Materialia最新文献

{"title":"An oxidative stress amplified antibacterial S-SEBS@CuLM coating with synergistic ROS scavenging inhibition","authors":"SiSi Ma ,&nbsp;Anqi Lu ,&nbsp;Wenhao Wei ,&nbsp;Qiqi Lu ,&nbsp;Jing Sun ,&nbsp;Chao Zhang ,&nbsp;Sen Liu ,&nbsp;Wei Ye","doi":"10.1016/j.mtla.2025.102473","DOIUrl":"10.1016/j.mtla.2025.102473","url":null,"abstract":"<div><div>As reactive oxygen species (ROS) can induce oxidative stress in bacteria and eliminate them without promoting bacterial drug resistance, ROS-based antibacterial strategies have garnered significant attention in recent years. However, bacteria possess a range of antioxidant mechanisms to counteract the bactericidal effects of ROS. Consequently, in this study, we developed an antibacterial surface based on Ga³⁺-enhanced ROS antibacterial efficacy. This surface consists of a superhydrophobic material sequentially modified with gallium-based liquid metal (GLM) and Cu²⁺. It is noteworthy that the increased H₂O₂ in the bacterial microenvironment enables Cu²⁺ to produce reactive oxygen species through catalyzing electron transfer in the Fenton reactions to achieve bactericidal effect. Meanwhile, the simultaneous use of Ga³⁺ and Cu²⁺ to destroy the bacterial redox process and inhibit its basic function further enhances antimicrobial properties. Results show that this superhydrophobic coating prevents bacterial adhesion and growth while releasing Ga³⁺ and Cu²⁺ for sustained bactericidal activity. The antimicrobial rate exceeds 99.99 % against <em>Escherichia coli</em> and <em>Staphylococcus aureus</em>. In addition, the coating also exhibits excellent in vitro biocompatibility. This work provides a novel and effective strategy for developing antimicrobial surfaces for biomedical materials.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102473"},"PeriodicalIF":3.0,"publicationDate":"2025-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144469968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Contribution of Post-Rolling Surface Treatment to Corrosion Performance of Duplex and Austenitic Stainless Steel Reinforcing Bar","authors":"Seyiwa Kope ,&nbsp;Fook-Yee Yang ,&nbsp;Mohaddeseh Abdolhosseini ,&nbsp;Ibrahim Ogunsanya","doi":"10.1016/j.mtla.2025.102472","DOIUrl":"10.1016/j.mtla.2025.102472","url":null,"abstract":"<div><div>This study elucidates the complex relationship between stainless steel (SS) rebar surface treatment and corrosion resistance in high chloride environments using microscopy, analytical, and conventional electrochemical and novel corrosion microscopy techniques in a short- and long-term assessment. Previous studies on carbon steel reported that millscale defects (cracks and porosity) compromise corrosion resistance by allowing chloride ions to reach the base steel. This study examining three SS grades with four different surface type shows that their high Cr content improves compactness and reduces defectiveness of the inner (Fe-Cr) millscale layer, resulting in better corrosion resistance which varied with surface treatment methods, alloy composition, concrete composition, and chloride exposure method. Despite its defective outer (Fe) millscale layer, as-rolled (AR) bars showed comparable or better corrosion resistance than bars subjected to post-rolling treatment. Treating SS surface with mechanical blasting or acid pickling alone deteriorates corrosion performance due to embedment of blasting particles into rebar surface and/or the presence of loose residual millscale. Employing both shotblasting and acid pickling (SBPK) causes micropits to develop on the bar surface, which deteriorates corrosion resistance.</div><div>Additionally, this study also show that pore solution tests do not adequately reflect the corrosion performance of SS millscales because such test uniformly exposes chloride ions to millscales, causing high corrosion rate resulting from uniform millscale dissolution and quicker exposure of underlying substrate. This behaviour is different from that encountered in concrete where non-uniform chloride exposures causes non-uniform millscale dissolution and lower corrosion of underlying substrate. Overall, this work shows that achieving consistent post-roll treatment or pristine SBPK surface between manufacturers and batches is a bigger challenge than achieving homogeneous millscale, making AR SS rebar a cost-effective corrosion resistant option for construction.