Luminescence最新文献_第5页

Selective Turn-On Luminescent Recognition of Perchlorate Ion Using Pyridyl-Benzimidazole–Based Probe 吡啶基苯并咪唑探针选择性发光识别高氯酸盐离子。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-20 DOI: 10.1002/bio.70087

Sudhanshu Naithani, Nidhi Goswami, Vikas Yadav, Jimmy Mangalam, Tapas Goswami, Sushil Kumar

{"title":"Selective Turn-On Luminescent Recognition of Perchlorate Ion Using Pyridyl-Benzimidazole–Based Probe","authors":"Sudhanshu Naithani, Nidhi Goswami, Vikas Yadav, Jimmy Mangalam, Tapas Goswami, Sushil Kumar","doi":"10.1002/bio.70087","DOIUrl":"10.1002/bio.70087","url":null,"abstract":"<div>\u0000 \u0000 Anions play a crucial role in various environmental, chemical, and biological processes. Among various anions, the production of perchlorate (ClO4−) ion is expected to rise in upcoming years, and thus, an efficient method for the detection of perchlorate ion is highly desirable. In this effort, a pyridyl-benzimidazole–based luminescent probe (RSB1) containing two N-H donor sites has been synthesized for selective detection of perchlorate ion. Different spectral techniques such as FT-IR, NMR, ESI-mass, UV–Vis, and fluorescence analyses have been used to characterize this probe. High selectivity of RSB1 for ClO4− was realized even in presence of strongly interfering species in aqueous-acetonitrile (CH3CN-H2O; 4:1, v/v) solution. Notably, RSB1 served as a “turn-on” perchlorate-responsive probe and exhibited an emission enhancement at 363 nm when excited at 300 nm. The detection limit (LoD) and the binding constant (Kb) values were depicted to be 0.121 μM and 2.6 × 105 M−1, respectively, while the binding mechanism for RSB1-ClO4− was validated via Job's plot, NMR, and DFT analyses. Furthermore, this probe was successfully employed to trace perchlorate in real samples such as tap water, distilled water, and soil samples with good to excellent recovery values.\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Novel Microfluidic-Based Fluorescence Detection Method Reveals Heavy Atom Effects on Photophysics of Fluorophores With High Triplet Quantum Yield: A Numerical Simulation Study 一种新的基于微流体的荧光检测方法揭示了重原子对高三态量子产率荧光团光物理的影响：数值模拟研究。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-20 DOI: 10.1002/bio.70090

Selim Can Dirican, Barış Demirbay

{"title":"A Novel Microfluidic-Based Fluorescence Detection Method Reveals Heavy Atom Effects on Photophysics of Fluorophores With High Triplet Quantum Yield: A Numerical Simulation Study","authors":"Selim Can Dirican, Barış Demirbay","doi":"10.1002/bio.70090","DOIUrl":"10.1002/bio.70090","url":null,"abstract":"The present study introduces the idea of a novel fluorescence-based imaging technique combined with a microfluidic platform that enables a precise control of dark transient state populations of fluorescent probes flowing over a uniform, top flat supergaussian excitation field with a constant flow rate. To demonstrate the imaging capability of the proposed detection method, numerical simulations have been performed by considering laser, microscope and flow parameters of experimental setup together with photophysical model and electronic transition rates of fluorescent dyes. As an output data to be assessed, fluorescence image data is simulated numerically for bromine-free carboxyfluorescein and its brominated derivatives having different numbers of bromine atoms. Based on the magnitudes of applied excitation irradiances and flow rates, which can be manually controlled by user during experiments, the presence of dark state populations can appear as broadening, shifts and decays in normalized fluorescence intensity signals that are computed from simulated fluorescence images. As such changes in signals become more pronounced upon an increase in the degree of bromination, it is elicited that heavy atom effect can be resolved by properly tuning excitation powers of laser and flow rates. Proposed imaging method has potential to provide invaluable means to conventional fluorescence methods and can open up new perspectives in biomedical research.","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11745564/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of Er3+-Doped BaF2 Single Crystals for Infrared Emission and Photovoltaic Efficiency Enhancement

