{"title":"Bimetallic zinc-silver nanocomposites for superior antimicrobial efficacy","authors":"Naveen Kumar Madipoju, Sarvani Jowhar Khanam, Greeshma Sunkari, Sai Madhuri Vasamsetti, Vangala Divyasri, Vijay Morampudi, Ramu Naidu Savu, Murali Banavoth, Sreenivas Banne, Imran Hasan, Parvathalu Kalakonda","doi":"10.1007/s00339-025-08289-1","DOIUrl":"10.1007/s00339-025-08289-1","url":null,"abstract":"<div><p>Traditional treatments for microbial infections often have adverse effects and consequences, while chemically synthesized nanoparticles can produce harmful by-products. This study employed a green synthesis approach to produce zinc-silver bimetallic nanoparticles (Zn-Ag BMNPs) using the leaf extract of <i>Tinospora cordifolia</i> (TC). Characterization of the synthesized ZnNPs and Zn-Ag BMNPs revealed diverse structural and functional properties. FTIR analysis of these samples confirmed the anchoring of pytochmical groups on the surface of BMNPs, while XRD pattern revealed structural details with a crystallite size of approximately 19 nm. UV–Vis spectroscopy confirmed the formation of Zn-Ag BMNPs with absorption peaks in the range of 250–450 nm, and the optical energy gap was measured as 3.1 eV using Tauc plot analysis. Stability in aqueous suspensions was supported by zeta potential values of – 20.5 mV and – 22.7 mV, suggesting minimal aggregation. The potential antibacterial efficacy was assessed using disk diffusion and minimum inhibitory concentration (MIC) assays against <i>Escherichia coli</i> (<i>E. coli</i>). Zn-Ag BMNPs exhibited superior antimicrobial properties, achieving a maximum inhibition zone of 4 mm at optimal concentrations, while ZnNPs displayed comparatively weaker activity. These findings suggest that synthesized Zn-Ag BMNPs nanocomposites may have significant senergetic effect in treating chronic diseases and addressing the aforementioned issues.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08289-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143110217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-31DOI: 10.1007/s00339-025-08247-x
Amin Abd El-Moneim, R. M. Ahmed, O. I. Sallam, Raouf El-Mallawany
{"title":"Physical, structural and elastic properties of Fe2O3-doped oxyfluoroborate glasses","authors":"Amin Abd El-Moneim, R. M. Ahmed, O. I. Sallam, Raouf El-Mallawany","doi":"10.1007/s00339-025-08247-x","DOIUrl":"10.1007/s00339-025-08247-x","url":null,"abstract":"<div><p>A series of Fe<sub>2</sub>O<sub>3</sub>-doped oxyfluoroborate 75B<sub>2</sub>O<sub>3</sub>–20NaF–5BaO glasses (Fe<sub>2</sub>O<sub>3</sub> = 0, 2, 4, and 6 mol) were synthesized using the conventional melt-quenching method. The effect of Fe<sub>2</sub>O<sub>3</sub> on the physical, structural, and elastic characteristics of synthesized glass samples has been studied. The non-crystalline characteristics of the prepared glass samples were validated through XRD analysis, while their structural properties were examined using FTIR spectroscopy. Elastic properties were investigated through the measurement of longitudinal and shear ultrasonic velocities, employing the pulse-echo technique. The observed density and computed molar volume were determined to be influenced by the content of Fe<sub>2</sub>O<sub>3</sub>. The ultrasonic velocities, elastic moduli, micro-hardness, and Debye temperature exhibited similar behavior across all glass compositions, showing an increase with increasing Fe<sub>2</sub>O<sub>3</sub> content. The findings are analyzed concerning the alteration in the topology of the borate network. The incorporation of Fe<sub>2</sub>O<sub>3</sub> led to the transformation of BO<sub>3</sub> structural groups into BO<sub>4</sub> structural groups, enhancing the network connectivity and increasing the rigidity of the glass structure and elastic moduli. A variety of compositional parameters, including the average separation between boron ions, mean atomic volume, glass packing density, dissociation energy per unit volume, and excess molar volume, were assessed in concerning Fe<sub>2</sub>O<sub>3</sub> content. These parameters were then correlated with the elastic properties, drawing on established models and theories within the discipline. The theoretical elastic moduli, micro-hardness, and Poisson's ratio values were ultimately calculated and compared with the experimental ones.