ACS Applied Energy Materials最新文献

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An Ethylene-Vinyl Acetate Copolymer Based Solid Polymer Electrolyte via Water Modification for Laminated WO3-NiO Electrochromic Devices 水改性乙烯-醋酸乙烯共聚物基固体聚合物电解质用于WO3-NiO层压电致变色器件
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-21 DOI: 10.1021/acsaem.4c0335910.1021/acsaem.4c03359
Chen Yuan, Ye Yang*, Qiongya Jin, Chengzhang Chen, Qi Cheng, Xinyu Ji, Qing Yang and Weijie Song*, 
{"title":"An Ethylene-Vinyl Acetate Copolymer Based Solid Polymer Electrolyte via Water Modification for Laminated WO3-NiO Electrochromic Devices","authors":"Chen Yuan,&nbsp;Ye Yang*,&nbsp;Qiongya Jin,&nbsp;Chengzhang Chen,&nbsp;Qi Cheng,&nbsp;Xinyu Ji,&nbsp;Qing Yang and Weijie Song*,&nbsp;","doi":"10.1021/acsaem.4c0335910.1021/acsaem.4c03359","DOIUrl":"https://doi.org/10.1021/acsaem.4c03359https://doi.org/10.1021/acsaem.4c03359","url":null,"abstract":"<p >The ethylene-vinyl acetate (EVA) copolymer, a popular transparent adhesive interlayer material for solar cell encapsulation, can be formed by a simple extrusion process at a relatively low temperature without the aid of an organic solvent. However, the inherently poor ionic conductivity (σ) restricts its application as a solid polymer electrolyte (SPE) for laminated WO<sub>3</sub>-NiO electrochromic devices (ECDs). Here, we propose a strategy to improve the σ by a water modification in the EVA matrix. The results demonstrate that the sample treated at 50 °C and 25% relative humidity (RH) for 1 h exhibits a higher σ of 3.80 × 10<sup>–4</sup> S cm<sup>–1</sup>, as well as a visual transmittance of more than 90%, a tensile strength of 1.61 MPa, and an excellent thermal stability up to 219 °C. Using this kind of EVA-based SPE (EVA-SPE) as the interlayer, WO<sub>3</sub>-NiO based ECDs with sizes varying from 2.5 × 5 to 20 × 20 cm<sup>2</sup> have been successfully laminated and exhibit favorable EC performances. Besides, the water modification is conducive to an enlarged light modulation range (Δ<i>T</i>) for the laminated ECD in the near-infrared zone, ensuring a high energy efficiency when the device is used as a smart window in buildings.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4466–4474 4466–4474"},"PeriodicalIF":5.4,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of Rare-Earth Phosphate as a Hydrophilic Promoter on Boosting Electrooxidation of 5-Hydroxymethylfurfural: A DyPO4/Ni2P Example 稀土磷酸盐作为亲水性促进剂对5-羟甲基糠醛电氧化的影响:以DyPO4/Ni2P为例
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-21 DOI: 10.1021/acsaem.5c0031810.1021/acsaem.5c00318
Wen-jing Yao, Sheng Liao, Hao-yi Fu, Wen-yi Xu, Meng Xu, Dan Zhao* and Chao Chen, 
{"title":"Impact of Rare-Earth Phosphate as a Hydrophilic Promoter on Boosting Electrooxidation of 5-Hydroxymethylfurfural: A DyPO4/Ni2P Example","authors":"Wen-jing Yao,&nbsp;Sheng Liao,&nbsp;Hao-yi Fu,&nbsp;Wen-yi Xu,&nbsp;Meng Xu,&nbsp;Dan Zhao* and Chao Chen,&nbsp;","doi":"10.1021/acsaem.5c0031810.1021/acsaem.5c00318","DOIUrl":"https://doi.org/10.1021/acsaem.5c00318https://doi.org/10.1021/acsaem.5c00318","url":null,"abstract":"<p >The hydrophilic property of the catalytic interface has been seldom focused on particularly, although many green and sustainable catalysis transformations involve water. Addressing the issue, we prepared Dy–Ni–P catalysts for the 5-hydroxymethylfurfural oxidation reaction (HMFOR) to 2,5-furandicarboxylic acid (2,5-FDCA) in this work. The catalysts were clarified as (DyPO<sub>4</sub>)<sub><i>m</i></sub>/Ni<sub>2</sub>P composites with molar ratio <i>m</i> within 0.08–0.28 by ICP-OES, XRD, XPS, and HRTEM characterizations. The catalytic performance of samples was comprehensively analyzed by the HPLC technique, <sup>1</sup>H NMR spectra, and various electrochemical