Amir Hossein Hamidian, Saba Sadat Miri Karahroudi, Meisam Feizi, Yu Zhang, Min Yang
{"title":"Comparative Removal Efficiency of Polypropylene Microplastics from Aqueous Solutions by Filtration, Centrifugation, and Flocculation.","authors":"Amir Hossein Hamidian, Saba Sadat Miri Karahroudi, Meisam Feizi, Yu Zhang, Min Yang","doi":"10.1007/s00128-025-04083-0","DOIUrl":"10.1007/s00128-025-04083-0","url":null,"abstract":"<p><p>Microplastics, which decompose from large pieces of plastic and cause water pollution, are becoming an increasing environmental problem due to their stable structure, high mobility, and ease of interaction with organic compounds in the environment. Large amounts of microplastics enter surface waters through wastewater and stormwater. Therefore, it is necessary to develop simple and accessible methodologies as a foundation for establishing reliable and effective strategies for microplastic removal from aquatic environmental samples. In this study, the removal of microplastics (< 1 mm) at laboratory scale using synthetic microplastics is investigated by three methods: filtration, centrifugation and flocculation. For this purpose, polypropylene-based microplastic particles are prepared and turbidity is used to measure removal. In this study, all three methods are investigated to determine a more effective method for the removal of microplastic particles. Among the three methods studied, the centrifuge method showed higher removal efficiency than the filtration and flocculation methods for the removal of microplastic particles from aqueous solution. The removal efficiency of microplastic particles by the centrifugation method reached 95.6% and was 90.6% by the filtration method. The flocculation method has a lower removal efficiency of microplastic particles than the centrifugation and filtration methods, ranging from 75.6 to 81.8%. In general, the results show that centrifugation is the more suitable and efficient method to remove microplastic particles from aqueous solution.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"12"},"PeriodicalIF":2.7,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144625113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai Che, Jinxing Yu, Yukun Ju, Xuan Zhao, Yunqian Gong, Chongming Chen
{"title":"Immobilization of Pb in Alkaline Soil Amend with Nano-hydroxyapatite: Speciation, Bioavailability, and Bioaccessibility.","authors":"Kai Che, Jinxing Yu, Yukun Ju, Xuan Zhao, Yunqian Gong, Chongming Chen","doi":"10.1007/s00128-025-04078-x","DOIUrl":"10.1007/s00128-025-04078-x","url":null,"abstract":"<p><p>With the development of nanotechnology, nano-hydroxyapatite (nHAP) is gradually used for the immobilization and remediation of heavy metals in soil. However, there are few studies on the immobilization of Pb in alkaline agriculture soil amend with nHAP. This study applied 0.5% and 1% nHAP as remediation materials to two Pb contaminated alkaline soils (A and B) from the surrounding of substation in northern China. Comprehensive evaluations of Pb mobility were conducted using the Tessier sequence extraction method, DTPA extraction, and in vitro gastrointestinal simulation (SBRC and PBET methods). The Tessier sequence extraction results revealed that following nHAP addition, there was a shift of Pb towards the residual fraction, with decreases in exchangeable, carbonate, and Fe/Mn oxide fraction. The risk assessment code (RAC) decreased from 27.7 to 36.0% to 21.9-35.1%, and the mobility factor (MF) dropped from 78.8 to 85.9% to 65.6-75.0%. DTPA extraction indicated contrasting effects: the bioavailable Pb extracted by DTPA assay in soil A increased from 36.6% to 43.0-58.3%, while the bioavailable Pb in soil B decreased from 68.3% to 48.4-52.7%. Similar to DTPA results, the Pb bioaccessibility of soil A increased from 63.9% to 41.9% to 70.0-72.6% and 47.6-63.8% in SBRC and PBET gastric phase after 0.5% and 1.0% nHAP treatments 90 days. However, the Pb bioaccessibility of soil B decreased from 76.6% to 56.5% to 54.9-56.5%, 35.0-35.6% by SBRC and PBET, respectively. The study highlights the potential of nHAP in alkaline soil, but the immobilization efficiency varied with soil characteristics.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"10"},"PeriodicalIF":2.7,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144607058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Edna Souza de Melo, Luis Felipe Pimentel, Cleyton Martins da Silva, Graciela Arbilla
