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Effect of SEBS-g-MA on recycled PS/HDPE blend miscibility SEBS-g-MA对再生PS/HDPE共混物混相的影响
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-25 DOI: 10.1007/s00396-025-05407-6
Davidyants Nikita G., Irina Yu. Gorbunova, Stepan V. Polunin, Tatyana P. Kravchenko, Alexey V. Khoroshilov
{"title":"Effect of SEBS-g-MA on recycled PS/HDPE blend miscibility","authors":"Davidyants Nikita G.,&nbsp;Irina Yu. Gorbunova,&nbsp;Stepan V. Polunin,&nbsp;Tatyana P. Kravchenko,&nbsp;Alexey V. Khoroshilov","doi":"10.1007/s00396-025-05407-6","DOIUrl":"10.1007/s00396-025-05407-6","url":null,"abstract":"<div><p>The article presents the results of thermal, rheological, and structural studies of a recycled polystyrene and recycled polyethylene blend by modifying it with maleinated styrene-ethylene-butylene-styrene thermoplastic elastomer as a compatibilizer. Thermal analysis showed that the introduction of a compatibilizer did not significantly affect the value of the glass transition temperatures of the composites, which indicates their stability. Thermogravimetric analysis showed an increase in the temperature of the onset of thermal degradation with the introduction of 2.5 wt.% of maleinated thermoplastic elastomer from 307 to 321 °C. Scanning electron microscopy images confirmed an improvement in the uniformity of the resulting blend structure with the introduction of maleinated thermoplastic elastomer. Blends of the studied recycled polymers with the introduction of a compatibilizer have a 3.5-fold increased impact strength compared to non-compatibilized blend.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1139 - 1154"},"PeriodicalIF":2.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mathematical modeling in the ZnO nanoparticle dispersing in the oil-in-water emulsions for potential Pickering formulation 氧化锌纳米粒子在水包油乳液中分散的数学模型
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-25 DOI: 10.1007/s00396-025-05404-9
Sameer Munir, Akhtar Ali, Zulfiqar Ali Raza, Naseer Ahmad
{"title":"Mathematical modeling in the ZnO nanoparticle dispersing in the oil-in-water emulsions for potential Pickering formulation","authors":"Sameer Munir,&nbsp;Akhtar Ali,&nbsp;Zulfiqar Ali Raza,&nbsp;Naseer Ahmad","doi":"10.1007/s00396-025-05404-9","DOIUrl":"10.1007/s00396-025-05404-9","url":null,"abstract":"<div><p>A Pickering emulsion is a system of two immiscible liquids like oil and water containing some solid particles like metal nanoparticles (NPs) that usually stay at the oil/water (O/W) interface, hence affecting their colloidal behavior. Due to their high surface energy, amphiphilic nature, and nanoscale dimensions, ZnO nanoparticles (ZNPs) can effectively function as Pickering stabilizers. The present study undertakes the stability of surfactant-reinforced O/W emulsions with ZNP-mediation under homogenization. The experiments were performed through Taguchi design, and the results were analyzed using the VIKOR approach. The responses included residual oil and ZNP contents, oil retention rate, droplet size/charge, emulsification index, and viscosity. UV–vis spectroscopy and DLS analyses demonstrated that introducing ZNPs facilitated the stability of O/W emulsions over time. The factor effect on the VIKOR index (<i>Q</i><sub><i>j</i></sub>) values revealed that temperature exerted the greatest influence (31%) on the response variable, closely followed by ZNP content (26%). CTAB content had a moderate impact (22%), while oil content had the least effect (13%). The optimal formulation was determined by selecting the levels that resulted in the lowest <i>Q</i><sub><i>j</i></sub> values, which were CTAB concentration at 450 mg/100 ml, oil content at 10,000 mg/100 ml, ZNP concentration at 50 mg/100 ml, and a processing temperature of 60 °C. The predicted recipe was assessed through a validation run and demonstrated well-fitting of experimental results. Such findings may be employed in optimizing the food, pharmaceuticals, cosmetic, and fine chemical formulations.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1123 - 1138"},"PeriodicalIF":2.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the impact of temperature dependency and activation energy applications on bioconvective flow of Burgers nanofluid with higher order slip effects 揭示温度依赖性和活化能应用对具有高阶滑移效应的Burgers纳米流体生物对流流动的影响