tests, indicating that the introduction of DyPO<sub>4</sub> in a proper amount (<i>m</i> = 0.16) would significantly enhance the catalytic efficiency versus singular Ni<sub>2</sub>P in terms of 2,5-FDCA yield (91 vs 26%), selectivity (99 vs 47%), and Faradaic Efficiency (F.E.: 98 vs 70%). The enhancements were accompanied by improved kinetic features such as the Tafel slope (53 vs 95 mV dec<sup>–1</sup>) and intrinsic activity (3.3 vs 1.7 mA cm<sup>–2</sup>). The boosting endowment (DyPO<sub>4</sub>)<sub><i>m</i></sub>/Ni<sub>2</sub>P stands among the top members of reported Ni-based HMFOR catalysts. The promoter effect of DyPO<sub>4</sub> was further investigated by H<sub>2</sub>O-TPD, contact angle, zeta potential, OCP, and EIS measurements. It was testified that the nonhydrophilic Ni<sub>2</sub>P surface would be converted to a hydrophilic composite interface with the introduction of DyPO<sub>4</sub>; in line with the essential change, transfer of reactants and activation of water were obviously intensified with the lowered charge transfer resistance along the catalytic interface, which was responsible for the enhanced catalytic behavior of (DyPO<sub>4</sub>)<sub><i>m</i></sub>/Ni<sub>2</sub>P versus Ni<sub>2</sub>P. The above discovery made the topic regarding water indicate that the hydrophilic property of the catalytic interface played a significant role in facilitating heterogeneous catalysis transformations involving water; exampled by the current (DyPO<sub>4</sub>)<sub><i>m</i></sub>/Ni<sub>2</sub>P for HMFOR, rare-earth phosphate could be referred to as an outstanding hydrophilic promoter to innovate excellent catalysts for technology-important chemical engineering involving water.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4824–4835 4824–4835"},"PeriodicalIF":5.4,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dopant-Free Polymeric Hole-Transport Materials for Perovskite Solar Cells: Simple Is Best! 用于钙钛矿太阳能电池的无掺杂聚合物空穴传输材料:简单就是最好!
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-21 DOI: 10.1021/acsaem.4c0263110.1021/acsaem.4c02631
Ekaterina A. Komissarova*, Sergei A. Kuklin, Victoria V. Ozerova, Andrey V. Maskaev, Azat F. Akbulatov, Nikita A. Emelianov, Alexander V. Mumyatov, Lavrenty G. Gutsev, Lyubov A. Frolova and Pavel A. Troshin*, 
{"title":"Dopant-Free Polymeric Hole-Transport Materials for Perovskite Solar Cells: Simple Is Best!","authors":"Ekaterina A. Komissarova*,&nbsp;Sergei A. Kuklin,&nbsp;Victoria V. Ozerova,&nbsp;Andrey V. Maskaev,&nbsp;Azat F. Akbulatov,&nbsp;Nikita A. Emelianov,&nbsp;Alexander V. Mumyatov,&nbsp;Lavrenty G. Gutsev,&nbsp;Lyubov A. Frolova and Pavel A. Troshin*,&nbsp;","doi":"10.1021/acsaem.4c0263110.1021/acsaem.4c02631","DOIUrl":"https://doi.org/10.1021/acsaem.4c02631https://doi.org/10.1021/acsaem.4c02631","url":null,"abstract":"<p >A series of (BDD-X)<sub>n</sub> conjugated polymers, comprised of 5,7-bis(2-ethylhexyl)benzo[1,2-<i>c</i>:4,5-<i>c</i>′]dithiophene-4,8-dione (BDD) and X = B (<b>P1</b>), X = TBT (<b>P2</b>), and X = TBTBT (<b>P3</b>), where T = thiophene and B = benzo[<i>c</i>][1,2,5]thiadiazole, have been synthesized and applied as dopant-free hole-transport layer materials in perovskite solar cells (PSCs). We explored the effect of the molecular structure of the block X on the optical and electronic properties of the polymers, the nanoscale morphology of their films, and the impact of all these parameters on the performance of the polymers in PSCs. As a result, using the polymer <b>P1</b> with the simplest molecular architecture provided a power conversion efficiency (PCE) of 20.1% in solar cells, thus outperforming devices assembled with the more sophisticated polymers <b>P2</b>–<b>P3</b> or the reference poly(triarylamine)-based hole-transport materials. The enhanced