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-20 DOI: 10.1002/bio.70102

A. Bitam, R. Fartas, M. Diaf, H. Boubekri, A. Cheddadi, I. R. Martin

{"title":"Investigation of Er3+-Doped BaF2 Single Crystals for Infrared Emission and Photovoltaic Efficiency Enhancement","authors":"A. Bitam, R. Fartas, M. Diaf, H. Boubekri, A. Cheddadi, I. R. Martin","doi":"10.1002/bio.70102","DOIUrl":"10.1002/bio.70102","url":null,"abstract":"<div>\u0000 \u0000 Er3+-doped BaF2 single crystals were investigated with two primary aims: first, to probe the infrared emissions from the 4I11/2 level (around 1.0 μm) under 1500-nm excitation and, second, to use the crystal to enhance the efficiency of silicon-based solar cells through upconversion mechanism. Upon excitation at 1500 nm, the upconversion emission spectrum of the Er3+-doped BaF2 single crystals, recorded in the range of 480–1080 nm, exhibited two well-structured visible bands at 538 and 650 nm, along with a strong near infrared emission at 971 nm. This strong 971-nm emission has an emission cross-section of approximately 0.23 × 10−20 cm2. As with any phenomenon inherent to energy transfer by upconversion, the 4I11/2 fluorescence decay exhibits a rise time followed by a long decay of approximately 15 ms and a positive optical gain from the low values of the population inversion coefficient, which could potentially give rise to laser emission from this level. When we place our crystal on a photovoltaic device illuminated by 1500-nm wavelength radiation, we record a photocurrent of 300 μA at an illumination power of 85 mW. This indicates that the Er3+-doped BaF2 crystal is highly suitable for significantly enhancing the efficiency of silicon-based solar cells.\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143059915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Novel Nitrogen Hybrid F− Sensors Based on ESIPT Mechanism Achieving Super Low Detection Limits 基于ESIPT机制的新型氮混合F-传感器实现超低检测限。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-20 DOI: 10.1002/bio.70098

Zeyang Zhu, Zixuan Xu, Xuemei Li, Hui Wang, Xinghui Cao, Shouzhu Li, Linhan Su, Shasha Wu

引用次数: 0

Correction to Clustering-Triggered Emission Mechanism of Carboxymethyl β-Cyclodextrin Aqueous Solution and Efficient Recognition of Fe3+ in Mixed Ions 羧甲基β-环糊精水溶液聚簇触发发射机理的修正及对混合离子中Fe3+的高效识别。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-19 DOI: 10.1002/bio.70091

{"title":"Correction to Clustering-Triggered Emission Mechanism of Carboxymethyl β-Cyclodextrin Aqueous Solution and Efficient Recognition of Fe3+ in Mixed Ions","authors":"","doi":"10.1002/bio.70091","DOIUrl":"10.1002/bio.70091","url":null,"abstract":"\u0000 H. Xu, J. Wang, Q. Li, Q. Zhou, “ Clustering-triggered emission mechanism of carboxymethyl β-cyclodextrin aqueous solution and efficient recognition of Fe3+ in mixed ions,” Luminescence 2024, 39(8), e4856, https://doi.org/10.1002/bio.4856.\u0000 The ranking of affiliations of this paper needs to be adjusted. The correct affiliations ranking should be as follows:1Engineering Research Center for Eco-Dyeingand Finishing of Textiles, Key Laboratory ofAdvanced Textile Materials and ManufacturingTechnology, Ministry of Education, College ofTextile Science and Engineering (InternationalInstitute of Silk), Zhejiang Sci-Tech University, Hangzhou, China2MOE Key Laboratory of MacromolecularSynthesis and Functionalization, Departmentof Polymer Science and Engineering, ZhejiangUniversity, Hangzhou, China3Zhejiang Sci-Tech University Shaoxing-Keqiao Research Institute, Zhejiang ProvincialInnovation Center of Advanced TextileTechnology, Building 7, Cross borderE-commerce Park, Huashe Street, KeqiaoDistrict, Shaoxing City, Zhejiang, ChinaThus, authors' affiliation links should be as follows:Haiyan Xu1,2 | Jun Wang1 | Qi Li3 | Qing Zhou1,2,3We apologize for these errors.","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.70091","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication of Highly Fluorescent Nitrogen and Phosphorus Dual-Doped Carbon Dots for Selective Sensing of Rutin 用于芦丁选择性传感的高荧光氮磷双掺杂碳点的制备。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-16 DOI: 10.1002/bio.70089

