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Multiphase Multicomponent Reactive Transport and Flow Modeling 多相多组分反应输运和流动建模
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2019-09-01 DOI: 10.2138/RMG.2019.85.6
I. Sin, J. Corvisier
{"title":"Multiphase Multicomponent Reactive Transport and Flow Modeling","authors":"I. Sin, J. Corvisier","doi":"10.2138/RMG.2019.85.6","DOIUrl":"https://doi.org/10.2138/RMG.2019.85.6","url":null,"abstract":"HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. Multiphase Multicomponent Reactive Transport and Flow Modeling Irina Sin, Jérôme Corvisier","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82518735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
Thermodynamics of Geothermal Fluids 地热流体热力学
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2018-12-01 DOI: 10.2138/RMG.2013.76.1
A. Stefánsson, T. Driesner, P. Bénézeth
{"title":"Thermodynamics of Geothermal Fluids","authors":"A. Stefánsson, T. Driesner, P. Bénézeth","doi":"10.2138/RMG.2013.76.1","DOIUrl":"https://doi.org/10.2138/RMG.2013.76.1","url":null,"abstract":"This volume presents an extended review of the topics conveyed in a short course on Geothermal Fluid Thermodynamics held prior to the 23rd Annual V.M. Goldschmidt Conference in Florence, Italy (August 24–25, 2013).\u0000\u0000Geothermal fluids in the broadest sense span large variations in composition and cover wide ranges of temperature and pressure. Their composition may also be dynamic and change in space and time on both short and long time scales. In addition, physiochemical properties of fluids such as density, viscosity, compressibility and heat capacity determine the transfer of heat and mass by geothermal systems, whereas, in turn, the physical properties of the fluids are affected by their chemical properties. Quantitative models of the transient spatial and temporal evolution of geochemical fluid processes are, therefore, very demanding with respect to the accuracy and broad range of applicability of thermodynamic databases and thermodynamic models (or equations of state) that describe the various datasets as a function of temperature, pressure, and composition. The application of thermodynamic calculations is, therefore, a central part of geochemical studies of very diverse processes ranging from the aqueous geochemistry of near surface geothermal features including chemosynthesis and thermal biological activity, through the utilization of crustal reservoirs for CO2 sequestration and engineered geothermal systems to the formation of magmatic-hydrothermal ore deposits and, even deeper, to the de-volatilization of subducted oceanic crust and the transfer of subduction fluids and trace elements into the mantle wedge.\u0000\u0000Application of thermodynamics to understand geothermal fluid chemistry and transport requires essentially three parts: first, equations of state to describe the physiochemical system; second, a geochemical model involving minerals and fluid species; and, third, values for various thermodynamic parameters from which the thermodynamic and chemical model can be derived. The two biggest current hurdles for comprehensive geochemical modeling of geothermal systems are …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83059171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Petrochronology Based on REE-Minerals: Monazite, Allanite, Xenotime, Apatite 基于ree矿物的岩石年代学:独居石、褐褐石、Xenotime、磷灰石
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-08-01 DOI: 10.2138/RMG.2017.83.12
M. Engi
{"title":"Petrochronology Based on REE-Minerals: Monazite, Allanite, Xenotime, Apatite","authors":"M. Engi","doi":"10.2138/RMG.2017.83.12","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.12","url":null,"abstract":"### REE-minerals\u0000\u0000Monazite, xenotime, and allanite are REE1-minerals sensu stricto because lanthanides (La…Lu) and yttrium are critical constituents in them. Apatite does not require REE, but because it contains substantial REE in many rocks, it is included in this review. All four minerals also host unusually high radionuclide concentrations, notably Th and U, forming the basis of their utility as geochronometers.\u0000\u0000This quartet of accessory minerals is playing an increasingly important role in petrochronology because they provide ways to link robust spot ages to petrogenetic ( P–T ) conditions so can lend petrogenetic context to chronology based on other minerals. Part I of this review assembles the basic requisites prior to integrative petrochronologic analysis. Individual characteristics of the four REE-minerals are addressed first, i.e., their crystal chemistry and stability relations. Thermobarometers and trace element geochemistry used for tracing petrogenesis are discussed next, and finally their chronology is summarized. Part II presents case studies to highlight the specific strengths of REE-minerals used to resolve the dynamics of a broad range of processes, from diagenetic to magmatic conditions. Finally, a brief section at the end outlines a few of the current challenges and promising perspectives for future work.