Jonathan C. Aitchison, Daniel Patias, Dominique Cluzel, Trevor R. Ireland, Renjie Zhou, Dongyang Lian, Jingsui Yang, Zhen Yan
{"title":"Recycling Subducted Organic Carbon as Diamonds: An Example From the New Caledonia Forearc Ophiolite","authors":"Jonathan C. Aitchison, Daniel Patias, Dominique Cluzel, Trevor R. Ireland, Renjie Zhou, Dongyang Lian, Jingsui Yang, Zhen Yan","doi":"10.1029/2025GC012250","DOIUrl":"https://doi.org/10.1029/2025GC012250","url":null,"abstract":"<p>Micro-diamonds and moissanite (SiC) have been identified in ophiolitic mantle harzburgites and chromitites of the New Caledonian Peridotite Nappe. The pale yellow (100–250 μm) micro-diamonds and light blue moissanite (mean −26.5‰, range −33.5‰ to −23.8‰ and mean −26.9‰, range −31.8‰ to −25.6‰ respectively) exhibit consistently strong negative <i>δ</i><sup>13</sup>C values consistent with vegetal (C3) photosynthesis. Preservation of U-Pb ages amongst co-occurring rutile xenocrysts, with a closure temperature of 620 ± 20°C, constrains the maximum thermal conditions experienced by these rocks. These temperatures indicate that the New Caledonian diamonds did not form under the deep mantle conditions typical of conventional diamond genesis but instead within a distinct supra-subduction zone (SSZ) forearc setting. The association with moissanite suggests formation within anoxic, organic carbon-rich sediments at the top of the subducting slab or within the subduction channel under localized super-reducing conditions. In light of mantle heterogeneity, extension of the known distribution of ophiolitic diamonds to the Southern Hemisphere supports interpretation of their formation in relation to an SSZ process rather than a deep mantle source. It also highlights a previously unrecognized aspect of the global carbon cycle, underscoring the significance of SSZ forearc ophiolites in deep carbon transport and transformation.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012250","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anita Di Chiara, Vassil Karloukovski, Barbara A. Maher, Maarten Van Daele, Thijs Van der Meeren, Dirk Verschuren
{"title":"A Continuous 150-kyr Record of Geomagnetic Field Variations From Lake Chala, Eastern Equatorial Africa","authors":"Anita Di Chiara, Vassil Karloukovski, Barbara A. Maher, Maarten Van Daele, Thijs Van der Meeren, Dirk Verschuren","doi":"10.1029/2024GC011933","DOIUrl":"https://doi.org/10.1029/2024GC011933","url":null,"abstract":"<p>Records of geomagnetic field variations from continental Africa are sparse yet provide a key dating tool for low-latitude paleoclimatic changes. Long-lived tectonic and crater lakes in eastern tropical Africa potentially provide important, long (>100,000 years, kyrs) and continuous sedimentary records of African monsoonal climate over past glacial and interglacial stages; the environmental backdrop to human evolution and dispersion. Here, notwithstanding its low latitude location, we present a detailed paleomagnetic record from eastern equatorial Africa extracted from the upper ∼129 m of a continuous sediment sequence drilled in Lake Chala (3°S; 37°E), a permanently stratified crater lake near Mt. Kilimanjaro. The high and stable sedimentation rate (∼0.85 m/kyr), lack of compaction and reliable paleomagnetic signal (assessed by paleo- and rock magnetic analyses) enabled the production of a new virtual geomagnetic pole (VGP) record for the last ∼150 ka for equatorial Africa. Six magnetic excursions are recorded: Blake 1 and 2, Post-Blake, Laschamp, Mono Lake and Hilina Pali. This exceptional record provides key information on the recurrence and duration of intervals of Quaternary geomagnetic instability, and independently-obtained constraints on the Hilina Pali excursion. Our new paleomagnetic record thus provides a reference data set for late-Quaternary geomagnetic excursions from African sites and a basis for better understanding of the temporal and spatial evolution of Earth's magnetic field. Finally, correlated with a revised geomagnetic instability timescale, these excursions provide a robust, independent age model for the Lake Chala sediment record, critical for correlating its paleoclimate and environmental proxy records to global reference records.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011933","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kaisa R. Autumn, Emilie E. E. Hooft, Douglas R. Toomey
