Luminescence最新文献

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Fluorescent Microscopy Investigation of Cytotoxic Impact on MCF-7 Cell Line Treated With Zinc Nanoparticles Synthesized From Jania rubens 用荧光显微镜研究从 Jania rubens 中合成的锌纳米颗粒对 MCF-7 细胞系的细胞毒性影响。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-31 DOI: 10.1002/bio.70007
Duraisamy Rajasekaran, Pomman Sathishkumar, Mani Neelakandan, Kannan Revathi, Jothi Vinoth Kumar, P. Srinivasan, Sandhanasamy Devanesan, Ponnusamy Selvamaleeswaran
{"title":"Fluorescent Microscopy Investigation of Cytotoxic Impact on MCF-7 Cell Line Treated With Zinc Nanoparticles Synthesized From Jania rubens","authors":"Duraisamy Rajasekaran,&nbsp;Pomman Sathishkumar,&nbsp;Mani Neelakandan,&nbsp;Kannan Revathi,&nbsp;Jothi Vinoth Kumar,&nbsp;P. Srinivasan,&nbsp;Sandhanasamy Devanesan,&nbsp;Ponnusamy Selvamaleeswaran","doi":"10.1002/bio.70007","DOIUrl":"10.1002/bio.70007","url":null,"abstract":"<div>\u0000 \u0000 <p>Zinc nanoparticles (ZnNPs) are a viable option in a number of disciplines, including cancer treatment, due to their special features. Among the several techniques for synthesizing ZnNP, biosynthesis with natural extracts is a highly effective and environmentally benign method, especially for uses in biomedicine. Using an aqueous extract of the marine red seaweed <i>Jania rubens</i>, we created a unique biosynthetic technique in this study to manufacture ZnNPs. The produced ZnNPs have a characteristic flower-like form, as seen by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The effective production of ZnNPs and the involvement of biomolecules in the synthesis process were validated by energy-dispersive X-ray spectroscopy (EDAX) and Fourier transform infrared spectroscopy (FTIR) techniques. Using the MTT assay, the cytotoxic effects of the biosynthesized ZnNPs were evaluated, indicating their ability to inhibit MCF-7 breast cancer cells. Furthermore, ZnNPs' cytotoxicity against MCF-7 cells was validated by live/dead imaging experiments, which supported the MTT results.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142548611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3-Hydroxy-2-naphthohydrazide: A Commercially Available Compound for Fluorescence Sensing of Ortho-Vanillin and Vanillin 3-Hydroxy-2-naphthohydrazide:用于正香兰素和香兰素荧光传感的市售化合物。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-29 DOI: 10.1002/bio.4934
Dhvani A. Patel, Vinita Bhardwaj, Bigyan R. Jali, Suban K. Sahoo
{"title":"3-Hydroxy-2-naphthohydrazide: A Commercially Available Compound for Fluorescence Sensing of Ortho-Vanillin and Vanillin","authors":"Dhvani A. Patel,&nbsp;Vinita Bhardwaj,&nbsp;Bigyan R. Jali,&nbsp;Suban K. Sahoo","doi":"10.1002/bio.4934","DOIUrl":"10.1002/bio.4934","url":null,"abstract":"<div>\u0000 \u0000 <p>Vanillin and <i>ortho</i>-vanillin are the most important flavoring additives used in the food industry at a large scale. Herein, the aggregation-induced emission (AIE) behavior of commercially available 3-hydroxy-2-naphthohydrazide (3HN) was explored and applied for the detection of vanillin and <i>ortho</i>-vanillin. The weakly fluorescent 3HN in DMSO showed fluorescence enhancement at 500 nm with the increase in HEPES or PBS buffer (pH 7.4) fractions in DMSO. The 3HN in DMSO containing 30% HEPES buffer is used as Probe 1 for the selective detection of <i>ortho</i>-vanillin. Probe 1 showed a new fluorescence emission at 415 nm for <i>ortho</i>-vanillin without altering the probe emission at 500 nm. With high specificity, Probe 1 can detect <i>ortho</i>-vanillin down to 0.3 μM. In contrast, 3HN in DMSO containing 20% PBS buffer is used as Probe 2 for the selective turn-off detection of vanillin. The green fluorescence emission of Probe 2 at 500 nm is selectively quenched by vanillin with a detection limit of 0.8 μM. Finally, the analytical novelty of the developed probes was examined by quantifying <i>ortho</i>-vanillin and vanillin in spiked food samples with good recovery percentages.