\u0000\u0000To introduce the four REE-minerals in style, let us recall the origins of their names. The three phosphates have well respected Greek grandparents, and allanite has solid Scottish roots, yet of all four of them show idiosyncracies in etymology or type material.\u0000\u0000Apatite had long puzzled naturalists, as it shows great chemical and physical variability and can resemble other minerals. Once properly identified, Abraham Gottlieb Werner named it apatite. His reasoning referred to the Greek root ἀπατὰω and giving the precise Latin translation: decipio . Taken literally, both mean “I deceive” or “I mislead”, which sounds like an apt confession from this mineral for having fooled …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87853557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 124
Garnet: A Rock-Forming Mineral Petrochronometer 石榴石:一种造岩矿物
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-08-01 DOI: 10.2138/RMG.2017.83.15
E. Baxter, M. Caddick, B. Dragovic
{"title":"Garnet: A Rock-Forming Mineral Petrochronometer","authors":"E. Baxter, M. Caddick, B. Dragovic","doi":"10.2138/RMG.2017.83.15","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.15","url":null,"abstract":"Garnet could be the ultimate petrochronometer. Not only can you date it directly (with an accuracy and precision that may surprise some), but it is also a common rock-forming and porphyroblast-forming mineral, with wide ranging—yet thermodynamically well understood—solid solution that provides direct and quantitative petrologic context. While accessory phase petrochronology is based largely upon establishing links to the growth or breakdown of key rock-forming pressure–temperature–composition ( P–T–X ) indicators (e.g., Rubatto 2002; Williams et al. 2007), garnet is one of those key indicator minerals. Garnet occurs in a great variety of rock types (see Baxter et al. 2013) and is frequently zoned (texturally, chemically) meaning that it contains more than just a snapshot of metamorphic conditions, but rather a semi-continuous history of evolving tectonometamorphic conditions during its often prolonged growth. In this way, garnet and its growth zonation have been likened to dendrochronology: garnet as the tree rings of evolving tectonometamorphic conditions (e.g., Pollington and Baxter 2010).\u0000\u0000In some ways, the dream of ‘petrochronology’ all started with garnet (Fig. 1). When Atherton and Edmunds (1965) or Hollister (1966) recognized the chemical zonation in garnet, when Rosenfeld (1968) noted the spiral ‘snowball’ of inclusions in rotated garnet, or when Tracy et al. (1976) drew the first 2-D map of garnet chemical zonation, illuminating those ‘tree-rings’ for the first time, they could only imagine what is now a reality decades later—direct zoned garnet geochronology of those concentric rings of growth. Geoscientists soon thereafter attempted the first garnet geochronology (van Breemen and Hawkesworth 1980), though several factors severely limited the development and wider-spread use of garnet geochronology from that point. These factors included 1) contamination of garnet by micro-mineral inclusions, 2) analytical limitations of small sample size, 3) the requirement of anchoring a garnet age analysis with another point on an isochron, and …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82134258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 93
Zircon: The Metamorphic Mineral 锆石:变质矿物
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-08-01 DOI: 10.2138/RMG.2017.83.9
D. Rubatto
{"title":"Zircon: The Metamorphic Mineral","authors":"D. Rubatto","doi":"10.2138/RMG.2017.83.9","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.9","url":null,"abstract":"A mineral that forms under conditions as variable as diagenesis to deep subduction, melt crystallization to low temperature alteration, and that retains information on time, temperature, trace element and isotopic signatures is bound to be a useful petrogenetic tool. The variety of conditions under which zircon forms and reacts during metamorphism is a great asset, but also a challenge as interpretation of any geochemical data obtained from zircon must be placed in pressure–temperature–deformation–fluid context. Under which condition and by which process zircon forms in metamorphic rocks remains a crucial question to answer for the correct interpretation of its precious geochemical information.In the last 20 years there has been a dramatic evolution in the