device performance is attributed to a better HOMO alignment of <b>P1</b> with respect to the perovskite valence band, a low concentration of defects and suppressed carrier recombination at the <b>P1</b>/perovskite interface and, most importantly, a highly uniform film structure, as revealed by atomic force microscopy and infrared scattering near-field optical microscopy (IR s-SNOM) techniques. The supramolecular interactions of the building blocks of polymers <b>P1</b>–<b>P3</b> with the perovskite films, resulting in the passivation of surface defects, were further studied by density functional theory calculations.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4072–4079 4072–4079"},"PeriodicalIF":5.4,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morphology Control of Immiscible Polymer-Blended Anion-Exchange Membranes 非混相聚合物-共混阴离子交换膜的形态控制
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-21 DOI: 10.1021/acsaem.5c0032210.1021/acsaem.5c00322
Erfan Asadipour,  and , Vijay Ramani*, 
{"title":"Morphology Control of Immiscible Polymer-Blended Anion-Exchange Membranes","authors":"Erfan Asadipour,&nbsp; and ,&nbsp;Vijay Ramani*,&nbsp;","doi":"10.1021/acsaem.5c0032210.1021/acsaem.5c00322","DOIUrl":"https://doi.org/10.1021/acsaem.5c00322https://doi.org/10.1021/acsaem.5c00322","url":null,"abstract":"<p >Membranes are an integral component of electrochemical flow reactors (EFRs), allowing charge carrier transport between electrodes while blocking active species. Many EFR technologies utilize cation-exchange membranes (CEMs) extensively due to their high conductivity and chemical stability; however, CEMs do not obstruct cationic active species and cause unwanted electrolyte cross-contamination in EFR technologies that use cations as active species, e.g., redox flow batteries (RFBs) and electrodialysis. Anion-exchange membranes (AEMs) innately block cations; however, they are not sufficiently durable. Developing strategies to enhance their durability is necessary to expand their application in RFBs and similar EFRs. This work investigates the morphology control of immiscible polymer-blended AEMs via tuning the blend composition and casting temperature. Marangoni-Bénard effect was identified as the dominant mechanism behind the perturbations in the casting solution film. Marangoni cells appear at AEMs cast at &gt;40 °C, leading to desirable lateral phase separation of polymers. The ionic conductivity of lateral phase-separated AEMs improved with lowering the casting temperature, indicating that excessively heightened perturbations in the casting films damage the conductivity routes. Adding 20% PVDF-<i>co</i>-HFP to the AEM reduced the water uptake (30 vs 58%), hence increasing the durability of the AEM (conductivity loss of 21 vs 63% over a week) while sacrificing minimal ionic conductivity (11 vs 13 mS·cm<sup>–1</sup>). Hence, polymer blending is a useful strategy to improve the durability of membranes for RFBs and similar electrochemical systems.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4681–4687 4681–4687"},"PeriodicalIF":5.4,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combined Effects of LiCl Addition and Solvent-in-Water Approaches on Aqueous Magnesium-Ion Battery Performance 添加LiCl和水溶溶剂对水镁离子电池性能的联合影响
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-21 DOI: 10.1021/acsaem.4c0333710.1021/acsaem.4c03337
N K Wally, Eslam Sheha, Ibrahim Mohamed Morad and Mohamed M. El-Desoky*, 