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08247-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143110218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation on microstructural, morphological, optical properties of pristine 2D WO3 nanoplates synthesized by one-pot non-aqueous sol–gel solvothermal method for photocatalysis applications","authors":"Laouedj Nadjia, Alaoui Chakib, Karmaoui Mohamed, Taibi Mohamed, Elaziouti Abdelkader","doi":"10.1007/s00339-024-08223-x","DOIUrl":"10.1007/s00339-024-08223-x","url":null,"abstract":"<div><p>An original strategy based on a one-pot non-aqueous sol–gel solvothermal method was developed to synthesize 2D Tungsten trioxide (WO<sub>3</sub>) nanoplatelets (identified as WO<sub>3</sub>-180-24 NPs). The as-prepared catalyst was characterized by using various description technique such as XRD, SEM, TEM, FT-IR and UV–vis DRS. Additionally, comparative study of various microstructural parameters of chemically prepared WO<sub>3</sub>-180-24 NPs based on the XRD peak broadening using different models (Scherrer (S, SEA and SS), Monshi-Scherrer (M-S), Williamson-Hall (W–H) (UD, USD and UDED), Size-Strain plot (SSP) and Halder-Wagner (H-W)). Therefore, WO<sub>3</sub>-180-24 was efficiently investigated for sustainable removal of Rhodamine B (RhB) dye under LED-light illumination as a function of different removal processes. XRD results revealed the successful design of WO<sub>3</sub>-180-24 NPs monoclinic sructure with space group P2<sub>1</sub>/n (N°.14). By comparing microstructure parameters, Size-Strain Plot (SSP<b>)</b> and Halder-Wagner (H-W) models gave similar values of particle size D<sub>XRD</sub> = 10.19 nm, negative lattice strain and the highest R<sup>2</sup> (0.870) means that WO<sub>3</sub>-180-24 crystal has a compressivez strain. In comparison with Scherrer, W–H and H-W mthods, SSP model exhibited a minimum of microstrain (ε = 0.00101) which indicate the narrower size distribution, trivial strains and the presence of defects and size-shape anisotropy in the WO<sub>3</sub>-180-24 environment. Further, the estimated higher value of strain <b>(ε = </b>0.0162) for H-W method may be accredited to the lattice dislocations. WO<sub>3</sub>-180-24 showed plate-like shaped particles which tend to form agglomerated plate-like nanostructures. WO<sub>3</sub>-180-24 nanoplatelets are composed of quadrangular nanoplatelets with an average width of 35–50 nm. FT-IR study validated similar functional groups of WO<sub>3</sub>. The band gap energy of 2.18 eV was obtained for the direc allowed electronic transitions of WO<sub>3</sub>-180-24 NPs. The substantial red shift observed in band compared to that reported for the bulk WO<sub>3</sub> (~ 2.4–2.8 eV) could be assigned to the strong hybridization between W 5s and O 2p orbitals. Finally, the synthesized WO<sub>3</sub>-180-24 NPs photocatalyst revealed substantially enhanced photocatalytic effectiveness of≈ 99% of RhB removed within 120 min, outperforming all other removal processes. Experimental kinetic study was correlated with the Langmuir–Hinshelwood kinetic model for pseudo first order reaction (R<sup>2</sup> > 0.98). The mechanistic understandings for the design of WO<sub>3</sub>-180-24 NPs photocatalyst and its applications in the degradation of RhB dye was also covered in this investigation. Subsequently, the exceptional photocatalytic ability and versatile applications of WO<sub>3</sub>-180-24 NPs-based photocatalyst, outperforming all other removal processes, could be can be synerg","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-024-08223-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143110216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of ZnO-CuO and ZnO-CuO-NiO nanocomposites prepared by co-precipitation and antibacterial properties","authors":"Sahar Karrari, Hurieh Mohammadzadeh, Robabeh Jafari","doi":"10.1007/s00339-025-08273-9","DOIUrl":"10.1007/s00339-025-08273-9","url":null,"abstract":"<div><p>Antibacterial resistance has become a global threat to health and development. Oxide nanoparticles are effective materials to overcome antibacterial resistance. In this study, ZnO-CuO-NiO nanoparticles were synthesized by co-precipitation with different NiO contents (0, 10, 20 and 30 wt%). The properties of the synthesized nanocomposite powder, including crystalline structure, size, morphology and composition, were investigated by FESEM, XRD and FTIR. The antibacterial effect of all nanocomposites was investigated using the disk diffusion method. Based on the metal–oxygen bonds in the FTIR spectra, the formation of metal oxides of Ni, Cu and Zn was confirmed. The results of XRD and FESEM proved the production of ZnO, CuO and NiO with a uniform elemental distribution and particle size < 150 nm with an irregular spherical morphology. All components showed desirable antibacterial activity against Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus bacteria. However, the level of antibacterial activity was significantly improved by the NiO nanoparticles in the component and at a low concentration of the nanocomposition of 1.25 and 0.313 mg/l, the Gram-negative and Gram-positive bacteria disappeared from the Petri dish for the ZnO-CuO-30% NiO sample, respectively, compared to > 10 and 5 mg/l for ZnO-CuO.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Correction: Tunning the omnidirectional bandgap of nanoporous silicon using a semi-sinusoidal refractive index profile","authors":"Mohamed Shaker Salem, Asmaa Mohamed Abdelaleem, Gamal Madboly Nasr, Mohamed Amin","doi":"10.1007/s00339-024-08211-1","DOIUrl":"10.1007/s00339-024-08211-1","url":null,"abstract":"","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-024-08211-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-30DOI: 10.1007/s00339-025-08262-y