use of zircon in metamorphic petrology. With the advent of in situ dating techniques zircon became relevant as a mineral for age determinations in high-grade metamorphic rocks. Since then, there has been incredible progress in our understanding of metamorphic zircon with the documentation of growth and alteration textures, its capacity to protect mineral inclusions, zircon thermometry, trace element patterns and their relation to main mineral assemblages, solubility of zircon in melt and fluids, and isotopic systematics in single domains that go beyond U–Pb age determinations.Metamorphic zircon is no longer an impediment to precise geochronology of protolith rocks, but has become a truly indispensable mineral in reconstructing pressure–temperature–time–fluid-paths over a wide range of settings. An obvious consequence of its wide use, is the rapid increase of literature on metamorphic zircon and any attempt to summarize it can only be partial: in this chapter, reference to published works are intended as examples and not as a compilation.This chapter approaches zircon as a metamorphic mineral reporting on its petrography and texture, deformation structure and mineral chemistry, including trace element and isotopic systematics. Linking this information together highlights the potential of zircon as a key mineral in petrochronology.","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78967470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 462
Electron Microprobe Petrochronology 电子探针岩石年代学
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-08-01 DOI: 10.2138/RMG.2017.83.5
M. L. Williams, M. Jercinovic, K. Mahan, G. Dumond
{"title":"Electron Microprobe Petrochronology","authors":"M. L. Williams, M. Jercinovic, K. Mahan, G. Dumond","doi":"10.2138/RMG.2017.83.5","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.5","url":null,"abstract":"The term petrochronology has increasingly appeared in publications and presentations over the past decade. The term has been defined in a somewhat narrow sense as “the interpretation of isotopic dates in the light of complementary elemental or isotopic information from the same mineral(s)” (Kylander-Clark et al. 2013). Although complementary isotopic and elementary information are certainly a central and critical part of most, if not all, petrochronology studies, the range of recent studies that might use the term covers a much broader scope. The term “petrochronology” might alternatively be defined as the detailed incorporation of chronometer phases into the petrologic (and tectonic) evolution of their host rocks, in order to place direct age constraints on petrologic and structural processes. As noted by Kylander-Clark et al. (2013), the linkage between geochronology and petrology can involve a variety of data including mineral textures and fabrics, the distribution of mineral modes or volume proportions, compositional zoning, mineral inclusion relationships, and certainly major element, trace element, and isotopic composition of the chronometer and all other phases.\u0000\u0000Electron probe micro-analysis (EPMA) has a central and critical role to play in establishing the linkage between chronometer phases and their host assemblage. The basic instrument is an electron microscope which can be used in either scanning or fixed beam modes, with integrated wavelength dispersive spectrometers (WDS), energy dispersive spectrometers (EDS), electron detectors (to image secondary and backscattered signals) a light optical system, and optionally cathodoluminescence (CL) detection. The electron microprobe is used to investigate the distribution, composition, and compositional zonation of all mineral phases, the data that underpin thermobarometric analysis and modeling of P–T histories. The microprobe, with μm-scale spatial resolution, can also characterize compositional zonation in very small accessory phases including monazite, xenotime, zircon, allanite, titanite, apatite, and others. This, as discussed below, can be a …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86066870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 54
Phase Relations, Reaction Sequences and Petrochronology 相关系、反应序列和岩石年代学
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-02-01 DOI: 10.2138/RMG.2017.83.2
C. Yakymchuk, C. Clark, R. White