{"title":"Combined Effects of LiCl Addition and Solvent-in-Water Approaches on Aqueous Magnesium-Ion Battery Performance","authors":"N K Wally,&nbsp;Eslam Sheha,&nbsp;Ibrahim Mohamed Morad and Mohamed M. El-Desoky*,&nbsp;","doi":"10.1021/acsaem.4c0333710.1021/acsaem.4c03337","DOIUrl":"https://doi.org/10.1021/acsaem.4c03337https://doi.org/10.1021/acsaem.4c03337","url":null,"abstract":"<p >The advancement of a competitive Mg-ion battery is restricted by the limited mobility of Mg ions in the current host materials. Herein, LiCl is added as a supporting salt to an MgCl<sub>2</sub> salt-based, polyethylene glycol (PEG) solvent-in-water electrolyte (SIW) to obtain the H-PG-Mg electrolyte. The LiCl addition is employed to benefit from its reported synergistic effects in minimizing cell potential and shielding effects, suppressing dendritic formation, and promoting the ability of MgCl<sub>2</sub> deposits to dissolve and expose a fresh anode surface. The H-PG-Mg@Li electrolyte shows the highest electrochemical stability window (ESW) of 3.3 V, which is 1.5 times higher than the LiCl-free electrolyte, and the highest ion transference number of 0.70. MgO-V<sub>2</sub>O<sub>5</sub>–P<sub>2</sub>S<sub>5</sub> (G) electrode is tested in a three-electrode configuration and displays superior capacity retention of 60% after 1000 cycles. The G/H-PG-Mg@Li/Mg cell exhibits the best cycling stability of up to 150 cycles. The ability of the G cathode to reversibly accommodate Mg<sup>2+</sup> cations in H-PG-Mg@Li due to lower overall charge density was highlighted using ex-situ elemental analysis, where the ratio of the ions followed the charging and discharging processes. These results highlight LiCl addition and SIW strategies as effective approaches to upgrading the electrochemical performance of current aqueous Mg batteries.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4441–4455 4441–4455"},"PeriodicalIF":5.4,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pyridinium-Benzoxazole-Based Anode Material for Sustainable All-Organic Polymer-Based Batteries 吡啶-苯并恶唑基可持续全有机聚合物基电池负极材料
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-20 DOI: 10.1021/acsaem.4c0312710.1021/acsaem.4c03127
Xhesilda Fataj, Andreas J. Achazi, Christian Stolze, Simon Muench, René Burges, Ilya Anufriev, Manon Mignon, Doreen Mollenhauer, Ivo Nischang, Martin D. Hager and Ulrich S. Schubert*, 
{"title":"Pyridinium-Benzoxazole-Based Anode Material for Sustainable All-Organic Polymer-Based Batteries","authors":"Xhesilda Fataj,&nbsp;Andreas J. Achazi,&nbsp;Christian Stolze,&nbsp;Simon Muench,&nbsp;René Burges,&nbsp;Ilya Anufriev,&nbsp;Manon Mignon,&nbsp;Doreen Mollenhauer,&nbsp;Ivo Nischang,&nbsp;Martin D. Hager and Ulrich S. Schubert*,&nbsp;","doi":"10.1021/acsaem.4c0312710.1021/acsaem.4c03127","DOIUrl":"https://doi.org/10.1021/acsaem.4c03127https://doi.org/10.1021/acsaem.4c03127","url":null,"abstract":"<p >In search of anode materials for organic batteries, we propose benzoxazole-based redox-active polymers. We report theoretically calculated redox properties of the monomer and polymer based on small polymer chain models using density functional theory (DFT). Subsequently, a straightforward synthesis of poly(4-(benzoxazol-2-yl)-1-(4-vinyl benzyl)pyridinium chloride) (PBO) via radical polymerization is presented. To our knowledge, PBO is the first representative of this class of redox-active polymers applied in batteries, and it has a theoretical specific capacity of 76.8 mA h g<sup>–1</sup> (first redox process). PBO was utilized as an anode and capacity-limiting electrode in an all-organic radical battery using aqueous- and organic-based electrolytes as well as 2,2,6,6-tetramethylpiperidinyl-<i>N</i>-oxy (TEMPO) derivatives as cathodes, providing a cell voltage of 1.3 and 1.4 V in aqueous- and organic-based electrolytes, respectively. The material revealed 99% capacity utilization at 1 C in the first cycle using an organic electrolyte (1 M LiClO<sub>4</sub> in CH<sub>3</sub>CN) and more than 75% capacity utilization in an aqueous electrolyte (1 M LiClO<sub>4</sub> in H<sub>2</sub>O). In both systems, after rate capability tests (from 0.2 to 50 C), the cells were cycled again at 1 C, where 50% of the initial capacity was retained after 100 cycles. Even though, due to the linearity and the molar mass of PBO, a capacity decay is observed during cycling tests, this study opens a promising class of molecules for the development of anode materials.