Reham E. Kannouma, Amira H. Kamal, Mohamed A. Hammad, Fotouh R. Mansour

{"title":"Fabrication of Highly Fluorescent Nitrogen and Phosphorus Dual-Doped Carbon Dots for Selective Sensing of Rutin","authors":"Reham E. Kannouma, Amira H. Kamal, Mohamed A. Hammad, Fotouh R. Mansour","doi":"10.1002/bio.70089","DOIUrl":"10.1002/bio.70089","url":null,"abstract":"<div>\u0000 \u0000 Based on nitrogen and phosphorus co-doped carbon dots (NP-CDs), a direct, quick, and selective sensing probe for fluorometric detection of rutin has been developed. Utilizing ethylene diamine tetra acetic acid (EDTA) as a carbon and nitrogen source and diammonium hydrogen phosphate (NH4)2HPO4 as a nitrogen and phosphorus source. The NP-CDs were synthesized in less than 3 min with a straightforward one-step microwave pyrolysis process with a high quantum yield (63.8%). After being excited at λ = 360 nm, the produced NP-CDs displayed a maximum bluish fluorescence at λem of 420 nm. Rutin quenched the fluorescence of the produced NP-CDs based on the inner filter effect and static quenching processes. Along with the International Council of Harmonization (ICH) requirements, the developed spectrofluorometric method was validated. The linearity range was 0.50–35.00 μg/mL of rutin. The developed NP-CDs were successfully employed to determine rutin concentrations in marketed tablets. The developed method is quick, simple, consistent, sensitive, and selective, and it does not require expensive chemicals or specialized instruments. This study paves the path for future application of NP-CD in pharmaceutical analysis.\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Elevating Red and Near-Infrared Detectivity With CsSnI3 Perovskite Photodetectors Featuring GO and PCBM as Charge Transport Layers 以氧化石墨烯和多氯联苯为电荷传输层的CsSnI3钙钛矿光电探测器提高红色和近红外探测能力。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-16 DOI: 10.1002/bio.70086

Pallavi Pandey, Akhilesh Kumar Chaudhary, Sudhanshu Verma

引用次数: 0

Green Synthesis of ZnO Nanoparticles Using Ficus benghalensis for Visible Light–Driven Photocatalytic Degradation of Crystal Violet and Antibacterial and Antibiofilm Activities 绿色合成氧化锌纳米粒子的红ficus benghalensis可见光驱动光催化降解结晶紫及其抗菌和抗生物膜活性

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-16 DOI: 10.1002/bio.70088

Perumal Karthiga, Kethrabalan Chitra, Mohammad Ahmad Wadaan, R. Mythili, Jintae Lee, Devaraj Bharathi

{"title":"Green Synthesis of ZnO Nanoparticles Using Ficus benghalensis for Visible Light–Driven Photocatalytic Degradation of Crystal Violet and Antibacterial and Antibiofilm Activities","authors":"Perumal Karthiga, Kethrabalan Chitra, Mohammad Ahmad Wadaan, R. Mythili, Jintae Lee, Devaraj Bharathi","doi":"10.1002/bio.70088","DOIUrl":"10.1002/bio.70088","url":null,"abstract":"<div>\u0000 \u0000 Crystal Violet (CV) is a vibrant and harmful dye known for its toxicity to aquatic life and potential carcinogenic effects on humans. This study explores the removal of CV through photocatalysis driven by visible light, as well as examining the antibacterial and antibiofilm characteristics of zinc oxide nanoparticles (ZnO NPs) synthesized from the aerial roots of Ficus benghalensis. Various characterization techniques were employed to confirm the optical properties, crystal lattices, and morphology of ZnO NPs. TEM images showed that the ZnO NPs had a spherical shape, with an average size of 40 to 80 nm. The photocatalytic analysis revealed that the synthesized ZnO NPs exhibited substantial activity under visible light, effectively degrading 90.6% of CV in an aqueous solution. The antibacterial activity of synthesized ZnO NPs was evaluated against clinically relevant bacterial strains such as Pseudomonas aeruginosa and Bacillus subtilis, revealing notable zones of inhibition. Moreover, the ZnO NPs exhibited antibiofilm activity of 96.8 ± 0.5% and 98.3 ± 0.3% against P. aeruginosa and Staphylococcus aureus, respectively. In conclusion, this study demonstrated the potential of the synthesized ZnO NPs as a sustainable solution for wastewater treatment and antibacterial applications.\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Norfloxacin Fluorescent Probe for the Assessment of Cefepime in Biological Fluids and Pharmaceutical Formulation; Investigation of the Greenness and Blueness Characteristics 诺氟沙星荧光探针评价头孢吡肟在生物液及制剂中的含量绿色和蓝色特性的研究。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-16 DOI: 10.1002/bio.70085

