Applied Physics A最新文献

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Structural and optical modifications in sodium zinc-based phosphate glass upon substitution of Na2O with Fe2O3 用 Fe2O3 替代 Na2O 时钠锌基磷酸盐玻璃的结构和光学变化
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-28 DOI: 10.1007/s00339-024-07974-x
H. A. AbdEl-Ghany, Hosam M. Gomaa
{"title":"Structural and optical modifications in sodium zinc-based phosphate glass upon substitution of Na2O with Fe2O3","authors":"H. A. AbdEl-Ghany,&nbsp;Hosam M. Gomaa","doi":"10.1007/s00339-024-07974-x","DOIUrl":"10.1007/s00339-024-07974-x","url":null,"abstract":"<div><p>In this study, Fe<sub>2</sub>O<sub>3</sub> was introduced into sodium zinc-based phosphate glass, replacing Na<sub>2</sub>O. Using the conventional melt quenching technique, a glass system with the chemical composition 45P<sub>2</sub>O<sub>5</sub> − 34ZnO − (21-<i>x</i>) Na<sub>2</sub>O - <i>x</i>Fe<sub>2</sub>O<sub>3</sub> (where, <i>x</i> = 1, 2, 3, 4, and 5 mol%) was prepared. X-ray diffraction (XRD) analysis showed that this substitution did not alter the glass’s amorphous structure. However, the density increased slightly, potentially due to the higher molecular mass of Fe<sub>2</sub>O<sub>3</sub> compared to Na<sub>2</sub>O. This density change suggests a possible alteration in the glass’s optical properties. Optical measurements revealed a shift towards the red spectrum and a decrease in transmittance, particularly at 543 nm, indicating increased optical loss. This loss was attributed to increased reflectance, not absorption. The optical band gaps decreased with higher Fe<sub>2</sub>O<sub>3</sub> content, enhancing the glass’s optical resistance, and making it suitable for applications like optical filters and shielding materials. The optical loss tangent analysis showed that the material’s efficiency in transmitting electromagnetic energy decreased with Fe<sub>2</sub>O<sub>3</sub> substitution, likely due to changes in the electronic structure. The study also noted that Fe<sub>2</sub>O<sub>3</sub> improved optical absorption, as demonstrated by the Hydrogenic Excitonic Model (HEM).</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Buckling behavior of nickel microbeams based on reformulated strain gradient theory 基于重构应变梯度理论的镍微梁屈曲行为
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-26 DOI: 10.1007/s00339-024-08013-5
Anıl Yıldırım, Bekir Akgöz
{"title":"Buckling behavior of nickel microbeams based on reformulated strain gradient theory","authors":"Anıl Yıldırım,&nbsp;Bekir Akgöz","doi":"10.1007/s00339-024-08013-5","DOIUrl":"10.1007/s00339-024-08013-5","url":null,"abstract":"<div><p>In this paper, the microstructure-dependent buckling behavior of microbeams is investigated. The material used for the microbeams is chosen as nickel. The reformulated strain gradient theory and Euler–Bernoulli beam theory are employed to develop the microbeam model with size effect. Rayleigh–Ritz method is used to achieve the critical buckling loads for cantilever and simply supported microbeams. Buckling behavior and size effects based on classical and nonclassical theories are investigated and compared. Some different conditions, such as inclusion of length scale parameters and increasing the length and thickness of microbeam, and their effects on the critical buckling loads are studied. Also, some comparative results are presented to demonstrate the accuracy and validity of the present analysis. It is found that the size effects become more pronounced, especially on smaller slenderness ratios.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the strain induced electronic optical and thermoelectric properties of monolayer SMoSiN2 and SeMoSiN2 揭示单层 SMoSiN2 和 SeMoSiN2 的应变诱导电子光学和热电特性
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-25 DOI: 10.1007/s00339-024-07986-7
Fawad Khan, Muhammad Ilyas, Bakhtawar Khan, Riaz Ullah, Zafar Iqbal,  Abdullah, Haleem Ud Din, Azhar Iqbal