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4220–4230 4220–4230"},"PeriodicalIF":5.4,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsaem.4c03127","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boosting High Energy Density for Aqueous Ni–Zn Batteries by Synergetic Engineering of Bimetal Doping and Se Vacancy in Ni3Se2 双金属掺杂与Ni3Se2中Se空位协同工程提高Ni-Zn水电池高能量密度
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-20 DOI: 10.1021/acsaem.5c0046610.1021/acsaem.5c00466
Xiaokang Fu, Shuangxing Cui, Minghui Xu, Guochang Li*, Yifan Tang, Wan Cui, Xunwen Xiao* and Lei Han*, 
{"title":"Boosting High Energy Density for Aqueous Ni–Zn Batteries by Synergetic Engineering of Bimetal Doping and Se Vacancy in Ni3Se2","authors":"Xiaokang Fu,&nbsp;Shuangxing Cui,&nbsp;Minghui Xu,&nbsp;Guochang Li*,&nbsp;Yifan Tang,&nbsp;Wan Cui,&nbsp;Xunwen Xiao* and Lei Han*,&nbsp;","doi":"10.1021/acsaem.5c0046610.1021/acsaem.5c00466","DOIUrl":"https://doi.org/10.1021/acsaem.5c00466https://doi.org/10.1021/acsaem.5c00466","url":null,"abstract":"<p >Developing transition metal selenide materials with high capacity, excellent rate capability, and satisfactory durability presents significant challenges due to their sluggish electrochemical kinetics, limited electrical conductivity, and detrimental volume change. To address these challenges, we have prepared four Ni<sub>3</sub>Se<sub>2</sub>-based cathode materials, named as Ni<sub>3</sub>Se<sub>2</sub>, Mo-Ni<sub>3</sub>Se<sub>2</sub>, V-Ni<sub>3</sub>Se<sub>2</sub>, and MoV-Ni<sub>3</sub>Se<sub>2</sub>, with selenium vacancies through a one-step hydrazine-hydrothermal process. Co doping with Mo and V demonstrates the synergistic effects of the bimetallic dopants and induces the generation of a higher density of selenium vacancies. The incorporation of Mo/V codoping and rich selenium vacancies confers upon MoV-Ni<sub>3</sub>Se<sub>2</sub> obvious advantages, such as improved electrical conductivity, enhanced structural flexibility, sufficient redox reaction sites, and reduction of charge-transfer resistance. Consequently, the MoV-Ni<sub>3</sub>Se<sub>2</sub> electrodes achieve a peak specific capacity of 1.78 mAh cm<sup>–2</sup> at a current density of 2 mA cm<sup>–2</sup> and sustain a high rate capability of 0.96 mAh cm<sup>–2</sup> at 50 mA cm<sup>–2</sup>. The MoV-Ni<sub>3</sub>Se<sub>2</sub>//Zn battery delivers an impressive surface energy density of 2.93 mWh cm<sup>–2</sup> and a remarkable power density of 51.55 mW cm<sup>–2</sup> with outstanding cycling stability (capacity retention of 87.44% at 20 mA cm<sup>–2</sup> after 3000 cycles). This study provides valuable insights for the development of high-performance cathode electrodes by synergetic engineering of doping and defects for aqueous nickel–zinc batteries.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4775–4783 4775–4783"},"PeriodicalIF":5.4,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rational Design Strategy for the Synthesis of Hyper-Cross-Linked Polymers Using Dipolar π-Systems and Proton Sorption Induced Pseudocapacitance 利用偶极π系和质子吸附诱导赝电容合成超交联聚合物的合理设计策略
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-20 DOI: 10.1021/acsaem.5c0004910.1021/acsaem.5c00049
Soujanya H. Goudar, Rituprava Dash, Deepu J. Babu, Narendra Kurra* and Kotagiri Venkata Rao*, 