{"title":"Fine Particulate Matter Levels in the Western Area of the City of Rio de Janeiro and the Potential Risks on Children's Health.","authors":"Edna Souza de Melo, Luis Felipe Pimentel, Cleyton Martins da Silva, Graciela Arbilla","doi":"10.1007/s00128-025-04081-2","DOIUrl":"10.1007/s00128-025-04081-2","url":null,"abstract":"<p><p>The main goal of this study is to evaluate the potential risk of high levels of particulate matter with diameter ≤ 2.5 μm (PM<sub>2.5</sub>) on children´s health, using PM<sub>2.5</sub> monitoring in the western zone of the city of Rio de Janeiro and health data determined in the same area. Results showed that, during this period, in more than 50% of days PM<sub>2.5</sub> concentration were > 15 µg m<sup>- 3</sup>. This value is the maximum concentration to ensure a good air quality according to the WHO guidelines and the Brazilian legislation. Furthermore, in 2023, 28.24% and 5.29% of mortality rates, for children between 1 and 5 years old, were due to respiratory and cardiovascular diseases respectively. On the basis of the particulate matter levels recorded in this study and the WHO AIRQ + software, we estimate that PM<sub>2.5</sub> levels may have contributed to approximately 8.5% of the total number of these deaths and could have been prevented.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"9"},"PeriodicalIF":2.7,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144607057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sediment Phosphorus Equilibrium Concentration (EPC<sub>0</sub>) Measured Using a Novel Dynamic Mesocosm System.","authors":"Tilak Patel, Chris Weisener, Ken G Drouillard","doi":"10.1007/s00128-025-04082-1","DOIUrl":"10.1007/s00128-025-04082-1","url":null,"abstract":"<p><p>The sediment equilibrium phosphorus concentration (EPC<sub>0</sub>) is used to estimate phosphorus (P) flux at the sediment-water interface. This parameter is most commonly measured by the batch method which potentially disrupts natural sediment structure at sampling. This manuscript describes the use of a dynamic mesocosm system consisting of sediment cores modified to recirculate overlying waters from the cores through an external reservoir that is subject to experimental manipulation. The method allows EPC<sub>0</sub> to be determined on intact cores while preserving in-situ sediment structure. Calibration of the system demonstrated time to steady state after P-spiking to vary by spike concentration and temperature. Comparisons between EPC<sub>0</sub> from batch and mesocosms revealed higher EPC<sub>0</sub> in cores compared to batch methods. When sediment structure was disrupted by homogenization, technique differences were reduced.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"11"},"PeriodicalIF":2.7,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144607059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Klaiani Bez Fontana, Eduardo Sidinei Chaves, Rennan Geovanny Oliveira Araujo, Tatiane de Andrade Maranhão
{"title":"Fractionation and Risk Assessment of Rare Earth Elements in Drill Cuttings from Petroleum Wells in Ultra-Deep Waters.","authors":"Klaiani Bez Fontana, Eduardo Sidinei Chaves, Rennan Geovanny Oliveira Araujo, Tatiane de Andrade Maranhão","doi":"10.1007/s00128-025-04079-w","DOIUrl":"10.1007/s00128-025-04079-w","url":null,"abstract":"<p><p>The mobility and bioavailability of rare earth elements (REE) from anthropogenic activity has aroused environmental interest and concern. In this work, we evaluated the chemical fractionation of REE in drill cutting (DC) samples from oil wells in ultra-deep waters by the European Community Bureau of Reference (BCR) sequential extraction procedure. Sequential extraction in the DC samples showed that the concentration of REE in the fractions followed the order of residual > reducible > weak acid soluble > oxidant. The environmental risk, evaluated by the risk assessment code (RAC), potential ecological risk factor ([Formula: see text]) and potential ecological risk index (IR), indicated, in general, a low ecological risk associated with the REE in DC samples. Furthermore, the mineralogical composition analysis of DC, performed by X-ray powder diffraction (XRD), showed that sample composition is mainly of quartz and calcite, while analysis by X-ray fluorescence spectrometry (XRF) indicated that the perforated rocks are composed of aluminosilicate minerals with high levels of SiO<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub>.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"7"},"PeriodicalIF":2.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abdullahi Bala Alhassan, Mohammed Othman Aljahdali