{"title":"Unveiling the strain induced electronic optical and thermoelectric properties of monolayer SMoSiN2 and SeMoSiN2","authors":"Fawad Khan,&nbsp;Muhammad Ilyas,&nbsp;Bakhtawar Khan,&nbsp;Riaz Ullah,&nbsp;Zafar Iqbal,&nbsp; Abdullah,&nbsp;Haleem Ud Din,&nbsp;Azhar Iqbal","doi":"10.1007/s00339-024-07986-7","DOIUrl":"10.1007/s00339-024-07986-7","url":null,"abstract":"<div><p>For technological applications, a noteworthy attention has been gain by Janus layered materials for their distinctive structure and properties. A comprehensive investigation is performed to calculate the electronic, optical and thermoelectric response, using density functional theory, for monolayer SMoSiN<sub>2</sub> and SeMoSiN<sub>2</sub>. Indirect band gap semiconducting nature is evidenced in these monolayers. Variations in band values are observed with application strain. Studying optical properties, blue and red shift are observed with the applications of compressive and tensile strain. Thermoelectric properties expose the productivity of SMoSiN<sub>2</sub> monolayer over SeMoSiN<sub>2</sub> in strain free condition. Biaxial tensile and compressional strain is applied to modify the thermoelectric properties of the understudy monolayers. The higher power factor of SMoSiN<sub>2</sub> and SeMoSiN<sub>2</sub> with compressional strain confirms that the thermoelectric efficiency of these materials can be affectively improved by applying strain. This work deepens the understanding of strain effects on Janus materials by providing detailed insights into their electronic, optical, and thermoelectric properties. These findings offer a foundation for designing next-generation materials with tailored properties for applications in thermoelectric devices, and optoelectronic technologies.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Ru-doped VO2 films fabricated by rapid thermal annealing of V–Ru co-sputtered alloy films with lowered phase transition temperature and narrowed hysteresis for smart windows 通过 V-Ru 共溅镀合金薄膜快速热退火制备的掺 Ru VO2 薄膜,相变温度降低,滞后变窄,可用于智能窗户
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-25 DOI: 10.1007/s00339-024-07962-1
Hongli Sun, He Liu, Chenming Dong, Chunbo Li, Wei Mi, Di Wang, Linan He, Liwei Zhou
{"title":"The Ru-doped VO2 films fabricated by rapid thermal annealing of V–Ru co-sputtered alloy films with lowered phase transition temperature and narrowed hysteresis for smart windows","authors":"Hongli Sun,&nbsp;He Liu,&nbsp;Chenming Dong,&nbsp;Chunbo Li,&nbsp;Wei Mi,&nbsp;Di Wang,&nbsp;Linan He,&nbsp;Liwei Zhou","doi":"10.1007/s00339-024-07962-1","DOIUrl":"10.1007/s00339-024-07962-1","url":null,"abstract":"<div><p>Vanadium dioxide (VO<sub>2</sub>), a current favorite in the field of smart windows as a thermochromic material, faces limitations in practical application due to its high phase transition temperature (<i>T</i><sub>t</sub>, ~ 68 ℃) and wide hysteresis curve (Δ<i>T</i>). In this study, Ru-doped VO<sub>2</sub> thin films with reduced <i>T</i><sub>t</sub> and narrower Δ<i>T</i> were prepared through co-sputtering tetravalent metal Ru and V using magnetron sputtering to form alloy thin films, followed by rapid thermal annealing. Compared with pure VO<sub>2</sub> thin films, at the Ru doping concentration of 4.98 at%, the <i>T</i><sub>t</sub> was lowered from 59.6 °C to 35.8 °C, and the Δ<i>T</i> was reduced from 10.5 °C to 2.8 °C, primarily due to the structural similarity between RuO<sub>2</sub> and rutile phase VO<sub>2</sub>, smaller grain size, and greater grain uniformity. The optical properties of Ru-doped VO<sub>2</sub> thin films had also been discussed, revealing only minor reductions in luminous transmittance (<i>T</i><sub>lum</sub>) and the solar modulation ability (Δ<i>T</i><sub>sol</sub>) when the <i>T</i><sub>t</sub> decreased to 35.8 °C. This methodology offers a viable path for applying VO<sub>2</sub> in smart windows, providing effective reductions in <i>T</i><sub>t</sub> and Δ<i>T</i> with minimal impact on optical performance.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, dielectric and magnetic characteristics of praseodymium doped Cobalt-Zinc spinel ferrites for communication and microwave frequency applications 用于通信和微波频率应用的掺镨钴锌尖晶铁氧体的结构、介电和磁特性
