Colloid and Polymer Science最新文献

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Assessment of SDS/CTAB-nafcillin sodium interactions in ethanol and ethylene glycol at different temperatures: thermodynamic and micellization perspectives 不同温度下SDS/ ctab -萘西林钠在乙醇和乙二醇中的相互作用的评价:热力学和胶束的观点
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-06 DOI: 10.1007/s00396-026-05594-w
Abhishek Srivastava, Ajaya Bhattarai, Vinay Kumar Singh, Madhav Krishn Goswami
{"title":"Assessment of SDS/CTAB-nafcillin sodium interactions in ethanol and ethylene glycol at different temperatures: thermodynamic and micellization perspectives","authors":"Abhishek Srivastava,&nbsp;Ajaya Bhattarai,&nbsp;Vinay Kumar Singh,&nbsp;Madhav Krishn Goswami","doi":"10.1007/s00396-026-05594-w","DOIUrl":"10.1007/s00396-026-05594-w","url":null,"abstract":"<div>\u0000 \u0000 <p>Comprehending the interactions between drugs and surfactants is critically significant for enhancing drug delivery processes and formulating effective drug compositions. This research aims to elucidate the temperature-induced aggregation of the cationic surfactant cetyltrimethylammonium bromide (CTAB) and the anionic surfactant sodium dodecyl sulphate (SDS) in combination with antibiotic nafcillin sodium (NafNa); in addition to emphasizing the influence of ethanol (EtOH) and ethylene glycol (EG) on micellization. Thermodynamic parameters (change in entropy, ΔS<sup>0</sup><sub>m</sub>; enthalpy, ΔH<sup>0</sup><sub>m</sub>; and Gibbs free energy, ΔG<sup>0</sup><sub>m</sub>) and physicochemical variables (critical micelle concentration, CMC; counter ion dissociation, α) have been used to characterise the interaction between SDS/CTAB and NafNa. The incorporation of NafNa into aqueous CTAB led to an increase in the CMC and α value, whereas a decrease in both was noticed in the case of SDS surfactant. The augmentation of CMC at heightened EtOH/EG concentrations is influenced by the synergistic effect of reduced dielectric constant (DC) and enhanced solvent hydrophobicity. In CTAB + NafNa, the CMC value increases with temperature, while in SDS + NafNa, it initially decreases before subsequently increasing. The SDS/CTAB + NafNa mixture spontaneously micellizes in both pure water and aqueous EtOH/EG environments, as evidenced by the negative ΔG<sup>0</sup><sub>m</sub> values. The − ΔH<sup>0</sup><sub>m</sub> and + ΔS<sup>0</sup><sub>m</sub> values for the drug-surfactant mixture suggest electrostatic and hydrophobic interactions contribute to aggregation, with micellization showing more entropic favorability (ΔS<sup>0</sup><sub>m</sub> &gt; ΔH<sup>0</sup><sub>m</sub>). The results offer critical understanding for scholars aiming to refine parameters, including temperature, concentration, and the incorporation of EtOH/EG additives, to improve the effectiveness and durability of drug delivery systems.</p>\u0000 </div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1169 - 1184"},"PeriodicalIF":2.3,"publicationDate":"2026-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-healing bioinks with β-cyclodextrin–adamantine supramolecular interpenetrating polymer networks based on alginate and hyaluronic acid methacrylates for tissue engineering 基于海藻酸盐和甲基丙烯酸透明质酸盐的β-环糊精-金刚烷超分子互穿聚合物网络的自修复生物墨水
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-06 DOI: 10.1007/s00396-026-05581-1
Elif Yüce, Burçin İzbudak, Banu Kocaağa, Seniha F. Güner, Ayça Bal Öztürk, Serkan Emik
{"title":"Self-healing bioinks with β-cyclodextrin–adamantine supramolecular interpenetrating polymer networks based on alginate and hyaluronic acid methacrylates for tissue engineering","authors":"Elif Yüce,&nbsp;Burçin İzbudak,&nbsp;Banu Kocaağa,&nbsp;Seniha F. Güner,&nbsp;Ayça Bal Öztürk,&nbsp;Serkan Emik","doi":"10.1007/s00396-026-05581-1","DOIUrl":"10.1007/s00396-026-05581-1","url":null,"abstract":"<div>\u0000 \u0000 <p>Three-dimensional (3D) bioprinting has revolutionized the field of tissue engineering by enabling the fabrication of complex biological structures with high precision. The development of bioinks with enhanced mechanical, rheological, and biological properties is critical for advancing this technology. In this study, we designed biocompatible bioinks with self-healing capabilities using host-guest molecules modified onto two distinct polymeric networks. To achieve this, two different polymer chains were utilized: one was functionalized with a host molecule (β-cyclodextrin) and the other with a guest molecule (1-adamantane acetic acid). Alginate methacrylate (AlgMa) was