{"title":"Phase Relations, Reaction Sequences and Petrochronology","authors":"C. Yakymchuk, C. Clark, R. White","doi":"10.2138/RMG.2017.83.2","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.2","url":null,"abstract":"At the core of petrochronology is the relationship between geochronology and the petrological evolution of major mineral assemblages. The focus of this chapter is on outlining some of the available strategies to link inferred reaction sequences and microstructures in metamorphic rocks to the ages obtained from geochronology of accessory minerals and datable major minerals. Reaction sequences and mineral assemblages in metamorphic rocks are primarily a function of pressure ( P ), temperature ( T ) and bulk composition ( X ). Several of the major rock-forming minerals are particularly sensitive to changes in P–T (e.g., garnet, staurolite, biotite, plagioclase), but their direct geochronology is challenging and in many cases not currently possible. One exception is garnet, which can be dated using Sm–Nd and Lu–Hf geochronology (e.g., Baxter et al. 2013). Accessory mineral chronometers such as zircon, monazite, xenotime, titanite and rutile are stable over a relatively wide range of P–T conditions and can incorporate enough U and/or Th to be dated using U–Th–Pb geochronology. Therefore, linking the growth of P–T sensitive major minerals to accessory and/or major mineral chronometers is essential for determining a metamorphic P–T–t history, which is itself critical for understanding metamorphic rocks and the geodynamic processes that produce them (e.g., England and Thompson 1984; McClelland and Lapen 2013; Brown 2014).\u0000\u0000Linking the ages obtained from accessory and major minerals with the growth and breakdown of the important P–T sensitive minerals requires an understanding of the metamorphic reaction sequences for a particular bulk rock composition along a well-constrained P–T evolution. Fortunately, the phase relations and reaction sequences for the most widely studied metamorphic protoliths (e.g., pelites, greywackes, basalts) can be determined using quantitative phase equilibria forward modelling (e.g., Powell and Holland 2008). Comprehensive activity–composition models of the major metamorphic minerals in large chemical systems (e.g., White et al. 2014a) allow …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89301918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 89
Significant Ages—An Introduction to Petrochronology 重要的年代——岩石年代学导论
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-02-01 DOI: 10.2138/RMG.2017.83.1
M. Engi, P. Lanari, M. Kohn
{"title":"Significant Ages—An Introduction to Petrochronology","authors":"M. Engi, P. Lanari, M. Kohn","doi":"10.2138/RMG.2017.83.1","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.1","url":null,"abstract":"Question : Why “Petrochronology”? Why add another term to an already cluttered scientific lexicon?\u0000\u0000Answer : Because petrologists and geochronologists need a term that describes the unique, distinctive way in which they apply geochronology to the study of igneous and metamorphic processes. Other terms just won’t do.\u0000\u0000Such evolution of language is natural and well-established. For instance, “Geochronology” was originally coined during the waning stages of the great Age-of-the-Earth debate as a means of distinguishing timescales relevant to Earth processes from timescales relevant to humans (Williams 1893). Eighty-eight years later, Berger and York (1981) coined the term “Thermochronology,” which has evolved as a branch of geochronology aimed at constraining thermal histories of rocks, where (typically) the thermally activated diffusive loss of a radiogenic daughter governs the ages we measure. Thermochronology may now be distinguished from “plain vanilla” geochronology, whose limited purpose, in the words of Reiners et al. (2005), is “…exclusively to determine a singular absolute stratigraphic or magmatic [or metamorphic] formation age, with little concern for durations or rates of processes” that give rise to these rocks.\u0000\u0000Neither of these terms describes what petrologists do with chronologic data. A single date is virtually useless in understanding the protracted history of magma crystallization or metamorphic pressure–temperature evolution. And we are not simply interested in thermal histories, but in chemical and baric evolution as well. Rather, we petrologists and geochronologists strive to understand rock-forming processes, and the rates at which they occur, by integrating numerous ages into the petrologic evolution of a rock. It is within this context that a new discipline, termed “Petrochronology”, has emerged1. In some sense petrochronology may be considered the sister of thermochronology: petrochronology typically focuses on the processes leading up to the formation of igneous and metamorphic rocks—the minerals and textures we observe …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89656742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 93
Petrochronology and TIMS 岩石年代学与TIMS
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-02-01 DOI: 10.2138/RMG.2017.83.8
B. Schoene, E. Baxter