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-25 DOI: 10.1007/s00339-024-07985-8
Noor-ul-Haq Khan, Zaheer Abbas Gilani, Mubashra Abid,  Samiullah, Gulzar Hussain, Muhammad Khalid, H. M. Noor Huda Khan Asghar, Muhammad Zubair Nawaz, Syed Mansoor Ali, Muhammad Azhar Khan, Furhaj Ahmed Sheikh, Rajeh Alotaibi
{"title":"Structural, dielectric and magnetic characteristics of praseodymium doped Cobalt-Zinc spinel ferrites for communication and microwave frequency applications","authors":"Noor-ul-Haq Khan,&nbsp;Zaheer Abbas Gilani,&nbsp;Mubashra Abid,&nbsp; Samiullah,&nbsp;Gulzar Hussain,&nbsp;Muhammad Khalid,&nbsp;H. M. Noor Huda Khan Asghar,&nbsp;Muhammad Zubair Nawaz,&nbsp;Syed Mansoor Ali,&nbsp;Muhammad Azhar Khan,&nbsp;Furhaj Ahmed Sheikh,&nbsp;Rajeh Alotaibi","doi":"10.1007/s00339-024-07985-8","DOIUrl":"10.1007/s00339-024-07985-8","url":null,"abstract":"<div><p>In this study, the sol-gel auto-combustion (SGAC) approach was used to synthesis praseodymium (Pr<sup>3+</sup>) substituted Zinc-Cobalt (ZC) ferrites, having general formula Co<sub>0.7</sub>Zn<sub>0.3</sub>Pr<sub>x</sub>Fe<sub>2−x</sub>O<sub>4</sub> (x = 0.0, 0.05, 0.10, 0.15, and 0.20). X-ray Diffraction (XRD) analysis revealed a secondary phase (<i>PrFeO</i><sub><i>3</i></sub>) with a composition of x ≥ 0.10 and the presence of FCC structure. The crystallite size (D) of Pr<sup>3+</sup> doped ZC SFs decreased from 17.36 nm to 12.44 nm as the amount of Pr<sup>3+</sup> doping increased. Additionally, the lattice constant saw an enhancement from 8.34 a (Å) to 8.96 a (Å) with the incorporation of Pr<sup>3+</sup> into the ZC SFs. XRD and FTIR analysis verified the replacement of Pr<sup>3+</sup> into ZC SFs. Inhomogeneous grain size distribution was seen in samples by applying the Scanning Electron Microscopic (SEM) technique. It was discovered that the dielectric loss decreased with the applied frequency, which is helpful for high frequency device applications. The substitutions of Pr<sup>3+</sup> ions resulted in remanence (Mr (emu/g)), saturation magnetization (Ms (emu/g)) and coercivity (Hc (Oe)) maximum at x = 0.00 and minimum for x = 0.20 in ZC SFs, respectively. The maximum microwave frequency in GHz maximum for x = 0.00 (18.8 (GHz)) and minimum at sample x = 0.20 (7.86 (GHz)). According to the findings of our research, Pr<sup>3+</sup> substituted spinel ferrites appear to be very useful in radar, satellite communication, space communication, and microwave frequency applications.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biocompatible synthesis of MoS2/Ag nanocomposite for enhanced photocatalytic activity via surface plasmon effects 通过表面等离子体效应合成具有生物相容性的 MoS2/Ag 纳米复合材料以增强光催化活性
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-25 DOI: 10.1007/s00339-024-07964-z
M. Khoshab, P. Iranmanesh, S. Saeednia
{"title":"Biocompatible synthesis of MoS2/Ag nanocomposite for enhanced photocatalytic activity via surface plasmon effects","authors":"M. Khoshab,&nbsp;P. Iranmanesh,&nbsp;S. Saeednia","doi":"10.1007/s00339-024-07964-z","DOIUrl":"10.1007/s00339-024-07964-z","url":null,"abstract":"<div><p>In the current investigation, we synthesized a biocompatible MoS<sub>2</sub>/Ag nanocomposite by decorating a hollow-like MoS<sub>2</sub> nanostructure with silver (Ag) nanoparticles through a straightforward hydrothermal method. The structural and morphological characteristics of the synthesized photocatalysts were thoroughly analyzed using a variety of techniques, including Fourier Transform Infrared spectroscopy, X-Ray Diffraction, Field Emission Scanning Electron Microscopy, Transmission Electron Microscopy, Energy Dispersive X-ray Spectroscopy, Ultraviolet-Visible spectroscopy, Photoluminescence and Raman spectroscopy. XRD analysis confirmed that both MoS<sub>2</sub> and the