synthesized and subsequently modified with the host molecule, while hyaluronic acid was methacrylated and then modified with the guest molecule. Consequently, host-guest interaction-based biominks with interpenetrating polymer network (IPN) structures were prepared, leading to the development of these advanced bioinks.The resulting interpenetrating polymer network (IPN) structures exhibited improved mechanical stability, as demonstrated by oscillation frequency sweep tests. Our bioinks demonstrated excellent shear-thinning behavior, facilitating printability and maintaining shape fidelity during and after the bioprinting process. These features make them highly suitable for use in tissue scaffold fabrication. By leveraging the unique properties of self-healing bioinks, we provide a significant contribution to the development of durable, functional materials for tissue engineering applications.</p>\u0000 </div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1155 - 1167"},"PeriodicalIF":2.3,"publicationDate":"2026-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biogenic fabrication of metal and metal oxide nanoparticles using plant extracts: a comprehensive overview 生物制备金属和金属氧化物纳米粒子使用植物提取物:一个全面的概述
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-06 DOI: 10.1007/s00396-026-05591-z
Nishtha Jain,  Pratibha, Komal Rajoriya, Anita Kumari
{"title":"Biogenic fabrication of metal and metal oxide nanoparticles using plant extracts: a comprehensive overview","authors":"Nishtha Jain,&nbsp; Pratibha,&nbsp;Komal Rajoriya,&nbsp;Anita Kumari","doi":"10.1007/s00396-026-05591-z","DOIUrl":"10.1007/s00396-026-05591-z","url":null,"abstract":"<div>\u0000 \u0000 <p>Using plants to produce metal and metal oxide nanoparticles is becoming a popular substitute for conventional chemical and physical techniques, largely because it’s simpler, safer, and more eco-friendly. This green synthesis approach is recognized for its environmental friendliness, cost-effectiveness, and sustainability. Plants are abundant in a wide variety of bioactive compounds-such as flavonoids, phenolics, alkaloids, terpenoids, and proteins-that naturally function as reducing, capping, and stabilizing agents during nanoparticle formation. This review presents a thorough examination of the underlying synthesis pathways, key factors that influence nanoparticle production, and the resulting structural and functional attributes of the plant-synthesized nanoparticles. Special attention is given to their diverse applications across multiple domains, including biomedical uses (e.g., antimicrobial, anticancer, and antioxidant effects), agricultural improvements (such as nano-fertilizers and pest management), environmental solutions (including pollutant breakdown and water treatment), and catalytic processes. While the approach shows great potential, several challenges persist-particularly in terms of large-scale production, achieving consistency in nanoparticle morphology, and fully elucidating the synthesis mechanisms. This review compiles existing findings and outlines prospective research directions to support the continued development and implementation of plant-mediated nanoparticle technologies.</p>\u0000 </div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"943 - 961"},"PeriodicalIF":2.3,"publicationDate":"2026-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the effects of hydrotropes and temperature on the micelle formation and physicochemical parameters of cetylpyridinium bromide and moxifloxacin hydrochloride mixture 研究了亲水剂和温度对溴化十六烷基吡啶与盐酸莫西沙星混合物胶束形成及理化参数的影响
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-05 DOI: 10.1007/s00396-026-05588-8
Md. Ashraful Islam, Md. Newaz Sharif, Shamim Mahbub, Kamrul Hasan, Md Abdul Goni, Md. Anamul Hoque, Shariff E. Kabir, Javed Masood Khan
{"title":"Investigation of the effects of hydrotropes and temperature on the micelle formation and physicochemical parameters of cetylpyridinium bromide and moxifloxacin hydrochloride mixture","authors":"Md. Ashraful Islam,&nbsp;Md. Newaz Sharif,&nbsp;Shamim Mahbub,&nbsp;Kamrul Hasan,&nbsp;Md Abdul Goni,&nbsp;Md. Anamul Hoque,&nbsp;Shariff E. Kabir,&nbsp;Javed Masood Khan","doi":"10.1007/s00396-026-05588-8","DOIUrl":"10.1007/s00396-026-05588-8","url":null,"abstract":"<div><p>This study explores the interactions between fourth-generation antibiotic moxifloxacin hydrochloride (MFH) and cationic surfactant cetylpyridinium bromide (CPB) in aqueous solutions containing various hydrotropes, including sodium benzoate (NaBenz), sodium