{"title":"Rational Design Strategy for the Synthesis of Hyper-Cross-Linked Polymers Using Dipolar π-Systems and Proton Sorption Induced Pseudocapacitance","authors":"Soujanya H. Goudar,&nbsp;Rituprava Dash,&nbsp;Deepu J. Babu,&nbsp;Narendra Kurra* and Kotagiri Venkata Rao*,&nbsp;","doi":"10.1021/acsaem.5c0004910.1021/acsaem.5c00049","DOIUrl":"https://doi.org/10.1021/acsaem.5c00049https://doi.org/10.1021/acsaem.5c00049","url":null,"abstract":"<p >Hyper-cross-linked polymers (HCPs) are one of the important classes of porous organic polymers and are known for their easy preparation under mild conditions by employing readily available precursors. Though there are many HCPs synthesized out of electron-rich π-systems, literature reports of HCPs with π-systems having electron-deficient functional groups such as imides are sparse. This is challenging due to the inherent inefficient nature of Friedel–Crafts alkylation on π-systems with electron-deficient functional groups. In this study, we report a rational strategy for the synthesis of HCPs using benzoperylene imide (BPI) based dipolar π-systems via Friedel–Crafts alkylation. This is achieved by attaching a phenylbutane chain at the imide position, in which the phenyl ring of the phenylbutane serves as the site for Friedel–Crafts alkylation. The resultant <b>BPI-HCP-I</b> exhibits a Brunauer–Emmett–Teller surface area of 544 m<sup>2</sup>/g and strong visible-light absorption up to 600 nm. On the other hand, HCPs synthesized without any phenyl ring at the imide side chain (<b>BPI-HCP-II</b> and <b>BPI-HCP-III</b>) exhibit poor surface area due to inefficient cross-linking via Friedel–Crafts alkylation. Interestingly, <b>BPI-HCP-I</b> showed good electrochemical performance, exhibiting a specific capacitance of 112 F/g, highlighting its reversible proton storage capability. Our study provides the pathway for the synthesis of HCPs with large dipolar π-systems, which are good candidates for strong visible-light absorption and energy storage applications.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4494–4500 4494–4500"},"PeriodicalIF":5.4,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2,4,6-Tris(4-fluorophenyl)cyclo-boroxine as an Electrolytes Additive to Form Ultrathin CEI Interfacial Membrane for Improved High-Voltage LiNi0.8Co0.1Mn0.1O2 Lithium-Ion Batteries 2,4,6-三(4-氟苯基)环硼辛作为电解质添加剂形成超薄CEI界面膜用于改进的高压LiNi0.8Co0.1Mn0.1O2锂离子电池
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-20 DOI: 10.1021/acsaem.4c0303410.1021/acsaem.4c03034
Liqing Li, Jie Liu, Lucheng Li, Jiaming Liu, Run Zhou, Lixu Zhang and Jun Chen*, 
{"title":"2,4,6-Tris(4-fluorophenyl)cyclo-boroxine as an Electrolytes Additive to Form Ultrathin CEI Interfacial Membrane for Improved High-Voltage LiNi0.8Co0.1Mn0.1O2 Lithium-Ion Batteries","authors":"Liqing Li,&nbsp;Jie Liu,&nbsp;Lucheng Li,&nbsp;Jiaming Liu,&nbsp;Run Zhou,&nbsp;Lixu Zhang and Jun Chen*,&nbsp;","doi":"10.1021/acsaem.4c0303410.1021/acsaem.4c03034","DOIUrl":"https://doi.org/10.1021/acsaem.4c03034https://doi.org/10.1021/acsaem.4c03034","url":null,"abstract":"<p >Increasing the cutoff voltage for charging lithium batteries can increase the capacity density of lithium-ion batteries. Still, it is also accompanied by some adverse effects, including electrode material corrosion and electrolyte loss. To mitigate these adverse effects, this article reports on a high-voltage catholyte additive, 2,4,6-tris(4-fluorophenyl)cyclo-boroxine (PFTB). Calculation demonstrates that the HOMO energy level of PFTB is lower than that of typical solvents. Consequently, PFTB can decompose selectively to generate a robust and conductive protective CEI membrane. This reduces the occurrence of interfacial side reactions and thus protects the electrode material’s structural integrity. The outcomes of extended cyclical assessments demonstrate that the capacity retention rates are 83.7% (4.2 V), 89.0% (4.3 V), 80.4% (4.4 V), and 81.8% (4.5 V), respectively, when 1.0 wt % PFTB is incorporated into the standard electrolyte. The results of the physical characterization demonstrate that PFTB undergoes preferential decomposition on the cathode, forming a CEI membrane rich in F and B elements. These elements can effectively enhance the conductivity and stability of the CEI membrane. Therefore, adding PFTB to the electrolyte as an additive provides an economical and effective method for studying high-energy lithium batteries.