{"title":"Growth Response of Lemna minor Exposed to Cd Using PlantCV Image-Based Analysis and Photosynthetic Pigments.","authors":"Abdullahi Bala Alhassan, Mohammed Othman Aljahdali","doi":"10.1007/s00128-025-04074-1","DOIUrl":"10.1007/s00128-025-04074-1","url":null,"abstract":"<p><p>The increase in environmental contaminants such as heavy metals in aquatic ecosystems has been on the increase due to an increase in anthropogenic activities. In this study, the effect of varying concentrations (0.8 µg/L, 5.7 µg/L, 9.5 µg/L, 13.1 µg/L, 24.6 µg/L, 37.9 µg/L) of cadmium on Lemna minor was evaluated using an automated image-based analysis PlantCV v.3.8.0 through processing pipeline developed in the Python programing language (v.3.7.3). Chlorophyll was determined using a UV-VIS Spectrophotometer at wavelengths of 664, 647 and 664 nm. There was significant variation (p < 0.05) in the concentration course inhibitory effect of Cd, with the highest inhibition for frond area, convex hull, perimeter and solidity at Cd concentration of 37.9 µg/L. This study demonstrates the applicability of the developed PlantCV measurement pipeline as an efficient and reproducible approach for assessing plant responses, thereby supporting enhanced monitoring and management of aquatic ecosystem health.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"6"},"PeriodicalIF":2.7,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Shear Strength and Stress-Strain Normalized Characterization of Alkali-Contaminated Red Clay.","authors":"Guiyuan Xiao, Dajin Zhang, Guangli Xu, Le Yin, Yuliang Zhou, Guanghui Jiang","doi":"10.1007/s00128-025-04071-4","DOIUrl":"10.1007/s00128-025-04071-4","url":null,"abstract":"<p><p>Alkali-contaminated soil is a severe global issue. Red clay, widely dispersed throughout southern China, is commonly employed as roadbed and foundation soils. As a result, it is vital to investigate the changes in shear strength and stress-strain relationships of alkali-contaminated soils. To examine the impact of alkali contamination on red clay's shear strength and stress-strain behavior, we conducted indoor consolidated undrained triaxial shear experiments on red clay samples contaminated with various pH levels (pH 7, pH 9, pH 10, pH 11). The findings indicated that the cementation effect of free oxides in red clay was compromised, and the interparticle connection structure was disrupted due to alkali contamination. As the pH increased, the shear strength of red clay exhibited a persistent decline. Next, an investigation was conducted into the stress-strain normalized characteristics of alkali-contaminated red clay, utilizing the stress-strain relationship curves acquired from the conducted experiments. Ultimately, a prediction equation for the stress-strain relationship of red clay under varying pH pollution was established by matching the stress-strain parameters and utilizing the asymptotic value of the principal stress difference as the normalization factor. The prediction equation accurately forecasts the stress-strain correlation of red clay under varying pH contamination. This study has enhanced comprehension of the shear strength and normalized characteristics of red clay polluted with alkali.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"5"},"PeriodicalIF":2.7,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144493327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sultan Alam, Najeeb Ur Rahman, Muhammad Ilyas, Iram -, AlSaba Gul, Muhammad Zahoor, Muhammad Naveed Umar, Riaz Ullah, Essam A Ali
{"title":"Preparation, Characterization and Removal of Acid Blue 129 and Erioglaucine Dyes from Aqueous Solution by Corn Cob Based Activated Carbon.","authors":"Sultan Alam, Najeeb Ur Rahman, Muhammad Ilyas, Iram -, AlSaba Gul, Muhammad Zahoor, Muhammad Naveed Umar, Riaz Ullah, Essam A Ali","doi":"10.1007/s00128-025-04076-z","DOIUrl":"10.1007/s00128-025-04076-z","url":null,"abstract":"<p><p>Herein, corn cobs (maize) have been converted into an activated carbon by subjecting to carbonization which were then treated with 1:1 solution of HCl and HNO<sub>3</sub> and finally passed through C<sub>6</sub>H<sub>12</sub> solution and finally activated at a high temperature of 400◦C. The obtained activated sample was subjected to XRD, EDX, and SEM analysis. The surface area was estimated as 913 m<sup>2</sup>/g using a reported method in literature. The synthesized activated carbon was utilized as sorbent for acid blue 129 and Erioglaucine dyes. The kinetics of the process was evaluated at 20, 40, and 60 °C with best fitting achieved with pseudo-2nd order kinetics model. The correlation coefficient (R<sup>2</sup>) of the Langmuir model was high approaching to 1 thus exhibited