L.K. Nolasco ,&nbsp;G.A. Flores ,&nbsp;S.N.C. Santos ,&nbsp;M.B. Andrade ,&nbsp;J.J. Rodrigues Jr. ,&nbsp;C.R. Mendonça","doi":"10.1016/j.omx.2023.100274","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100274","url":null,"abstract":"<div><p><span>l</span>-threonine aminoacid crystals exhibit high second-order optical nonlinearities that can be exploited for second harmonic generation, optical parametric amplification, and optical parametric oscillation. In addition, it possesses a large transparency window and low refractive index, making them an attractive material for photonics devices. Among several processing methods used to develop photonic integrated micro-devices, fs-laser micromachining has stood out for its high resolution, either on the surface or in the bulk, as well as to its flexibility to be used with various types of materials. Although organic crystals present relevant linear and nonlinear optical features, studies on fs-laser processing in such materials are yet scarce. Thus, this work presents a study of the fs-laser incubation and damage threshold fluence determination in <span>l</span>-threonine crystals at 515 nm and 1030 nm. The damage threshold fluence was determined for one up to 10<sup>5</sup> pulses. For the single pulse regime, we obtained F<sub>th</sub> = (0.94 ± 0.04) J/cm<sup>2</sup> at 1030 nm and F<sub>th</sub> = (0.31 ± 0.01) J/cm<sup>2</sup> at 515 nm. Such difference is explained by the number of photons involved in each case; 5-photons at 1030 nm and 3-photons at 515 nm. Also, a slower incubation dynamic was observed at 515 nm. Still, micro-Raman spectroscopy revealed that no structural modifications were induced by the fs-laser pulses on the sample upon micromachining. Such results provide relevant data for the processing of <span>l</span>-threonine crystals via fs-laser micromachining to achieve organic photonic integrated devices.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49739010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Terbium-doped transparent glass-ceramics containing TbPO4 crystals: A promising material for photonic applications 含TbPO4晶体的掺铽透明玻璃陶瓷:一种具有光子应用前景的材料
Optical Materials: X Pub Date : 2023-10-07 DOI: 10.1016/j.omx.2023.100272
Douglas F. Franco, Fábio J. Caixeta, Leonardo V. Albino, Thiago A. Lodi, Juliane R. Orives, Eduardo O. Ghezzi, Marcelo Nalin
{"title":"Terbium-doped transparent glass-ceramics containing TbPO4 crystals: A promising material for photonic applications","authors":"Douglas F. Franco,&nbsp;Fábio J. Caixeta,&nbsp;Leonardo V. Albino,&nbsp;Thiago A. Lodi,&nbsp;Juliane R. Orives,&nbsp;Eduardo O. Ghezzi,&nbsp;Marcelo Nalin","doi":"10.1016/j.omx.2023.100272","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100272","url":null,"abstract":"<div><p>Glasses and glass-ceramics based on the Tb<sup>3+</sup>-doped SbPO<sub>4</sub>-GeO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub> composition have been studied. Samples containing up to 0.4 mol % of Tb<sub>4</sub>O<sub>7</sub> form glasses when obtained by melt-quenching while concentrations above that tends to form glass-containing single crystals. This work reports the thermal, structural, morphological, and optical studies of (96-x)(40SbPO<sub>4</sub>-60GeO<sub>2</sub>)-4Al<sub>2</sub>O<sub>3</sub>-xTb<sub>4</sub>O<sub>7</sub> samples (where 0.2 ≤ x ≤ 0.7, in mol %) using Differential Scanning Calorimetry, X-ray Powder Diffraction, Scanning Electron Microscopy, Energy Dispersive Spectroscopy, UV–Vis absorption, Raman, and Photoluminescence spectroscopies. The diffraction pattern for the glass-ceramic containing 0.7 mol% of Tb<sub>4</sub>O<sub>7</sub> shows diffraction peaks, which were assigned to the crystalline phase derived from terbium orthophosphate (TbPO<sub>4</sub>). In the same direction, the Raman spectra of the glass-ceramics containing 0.5, 0.6, and 0.7 mol% of Tb<sub>4</sub>O<sub>7</sub> exhibited narrow bands in the region between 900 and 1300 cm<sup>-1</sup>, which are characteristic of the main vibrational modes of the PO<sub>4</sub> tetrahedral units of TbPO<sub>4</sub>. The TbPO<sub>4</sub> crystals exhibited an average size distribution ranging from 10 to 200 μm. The TbPO<sub>4</sub> crystals exhibited an unusual morphology and design, resembling the shape of the letter \"H\" and is completely different from the crystals reported in the literature. Strong green emission from TbPO<sub>4</sub> crystals was verified at 547 nm for all samples. The emission spectra showed not only bands assigned to <sup>5</sup>D<sub>4</sub>→<sup>7</sup>F<sub>J</sub> electronic transitions in the green-red range, but also those coming from <sup>5</sup>D<sub>3</sub>→<sup>7</sup>F<sub>J</sub> in blue region.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49739008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal, structural and optical properties of tungsten-fluorophosphate glasses and glass-ceramics with high lead fluoride contents 高氟化铅氟磷钨玻璃和玻璃陶瓷的热学、结构和光学性能
Optical Materials: X Pub Date : 2023-10-01 DOI: 10.1016/j.omx.2023.100269