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102472"},"PeriodicalIF":3.0,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimizing hydrogen resistance in fusion energy structural stainless steel via controlled uniaxial strain","authors":"L.Y. Mao ,&nbsp;Manquan Fang ,&nbsp;Chongyu Shen ,&nbsp;C. Huang ,&nbsp;M.R. Fan ,&nbsp;M.K. Wang ,&nbsp;Z.A. Luo","doi":"10.1016/j.mtla.2025.102469","DOIUrl":"10.1016/j.mtla.2025.102469","url":null,"abstract":"<div><div>Fusion energy as a sustainable clean power shaping our future. However, the prevalent issue of hydrogen embrittlement (HE) of secondary processing structural materials in fusion energy systems has been widely concerned. This study explored the effect of secondary deformation on HE resistance of nickel-economized stainless steel (NEASS) used in tritium plant through varying degrees of uniaxial pre-strain. Unexpectedly, the high pre-strained NEASS with H-charging simultaneously exhibited high ultimate strength and low HE susceptibility. The increase in ultimate strength comes from the strain hardening effect caused by dislocation multiplication, while the improvement of HE resistance is contributed by the synergistic effect of deformation substructure, preferred orientation, and dislocation configuration. The interplay of these effects altered the hydrogen distribution inside the material, the hydrogen trapping capacity of microstructure, and the initiation behavior of hydrogen-induced cracks (HICs). Consequently, the NEASS exhibited low HE susceptibility during subsequent slow- strain rate tensile deformation, eventually resulting in shallower brittle fracture region, fewer HICs, and lower elongation loss after fracture with H-charging.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102469"},"PeriodicalIF":3.0,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144364367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructural evolution during beta annealing after hot deformation in the alpha+beta field of metastable-beta Ti-10V-2Fe-3Al alloy","authors":"I. Skordilis ,&nbsp;S. Delannoy ,&nbsp;F. Prima ,&nbsp;N. Bozzolo","doi":"10.1016/j.mtla.2025.102468","DOIUrl":"10.1016/j.mtla.2025.102468","url":null,"abstract":"<div><div>In metastable-β titanium alloys, heating to the β field to carry out β recrystallization induces the transformation of the α phase to the β phase. The dissolving α phase directly affects the progress of the stored energy release processes in the β phase. In this study, the behavior of the β and α phases during heating and annealing in the β field of hot-forged Ti-10V-2Fe-3Al is investigated using SEM/EBSD. The experimental data indicate a strong pinning effect of the β boundaries by α precipitates, controlling the extent of recovery and recrystallization in the β phase. Overall, the results of this investigation provide a clearer view of the material’s behavior during this processing step and enable a refinement of the recrystallized β grains.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102468"},"PeriodicalIF":3.0,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methodical approach to interface design: Role of sizing in the micro-mechanical performance and durability of basalt fibers-based composites","authors":"I. Castro-Cabrera ,&nbsp;A. Chénier ,&nbsp;A. Blanchard ,&nbsp;J.F. Gérard ,&nbsp;F. Lortie ,&nbsp;J. Rumeau-Duchet","doi":"10.1016/j.mtla.2025.102467","DOIUrl":"10.1016/j.mtla.2025.102467","url":null,"abstract":"<div><div>Basalt fibers are renowned for their outstanding mechanical performance and promising end-of-life recyclability, while maintaining adequate performance compared to glass fibers. While their use is expanding, a deep comprehension of the fiber surface chemistry and particularly sizing is crucial. This thin layer, mainly made of film formers, organosilanes, among other components, governs the interface properties and thus the global performance of fiber-reinforced polymer composites. This study investigates the surface properties of basalt fibers treated with a range of film former, employing advanced surface characterization techniques. These including XPS, TGA, SEM-EDX, wettability, and five-parameter Weibull statistical analysis. The results show that the film former, polymeric versus oligomeric, strongly influences surface morphology, coverage, and flaw distribution. Oligomeric sizing, such as epoxy-based, achieves a coating with a narrower interfacial shear strength distribution. Polymeric film formers, generate thicker and more heterogeneous coatings, exhibiting dynamic rearrangements under hygrothermal conditions, showing a time-dependent healing effect. Its status modifies the surface key properties for further adhesion with polymer matrices. Beyond the insights into sizing-dependent surface performance, this work proposes a structured framework for characterizing and interpreting fiber surface to understand composite performance. By mapping different properties, the study encourages the transition from empirical, trial-and-error material development, still prevalent in industrial settings, towards more predictive, data-informed composite design. Our findings aim to contribute to a collaborative and continuous effort concerning interphase engineering in the growing field of basalt fiber composites. By positioning on fiber surface understanding, this work looks for unlocking the full potential of polymer-reinforced materials.