Rasmih M. K. Alshamery, Tarek Ahmed Seaf Elnasr, Hajer Hrichi, Mohammed Gamal, Hazim M. Ali, Tamer H. A. Hasanin

{"title":"Norfloxacin Fluorescent Probe for the Assessment of Cefepime in Biological Fluids and Pharmaceutical Formulation; Investigation of the Greenness and Blueness Characteristics","authors":"Rasmih M. K. Alshamery, Tarek Ahmed Seaf Elnasr, Hajer Hrichi, Mohammed Gamal, Hazim M. Ali, Tamer H. A. Hasanin","doi":"10.1002/bio.70085","DOIUrl":"10.1002/bio.70085","url":null,"abstract":"<div>\u0000 \u0000 In the present study, a norfloxacin (NFX) fluorescent probe was tailored for the spectrofluorometric measurement of cefepime (CFP). The proposed approach measured the quenching effect of CFP on the fluorescence intensity of NFX in acetate buffer solution. The obtained results show that CFP strongly quenches the fluorescence of NFX in a static mechanism. Under the optimal conditions, plotting the fluorescence quenching values (∆F) against CFP concentrations resulted in two ranges varying from 0.8 to 28 μg/mL (r2 = 0.9979) and from 40 to 92 μg/mL (r2 = 0.9929). Furthermore, the limits of quantification and detection were 2.0526 and 0.6773 μg/mL, respectively. In terms of intra- and inter-day recorded precisions (n = 5), the % RSD ranged between 0.31% and 0.6% and 0.55% and 1.02%, respectively. Additionally, practicality/applicability and the green feature of the new method were considered by BAGI and AGREE automated approaches. The new spectrofluorometric approach was positively applied for the quantification of CFP in injection powder and spiked biological fluids, including spiked human urine and plasma samples. According to previously published fluorescence methods, the present method is considered the first fluorescence one for the assay of CFP in human biological fluids with accurate and precise results.\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly Sensitive Spectrofluorimetric and Colorimetric Quantitation of Neomycin Using Nanosilver-Fluorescein Hybrid: A Comprehensive Assessment of Greenness and Blueness 利用纳米银-荧光素杂交的高灵敏度荧光光谱法和比色法定量测定新霉素：绿色和蓝色的综合评价。

IF 3.2 4区化学

Luminescence Pub Date : 2025-01-16 DOI: 10.1002/bio.70094

Mai A. El-Didamoony, Ehab F. Elkady, Rawda M. Sayed, Hany A. Batakoushy, Eman A. Mostafa

{"title":"Highly Sensitive Spectrofluorimetric and Colorimetric Quantitation of Neomycin Using Nanosilver-Fluorescein Hybrid: A Comprehensive Assessment of Greenness and Blueness","authors":"Mai A. El-Didamoony, Ehab F. Elkady, Rawda M. Sayed, Hany A. Batakoushy, Eman A. Mostafa","doi":"10.1002/bio.70094","DOIUrl":"10.1002/bio.70094","url":null,"abstract":"<div>\u0000 \u0000 Two versatile yet simple methods, colorimetric and spectrofluorimetric, were utilized for the quantitation of nonchromophore neomycin using silver nanoparticles modified with fluorescein. Fluorescein was excited at 485 nm (emission at 515 nm); when it is deposited on the surface of silver nanoparticles, its fluorescence intensity at 515 nm is quenched. Neomycin restores the fluorescence level at 515 nm by displacing fluorescein from nanoparticle binding sites. When neomycin reacts with silver nanoparticles modified with fluorescein, it causes reduction of silver nanoparticles' plasmon resonance surface band at 395 nm and changes of the solution's color from yellow to pale pink. For the spectrofluorimetric and colorimetric techniques, the calibration graphs with a linearity range of 5–45 ng/mL and 0.5–10 μg/mL, respectively. The suggested techniques were used to determine neomycin in neomycin tablets, yielding mean recovery of 99.696 ± 0.764 and 99.925 ± 1.515 for the spectrofluorimetric and colorimetric methods, respectively. The established techniques were validated according to the ICH guidelines. Analytical greenness calculator (AGREE) along with greenness tool for sample preparation (AGREEprep) was used to evaluate how environmentally friendly the sample preparation and analytical process were. In addition, the suggested approaches' practicality is assessed using the Blue Applicability Grade Index (BAGI).\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143015233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0