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-24 DOI: 10.1007/s00396-024-05364-6
Sami Ullah Khan, M. Ijaz Khan, Farwa Asmat, Fahad Sikander, Abdulbasid S. Banga, Mehdi Akermi
{"title":"Unveiling the impact of temperature dependency and activation energy applications on bioconvective flow of Burgers nanofluid with higher order slip effects","authors":"Sami Ullah Khan,&nbsp;M. Ijaz Khan,&nbsp;Farwa Asmat,&nbsp;Fahad Sikander,&nbsp;Abdulbasid S. Banga,&nbsp;Mehdi Akermi","doi":"10.1007/s00396-024-05364-6","DOIUrl":"10.1007/s00396-024-05364-6","url":null,"abstract":"<div><p>The heat and mass transfer phenomenon due to Burgers nanofluid with suspension of microorganisms is studied. The analysis for bioconvective Burgers nanofluid model is further influenced by activation energy and thermal radiation. The variable effects of thermal conductivity are considered. Furthermore, the higher order slip features are contributed to analyze the flow problem. Based on implementation of governing hypothesis, the equations for the problem are modeled. The numerical evaluation of the problem is detected with shooting method. The results are confirmed after addressing the comparison of numerical data. The physical insight of problem is announced in view of fluctuated parameters. It is observed that velocity profile reduces due to slip parameters and relaxation constant. The concentration profile enhances due to slip parameter. Moreover, the concentration profile reduces due to retardation parameter.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1113 - 1122"},"PeriodicalIF":2.2,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing sustainable materials: characterization of pistachio shell and talc filled polyester composites 推进可持续材料:开心果壳和滑石粉填充聚酯复合材料的表征
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-20 DOI: 10.1007/s00396-025-05406-7
İdris Karagöz, İlayda Arslan Ocak, Aysu Çavuşoğlu, Harun Sepetçioğlu
{"title":"Advancing sustainable materials: characterization of pistachio shell and talc filled polyester composites","authors":"İdris Karagöz,&nbsp;İlayda Arslan Ocak,&nbsp;Aysu Çavuşoğlu,&nbsp;Harun Sepetçioğlu","doi":"10.1007/s00396-025-05406-7","DOIUrl":"10.1007/s00396-025-05406-7","url":null,"abstract":"<div><p>This study aims to develop sustainable polyester hybrid composites by incorporating environmentally friendly fillers such as pistachio shell and talc into an orthophthalic polyester matrix. The goal is to produce cost-effective, eco-friendly materials for applications such as exterior cladding and electronic enclosures. The mechanical (tensile, flexural, impact), thermal (FT-IR, TGA, DSC), and physical (water absorption, hardness, density, gloss) properties of the prepared composites were tested. Pure polyester exhibited the highest tensile strength at approximately 50 MPa, while the addition of 40% pistachio shell reduced the mechanical properties by 69%. In contrast, the addition of talc increased the tensile strength by 55% compared to the composite with only pistachio shell. Talc also improved thermal stability (increasing the T5 temperature by 7% and Tmax by 2%) and reduced water absorption by 4%. The combination of both fillers optimized the material properties, providing a sustainable and high-performance alternative. These findings suggest that further optimization of filler content could improve performance and expand material applications.</p><h3>Graphical abstract</h3><p>From raw pistachio shell to composite: processing in a polyester matrix</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1097 - 1112"},"PeriodicalIF":2.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the properties of PLA/TPS blends using PLA-g-MA as a compatibilizer: a study on thermal, morphological, mechanical, chemical, and biodegradation characteristics 用PLA-g- ma作为增容剂增强PLA/TPS共混物的性能:热、形态、机械、化学和生物降解特性的研究