salicylate (NaSal), p-aminobenzoic acid (4-ABA), and caffeine. Conductivity measurement technique was used to determine the key physicochemical parameters such as critical micelle concentration (<i>CMC</i>), micellar ionization degree (α), and counter-ion binding fraction (β). The <i>CMC</i> values were found to be dependent strongly on the presence of MFH, the type of hydrotropes and their concentrations as well as temperature variation. The standard thermodynamic functions of micellization were estimated from the temperature dependence of <i>CMC</i>. Negative values of free energy across all systems confirmed the spontaneous nature of micellization, which was further promoted at higher temperatures. The results suggest that hydrophilic, hydrophobic, ion–dipole, and electrostatic interactions jointly govern the association between MFH and CPB, while the favorable enthalpic contribution highlights the enhanced stability of the micelles formed in the respective system. Beyond the fundamental insights, these significant research findings hold practical applications, as MFH–CPB mixed systems stabilized by hydrotropes can be exploited in various pharmaceutical and industrial formulations to improve drug solubilization, stability, and delivery efficiency.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1141 - 1153"},"PeriodicalIF":2.3,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acrylate emulsion synthesized via glow discharge electrolysis for restoration of flaking mural in Mogao Grottoes 辉光放电电解合成丙烯酸酯乳液修复莫高窟剥落壁画
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-05 DOI: 10.1007/s00396-026-05595-9
Wen-jie An, Xiao-yun Fang, Qing-ying Ma, Jie Yu, Yan-fei Li, Lin-yi Zhao, Quan-fang Lu
{"title":"Acrylate emulsion synthesized via glow discharge electrolysis for restoration of flaking mural in Mogao Grottoes","authors":"Wen-jie An,&nbsp;Xiao-yun Fang,&nbsp;Qing-ying Ma,&nbsp;Jie Yu,&nbsp;Yan-fei Li,&nbsp;Lin-yi Zhao,&nbsp;Quan-fang Lu","doi":"10.1007/s00396-026-05595-9","DOIUrl":"10.1007/s00396-026-05595-9","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The acrylate emulsion was prepared by glow discharge electrolysis.</p>\u0000 </li>\u0000 <li>\u0000 <p>The emulsion shows spherical structure and has lower content of soluble salts.</p>\u0000 </li>\u0000 <li>\u0000 <p>The polymerization mechanism is a free radical-initiated chain addition process.</p>\u0000 </li>\u0000 <li>\u0000 <p>The emulsion can be used as an adhesive for restoring the damaged mural.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1125 - 1140"},"PeriodicalIF":2.3,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comparative study on mechanical, swelling and thermal degradation behaviors of sulfur cured and peroxide cured NBR/CR/ENR ternary elastomeric composites 硫化与过氧化物硫化NBR/CR/ENR三元弹性体复合材料力学、膨胀及热降解性能的对比研究
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-04 DOI: 10.1007/s00396-026-05576-y
S. Vishnu, M. Gowthamraaj, M. Elamathian, B. Prabu
{"title":"A comparative study on mechanical, swelling and thermal degradation behaviors of sulfur cured and peroxide cured NBR/CR/ENR ternary elastomeric composites","authors":"S. Vishnu,&nbsp;M. Gowthamraaj,&nbsp;M. Elamathian,&nbsp;B. Prabu","doi":"10.1007/s00396-026-05576-y","DOIUrl":"10.1007/s00396-026-05576-y","url":null,"abstract":"<div><p>Most of the elastomeric components such as mounts, seals, gaskets, and liners are subjected to harsh environmental conditions, hence it demands materials with multifunctional property balance of mechanical strength, thermal and chemical resistance, which can achieved remarkably by ternary elastomeric composites than single and binary blend elastomeric composites. Hence, in this work, an attempt is made to develop novel ternary elastomeric composites by selecting three elastomers, namely nitrile-butadiene rubber (NBR), chloroprene rubber (CR), and epoxidized natural rubber (ENR), primarily based on their solubility parameters and application requirements. These composites can be conventionally cured using either sulfur or peroxide. To study the effect of these curing systems and to determine the optimum content of elastomers, different composites were developed following a simplex centroid mixture design approach. Accordingly, seven composites of each set of curing were developed and studied for their mechanical, thermal, and swelling behaviors. By adopting grey relation analysis (GRA), the optimum content of elastomer based on mechanical properties is determined. To support the findings, morphological and FTIR studies were also carried out. Further to evaluate the chemical resistance and thermal stability of the prepared composites, swelling studies and thermal degradation studies were also carried out respectively.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1101 - 1123"},"PeriodicalIF":2.3,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of N-terminal temperature-sensitive epitope imprinted particles by reversible addition-fragmentation chain transfer strategy for cytochrome c recognition 用可逆加成-断裂链转移策略制备细胞色素c识别用n端温度敏感表位印迹颗粒