MoS<sub>2</sub>/Ag nanocomposite crystallized in the expected crystalline phases. Notably, PL spectra indicated a reduction in peak intensity for the MoS<sub>2</sub>/Ag nanocomposite compared to pure MoS<sub>2</sub>, attributed to the surface plasmon resonance effects of the Ag nanoparticles. The incorporation of Ag nanoparticles into the MoS<sub>2</sub> matrix significantly mitigated the recombination rate of charge carriers, functioning effectively as an electron sink. Furthermore, we evaluated the photocatalytic performance of the MoS<sub>2</sub>/Ag nanocomposite in the degradation of methylene blue and methyl orange dyes under UV and visible light irradiation. The results demonstrated a marked enhancement in photocatalytic efficiency for the MoS<sub>2</sub>/Ag nanocomposite, which can be ascribed to the suppression of photogenerated electron-hole pair recombination and the improved electron transport dynamics within the composite structure. This study highlights the potential of MoS<sub>2</sub>/Ag nanocomposites as effective photocatalysts for environmental remediation applications.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, electrical, and mechanical properties of nano-SiC added MgB2 wire manufactured by cold working process: a comprehensive study 冷加工工艺制造的纳米碳化硅添加 MgB2 金属丝的结构、电气和机械性能:综合研究
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-25 DOI: 10.1007/s00339-024-07994-7
Sigit Dwi Yudanto, Septian Adi Chandra, Muhammad Yunan Hasbi, Rahadian Roberto, Dedi Irawan, Sausan Kanaya Narendra Rosoningtyas, Budhy Kurniawan, Ferry Budhi Susetyo, Lalu Suhaimi
{"title":"Structural, electrical, and mechanical properties of nano-SiC added MgB2 wire manufactured by cold working process: a comprehensive study","authors":"Sigit Dwi Yudanto,&nbsp;Septian Adi Chandra,&nbsp;Muhammad Yunan Hasbi,&nbsp;Rahadian Roberto,&nbsp;Dedi Irawan,&nbsp;Sausan Kanaya Narendra Rosoningtyas,&nbsp;Budhy Kurniawan,&nbsp;Ferry Budhi Susetyo,&nbsp;Lalu Suhaimi","doi":"10.1007/s00339-024-07994-7","DOIUrl":"10.1007/s00339-024-07994-7","url":null,"abstract":"<div><p>Magnetic Resonance Imaging (MRI) is a medical device that relies on magnetic fields generated by superconducting wires to detect brain tumors. To generate magnetic fields, the medical device employs Niobium-based superconductor. This superconductor has several disadvantages, such as low critical temperature, limited raw material resources, and expensive raw material prices. Magnesium diboride (MgB<sub>2</sub>) has a critical temperature of 39 K, allowing it to be a suitable replacement for Niobium-based superconductors. In this research, a comprehensive analysis was conducted on the effect of adding nano-SiC on the structure and electrical transport properties of MgB<sub>2</sub> superconducting wire. An investigation into the mechanical properties of the wire sheath was also done to determine if the wire can proceed to the next process. Using the Powder in Tube (PIT) method, followed by a cold deformation scheme, MgB<sub>2</sub>-based monofilament wire was manufactured. The findings of the X-Ray Diffraction (XRD) test confirm that the lattice constant <b>-a</b> of the MgB<sub>2</sub> hexagonal phase decreases with increasing nano-SiC content addition. This lattice distortion causes the critical temperature of the MgB<sub>2</sub> superconducting phase to drop from 37.99 K to 36.94 K. The addition of 5 wt% nano-SiC at 290 K causes the material to become more insulating, as evidenced by an increase in resistivity value from 256.18 µΩ.cm to 411.61 µΩ.cm. The mechanical characteristics of sheath demonstrate recovery following a cold reduction of around 56.25% and subsequent heating at 1073 K. The ultimate tensile strength and average hardness value are 585 MPa and 215.30 HV, respectively.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Exploration of physical, structural, thermal, and optical properties of alkali zinc boro tellurite glasses doped with europium trioxide 更正:掺杂三氧化二铕的碱锌硼碲玻璃的物理、结构、热和光学特性探索