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-19 DOI: 10.1007/s00396-025-05405-8
Nilesh S. Vala, Kaushal J. Bavaliya, Mahendrasinh Raj, Lata Raj
{"title":"Enhancing the properties of PLA/TPS blends using PLA-g-MA as a compatibilizer: a study on thermal, morphological, mechanical, chemical, and biodegradation characteristics","authors":"Nilesh S. Vala,&nbsp;Kaushal J. Bavaliya,&nbsp;Mahendrasinh Raj,&nbsp;Lata Raj","doi":"10.1007/s00396-025-05405-8","DOIUrl":"10.1007/s00396-025-05405-8","url":null,"abstract":"<p>This study investigates the development and optimization of biodegradable polymer blends consisting of polylactic acid (PLA) and thermoplastic starch (TPS), using PLA-grafted maleic anhydride (PLA-g-MA) as a compatibilizer. Blends were prepared with PLA: TPS ratios ranging from 100:0 to 0:100 and compatibilizer concentrations of 0%, 3%, 5%, 7%, and 9%. Mechanical properties and melt flow index (MFI) were assessed for all blends, while thermal stability (TGA), morphological properties (SEM), and chemical and biodegradation behavior were specifically studied for the 70:30 and 80:20 blends at all compatibilizer concentrations. The 70:30 blend demonstrated superior thermal stability, with a weight loss reduction from 9.4 at 0% compatibilizer to 1.9 at 9% PLA-g-MA at 300 °C. SEM analysis revealed a transition from distinct phase separation at 0% compatibilizer to a homogeneous structure at 7% PLA-g-MA, particularly in the 70:30 blend. Biodegradation studies confirmed faster decomposition for the 70:30 blend, achieving 8.7% weight loss over 15 days at 7% compatibilizer, compared to 7.6% for the 80:20 blend under the same conditions. Mechanical property analysis showed significant improvements in tensile strength, impact resistance, and ductility with increasing compatibilizer concentration, particularly for blends with higher TPS content. These findings highlight the versatility of PLA/TPS blends for applications requiring tailored mechanical and thermal properties, along with enhanced biodegradability.</p>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1081 - 1095"},"PeriodicalIF":2.2,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular dynamics simulations investigating the influence of different chitosan-based graft polymer monomer types on their flocculation behavior 分子动力学模拟研究不同壳聚糖基接枝聚合物单体类型对其絮凝行为的影响
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-14 DOI: 10.1007/s00396-025-05399-3
Fengyang Liu, Wenjie Zou, Ting Xiao, Wentao Hu, Ming Zhang, Zhijun Zhang, Fang Zhou
{"title":"Molecular dynamics simulations investigating the influence of different chitosan-based graft polymer monomer types on their flocculation behavior","authors":"Fengyang Liu,&nbsp;Wenjie Zou,&nbsp;Ting Xiao,&nbsp;Wentao Hu,&nbsp;Ming Zhang,&nbsp;Zhijun Zhang,&nbsp;Fang Zhou","doi":"10.1007/s00396-025-05399-3","DOIUrl":"10.1007/s00396-025-05399-3","url":null,"abstract":"<div><p>The selection of the grafting monomer plays a pivotal role in determining the flocculation performance of chitosan-based grafted copolymers. In this work, the flocculation behavior and mechanism of chitosan-based graft copolymers with different grafting monomers (i.e. carboxymethyl chitosan-grafted polyacrylamide (CMCP), carboxymethyl chitosan-graft-poly (acrylamide-dimethyl diallyl ammonium chloride) (CMCPD), and chitosan-graft-poly (acrylamide-dimethyl diallyl ammonium chloride) (CPD)) on the kaolinite (001) surface were investigated using molecular dynamics simulations, flocculation experiments and flocs size measurement. The interaction energy calculations revealed that the copolymers exhibited the following order: CPD (− 943.105 kcal/mol) &gt; CMCPD (− 522.812 kcal/mol) &gt; CMCP (− 340.026 kcal/mol). The calculated solvent-accessible surface area (SASA) showed that amphoteric CMCPD exhibited complete extension and unrestricted diffusion in solution, surpassing the capabilities of both CMCP and CPD. The diffusion coefficients of CMCPD, CPD, and CMCP, were determined to be 5.17 × 10<sup>–10</sup> m<sup>2</sup>/s, 2.68 × 10<sup>–10</sup> m<sup>2</sup>/s and 4.25 × 10<sup>–10</sup> m<sup>2</sup>/s, respectively. It can be inferred