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142548608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LIFs-Based Fluorescent Analysis of Silver Ions in Water Using AIEgen-Embedded PVA Hydrogel 使用嵌入 AIEgen 的 PVA 水凝胶进行基于 LIFs 的水中银离子荧光分析。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-29 DOI: 10.1002/bio.70017
Li Yao, Lixia Feng, Mengting Wang, Shujun Wu, Zhibiao Zhou, Sheng Xie
{"title":"LIFs-Based Fluorescent Analysis of Silver Ions in Water Using AIEgen-Embedded PVA Hydrogel","authors":"Li Yao,&nbsp;Lixia Feng,&nbsp;Mengting Wang,&nbsp;Shujun Wu,&nbsp;Zhibiao Zhou,&nbsp;Sheng Xie","doi":"10.1002/bio.70017","DOIUrl":"10.1002/bio.70017","url":null,"abstract":"<p>The detection and quantification analysis of silver ions is important to protect human health and improve the level of wastewater treatment. In this work, a polyvinyl alcohol (PVA) hydrogel-based sensing material based on an aggregation-induced emission strategy was developed and combined with a portable laser-induced fluorescence spectroscopy (LIFs) device for the direct detection and quantification of silver ions in water. Considering the requirements of environmental water analysis regarding portability, reliability, and convenience, this fluorescence turn-on strategy was optimized accordingly to ensure the accuracy and stability of the analysis in complex natural water environmental. This sensing method showed operational excellence and good sensitivity (down to 1 ppb) and may provide a stable and convenient strategy for the on-site, real-time analysis of environmental water samples.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142548612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spectrofluorometric Turn-Off Sensing Probe for Tolmetin Determination Using Cerium and Nitrogen Codoped Carbon Dots 使用铈和氮掺杂碳点测定托美汀的分光荧光熄灭传感探针
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-29 DOI: 10.1002/bio.70008
Mokhtar M. Mabrouk, Fotouh R. Mansour, Hamsa B. Hassan, Aya A. Abdella
{"title":"Spectrofluorometric Turn-Off Sensing Probe for Tolmetin Determination Using Cerium and Nitrogen Codoped Carbon Dots","authors":"Mokhtar M. Mabrouk,&nbsp;Fotouh R. Mansour,&nbsp;Hamsa B. Hassan,&nbsp;Aya A. Abdella","doi":"10.1002/bio.70008","DOIUrl":"10.1002/bio.70008","url":null,"abstract":"<div>\u0000 \u0000 <p>A facile, low-cost, and rapid method was developed for spectrofluorometric determination of tolmetin (TOL) using highly fluorescent (QY = 35%) cerium and nitrogen codoped carbon dots (Ce–NCDs) sensing platform prepared by one-step hydrothermal method. Owing to the severe overlap between TOL absorption and Ce–NCDs excitation spectra around 320 nm, TOL could attenuate the emission of Ce–NCDs at 407 nm through primary inner filter effect (IFE). This concentration dependent attenuation was linear between 2 and 10 μg/mL (r = 0.9993) with a limit of detection of 0.5 μg/mL. The sensor showed very good accuracy (% recovery = 98%–100%) and precision (%RSD &lt; 2). The developed sensing strategy was successfully applied for TOL detection as an active pharmaceutical ingredient in pharmaceutical formulation and as a potential pollutant in environmental water samples, such as tap and river water, with acceptable recovery and considerable selectivity. Thus, the direct single-step spectrofluorometric determination of TOL was enabled without extensive processing or chemical derivatization.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142548613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of Luminescent Titanium Dioxide Nanoparticles in a Biocompatible Approach: Its Potential for Photodecomposition and Germicidal Effects 用生物兼容方法制造发光二氧化钛纳米粒子:其光分解和杀菌作用的潜力。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-29 DOI: 10.1002/bio.70015