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102467"},"PeriodicalIF":3.0,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"CFD-integrated kinetic model for high-temperature iron oxidation in multispecies reactive environments","authors":"M.A. Gómez ,&nbsp;J.M. Casal ,&nbsp;L. González-Gil ,&nbsp;C. Álvarez-Bermúdez ,&nbsp;J. Porteiro","doi":"10.1016/j.mtla.2025.102464","DOIUrl":"10.1016/j.mtla.2025.102464","url":null,"abstract":"<div><div>This paper introduces a novel model that integrates the high-temperature kinetics of iron oxidation into a CFD framework, aiming to predict oxide scale evolution in complex systems such as combustion furnaces. Considering atmospheres with O₂, CO₂, CO, H₂O, and H₂ as reactive species, the model employs CFD techniques to accurately forecast local gas composition, enabling the application of the oxidation model to each element of the iron surface. The scale evolution is represented by either linear or parabolic growth, depending on whether oxidation kinetics or ion diffusion across the scale is the limiting factor.</div><div>Simulations are conducted on an experimental reactor where low-carbon iron samples undergo oxidation in various atmospheres and temperatures (900 °C to 1200 °C). Comparisons with the measured gained mass show satisfactory agreement, particularly in oxygen atmospheres at high temperatures and regarding the linear growth predicted in 10 % CO₂ or 10 % H₂O atmospheres. The model also performs reasonably well in quaternary atmospheres, with discrepancies attributed to initial linear constants at lower temperatures. Despite these challenges, the model demonstrates favorable performance in representing the parabolic growth observed in the tests. Overall, in intricate operational scenarios with numerous parameters, the model's performance is reasonably favorable, which allows the simulation of iron oxidation in complex reactors or combustion systems.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102464"},"PeriodicalIF":3.0,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144364366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of precompression on the thermal cycling stability of glass-to-metal seals","authors":"Zhangjing Shi ,&nbsp;Keqian Gong ,&nbsp;Zifeng Song ,&nbsp;Zheng Liu ,&nbsp;Chao Zhou ,&nbsp;Yangyang Cai ,&nbsp;Yanfei Sun ,&nbsp;Cheng Ren ,&nbsp;Yong Zhang","doi":"10.1016/j.mtla.2025.102466","DOIUrl":"10.1016/j.mtla.2025.102466","url":null,"abstract":"<div><div>Hermeticity is a critical performance attribute of glass-to-metal (GTM) compressive seals, whose long-term reliability is often compromised by crack initiation and propagation. These failures primarily originate from the nonuniform stress distribution on the GTM seal surface and the inherent material properties, such as the weak mechanical strength, both of which exacerbate structural vulnerabilities over prolonged service periods. In this study, precompression was introduced during the heat treatment stage as a means to increase the thermal cycling stability of GTM seals. The results indicated a proportional relationship between the precompression stress and the thermal cycling stability of GTM seals. Porosity analysis was conducted on three different samples, which demonstrated that precompression improved the distribution of bubbles within the GTM seals, as evidenced by a reduction in the porosity and a decrease in the bubble size. In addition, the mechanical properties of the sealing glass were enhanced, thereby reducing the probability of leakage. Furthermore, nanoindentation measurements and finite element analysis of the surface stress distribution revealed that precompression led to an increase in residual compressive stress. The alleviation of stress concentration regions significantly lowered the probability of crack initiation during thermal cycling, thus establishing a more uniform stress distribution and enhancing the thermal stability of GTM seals.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102466"},"PeriodicalIF":3.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144331297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of solute clusters in the nucleation of precipitates in Al–Mg–Si–Cu alloys","authors":"J.R. Famelton ,&nbsp;C.A. Williams ,&nbsp;C. Barbatti ,&nbsp;P.A.J. Bagot ,&nbsp;M.P. Moody","doi":"10.1016/j.mtla.2025.102448","DOIUrl":"10.1016/j.mtla.2025.102448","url":null,"abstract":"<div><div>In this work the precipitation behaviour of both high and low Cu variants of a Al-6xxx alloy were investigated with and without natural ageing. The material yield strength was greater in the high Cu alloy and without natural ageing. The strength was seen to correspond to changes in precipitate number density and a mechanism of dislocation bowing around these precipitates. In the samples without natural ageing, Cu was seen to increase the number density of nuclei and hence the final precipitate number density. In the samples with natural ageing, solute clusters were observed to dissolve during subsequent artificial ageing, but a higher proportion remained in the high Cu alloy and acted as nucleation sites for further precipitation.