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4200–4210 4200–4210"},"PeriodicalIF":5.4,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Innovative Synthesis and Advancement Strategies for GCN as Supercapacitor Electrodes: A Comprehensive Review Revealing New Insights GCN作为超级电容器电极的创新合成和推进策略:全面综述揭示新见解
IF 5.4 3区 材料科学
ACS Applied Energy Materials Pub Date : 2025-03-20 DOI: 10.1021/acsaem.4c0266710.1021/acsaem.4c02667
Mahdi Saadati pour, Mercedeh Delyanee and Mona Zamani Pedram*, 
{"title":"Innovative Synthesis and Advancement Strategies for GCN as Supercapacitor Electrodes: A Comprehensive Review Revealing New Insights","authors":"Mahdi Saadati pour,&nbsp;Mercedeh Delyanee and Mona Zamani Pedram*,&nbsp;","doi":"10.1021/acsaem.4c0266710.1021/acsaem.4c02667","DOIUrl":"https://doi.org/10.1021/acsaem.4c02667https://doi.org/10.1021/acsaem.4c02667","url":null,"abstract":"<p >Graphitic carbon nitride (GCN), a graphite-like material composed of aromatic tri-s-triazine units, has recently gained recognition as a promising candidate for supercapacitor electrode applications. Its abundant availability, metal-free composition, high nitrogen content, and responsiveness to environmental conditions make GCN a highly attractive material for energy storage solutions. Despite this potential, challenges remain in optimizing its specific capacity and energy density. This review stands out by comprehensively analyzing various GCN synthesis methods such as hydrothermal, solvothermal, and sol–gel techniques and critically examining how these methods influence electrochemical performance. A particular focus is placed on identifying optimal synthesis techniques through a detailed comparison of their impact on key functional parameters. This review differentiates from previous studies’ in-depth exploration of advanced strategies to enhance GCN’s electrochemical properties. Specifically, the review delves into innovative approaches like element doping and hybridization with polymers, metals, and carbon-based materials, offering new pathways to significantly boost the performance of GCN electrodes. These cutting-edge strategies have not been systematically explored in other reviews, positioning this article as a forward-thinking contribution to the field. In addition, the review takes a broader, interdisciplinary approach by examining GCN’s functionality in other applications, such as water splitting, and identifying critical commonalities between the functional parameters of these applications and those of supercapacitors. This cross-application analysis, rarely addressed in previous literature, opens new avenues for GCN development, suggesting that insights from related fields can accelerate the optimization of GCN as a supercapacitor electrode. By emphasizing the innovative combination of element doping and metal-based hybridization, this review offers a novel perspective on advancing GCN technology. It also addresses current challenges and provides practical recommendations, making it a pivotal resource for future breakthroughs in energy storage and related applications.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"3997–4031 3997–4031"},"PeriodicalIF":5.4,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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