K. Sajeevan, S. Vijayakumar, S. Vasantha, S. Prathipkumar, Mysoon M. Al-Ansari, P. Srinivasan, E. Vidhya
{"title":"Fabrication of Luminescent Titanium Dioxide Nanoparticles in a Biocompatible Approach: Its Potential for Photodecomposition and Germicidal Effects","authors":"K. Sajeevan,&nbsp;S. Vijayakumar,&nbsp;S. Vasantha,&nbsp;S. Prathipkumar,&nbsp;Mysoon M. Al-Ansari,&nbsp;P. Srinivasan,&nbsp;E. Vidhya","doi":"10.1002/bio.70015","DOIUrl":"10.1002/bio.70015","url":null,"abstract":"<div>\u0000 \u0000 <p>The fabrication of the green strategy of metallic oxide creation provides considerable profits via a minimum of effort, making it an acceptable substitute to the most laborious and challenging conventional processes. The suggested approach involved the creation of titanium dioxide (TiO<sub>2</sub>) nanoparticles through <i>Orthosiphon stamineus</i> extracts of leaves. The synthesized nanoparticles (NPs) were then characterized using XRD, FT-IR, FE-SEM with EDX, and UV–visible spectroscopy. UV–visible spectroscopy validated the presence of optical imperfections in the TiO<sub>2</sub> NPs at frequencies of 286 nm. This research specifically focused on examining the photodecomposition and germicidal traits of NPs. Initiatives aimed must be made to mitigate the hazardous effects of TiO<sub>2</sub> NPs in an ecologically sensitive way throughout their production. Exposing the dye methylene blue (MB), a major water polluting produced by garment manufacturing, to TiO<sub>2</sub> NPs resulted in a considerable increase in photodecomposition efficiency. The photodecomposition process exhibited a rate of breakdown of 83%. The findings indicate that the diameter inhibition zone exhibits the most potent resistance versus pathogenic microorganisms. These results have led to the identification of a long-term, sustainable, and ecologically beneficial solution for removing pollutants from water and biological properties.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142548610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Live Cell Imaging Studies on Orange Emitting Thiazole-Pyridone Azo Fluorophore and Its Latent Fingerprints, Computational, Electrochemical Sensing for Dopamine Detection 橙色发光噻唑-吡啶酮偶氮荧光团及其潜在指纹的活细胞成像研究、多巴胺检测的计算、电化学传感。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-28 DOI: 10.1002/bio.70003
Fiza Noor Zahara, J. Keshavayya, Chethan Krishnamurthy, K. M. Pallavi
{"title":"Live Cell Imaging Studies on Orange Emitting Thiazole-Pyridone Azo Fluorophore and Its Latent Fingerprints, Computational, Electrochemical Sensing for Dopamine Detection","authors":"Fiza Noor Zahara,&nbsp;J. Keshavayya,&nbsp;Chethan Krishnamurthy,&nbsp;K. M. Pallavi","doi":"10.1002/bio.70003","DOIUrl":"10.1002/bio.70003","url":null,"abstract":"<div>\u0000 \u0000 <p>The fluorescent materials have sparked a lot of research interests due to their unique electronic, optical and chemical characteristics. Here, we are intended to present a simple and facile synthesis of novel orange emitting thiazole-pyridone fluorescent tag (TPFT) by a simple diazo coupling reaction and the structural elucidation was carried out by IR, NMR (<sup>1</sup>H and <sup>13</sup>C), UV–Vis, photoluminescence and HR-MS spectrometry. The solvatochromic behaviour of the TPFT offered crucial information about the formation of hydrazone and azo tautomeric forms. The DFT simulations are computed to calculate HOMO-LUMO energy gap (3.028 eV) of TPFT along with MEP and RDG analyses. Comprehensive LFP visualization is revealed under both normal and UV light conditions (365 nm). The cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used to analyse the electrochemical behaviour of the TPFT-modified glassy carbon electrode (MGCE) and exhibited a lower detection limit of 7.89 × 10<sup>−8</sup> M (S/<i>N</i> = 3) with a linear range of 0.5–8.0 μM for DA detection. The live-cell imaging study of TPFT showed a strong blue emission at 453 nm, which generally indicates the existence of fluorescence stability.