Soraya Abdelhaleem, Mohammed O. Alziyadi, Amani Alruwaili, Mohammed Jameel Alawi, Asma Alkabsh, M. S. Shalaby
{"title":"BSCCO high Tc -superconductor materials: strategies toward critical current density enhancement and future opportunities","authors":"Soraya Abdelhaleem, Mohammed O. Alziyadi, Amani Alruwaili, Mohammed Jameel Alawi, Asma Alkabsh, M. S. Shalaby","doi":"10.1007/s00339-025-08262-y","DOIUrl":"10.1007/s00339-025-08262-y","url":null,"abstract":"<div><p>Superconducting materials offer compact and lightweight electrical devices that can significantly alter high-field magnet technology and electric power production, offering an enhanced generation of electric power and high-capacity loss-less electric power transmission. Technological uses of high-temperature superconductors (HTSC) demand high critical current density and high critical field (<i>H</i><sub><i>c2</i></sub>). Achieving high critical current density for Bismuth strontium calcium copper oxide (BSCCO) HTSC is challenging, so exploring the technical challenges, the factors that affect <span>({J}_{c})</span> and the development efforts, and current research are discussed. The investigation of BSCCO HTSC discusses future advancements and innovations in BSCCO HTSC, exploring the possibilities of improved performance, broader commercialization, and new applications. Additionally, it addresses the barriers and limitations that must be overcome for BSCCO HTSC to become more widely integrated into various industries. So, the high anisotropic character of BSCCO HTSC is directly associated with these two parameters, <i>J</i><sub><i>c</i></sub> and <i>H</i><sub><i>c</i></sub>. One of the most commonly used techniques to increase <span>({J}_{c})</span> values is the doping (substitution) of another element or nanoparticles, which generates artificial defects that increase flux pinning and the critical current density. This review sheds light on the basics of BSCCO superconducting materials, the key parameters, dopant roles, the industrial challenges, and the recent findings on the efforts made to improve the achievable critical current densities and overall superconducting properties for BSCCO HTSC.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08262-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-30DOI: 10.1007/s00339-025-08263-x
S. Bhattacharjee, Harshavardhan Chouhan, Saurabh Prasad, R. K. Parida, B. N. Parida
{"title":"An investigation of new inorganic perovskite oriented material for NTC-thermistor and other multifunctional application","authors":"S. Bhattacharjee, Harshavardhan Chouhan, Saurabh Prasad, R. K. Parida, B. N. Parida","doi":"10.1007/s00339-025-08263-x","DOIUrl":"10.1007/s00339-025-08263-x","url":null,"abstract":"<div><p>The inorganic perovskite oriented material is found to exhibit fascinating multifunctional features. Some among them were reported to exhibit multiferroic features too. In this work, a new inorganic perovskite oriented material, namely double perovskite oxide (DPO) BaCaFeVO<sub>6</sub> is synthesized. The structural/micro-structural investigation reveals some vital information like formation of phase, influence of different dimensional grains etc. towards the multifunctional feature. The investigating sample is found to possess dual phase: Orthorhombic (space group = Pcmn) and Trigonal (space group = R-3 m:R) with cell parameters a = 5.691Å, b = 14.684 Å, c = 5.476 Å, α = β = γ = 90<sup>0</sup> and a = b = c = 7.819 Å, α = β = γ = 43.23<sup>0</sup> respectively. Different oxidation states of Fe and V and its influence towards the creation of oxygen vacancies (OV) are identifies through the X-ray Photoelectron spectroscopy (XPS) analysis. The expected phase of perovskite as well as some prominent modes are identifies through Fourier transformed infrared (FTIR) and RAMAN spectroscopic analysis. The nature of the material and its response towards UV–Visible light are also investigated. Through Tauc plot, the bandgap (E<sub>g</sub> = 3.39 eV) was extracted from the UV–Visible spectra. For storage energy oriented device application, the dielectric and related parameters were inspected through analyzing the influence of various factors like polarization, OV, grains, grain boundaries etc. in the sample. For Negative temperature coefficient (NTC)-thermistor oriented application, Thermistor coefficient (β = 5390.58 K) and sensitivity factor (α = − 2.456) were evaluated through fitting from the variation of resistance with temperature graph. The multiferroicity is clarified through the analysis of P-E and M-H hysteresis loop.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08263-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-30DOI: 10.1007/s00339-025-08254-y