{"title":"Petrochronology and TIMS","authors":"B. Schoene, E. Baxter","doi":"10.2138/RMG.2017.83.8","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.8","url":null,"abstract":"Thermal ionization mass spectrometers, or TIMS, were developed by the pioneers of mass spectrometry in the mid-20th century, and have since been workhorses for generating isotopic data for a wide range of elements. Later-developed mass spectrometric techniques have many advantages over TIMS, including higher spatial resolution with in situ techniques, such as secondary ion mass spectrometry (SIMS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), and greater versatility in terms the elements that can be easily-and well-measured. The reason TIMS persists as an important method for geochronology is that for some key parent-daughter systems (e.g., U–Pb, Sm–Nd), it can produce isotopic data and resultant dates with 10–100 times higher precision and more quantifiable accuracy than in situ techniques, even when sample sizes are very small (such as those that might result from single crystals, or even small portions of zoned crystals). For many questions in the geosciences, the highest achievable precision and accuracy are required to resolve the timescales of processes and/or correlate events globally. As an example, modern TIMS U–Pb geochronology is capable of producing dates with precision and accuracy better than 0.1% of the age for single crystals with only a few picograms (pg) of Pb. Therefore, it is possible to constrain the durations of single zircon crystal growth in magmatic systems over tens to hundreds of kyr in Mesozoic and younger rocks. If these dates and rates can be connected with other igneous processes such as magma transfer, emplacement and crystallization, then it becomes possible to calibrate thermal and mass budgets in magmatic systems and evaluate competing models for pluton assembly and subvolcanic magma storage. As another example, Sm–Nd geochronology of garnet permits dates with precision better than ±1 million years for garnets of any age, including multiple concentric growth zones in single crystals. Such …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86498854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Petrochronology by Laser-Ablation Inductively Coupled Plasma Mass Spectrometry 激光烧蚀电感耦合等离子体质谱测定岩石年代学
1区 地球科学
Reviews in Mineralogy & Geochemistry Pub Date : 2017-02-01 DOI: 10.2138/RMG.2017.83.6
A. Kylander‐Clark
{"title":"Petrochronology by Laser-Ablation Inductively Coupled Plasma Mass Spectrometry","authors":"A. Kylander‐Clark","doi":"10.2138/RMG.2017.83.6","DOIUrl":"https://doi.org/10.2138/RMG.2017.83.6","url":null,"abstract":"Petrochronology is a field of Earth science in which the isotopic and / or elemental composition of a mineral chronometer is interpreted in combination with its age, thus yielding a more synergistic combination of petrology and chronology that can be used to interpret geologic processes. It has recently attracted renewed interest as technologies for mineral analysis have improved. Examples are many, and continue to grow, from the early adoption of U / Th ratios in zircon as an indicator for magmatic vs. igneous crystallization (e.g., Ahrens 1965), to using the Nd isotopic composition in titanite to track source contribution over time (see Applications ; B. R. Hacker, personal communication). Age and chemical information can be obtained by a variety of techniques: electron microprobe (age; major and minor elements; see Williams et al. 2017), secondary ion mass spectrometry (SIMS; age; trace elements; isotopic ratios; see Schmitt and Vazquez 2017), and laser-ablation inductively coupled plasma mass spectrometry (LA-ICPMS; age; trace elements; isotopic ratios).\u0000\u0000Laser-ablation ICPMS instrumentation and techniques, the focus of this chapter, have been employed as a petrochronologic tool for decades, starting with separate analyses of ages and elemental and / or isotopic compositions, which were then combined and interpreted. For example, Zheng et al. (2009) employed LA-ICPMS to analyze the trace-element (TE) chemistry, Hf isotopic composition, and age of zircons from kimberlites by using three spots on each zircon grain, one for each type of analysis. This work was relatively time consuming and expensive, given the required number of analytical sessions, but yielded far better confidence in the conclusions, because of the link between physical conditions (petrology) and time (chronology).\u0000\u0000Instrumentation and techniques which employ LA-ICPMS have continued to improve, particularly in the ease with which petrochronologic data can be obtained. A single LA-ICPMS instrument can now measure both the …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78195593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 44
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