that the bridging ability of the CMCPD flocculant in solution is directly proportional to its higher diffusion coefficient. However, excessive adsorption of CPD onto kaolinite resulted in a reduction in the bridging capacity of CPD. The simulation results were validated by conducting flocculation experiments, and it was observed that CMCPD, possessing the strongest bridging capability, exhibited a significantly higher settling rate (19.47 m/h) compared to CPD (12.56 m/h) and CMCP (9.81 m/h). The analysis of flocs particle size further confirmed the superior bridging ability of CMCPD, as evidenced by its largest flocs particle size, thereby facilitating rapid settling. This study provides valuable insights for the design and development of chitosan-based flocculants.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1071 - 1080"},"PeriodicalIF":2.2,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microemulsions constructed by a biosurfactant 由生物表面活性剂构成的微乳
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-12 DOI: 10.1007/s00396-025-05401-y
Lin Han, Lin Ma, Liya Zhang, Rui Qu, Yang Han, Jingcheng Hao, Shuli Dong
{"title":"Microemulsions constructed by a biosurfactant","authors":"Lin Han,&nbsp;Lin Ma,&nbsp;Liya Zhang,&nbsp;Rui Qu,&nbsp;Yang Han,&nbsp;Jingcheng Hao,&nbsp;Shuli Dong","doi":"10.1007/s00396-025-05401-y","DOIUrl":"10.1007/s00396-025-05401-y","url":null,"abstract":"<div><p>Due to their biodegradability and low toxicity, biosurfactants have recently attracted much attention. Here, microemulsions (MEs) are constructed by an excellent biosurfactant, surfactin, via low energy emulsification. Rheological properties, kinetic stability, thermodynamic stability, and long-term storage capacity of microemulsions were characterized. The effect of pH and different gelling agents on the phase behavior and the formation of microemulsion-gels were also explored. The results reveal that the MEs show no significant change in droplet size under high-speed centrifugation, providing great kinetic stability, which enables the MEs to maintain their stability under bumpy and rugged transportation conditions. The MEs are thermodynamically stable and can be restored to their original state after experiencing extreme conditions such as high temperature (58 °C) or freeze-thawing cycles, facilitating the use of the MEs under extreme conditions and promoting the shelf-life of production. The addition of different gelling agents did not show any significant changes to MEs and not disrupt the formation of the MEs, meaning that the MEs constructed by surfactin are stable and possess antioxidant potential and moisturizing effects.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1059 - 1069"},"PeriodicalIF":2.2,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Antioxidant Pickering emulsions stabilized by core cross-linked diblock copolymer nanoparticles bearing polyphenol groups 含多酚基团的核心交联二嵌段共聚物纳米颗粒稳定的抗氧化皮克林乳液
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-08 DOI: 10.1007/s00396-025-05397-5
Jiani Peng, Liangliang Shi, Shiqi Zhu, Xinyi Wu, Yong Gao
{"title":"Antioxidant Pickering emulsions stabilized by core cross-linked diblock copolymer nanoparticles bearing polyphenol groups","authors":"Jiani Peng,&nbsp;Liangliang Shi,&nbsp;Shiqi Zhu,&nbsp;Xinyi Wu,&nbsp;Yong Gao","doi":"10.1007/s00396-025-05397-5","DOIUrl":"10.1007/s00396-025-05397-5","url":null,"abstract":"<div><p>Pickering emulsions with antioxidative properties have significant applications across various fields such as biomedicine, skincare, and food. The fabrication of antioxidant Pickering emulsions using core cross-linked diblock copolymer nanoparticles bearing polyphenol groups as both Pickering emulsifiers and the interfacial reservoirs of antioxidants was demonstrated in this study. Poly[oligo(ethylene glycol) methyl ether methacrylate]<sub>18</sub>-poly(diacetone acrylamide)<sub>50</sub> (POEGMA<sub>18</sub>-PDAAM<sub>50</sub>, E<sub>18</sub>D<sub>50</sub>) diblock copolymer nanoparticles were first synthesized via RAFT-mediated dispersion polymerization in water. Subsequently, PDAAM cores of