J. M. Montes, F. G. Cuevas, J. Cintas, F. Ternero
{"title":"Porosity effect on the thermal conductivity of sintered powder materials","authors":"J. M. Montes, F. G. Cuevas, J. Cintas, F. Ternero","doi":"10.1007/s00339-025-08254-y","DOIUrl":"10.1007/s00339-025-08254-y","url":null,"abstract":"<div><p>In this work, the effective thermal conductivity of sintered powder materials is studied. The extensive literature related to the proposed models about this property in all kind of porous materials is reviewed, and a new equation is proposed as a function of the fully dense material conductivity, the porosity of the material and the tap porosity of the starting powder. This equation covers the porosity range of powder aggregates from the tap porosity to zero porosity, and also applies to sintered powders. The proposed equation has been experimentally validated by fitting to experimental data of metallic sintered powder materials measured at room temperature, resulting very good agreements. Also, alternative models proposed by other authors have been fitted to the same experimental data to check the relative goodness of the proposed model. The results allow to conclude that a percolation model can describe the behaviour of the effective thermal conductivity of sintered powder materials with low and medium porosity levels.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08254-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-30DOI: 10.1007/s00339-025-08286-4
Shafaq Arif, Rida Nadeem, Kiran Shahzadi, Sofia Siddique, M. S. Anwar
{"title":"Synthesis and characterization of ZnO and Zn0.9TM0.1O (TM = Cu and Co) nanoparticles to enhance the shelf life of jujubes and green chilies","authors":"Shafaq Arif, Rida Nadeem, Kiran Shahzadi, Sofia Siddique, M. S. Anwar","doi":"10.1007/s00339-025-08286-4","DOIUrl":"10.1007/s00339-025-08286-4","url":null,"abstract":"<div><p>Doped and undoped Zinc oxide (ZnO) nanoparticles (NPs) were synthesized via co-precipitation protocol. Transition metals Co and Cu are used as dopants with 10% doping. The NPs are characterized systematically using XRD, SEM, EDX, and UV-Vis spectroscopy. The NPs exhibit wurtzite hexagonal structure and agglomerated morphology. The bandgap energy of 3.13 eV of undoped NPs increases to 4.10 eV (31%) and 4.24 eV (35%) for Cu and Co dopant, respectively. The antimicrobial activity of nanoparticles is investigated using the well-diffusion method. Antimicrobial studies revealed enhanced activity of Zn<sub>0.9</sub>Cu<sub>0.1</sub>O NPs against Pseudomonas aeruginosa and Klebsiella pneumonia. Comparatively, Zn<sub>0.9</sub>Co<sub>0.1</sub>O NPs showed superior efficiency against Staphylococcus aureus, Escherichia coli, Aspergillus Niger, and Sclerotium microbial stains. Shelf life of NPs coated jujubes and chilies is investigated with coating of chitosan-Gelatin CH/GL-ZnO and CH/GL-doped-ZnO, and stored for 45 days at ambient conditions. During the storage period, the physiological weight loss, moisture content and decay index of coated and uncoated jujubes and chilies are assessed every five-days. It is observed that the coating delayed ripening and oxidative deterioration compared to the uncoated jujubes and chilies. In addition, the doped ZnO coatings significantly reduced the loss of the weight and moisture content, while maintaining their physical appearance.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Applied Physics APub Date : 2025-01-29DOI: 10.1007/s00339-025-08280-w
Sumayya Begum, Vijaykiran N. Narwade, Sabah Taha, Devidas I. Halge, Hemlata J. Bhosale, Zuzana Danková, Jagdish W. Dadge, Kashinath A. Bogle
{"title":"HAp-ZnO nanocomposites: efficient and recyclable photocatalysts for water pollutants degradation","authors":"Sumayya Begum, Vijaykiran N. Narwade, Sabah Taha, Devidas I. Halge, Hemlata J. Bhosale, Zuzana Danková, Jagdish W. Dadge, Kashinath A. Bogle","doi":"10.1007/s00339-025-08280-w","DOIUrl":"10.1007/s00339-025-08280-w","url":null,"abstract":"<div><p>Remazol Brilliant Blue R (RBBR), an anthraquinone-based dye, has emerged as a contaminant in water sources, posing ecological threats. This study explores the photocatalytic degradation and adsorption of RBBR and its byproducts using a biocompatible HAp-ZnO nanocomposite. The nanocomposite was synthesized for its optical and antibacterial properties. The combined experimental and theoretical approach aims to elucidate the degradation mechanism. Under UV irradiation, the nanocomposite effectively eliminates RBBR (> 93%) and inhibits bacterial growth. The high efficiency is attributed to the interaction between photogenerated electrons and hydroxyl radicals during UV exposure. These findings demonstrate the potential of HAp-ZnO nanocomposites for dye remediation and highlight the value of nanocomposite materials in developing advanced photocatalysts for wastewater treatment.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143110062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}