{"title":"Exploring Mid-to-Lower Crustal Magma Plumbing of Santorini and Kolumbo Volcanoes Using PmP Tomography","authors":"Kaisa R. Autumn, Emilie E. E. Hooft, Douglas R. Toomey","doi":"10.1029/2025GC012170","DOIUrl":"https://doi.org/10.1029/2025GC012170","url":null,"abstract":"<p>Deep-crustal magma plumbing at arc volcanoes controls the volume, frequency, and composition of magma being transported to and stored in the upper crust. However, the mid-to-lower crust remains a challenging region to image. We explore the mid-to-lower crustal velocity structure beneath the Christiana-Santorini-Kolumbo Volcanic Field (CSKVF) to better understand how an established stratovolcano and flanking volcano (Santorini and Kolumbo) are fed through the mid-to-lower crust. We use active-source seismic data to obtain a P-wave velocity model of the crust below the CSKVF. We invert direct and reflected P phases to cover the entire depth extent of the crust and solve for the Moho interface depth. Our model requires a curved Moho interface representative of crustal thickening via underplating. Results show a high <i>V</i><sub><i>p</i></sub> anomaly in the lower crust under Santorini and a mid-crustal low <i>V</i><sub><i>p</i></sub> anomaly offset from both Santorini and Kolumbo. We find that accumulation of magma is located under the local extensional basin in the upper mid-crust (<10 km) but is offset at deeper depths. We find evidence for melt storage at 11–13 km depth feeding volcanism at the Kolumbo volcanic chain. This melt is also a plausible source for the 2025 seismic swarm and dike intrusion. Resolution is limited in the mid-crust below the Santorini caldera, leaving Santorini's mid-crustal magma plumbing unconstrained. We think it likely that Santorini and Kolumbo have entirely separate crustal plumbing systems and mantle sources, but allow the possibility of a connection in the mid or lower crust.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012170","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Léger, P. Sarda, C. Bailly, H. Zeyen, M. Pessel, E. Portier, G. Dupuy, R. Lambert, A. Courtin, D. Guinoiseau, D. Calmels, V. Durand, G. Monvoisin, A. Battani, M. Moreira, F. Stuart, J. Barbarand, B. Brigaud
{"title":"Deciphering Degassing Mechanisms of He and \u0000 \u0000 \u0000 \u0000 H\u0000 2\u0000 \u0000 \u0000 ${mathbf{H}}_{mathbf{2}}$\u0000 at the Sedimentary Basin-Basement Interface by Surface Geophysics and Gas Geochemistry","authors":"E. Léger, P. Sarda, C. Bailly, H. Zeyen, M. Pessel, E. Portier, G. Dupuy, R. Lambert, A. Courtin, D. Guinoiseau, D. Calmels, V. Durand, G. Monvoisin, A. Battani, M. Moreira, F. Stuart, J. Barbarand, B. Brigaud","doi":"10.1029/2024GC012021","DOIUrl":"https://doi.org/10.1029/2024GC012021","url":null,"abstract":"<p>With the increasing importance of the carbon footprint of transport, new sources, closer to consumers, of <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>H</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${mathrm{H}}_{2}$</annotation>\u0000 </semantics></math> and He are explored. Within this context, we present a combined near-surface geophysical imaging, soil gas sampling, and bubbling well gas sampling approach to study fluid and gas pathways near a fault system in the Morvan massif, part of the French Massif Central, in the south-east of the Paris Basin. Electrical resistivity and seismic refraction tomography profiles allowed identifying a fault network. The co-located soil gas sampling shows a He hot-spot clearly linked to a section of one fault, suggesting a preferential pathway via water advection. Very high He concentrations, are also measured in <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>N</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${mathrm{N}}_{2}$</annotation>\u0000 </semantics></math>-dominated free gas from two bubbling wells very close to the soil He hot-spot. Evidence for a water reservoir with high <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>N</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${mathrm{N}}_{2}$</annotation>\u0000 </semantics></math>-He gas bubbles in the very shallow basement-sediment cover interface is obtained through our geophysical data. In contrast, <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>H</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${mathrm{H}}_{2}$</annotation>\u0000 </semantics></math> spreads more widely, pointing to biological production and consumption coupled to soil aeration, as well as a possible geological seep with diffusion processes controlled by clay/marls. The very distinct spatial variability observed for He and <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>H</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${mathrm{H}}_{2}$</annotation>\u0000 </semantics></math> results from these different transport processes. A simple geochemical model is proposed to explain the geochemical signature of bubble gas, rich in <span></span><math>\u0000 <s","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC012021","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}