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-03-04 DOI: 10.1007/s00396-026-05596-8
Zeyu Wei, Xinxin Li, Zixiang Xu, Zhen Fan, Yuzeng Li, Zhenyu Feng, Qinran Li, Hongfeng Zhang, Qiliang Deng
{"title":"Preparation of N-terminal temperature-sensitive epitope imprinted particles by reversible addition-fragmentation chain transfer strategy for cytochrome c recognition","authors":"Zeyu Wei,&nbsp;Xinxin Li,&nbsp;Zixiang Xu,&nbsp;Zhen Fan,&nbsp;Yuzeng Li,&nbsp;Zhenyu Feng,&nbsp;Qinran Li,&nbsp;Hongfeng Zhang,&nbsp;Qiliang Deng","doi":"10.1007/s00396-026-05596-8","DOIUrl":"10.1007/s00396-026-05596-8","url":null,"abstract":"<div>\u0000 \u0000 <p>N-terminal epitope-imprinted temperature-sensitive polymer on silica particle was prepared using a reversible addition-fragmentation chain transfer (RAFT) strategy, with the N-terminal nonapeptide of cytochrome c as template. 2-Dodecylsulfanylcarbothioylsulfanyl-2-methylpropionic acid (DMP) was used as a chain transfer agent to regulate the polymerization of the imprinted layer, thereby enhancing the recognition performance for the peptide and target protein. After the epitope modification, a surface-imprinted polymer with a controlled imprinted layer was synthesized using monomers and crosslinkers via the RAFT radical polymerization method. As the classic temperature-sensitive functional monomer, the addition of N-isopropylacrylamide imparts temperature-responsive properties to the prepared imprinted polymer. After optimizing the ratio of functional monomers and the recognition temperature, the imprinted particles achieve optimal adsorption capacity and imprinting factor (IF) at a recognition temperature of 45 °C. The highest adsorption capacity for GI-9 is 1.50 mg/g, with an IF of 2.33, while the maximum adsorption capacity for Cyt c reaches 8.39 mg/g, with an IF of 2.16, which were clearly higher than the IF of the material without the RAFT strategy. Furthermore, the temperature-sensitive imprinted polymers exhibit acceptable binding capacity and IF for Cyt c, enabling selective recognition within multi-protein mixtures. The protein recognition performance remained at approximately 89.3% after five adsorption-desorption cycles, with almost no decrease of IF. All these results indicate that the imprinted particles exhibit acceptable selectivity, good reusability, and sensitivity to recognition temperature conditions. It is expected to be further applied in the selective recognition and controlled release of target proteins.</p>\u0000 </div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1083 - 1099"},"PeriodicalIF":2.3,"publicationDate":"2026-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of structural, optical, morphological, dielectric and electrical properties of MoS2 doped NaAlg polymer nanocomposites 二硫化钼掺杂NaAlg聚合物纳米复合材料的结构、光学、形态、介电和电学性能研究
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-02-28 DOI: 10.1007/s00396-026-05589-7
R. Sahanakumari, V. Ravindrachary, R. Padmakumari, Rohan N. Sagar, M. Thirumala Patil, B. K. Mahantesha, Shreedatta Hegde
{"title":"Study of structural, optical, morphological, dielectric and electrical properties of MoS2 doped NaAlg polymer nanocomposites","authors":"R. Sahanakumari,&nbsp;V. Ravindrachary,&nbsp;R. Padmakumari,&nbsp;Rohan N. Sagar,&nbsp;M. Thirumala Patil,&nbsp;B. K. Mahantesha,&nbsp;Shreedatta Hegde","doi":"10.1007/s00396-026-05589-7","DOIUrl":"10.1007/s00396-026-05589-7","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, sodium alginate (NaAlg) polymer doped with molybdenum disulfide (MoS<sub>2</sub>) were prepared using the solution casting method. FTIR analysis revealed strong interactions between NaAlg and MoS<sub>2</sub> nanoparticle, evidenced by the complexation of O–H and –COO⁻ functional groups, indicating hydrogen bonding and electrostatic interactions between nanofiller and the polymer host. The observed shifts and intensity variations in the characteristic peaks of the pristine polymer upon doping further confirm the