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142523497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accelerated Charge Transfer in the AgInS2-Polymer Layer-by-Layer Films AgInS2 聚合物逐层薄膜中的加速电荷转移。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-27 DOI: 10.1002/bio.70001
Vasylyna Kopach, Yuriy Khalavka, Yuliana Yosypenko, Nataliia Doskaliuk, Oleh Kopach, Mykhailo Dmytruk, Igor Dmytruk, Andriy Dmytruk
{"title":"Accelerated Charge Transfer in the AgInS2-Polymer Layer-by-Layer Films","authors":"Vasylyna Kopach,&nbsp;Yuriy Khalavka,&nbsp;Yuliana Yosypenko,&nbsp;Nataliia Doskaliuk,&nbsp;Oleh Kopach,&nbsp;Mykhailo Dmytruk,&nbsp;Igor Dmytruk,&nbsp;Andriy Dmytruk","doi":"10.1002/bio.70001","DOIUrl":"10.1002/bio.70001","url":null,"abstract":"<div>\u0000 \u0000 <p>In this work, the luminescence properties of AgInS<sub>2</sub> colloid nanoparticles in solution and in films were investigated and compared. Decay time of fast and slow relaxation processes differ by about an order of magnitude. Both components are significantly reduced in films compared to the corresponding contributions in colloids that hint towards charge carrier transfer between AgInS<sub>2</sub> particles enhanced in the films.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142511899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoluminescence and Kinetic Parameters of Beta Rays Irradiated Egyptian Muscovite 经 Beta 射线辐照的埃及黑云母的热致发光和动力学参数
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-27 DOI: 10.1002/bio.70002
Shrouk Farouk, Nabil El-Faramawy
{"title":"Thermoluminescence and Kinetic Parameters of Beta Rays Irradiated Egyptian Muscovite","authors":"Shrouk Farouk,&nbsp;Nabil El-Faramawy","doi":"10.1002/bio.70002","DOIUrl":"10.1002/bio.70002","url":null,"abstract":"<div>\u0000 \u0000 <p>The current work was going to study the dosimetric properties of Egyptian muscovite minerals irradiated with β-rays using the thermoluminescence technique (TL). The analysis of the TL glow curves was done using the (T<sub>m</sub> − T<sub>stop</sub>) and the initial rise methods. The deconvolution of the muscovite glow curves was analyzed to have eight superimposed trapping peaks. These trapes were located at 0.72, 0.80, 0.98, 1.09, 1.19, 1.30, 1.50, and 1.59 eV. Muscovite samples were studied at doses up to 330 Gy and exhibited good linearity in relation to beta radiation. The kinetic parameters, sensitivity, and dosimetric characteristics were evaluated. High accuracy was achieved through the repeatability of TL measurements.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142511910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
AIEE—Active Green Fluorescence Imaging Technique for Latent Fingerprint Application 用于潜伏指纹应用的 AIEE-活性绿色荧光成像技术。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-25 DOI: 10.1002/bio.70004
Palani Purushothaman, S. Nishanthi, B. Induja, P. S. Umabharathi, M. Sethupathi, Subramanian Karpagam