best fitting of the data. The maximal adsorption capacity was 769.23 mg/g for erioglaucine and 833.33 mg/g for acid blue 129 recorded at 333 K. The thermodynamic parameters such as Gibbs free energy, enthalpy and entropy changes were also determined. The ΔG° and ΔH° (- 16.805 kJmol<sup>- 1</sup> & - 9.054 kJmol<sup>- 1</sup>) values were negative indicated the feasibility of the process and its exothermic nature. The increase in disorder at solid-solution interface during the adsorption process was evident from the positive values of ΔS° (79.253 JK<sup>- 1</sup> mol<sup>- 1</sup> & 39.633 JK<sup>- 1</sup>) indicated the spontaneity of the process. Further equilibrium was established from 5 to 7 min for both the dyes whereas optimum adsorbent dosage selected was 0.01 g. The synthesized activated carbon has been prepared from a renewable biomass source therefore; it could be the best alternative of synthetic water reclamation methods subjected to further validation by other researchers.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"4"},"PeriodicalIF":2.7,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144493326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jinghong Huang, Bo Gao, Hao Tong, Yaqing Wu, Peng Xiao
{"title":"Exposure to Dimefluthrin Affects the Development of Zebrafish (Danio rerio).","authors":"Jinghong Huang, Bo Gao, Hao Tong, Yaqing Wu, Peng Xiao","doi":"10.1007/s00128-025-04073-2","DOIUrl":"10.1007/s00128-025-04073-2","url":null,"abstract":"<p><p>Dimefluthrin is a widely used insecticide that exhibits toxicity to numerous aquatic organisms. However, its developmental effects on fish remain poorly understood. This study investigated the impact of dimefluthrin exposure on zebrafish (Danio rerio) development. Embryos were exposed to 0.2, 0.6, and 0.8 µM dimefluthrin for 96 h post-fertilization (hpf). Morphological alterations, oxidative stress levels, and the transcription of embryogenesis-related marker genes were assessed. Dimefluthrin exposure induced significant locomotor impairments, characterized by intensified spastic movements and altered swimming trajectories in larvae. Swim bladder formation was inhibited, leading to non-inflated swim bladders. Notably, dimefluthrin exposure resulted in a 43.33% increase in superoxide dismutase (SOD) enzymatic activity and an 82.25% decrease in malondialdehyde (MDA) content compared to controls. Furthermore, dimefluthrin disrupted the expression of dopamine-related genes (th and slc6a3) and swim bladder marker genes (anxa5b and hprt1l). These findings demonstrated that dimefluthrin induces locomotor dysfunction, oxidative stress, and swim bladder non-inflation in zebrafish, providing valuable insights into its potential environmental risk assessment.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"115 1","pages":"3"},"PeriodicalIF":2.7,"publicationDate":"2025-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lilian G Crisanto-Téllez, Guillermo Espinosa-Reyes, Felipe Ascencio, Jaime Rendón-von Osten, Begoña Jiménez, Ricardo Rodríguez-Estrella, Ernesto Ruelas Inzunza
{"title":"Hexachlorocyclohexane in Non-breeding Populations of American Kestrel (Falco sparverius) in Central Mexico.","authors":"Lilian G Crisanto-Téllez, Guillermo Espinosa-Reyes, Felipe Ascencio, Jaime Rendón-von Osten, Begoña Jiménez, Ricardo Rodríguez-Estrella, Ernesto Ruelas Inzunza","doi":"10.1007/s00128-025-04069-y","DOIUrl":"10.1007/s00128-025-04069-y","url":null,"abstract":"<p><p>We studied the concentration of hexachlorocyclohexane (HCH) and isomers in blood samples of American kestrels (Falco sparverius) during the non-breeding season in agricultural fields across two states of central Mexico. The majority of the 36 kestrels we sampled were females (72%). In both, Tlaxcala and Hidalgo, the mean concentrations of ∑HCH were 0.07 µg/mL, and the presence of this contaminant did not vary between sexes, nor within or between states. We also detected the isomers β-HCH and γ-HCH (lindane) in most samples (97 and 80%, respectively), while α-HCH was the only other isomer found in a single sample. Our results confirm the presence of HCH in the non-breeding, overwintering populations of American kestrels in central Mexico. This report warrants further investigation of the timing, sources, and intake pathways of these contaminants in this migratory raptor.</p>","PeriodicalId":501,"journal":{"name":"Bulletin of Environmental Contamination and Toxicology","volume":"114 6","pages":"94"},"PeriodicalIF":2.7,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144293113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}