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102448"},"PeriodicalIF":3.0,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Slip vs. Twin martensite in additively manufactured Ti-6Al-4V: A grain boundary perspective","authors":"Vikrant Saumitra ,&nbsp;Avinash Gonnabattula ,&nbsp;V. Anil Kumar ,&nbsp;Anand K Kanjarla","doi":"10.1016/j.mtla.2025.102463","DOIUrl":"10.1016/j.mtla.2025.102463","url":null,"abstract":"<div><div>There is an ongoing debate regarding whether martensitic transformation in Ti alloys is governed by slip or twin-based mechanisms. The mechanism that predominates depends on lattice parameter changes caused by composition. For instance, CP-Ti typically under- goes slip-based transformation, while Ti-6Al-4V tends to favor twin-based transformation. However, processing conditions, particularly in additive manufacturing (AM), can introduce lattice strains and alter lattice parameters, resulting in distinct martensitic transformation mechanisms. Both mechanisms influence the variant selection and the formation of character- istic variant cluster morphologies, such as triangular (slip-based) and V-shaped (twin-based), which in turn dictate the selection of intervariant boundaries (IBs). This study explores the characteristics and network of IBs in Ti-6Al-4V for two distinct AM processes: Laser-Powder Bed Fusion (L-PBF) and Wire Laser-Direct Energy Deposition (L-DED). The sympathetic approach to variant selection is extended to the selection of IB and twin boundaries. Key features of the IB network, including triple points and dihedral angles, are examined to pro- vide a deeper understanding of the stability, configuration, and correlation of grain boundary networks with variant selection mechanisms. It is observed that V-shaped clusters dominate in L-DED, while triangular clusters are more common in L-PBF. Furthermore, L-DED ex- hibits a higher fraction of Σ13<em>b</em> twin boundaries than L-PBF samples. These findings suggest that martensitic transformation in L-DED is primarily twin-based, whereas in L-PBF, it is more likely to be slip-based. The sympathetic approach provides valuable insights into the martensitic transformation mechanisms in Ti alloys.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102463"},"PeriodicalIF":3.0,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144297865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and thermal properties of a new hydrated salt phase change material without phase separation","authors":"Chuang Wang ,&nbsp;Pengcheng Liu ,&nbsp;Xingxing Cheng ,&nbsp;Yiteng Zhang ,&nbsp;Zhiqiang Wang","doi":"10.1016/j.mtla.2025.102462","DOIUrl":"10.1016/j.mtla.2025.102462","url":null,"abstract":"<div><div>This article discusses the use of hydrated salts as phase change materials for heat accumulators in distributed energy systems. Despite their potential, challenges like phase separation and supercooling hinder their widespread use. Common solutions with nucleating agents and thickeners often fall short. The study explores permanent solutions through composite materials and investigates new ways to maintain stability. Two new eutectic hydrated salts are introduced: SAT+SMN (sodium acetate trihydrate + sodium metasilicate nonahydrate) and SAT+LAD (sodium acetate trihydrate + lithium acetate dihydrate). The common ion effect reduces the solubility of nucleating agents, creating durable crystal seeds to trigger nucleation and reduce supercooling. In terms of thermal properties, SAT+SMN with a 20 % SMN mass fraction has a melting point of 52.2 °C and a latent heat of 248.4 J/g. SAT+LAD with a 10 % LAD mass fraction melts at 49.7 °C with a latent heat of 212.8 J/g. Supercooling in SAT+SMN is reduced to less than 0.5 °C, and in SAT+LAD, it drops to less than 3 °C. After 500 cycles, SAT+SMN maintains a supercooling degree within 0.5 °C with only a 0.02 % decrease in latent heat, demonstrating excellent thermal stability. The introduction of hydrated salts with more polar molecules in SAT increases the difference in the number of hydrogen bonds and bond energy between the solid and liquid states. This leads to new crystals with different lattice parameters and smaller cell sizes. While traditional stirring achieves uniform mixing up to 2 μm, ultrasonic mixing allows for a more even distribution, crucial for effective heat storage.</div></div>","PeriodicalId":47623,"journal":{"name":"Materialia","volume":"42 ","pages":"Article 102462"},"PeriodicalIF":3.0,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144605615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}