E<sub>18</sub>D<sub>50</sub> were chemically cross-linked using 4,6-diaminoresorcinol dihydrochloride (DAR.2HCl) as the cross-linker. The cross-linking process involved the Schiff base reaction between carbonyl groups of the PDAAM core-forming blocks and the amine groups of DAR.2HCl. Polyphenols were readily introduced into the cores of nanoparticles while the cross-linking of PDAAM core, affording core cross-linked copolymer nanoparticles bearing polyphenols (CCE<sub>18</sub>D<sub>50</sub>-P). The prepared CCE<sub>18</sub>D<sub>50</sub>-P nanoparticles exhibited excellent emulsification performances and outstanding free radical scavenging ability. Antioxidant dodecane-in-water Pickering emulsions were formulated using CCE<sub>18</sub>D<sub>50</sub>-P as Pickering emulsifiers, which demonstrated a desired effect in preserving vitamin E, with retentions of 88.4% and 82.1% after 28 days and 45 days of storage at room temperature, respectively.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1047 - 1058"},"PeriodicalIF":2.2,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00396-025-05397-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of zein microfibre diameter and concentration on the development of mechanical and physico-chemical properties of ɩ-carrageenan 玉米蛋白微纤维直径和浓度对磁叉-卡拉胶力学和理化性质发展的影响
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-06 DOI: 10.1007/s00396-025-05402-x
Mojtaba Rezaei, Sara Naji-Tabasi, Behrouz Ghorani, Bahareh Emadzadeh, Nick Tucker
{"title":"The influence of zein microfibre diameter and concentration on the development of mechanical and physico-chemical properties of ɩ-carrageenan","authors":"Mojtaba Rezaei,&nbsp;Sara Naji-Tabasi,&nbsp;Behrouz Ghorani,&nbsp;Bahareh Emadzadeh,&nbsp;Nick Tucker","doi":"10.1007/s00396-025-05402-x","DOIUrl":"10.1007/s00396-025-05402-x","url":null,"abstract":"<div><p>This paper explores the effect on mechanical, thermal and physico-chemical properties of ɩ-carrageenan hydrogels when enriched with zein microfibres. The microfibres were generated from varying concentrations (20%W/V, 30%W/V and 40% W/V) of zein using an antisolvent technique. The microfibres were incorporated into ɩ-carrageenan hydrogels at concentrations of 0.2%W/V and 0.5%W/V. Scanning electron microscopy showed that zein concentration correlates with microfibre diameter (ranging from 4.37 ± 0.02 to 11.31 ± 0.1 μm) (<i>p</i> &lt; 0.05). By increasing the zein concentration, the microfibres also become less polar (<i>p</i> &lt; 0.05). Examination by Fourier transform infrared spectroscopy, X-ray diffraction and differential scanning calorimetry indicates that the synthesis of microfibres did not affect protein structure. Zein fibres made from 40%W/V concentration solutions and added to the hydrogel at 0.5%W/V (hereafter Z40%-0.5) exhibited the highest hardness (7.89 g) (<i>p</i> &lt; 0.05). The Z40%-0.5 sample also displayed both the highest storage modulus (<i>G′)</i> value (7550 ± 2.66 Pa) and loss modulus (<i>G″)</i> values (1720 ± 0.47 Pa) (<i>p</i> &lt; 0.05), indicating superior quasi-solid characteristics. Both loss and storage moduli of the samples were frequency-dependent, increasing frequency correlated with higher values for both moduli, signifying weak gel behaviour. The Z40%-0.5 hydrogel (<i>p</i> &lt; 0.05) achieved the highest water holding capacity (WHC) but the highest swelling rate (<i>p</i> &lt; 0.05) was associated with the fibre-free control sample. We demonstrate that incorporating fibres into ɩ-carrageenan hydrogels enhances their mechanical properties, thus addressing a significant commercial application issue.</p></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"303 6","pages":"1031 - 1046"},"PeriodicalIF":2.2,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the binding interactions of cetirizine and diphenhydramine in SDS-SDBS mixed micelles 研究了西替利嗪和苯海拉明在SDS-SDBS混合胶束中的结合作用
IF 2.2 4区 化学
Colloid and Polymer Science Pub Date : 2025-03-04 DOI: 10.1007/s00396-025-05400-z
Anirudh Srivastava, Swarnima Tiwari, Javed Masood Khan, Debojit Kumar Deb, Muhammad Wajid Ullah
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