successful incorporation of MoS₂ into the alginate matrix. X-ray diffraction (XRD) studies demonstrated a transformation from the predominantly amorphous nature of pure NaAlg to enhanced crystallinity in the polymer nanocomposites, with sharper diffraction peaks appearing as the MoS₂ concentration increased. UV-visible spectroscopy revealed a shift in absorption band towards higher wavelength and a reduction in the optical band gap from 4.9 to 4.3 eV with increasing nanoparticle content. Thermogravimetric analysis (TGA) confirmed improved thermal stability of the nanocomposites, indicating the role of MoS<sub>2</sub> in retarding thermal degradation. Surface morphology studies showed a smooth and porous structure for pure NaAlg, while increased surface roughness was observed with higher MoS₂ loading. Dielectric investigations revealed enhanced dielectric parameters with increasing MoS<sub>2</sub> concentration, with the maximum dielectric performance observed for the 1wt% MoS<sub>2</sub> incorporated polymer nanocomposite. The same composition also exhibited the highest dc conductivity of 3.33 × 10<sup>− 4</sup> Scm<sup>− 1</sup> for the 1wt% MoS<sub>2</sub> incorporated polymer nanocomposite.</p>\u0000 </div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1051 - 1065"},"PeriodicalIF":2.3,"publicationDate":"2026-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-assembly of poly(1-vinylimidazole)-stabilized Au and Ag nanoparticles: formation of spatially ordered aggregates during radiation-chemical synthesis 聚(1-乙烯基咪唑)稳定金和银纳米粒子的自组装:辐射化学合成过程中空间有序聚集体的形成
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-02-27 DOI: 10.1007/s00396-026-05586-w
Alexey A. Zharikov, Rodion A. Vinogradov, Artem V. Bakirov, Elena A. Zezina, Alexey A. Mikhutkin, Evgeny V. Yastremsky, Yuri M. Chesnokov, Alexander L. Vasiliev, Oxana V. Vyshivannaya, Andrey V. Sybachin, Alexander S. Pozdnyakov, Vladimir I. Feldman, Sergei N. Chvalun, Alexey A. Zezin
{"title":"Self-assembly of poly(1-vinylimidazole)-stabilized Au and Ag nanoparticles: formation of spatially ordered aggregates during radiation-chemical synthesis","authors":"Alexey A. Zharikov,&nbsp;Rodion A. Vinogradov,&nbsp;Artem V. Bakirov,&nbsp;Elena A. Zezina,&nbsp;Alexey A. Mikhutkin,&nbsp;Evgeny V. Yastremsky,&nbsp;Yuri M. Chesnokov,&nbsp;Alexander L. Vasiliev,&nbsp;Oxana V. Vyshivannaya,&nbsp;Andrey V. Sybachin,&nbsp;Alexander S. Pozdnyakov,&nbsp;Vladimir I. Feldman,&nbsp;Sergei N. Chvalun,&nbsp;Alexey A. Zezin","doi":"10.1007/s00396-026-05586-w","DOIUrl":"10.1007/s00396-026-05586-w","url":null,"abstract":"<div><p>Self-assembly of nanoparticles (NPs) is attracted considerable attention as a way to designing advanced functional materials. Poly(1-vinylimidazole) (PVI), being a water-soluble, non-toxic and biocompatible polymer, is an excellent candidate for the creation of metal-polymer nanocomposites intended for biomedical applications. In this article, we report that X-ray irradiation of aqueous solutions of PVI-Au(III) and PVI-Ag(I) complexes leads to the formation of Au and Ag NPs smaller than 7 and 15 nm, respectively. Importantly, a combination of cryogenic electron microscopy and small-angle X-ray scattering studies has shown that, within the polymer matrix, the ultrasmall Au NPs tend to arrange in chains, while the larger Ag NPs assemble into more compact three-dimensional aggregates. Based on electrophoretic mobility measurements and Fourier transform infrared spectroscopy, we infer that in the liquid phase the PVI-stabilized Au and Ag NPs possess different effective surface charge, resulted from the adsorption of metal ions forming coordinate bonds with the imidazole groups. Thus, the present study explicitly demonstrates that the radiation-chemical synthesis, free from the use of chemical reducing agents, is accompanied by the formation of PVI-NPs agglomerates, the spatial order of which is primarily determined by the effective surface charge and sizes of NPs.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"304 5","pages":"1039 - 1049"},"PeriodicalIF":2.3,"publicationDate":"2026-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147808235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the application of cellulose to enhance the oil resistance of aqueous foam systems 纤维素增强水性泡沫体系耐油性能的实验研究
IF 2.3 4区 化学
Colloid and Polymer Science Pub Date : 2026-02-27 DOI: 10.1007/s00396-026-05578-w
Ping Jiang, Hui Lu, Chenxi Li, Jiaxing Teng, Xiaoyang Liang, Hao Li, Zhaoxin Yuan
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