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-24 DOI: 10.1007/s00339-024-07988-5
G. V. Jagadeesha Gowda, Utpal Deka, A. Dahshan, G. V. Ashok Reddy, B. Eraiah, R. S. Gedam, K. Keshavamurthy, C. Devaraja
{"title":"Correction: Exploration of physical, structural, thermal, and optical properties of alkali zinc boro tellurite glasses doped with europium trioxide","authors":"G. V. Jagadeesha Gowda,&nbsp;Utpal Deka,&nbsp;A. Dahshan,&nbsp;G. V. Ashok Reddy,&nbsp;B. Eraiah,&nbsp;R. S. Gedam,&nbsp;K. Keshavamurthy,&nbsp;C. Devaraja","doi":"10.1007/s00339-024-07988-5","DOIUrl":"10.1007/s00339-024-07988-5","url":null,"abstract":"","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-024-07988-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the impact of Gd3+ ion substitution in Sr2FeTiO6: insights into magnetic, electrical, and structural properties 研究 Sr2FeTiO6 中 Gd3+ 离子替代的影响:对磁性、电性和结构特性的见解
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-24 DOI: 10.1007/s00339-024-08012-6
J. Stella Punitha, Ramesh Kumar Raji, K. Saravana Kumar, Tholkappiyan Ramachandran, Fathalla Hamed, A. Nataraj
{"title":"Investigating the impact of Gd3+ ion substitution in Sr2FeTiO6: insights into magnetic, electrical, and structural properties","authors":"J. Stella Punitha,&nbsp;Ramesh Kumar Raji,&nbsp;K. Saravana Kumar,&nbsp;Tholkappiyan Ramachandran,&nbsp;Fathalla Hamed,&nbsp;A. Nataraj","doi":"10.1007/s00339-024-08012-6","DOIUrl":"10.1007/s00339-024-08012-6","url":null,"abstract":"<div><p>In the present investigations, Gd<sup>3+</sup> ions were substituted at the Sr<sup>2+</sup> site through conventional solid state reaction technique. The influence of Gd<sup>3+</sup> ion substitution on the physical attributes of Sr<sub>2</sub>FeTiO<sub>6</sub> (SFTO) was meticulously examined. The basic structure of Sr<sub>2 − x</sub>Gd<sub>x</sub>FeTiO<sub>6</sub> (SGFTO) (x = 0.2 to 0.8), was employed to start the Rietveld structural refinement of the powder X-ray diffraction patterns. This process confirmed the presence of a cubic structure with a space group of <i>Pm3m</i>. The replacement of Gd<sup>3+</sup> ions, noted for their larger ionic radii, led to a minor increase in the lattice parameters and the volume of the unit cell. The identity of the elements within the compound was determined by examining their oxidation states through X-ray photoelectron spectroscopy. The SEM images reveal that as Gd content increases in the SGFTO samples, the structure becomes denser and more agglomerated, with reduced porosity and less uniform particle sizes. This suggests that higher Gd content leads to a more compact morphology, potentially impacting the material’s electrochemical performance and mechanical stability. The use of diffuse reflectance measurements confirmed that the band gap values decreased slightly from 2.95 eV to 2.24 eV for the Sr<sub>2 − x</sub>Gd<sub>x</sub>FeTiO<sub>6</sub> (x = 0.2–0.8) materials, indicating that these synthesized samples exhibit semiconductor nature. The study investigated how often the dielectric constant and its behavior change with temperature, and these measurements proved that as the amount of Gd<sup>3+</sup> in the material increased from 0.2 to 0.8, the dielectric constant also increases. The research on magnetization showed that the prepared materials had a stronger magnetic property and displayed a antiferromagnetic behavior. All synthesized materials made in this way has the possibility to be used in today’s electronic devices, magneto-optical storage devices, and magneto-dielectric technologies.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"130 11","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of ozone gas exposure on drain current of solution-processed IGZO-TFT 臭氧气体暴露对溶液处理 IGZO-TFT 漏极电流的影响
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2024-10-24 DOI: 10.1007/s00339-024-07958-x
Hiroharu Sasajima, Takaaki Morimoto, Nobuko Fukuda, Keisuke Ishii
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