{"title":"AIEE—Active Green Fluorescence Imaging Technique for Latent Fingerprint Application","authors":"Palani Purushothaman,&nbsp;S. Nishanthi,&nbsp;B. Induja,&nbsp;P. S. Umabharathi,&nbsp;M. Sethupathi,&nbsp;Subramanian Karpagam","doi":"10.1002/bio.70004","DOIUrl":"10.1002/bio.70004","url":null,"abstract":"<div>\u0000 \u0000 <p>Latent fingerprint imaging is a crucial tool for national security and crime recognition, requiring environmentally sustainable, nontoxic materials. To address this need, we have developed a green fluorescence-emitting material, THCHO, that binds effectively to latent fingerprints, enabling clear, high-resolution visualization. The solution produces strong green fluorescence that highlights fingerprint imprints with exceptional detail and contrast. The material is applicable across various substrates, making it efficient for on-site visualization. The synthesized organic conjugated material THCHO rapidly visualizes precise fingerprint substructures within 5 s using a simple spray method. It maintains high contrast and low interference across different substrates, such as glass, aluminum foil, plastic, and ironware, even in diverse backgrounds. Additionally, the THCHO material demonstrates high stability, retaining its fluorescence imaging capabilities for up to 35 days and after water washing. This is the first report of using a conjugated organic thiophene material for latent fingerprint fluorescence imaging, suggesting potential applications in other fields.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142511900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Anthracene-Appended Calix[4]triazacrown-5 as an Effective Fluorescence Probe for Co2+ and Hazardous Cr2O72− Ions 新型蒽添加型 Calix[4]triazacrown-5 作为 Co2+ 和有害 Cr2O7 2- 离子的有效荧光探针。
IF 3.2 4区 化学
Luminescence Pub Date : 2024-10-24 DOI: 10.1002/bio.4920
Serkan Sayin
{"title":"Novel Anthracene-Appended Calix[4]triazacrown-5 as an Effective Fluorescence Probe for Co2+ and Hazardous Cr2O72− Ions","authors":"Serkan Sayin","doi":"10.1002/bio.4920","DOIUrl":"10.1002/bio.4920","url":null,"abstract":"<div>\u0000 \u0000 <p>A new calix[4]triazacrown-5–derived fluorescence chemosensor (<b>AntUr-AzClx</b>) at cone conformation was synthesized to afford an effective fluorescent probe, which enables an enhancement in the fluorescence intensity specifically in the presence of Co<sup>2+</sup> metal ions as well as a turnoff response for hazardous dichromate anions. <sup>1</sup>H-NMR, <sup>13</sup>C-NMR, ESI-MS, and elemental analysis techniques were used to characterize the structure of the anthracene-appended calix[4]triazacrown-5 (<b>AntUr-AzClx</b>). The metal ion–binding ability of <b>AntUr-AzClx</b> was evaluated against Co<sup>2+</sup>, Ba<sup>2+</sup>, Ni<sup>2+</sup>, Pb<sup>2+</sup>, and Zn<sup>2+</sup> ions. On the basis of various metal ion recognition phenomena, <b>AntUr-AzClx</b> exhibited outstanding selectivity for only the Co<sup>2+</sup> ion among other metal ions. Also, the calix[4]triazacrown-5–derived fluorescence chemosensor showed high sensitivity towards the Co<sup>2+</sup> ion with a very low limit of detection (LOD) 0.142 μmol L<sup>−1</sup>. In addition, anion binding abilities of <b>AntUr-AzClx</b> against various anions such Cr<sub>2</sub>O<sub>7</sub><sup>2−</sup>, HCO<sub>3</sub><sup>−</sup>, CO<sub>3</sub><sup>2−</sup>, NO<sub>3</sub><sup>−</sup>, SO<sub>3</sub><sup>2−</sup>, SO<sub>4</sub><sup>2−</sup>, N<sub>3</sub><sup>−</sup>, F<sup>−</sup>, and I<sup>−</sup> demonstrated that <b>AntUr-AzClx</b> enables selective and highly sensitive detection of the Cr<sub>2</sub>O<sub>7</sub><sup>2−</sup> anion with an excellent LOD of 4.182 nmol L<sup>−1</sup> in DMF/PBS (1/1, v/v; pH: 7.05). Furthermore, the calix[4]triazacrown-5–derived fluorescence chemosensor displayed a significant sensing behavior to detect the presence of dichromate anions even in real samples.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142511909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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