Rachel Prado Russo Delorenzo Nardi , Raphael Rodrigues Faleiros , Andrea Simone Stucchi De Camargo , Sidney José Lima Ribeiro , Camila Pereira , Lia Mara Marcondes , Gislene Batista , Fábia Castro Cassanjes , Gael Poirier
{"title":"Thermal, structural and optical properties of tungsten-fluorophosphate glasses and glass-ceramics with high lead fluoride contents","authors":"Rachel Prado Russo Delorenzo Nardi ,&nbsp;Raphael Rodrigues Faleiros ,&nbsp;Andrea Simone Stucchi De Camargo ,&nbsp;Sidney José Lima Ribeiro ,&nbsp;Camila Pereira ,&nbsp;Lia Mara Marcondes ,&nbsp;Gislene Batista ,&nbsp;Fábia Castro Cassanjes ,&nbsp;Gael Poirier","doi":"10.1016/j.omx.2023.100269","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100269","url":null,"abstract":"<div><p>Eu<sup>3+</sup>-doped lead fluorophosphate glass samples were prepared in the ternary system (40-x)NaPO<sub>3</sub>-xWO<sub>3</sub>-60PbF<sub>2</sub> by the melt-quenching method. The influence of the NaPO<sub>3</sub>/WO<sub>3</sub> ratio on the thermal and structural properties as well as on the ability of these compositions to crystallize as glass-ceramics containing lead fluoride phase β-PbF<sub>2</sub> was investigated. Thermal properties and characteristic temperatures were determined by DSC and used to define suitable heat-treatment temperatures for selective crystallization. The corresponding crystalline phases and average crystallite sizes were determined by X-ray diffraction. Structural changes versus composition were also studied by Raman spectroscopy. UV-visible absorption spectra were used to determine the bandgap energies versus composition. Specific compositions exhibiting β-PbF<sub>2</sub> crystallization were selected and Eu<sup>3+</sup> emission spectra were used to check the Eu<sup>3+</sup> environment and crystallization state as a function of heat-treatment conditions and glass composition. The results suggest that progressive β-PbF<sub>2</sub> crystallization promotes a higher symmetry and lower phonon energy environment of Eu<sup>3+</sup> resulting in longer excited state lifetimes only for WO<sub>3</sub> richer compositions.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49739005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding the coupling between MIM cavities due to single and double Tamm plasmon polaritons 了解由于单和双Tamm等离子激元极化引起的MIM腔之间的耦合
Optical Materials: X Pub Date : 2023-09-30 DOI: 10.1016/j.omx.2023.100273
Leandro Luis Missoni , Guillermo Pablo Ortiz , María Luz Martínez Ricci
{"title":"Understanding the coupling between MIM cavities due to single and double Tamm plasmon polaritons","authors":"Leandro Luis Missoni ,&nbsp;Guillermo Pablo Ortiz ,&nbsp;María Luz Martínez Ricci","doi":"10.1016/j.omx.2023.100273","DOIUrl":"https://doi.org/10.1016/j.omx.2023.100273","url":null,"abstract":"<div><p>The interplay between light and matter plays a crucial role in various applications, ranging from sensor technologies to integrated optoelectronic architectures. In this contribution, a systematic numerical study is made over the symmetry role of the 1D photonic structures (PhSs) containing a low number of slabs embedded in thin metal layers, in order to find the adequate conditions to enhance the quality factor of resonances and energy confinement in the subwavelength scale. We show the existence of single and double Tamm plasmon polaritons (TPPs) states according to the symmetry of the PhS, which allow to tune weak and strong coupling regimes with Metal–Insulator–Metal (MIM) platforms combined in a unique MIM-PhS-MIM structure. We found that while weak coupling is observable between MIM and PhS states at the PhS cavity mode wavelengths, strong coupling among the 2 MIMs and the PhS is obtained only at the TPP resonance wavelengths, exhibited by anti-crossing splittings at adequate insulator thicknesses. We found that for the double Tamm plasmon polaritons, the energy splitting can reach up to 134 meV, unlike the single TPPs where the maximum energy splitting is on the order of 50 meV. The degree of coupling was explained by the implementation of a variational method that exploits the analogy the optical superlattice herein proposed and an analogous superlattice quantum well. This article shows that TPP resonances are responsible for the coherent coupling between the two MIMs placed at a long distance given by the PhSs. Thus, these platforms provide an interesting and experimentally accessible route for the coupling of emitters in optoelectronic devices.</p></div>","PeriodicalId":52192,"journal":{"name":"Optical Materials: X","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49739007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of hyperbranched conjugated polymers based on triphenylamine, phenoxazine, and benzothiadiazole for optoelectronic applications 光电应用中基于三苯胺、苯恶嗪和苯并噻唑的超支化共轭聚合物的合成和表征
Optical Materials: X Pub Date : 2023-09-28 DOI: 10.1016/j.omx.2023.100270
Tam Huu Nguyen , Thao Thanh Bui , Thao Phuong Le Nguyen , Ngoc Xuan Dat Mai , Bao Kim Doan , Tam Hoang Luu , Le-Thu T. Nguyen , Chau Duc Tran , Hai Le Tran , Son Thanh Cu , Minh Nghia Phan , Quoc-Thiet Nguyen , Ha Tran Nguyen
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引用次数: 0
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